SAFETY DATA SHEET. 1. Identification. 2. Hazard(s) identification. Version: 7.0 Revision Date: 05/12/2015. Product identifier: BLUESIL VICURE 2

Transcription

1 SAFETY DATA SHEET 1. Identification Product identifier: BLUESIL VICURE 2 Other means of identification Synonyms: RHODORSIL VICURE 2 Recommended use and restriction on use Recommended use: Catalyst Restrictions on use: None known. Manufacturer/Importer/Supplier/Distributor Information Supplier Company Name: Bluestar Silicones USA Corp. Address: Two Tower Blvd, Suite East Brunswick, NJ Telephone: +1 (732) Fax: +1 (732) Emergency telephone number: +1 (800) CHEMTREC 2. Hazard(s) identification Hazard Classification Health Hazards Serious Eye Damage/Eye Irritation Category 1 Skin sensitizer Category 1 Toxic to reproduction Category 2 Environmental Hazards Acute hazards to the aquatic environment Chronic hazards to the aquatic environment Label Elements Hazard Symbol: Category 3 Category 3 Signal Word: Hazard Statement: Danger May cause an allergic skin reaction. Causes serious eye damage. Suspected of damaging fertility or the unborn child. Harmful to aquatic life with long lasting effects. SDS_US 1/11

2 Precautionary Statement Prevention: Response: Storage: Disposal: Wear protective gloves/protective clothing/eye protection/face protection. Avoid release to the environment. IF ON SKIN: Wash with plenty of soap and water. IF IN EYES: Rinse cautiously with water for several minutes. Get immediate medical advice/attention. Store in a well-ventilated place. Dispose of contents/container to an appropriate treatment and disposal facility in accordance with applicable laws and regulations, and product characteristics at time of disposal. Other hazards which do not result in GHS classification: 3. Composition/information on ingredients Mixtures Chemical Identity Common name and synonyms CAS number Content in percent (%)* Hexanoic acid, 2-ethyl-, tin(2+) METATIN S-26, % salt (2:1) ACIDE 2- ETHYLHEXANOIQU E, % * All concentrations are percent by weight unless ingredient is a gas. Gas concentrations are in percent by volume. Composition Comments: Silicone curing agent 4. First-aid measures General information: Ingestion: Inhalation: Skin Contact: Eye contact: For further information refer to section 8 "Exposure-controls/personal protection". Do not induce vomiting. Rinse mouth thoroughly. Get medical attention immediately. Move to fresh air. If breathing is difficult, give oxygen. If breathing stops, provide artificial respiration. Get medical attention if any discomfort continues. Immediately flush with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Get medical attention if symptoms occur. Wash contaminated clothing before reuse. Destroy or thoroughly clean contaminated shoes. Immediately rinse with water. Continue to rinse for at least 15 minutes. Get medical attention immediately. Most important symptoms/effects, acute and delayed Symptoms: None known. SDS_US 2/11

3 Hazards: No specific recommendations. Indication of immediate medical attention and special treatment needed Treatment: No specific recommendations. 5. Fire-fighting measures General Fire Hazards: No specific recommendations. Suitable (and unsuitable) extinguishing media Suitable extinguishing media: Unsuitable extinguishing media: Specific hazards arising from the chemical: Dry chemical, alcohol resistant foam or carbon dioxide (CO2). None known. Hazardous Decomposition Products : oxides of carbon and tin. Special protective equipment and precautions for firefighters Special fire fighting procedures: Special protective equipment for fire-fighters: Water spray should be used to cool containers. Firefighters should wear NIOSH/MSHA approved self-contained breathing apparatus and full protective clothing. 6. Accidental release measures Personal precautions, protective equipment and emergency procedures: Methods and material for containment and cleaning up: Notification Procedures: Environmental Precautions: Use personal protective equipment. See Section 8 of the MSDS for Personal Protective Equipment. Absorb with inert material. Scrape up and place in appropriate closed container see Section 7 of the MSDS. For waste disposal, see section 13 of the MSDS. Do not allow to enter drains, sewers or watercourses. 7. Handling and storage Precautions for safe handling: Conditions for safe storage, including any incompatibilities: Provide adequate ventilation if fumes or vapors are generated. See Section 8 of the MSDS for Personal Protective Equipment. For further information, refer to Section 10: "Stability and Reactivity". Store in tightly closed original container in a dry, cool and well-ventilated place. Protect against direct sunlight. 8. Exposure controls/personal protection Control Parameters SDS_US 3/11

