9/4/2013. Training for all employees on the Haz Com Program. Manufacturer Labels on every chemical container

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1 Employee s Right to Know Known as the Right to Know Law. Worker s safety can be compromised through the improper handling of chemicals, which can result in injury or death due to fire, explosion or other serious accidents. Hazard Communication determines the dangers of the chemicals you use on the job, tells you what these hazards are and how to protect yourself from them. Hazardous chemical Any chemical which is classified as a physical hazard or a health hazard, a simple asphyxiant, combustible dust, pyrophoric gas, a hazard not otherwise classified, or is included in the List of Hazardous Substances prepared by the Director pursuant to Labor Code section A chemical is considered hazardous to a person and/or the environment whenever an exposure to the chemical can produce a negative response; (e.g., nausea, vomiting, rash, eye or throat irritation.) Most chemical hazards on school sites are minimal, if they are used according to the directions on their label and SDS and with the listed appropriate protective equipment. Training for all employees on the Haz Com Program Manufacturer Labels on every chemical container Safety Data Sheets (SDS) for every chemical kept near the chemical use area 1

2 Name, Address and Telephone Number of the chemical manufacturer, importer or other responsible party Product Identifier how the hazardous chemical is identified. This can be (but is not limited to) the chemical name, code number or batch number. The manufacturer, importer or distributor can decide the appropriate product identifier. The same product identifier must be both on the label and in section 1 of the SDS Signal Words Used to indicate the relative level of severity of the hazard and alert the reader to a potential hazard on the label. There are only two words used as signal words, Danger and Warning Warning. Within a specific hazard class, Danger is used for the more severe hazards and Warning is used for the less severe hazards. There will only be one signal word on the label no matter how many hazards a chemical may have. If one of the hazards warrants a Danger signal word and another warrants the signal word Warning, then only Danger should appear on the label. Hazard Statements: Describe the nature of the hazard(s) of a chemical, including, where appropriate, the degree of hazard. For example: Causes damage to kidneys through prolonged or repeated exposure when absorbed through the skin. All of the applicable hazard statements must appear on the label. Hazard statements may be combined where appropriate to reduce redundancies and improve readability. The hazard statements are specific to the hazard classification categories, and chemical users should always see the same statement for the same hazards no matter what the chemical is or who produces it. Precautionary Statements: Describe recommended measures that should be taken to minimize or prevent adverse effects resulting from exposure to the hazardous chemical or improper storage or handling. There are four types of precautionary statements: Prevention (to minimize exposure) Response (in case of accidental spillage or exposure emergency response, and first aid); Storage Disposal 2

3 Pictograms: Pictograms: Pictograms: Safety data sheet (SDS) Written or printed material concerning a hazardous chemical that is prepared in accordance with section 5914(g). The SDS includes information such as: the properties of each chemical the physical, health, and environmental health hazards protective measures safety precautions for handling, storing, and transporting the chemical The information contained in the SDS must be in English (although it may be in other languages as well). Sections 1 through 8 contain general information about the chemical, identification, hazards, composition, safe handling practices, and emergency control measures (e.g., fire fighting). This information should be helpful to those that need to get the information quickly. 3

4 Section 1, Identification includes product identifier; manufacturer or distributor name, address, phone number; emergency phone number; recommended use; restrictions on use. Section 2, Hazard(s) identification includes all hazards regarding the chemical; required label elements. Section 3, Composition/information on ingredients includes information on chemical ingredients; trade secret claims. Section 4, First aid measures includes important symptoms/effects, acute, delayed; required treatment. Section 5, Fire fighting measures lists suitable extinguishing techniques, equipment; chemical hazards from fire. Section 6, Accidental release measures lists emergency procedures; protective equipment; proper methods of containment and cleanup. Section 7, Handling and storage lists precautions for safe handling and storage, including incompatibilities. Section 8, Exposure controls/personal protection lists. OSHA s Permissible Exposure Limits (PELs); Threshold Limit Values (TLVs); appropriate engineering controls; personal protective equipment (PPE). Sections 9 through 11 and 16 contain other technical and scientific information, such as physical and chemical properties, stability and reactivity information, toxicological information, exposure control information, and other information including the date of preparation or last revision. The SDS must also state that no applicable information was found when the preparer does not find relevant information for any required element. 4

5 Ignitable Corrosive Reactive Toxic EASILY COMBUSTIBLE OR FLAMMABLE MOST COMMON HAZARD CLASS CAN BE GAS, LIQUID, OR SOLID Ignitables CORROSIVE ACIDS = ph 0, 1, and 2 CORROSIVE BASES = ph 12, 13, and 14 UPON CONTACT WILL CAUSE IMMEDIATE DAMAGE TO EYES OR SKIN WILL GENERATE HEAT DUE TO CHEMICAL REACTION WILL CORRODE STEEL Corrosive Reactive NORMALLY UNSTABLE READILY UNDERGOES VIOLENT CHANGE GENERATES TOXIC GASES, VAPORS, OR FUMES WHEN MIXED WITH WATER REACTS VIOLENTLY WITH WATER 5

6 Toxic POSES A HAZARD TO HUMAN HEALTH OR ENVIRONMENT THROUGH: CARCINOGENITY ACUTE (IMMEDIATE) TOXICITY CHRONIC (DELAYED FROM REPEATED EXPOSURE) TOXICITY BIOACCUMULATIVE (PERSISTENCE IN THE ENVIRONMENT) TWO SYSTEMS: NFPA NATIONAL FIRE PROTECTION ASSOCIATION O HMIS HAZARDOUS MATERIAL IDENTIFICATION SYSTEM FIVE NFPA HAZARD LEVELS 4 EXTREME 3 HIGH 2 MODERATE REACTIVITY 1 SLIGHT 0 INSIGNIFICANT W SPECIFIC HAZARD (WATER REACTIVE) Materials that on short exposure could cause serious temporary or residual injury even though prompt medical treatment was given. 2 Materials that on intense or continued exposure could 4 Materials that on very short exposure could cause death or major residual injury even though prompt medical treatment was given. cause temporary incapacitation or possible residual injury unless prompt medical treatment was given. 1 Materials that on exposure would cause irritation but only minor residual injury even if no treatment was given. 0 Materials that on exposure under fire conditions would offer no hazard beyond that of ordinary combustible material. 4 Materials that will rapidly or completely vaporize at atmospheric pressure and normal ambient temperature, or that are readily dispersed in air, and will burn readily. 3 Liquids and solids that can be ignited under almost all ambient temperature conditions. 2 Materials that must be moderately heated or exposed to relatively high ambient temperatures before ignition can occur. 1 Materials that must be preheated before ignition can occur. 0 Materials that will not burn Materials that in themselves are readily capable of detonation or of explosive decomposition or reaction at normal temperatures and pressures. 3 Materials that in themselves are capable of detonation or explosive reaction but require a strong initiating source or that must be heated under confinement before initiation or that react explosively with water. 2 Materials that in themselves are normally unstable and readily undergo violent chemical change but do not detonate. 1 Materials that in themselves are normally stable, but which can become unstable at elevated temperatures and pressures or which may react with water with some release of energy but not violently. 0 Materials that in themselves are normally stable, even under fire exposure condition, and which are not reactive with water. 6

7 RADIOACTIVE FIVE HMIS HAZARD LEVELS COR OXY W CORROSIVE OXIDIZER WATER REACTIVE 4 SEVERE 3 SERIOUS 2 MODERATE 1 SLIGHT 0 MINIMAL Sulfuric Acid Health 2 Flammability 0 Reactivity 1 Personal Protection C Hazardous Chemicals can be inhaled, ingested, or absorbed through the skin. When using Hazardous Chemicals, you are required to use the appropriate PPE as prescribed on the label and the SDS Make sure the PPE fits and is not torn or broken All Hazardous Chemicals must be properly stored according to the Hazard Communication Program 7