4 Occupational Exposure Limits Chemical Identity Type Exposure Limit Values Source Hexanoic acid, 2-ethyl-, tin(2+) salt (2:1) - as Sn Hexanoic acid, 2-ethyl-, tin(2+) salt (2:1) Hexanoic acid, 2-ethyl-, tin(2+) salt (2:1) - as Sn TWA 2 mg/m3 US. ACGIH Threshold Limit Values ( ) TWA 0.1 mg/m3 US. ACGIH Threshold Limit Values ( ) STEL 0.2 mg/m3 US. ACGIH Threshold Limit Values ( ) REL 0.1 mg/m3 US. NIOSH: Pocket Guide to Chemical Hazards (2005) REL 2 mg/m3 US. NIOSH: Pocket Guide to Chemical Hazards (2005) PEL 2 mg/m3 US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR ) ( ) PEL 0.1 mg/m3 US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR ) ( ) TWA 2 mg/m3 US. OSHA Table Z-1-A (29 CFR ) (1989) TWA 0.1 mg/m3 US. OSHA Table Z-1-A (29 CFR ) (1989) TWA 2 mg/m3 US. Tennessee. OELs. Occupational Exposure Limits, Table Z1A ( ) TWA 0.1 mg/m3 US. Tennessee. OELs. Occupational Exposure Limits, Table Z1A ( ) AN ESL 0.1 µg/m3 US. Texas. Effects Screening Levels (Texas Commission on Environmental Quality) ( ) ST ESL 1 µg/m3 US. Texas. Effects Screening Levels (Texas Commission on Environmental Quality) ( ) TWA PEL 0.1 mg/m3 US. California Code of Regulations, Title 8, Section Airborne Contaminants ( ) STEL 0.2 mg/m3 US. California Code of Regulations, Title 8, Section Airborne Contaminants ( ) TWA 5 mg/m3 US. ACGIH Threshold Limit Values ( ) - Inhalable fraction and vapor. ST ESL 250 µg/m3 US. Texas. Effects Screening Levels (Texas Commission on Environmental Quality) ( ) AN ESL 25 µg/m3 US. Texas. Effects Screening Levels (Texas Commission on Environmental Quality) ( ) Appropriate Engineering Controls Adequate ventilation should be provided so that exposure limits are not exceeded. Individual protection measures, such as personal protective equipment General information: Eye/face protection: Skin Protection Hand Protection: Other: Respiratory Protection: Hygiene measures: Observe occupational exposure limits and minimize the risk of inhalation of vapors and mist. Wear approved chemical safety glasses with side shields or goggles. Protective gloves are recommended. Wear appropriate clothing to prevent any possibility of skin contact. If ventilation is insufficient, suitable respiratory protection must be provided. Use a NIOSH/MSHA approved respirator if there is a risk of exposure to fumes at levels exceeding the exposure limits. Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. SDS_US 4/11

5 9. Physical and chemical properties 9.1 Information on basic physical and chemical properties: Appearance Physical state: Form: Color: Odor: Odor threshold: ph: Melting point/freezing point: International Inventories: Flash Point: Evaporation rate: Flammability (solid, gas): Flammability limit - upper (%): Flammability limit - lower (%): Vapor pressure: Vapor density: Relative density: Solubility(ies) Solubility in water: Solubility (other): Partition coefficient (n-octanol/water): Auto-ignition temperature: Decomposition temperature: Viscosity: Liquid Mobile. Dark yellow Characteristic Not applicable < -13 F (-25 C) > 392 F (200 C) > 288 F (142 C) (Pensky-Martens Closed Cup) (77 F (25 C)) Insoluble in water Approximate 250 mm2/s (68 F (20 C)) 10. Stability and reactivity Reactivity: Chemical Stability: Possibility of Hazardous Reactions: Conditions to Avoid: Incompatible Materials: Hazardous Decomposition Products: Stable Will not occur. Protect against direct sunlight. Strong oxidizers, strong acids, and strong bases. Thermal decomposition may liberate oxides of carbon and tin. 11. Toxicological information Information on likely routes of exposure Ingestion: Inhalation: SDS_US 5/11