8 What do you do if you need materials (chemicals, paint, toners, etc.) removed from your site? Develop an inventory of materials for disposal Indicate how much material needs to be removed Identify where the material is located on site Include the name and phone number of a contact person on site inventory to Risk Management: Contact Vanessa Sibley vsibley@egusd.net The vendor will: come out to the site and may conduct an additional inventory, package and remove materials to be disposed. leave empty replacement receptacle when making a pick up. Even though biology waste is not considered hazardous waste, the same procedures are followed for disposing of biology waste as for hazardous waste. How much chemical can you keep on site before it has to be reported to the County Office of Environmental Management? How long can you accumulate used chemicals on site before you have to dispose of them? How should chemicals be labeled and handled? You must disclose all hazardous materials and hazardous wastes at or above these threshold reportable quantities: 55 gallons of liquid (this includes custodial supplies) 500 lbs. of a solid 200 cubic feet (at standard temperature and pressure) of a compressed gas Containers Must Be: Properly labeled Inspected weekly for leaks, spills and deterioration Suitable for storing the waste and compatible with the contents Empty containers >5 gallons which previously held a hazardous material or waste must be labeled empty with the date they were emptied and recycled, reused or returned to the vendor within 1 year In good condition Kept closed when not in use Located 50 feet from the property line if holding ignitable or reactive wastes Grounded if holding flammable waste Reactive wastes must be stored separately or be separated by a dike, berm, wall or other barrier Label must include: The words Hazardous Waste Wording such as Federal law prohibit improper disposal. If found, contact the nearest police or public safety authority or the U.S. Environmental Protection Agency or the California Department of Toxic Control The initial date of accumulation The composition (name of the waste) and physical state (gas, liquid, solid, sludge). A description of the hazardous properties of the waste (flammable, reactive, etc.) The name, address, and EPA ID number of the generator Example of an acceptable Hazardous Waste label: 8

9 Accumulation Limits: EGUSD sites are Small Quantity Generators, so each site may not dispose of more than 270 gallons of waste per month. Sites may not store hazardous waste for more than 180 days from the first day of accumulation. Storage: Only chemicals that are used are stored (chemicals not needed are to be disposed of). Chemicals on hand will be consumed essentially within the next year. Chemicals are properly labeled and stored in appropriate containers. SDS is on file for each chemical received and made accessible for review. There is a continual up to date inventory of all chemicals. No chemicals are stored above eye level. No chemicals are stored on the floor. Shelves or cabinets are secured firmly to the walls. Earthquake lips or barriers are in place on storage shelves. A storage cabinet for flammables is on site and is appropriately used Compressed gas cylinders are secured upright to the wall, with caps in place. What is a HMP (Hazardous Materials Plan)? When is an HMP required? If you need one, what do you do to get one? What is the purpose for the forms? Who submits what? After you complete one, what s the next step? HMP: A management plan for hazardous materials, hazardous wastes and underground storage tanks having these required components: Type of business activity Owner/operator identification Hazardous Material Chemical Inventory Form Site map Contingency Plan for emergencies Inventories should be conducted at the end of each school year. The inventory will generate a disposal list and determine the quantity of the chemicals to be retained or ordered for the coming year. Remember to look everywhere. Examine all areas in each room including desks, drawers, closets, under the sink, and storage cabinets. A chemical cleanout addresses immediate threats, as well as unneeded and outdated chemicals to prevent accidents before they happen. Conducting a chemical cleanout that includes proper disposal is an important step to creating a safer schools that protects the health and safety of students and staff. 9

10 Call Resist the urge to rush in: others cannot be helped until the situation has been fully assessed Assess the situation: What actions should be taken Is an evacuation necessary What can be done immediately Understand the potential hazards Secure the scene: Without entering the immediate hazard area, isolate the area Assure the safety of people and the environment Keep people away from the scene and outside the safety perimeter NOTIFY SUPERVISOR Be prepared to administer First Aid Know the risks of chemicals and have neutralizing solutions available Have supplies ready and available in case of a small spill or leak. Appropriate materials may be: Absorbent 5 gallon container, with lid Broom and dustpan PPE 10

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