6 Skin Contact: Eye contact: Symptoms related to the physical, chemical and toxicological characteristics Ingestion: Inhalation: Skin Contact: Eye contact: Information on toxicological effects Acute toxicity (list all possible routes of exposure) Oral Dermal Inhalation ATEmix: 3,640 mg/kg ATEmix: 2,000 mg/kg Repeated Dose Toxicity Skin Corrosion/Irritation Serious Eye Damage/Eye Irritation Respiratory or Skin Sensitization Carcinogenicity IARC Monographs on the Evaluation of Carcinogenic Risks to Humans: No carcinogenic components identified US. National Toxicology Program (NTP) Report on Carcinogens: No carcinogenic components identified US. OSHA Specifically Regulated Substances (29 CFR ): No carcinogenic components identified SDS_US 6/11

7 Germ Cell Mutagenicity In vitro In vivo Bacteria: No mutagenic components identified Reproductive Toxicity Specific Target Organ Toxicity - Single Exposure Specific Target Organ Toxicity - Repeated Exposure Aspiration Hazard Other Effects: 12. Ecological information Ecotoxicity: Acute hazards to the aquatic environment: Fish Aquatic Invertebrates LC 50 (Atlantic Salmon, 96 h): 180 mg/l LC 50 (Common Carp, 48 h): > 302 mg/l EC 50 (Water flea (Daphnia magna), 48 h): mg/l Chronic hazards to the aquatic environment: Fish Aquatic Invertebrates NOEC (Water flea (Daphnia magna), 21 d): 25 mg/l SDS_US 7/11

8 Toxicity to Aquatic Plants EC 50 (Alga, 72 h): 49.3 mg/l Persistence and Degradability Biodegradation BOD/COD Ratio % (28 d) The product is easily biodegradable % (6 d) Bioaccumulative Potential Bioconcentration Factor (BCF) Partition Coefficient n-octanol / water (log Kow) Log Kow: 2.64 Mobility in Soil: Known or predicted distribution to environmental compartments Other Adverse Effects: 13. Disposal considerations Disposal instructions: Dispose of waste at an appropriate treatment and disposal facility in accordance with applicable laws and regulations, and product characteristics at time of disposal. 14. Transport information This material is not subject to transport regulations. Environmental hazards: Special precautions for user: Not regulated. No special precautions. 15. Regulatory information US Federal Regulations SDS_US 8/11

9 TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D) CERCLA Hazardous Substance List (40 CFR 302.4): Superfund Amendments and Reauthorization Act of 1986 (SARA) Hazard categories X Acute (Immediate) X Chronic (Delayed) Fire Reactive Pressure Generating SARA 302 Extremely Hazardous Substance SARA 304 Emergency Release Notification SARA 313 (TRI Reporting) Clean Water Act Section 311 Hazardous Substances (40 CFR 117.3) Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR ): US State Regulations US. California Proposition 65 This product contains chemical(s) known to the State of California to cause cancer and/or to cause birth defects or other reproductive harm. Developmental toxin. US. New Jersey Worker and Community Right-to-Know Act Chemical Identity Hexanoic acid, 2-ethyl-, tin(2+) salt (2:1) US. Massachusetts RTK - Substance List No ingredient regulated by MA Right-to-Know Law present. US. Pennsylvania RTK - Hazardous Substances No ingredient regulated by PA Right-to-Know Law present. US. Rhode Island RTK No ingredient regulated by RI Right-to-Know Law present. SDS_US 9/11

10 Inventory Status: Australia AICS: Canada DSL Inventory List: EU EINECS List: Japan (ENCS) List: China Inv. Existing Chemical Substances: Korea Existing Chemicals Inv. (KECI): Philippines PICCS: US TSCA Inventory: New Zealand Inventory of Chemicals: 16.Other information, including date of preparation or last revision HMIS Hazard ID Health * 2 H - Goggles, Gloves, Apron & Vapor Respirator Flammability 1 Physical Hazards 0 PERSONAL PROTECTION H Hazard rating: 0 - Minimal; 1 - Slight; 2 - Moderate; 3 - Serious; 4 - Severe; *Chronic health effect NFPA Hazard ID 2 Flammability Health Reactivity Special hazard. Hazard rating: 0 - Minimal; 1 - Slight; 2 - Moderate; 3 - Serious; 4 - Severe 1 0 Issue Date: 05/12/2015 Revision Date: Version #: 7.0 SDS_US 10/11

11 Further Information: Disclaimer: The information given is based on data available for the material, the components of the material, and similar materials. The information is believed to be correct. It is given in good faith. This information should be used to make an independent determination of the methods to safeguard workers and the environment. SDS_US 11/11