Issue Date: 31-Mar-2015 Revision Date: 23-Mar-2016 Version 1 1. IDENTIFICATION. Water based carpet spotter. 2. HAZARDS IDENTIFICATION

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1 Safety Data Sheet Issue Date: 31-Mar-2015 Version 1 1. IDENTIFICATION Product Identifier Product Name Other means of identification SDS # Buckeye Eco E51 BE-6051 Product Code 6051 Recommended use of the chemical and restrictions on use Recommended Use Water based carpet spotter. Details of the supplier of the safety data sheet Supplier Address Buckeye International, Inc Wagner Place Maryland Heights, MO USA Emergency Telephone Number Company Phone Number Hr Medical Emergency Phone: Emergency Telephone (24 hr) INFOTRAC (International) (North America) 2. HAZARDS IDENTIFICATION Appearance Clear liquid Physical State Liquid Odor Fresh and clean fragrance Classification Skin corrosion/irritation Category 2 Serious eye damage/eye irritation Category 1 Signal Word Danger Hazard Statements Causes skin irritation Causes serious eye damage Page 1 / 7

2 Precautionary Statements - Prevention Wash face, hands and any exposed skin thoroughly after handling Wear protective gloves/protective clothing/eye protection/face protection Precautionary Statements - Response IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing Immediately call a poison center or doctor/physician IF ON SKIN: Wash with plenty of soap and water Take off contaminated clothing and wash it before reuse If skin irritation occurs: Get medical advice/attention Other Hazards Toxic to aquatic life with long lasting effects 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name CAS No Weight-% <5 Proprietary Fragrance PROPRIETARY <1 <1 **If Chemical Name/CAS No is "proprietary" and/or Weight-% is listed as a range, the specific chemical identity and/or percentage of composition has been withheld as a trade secret.** First Aid Measures 4. FIRST-AID MEASURES Eye Contact Skin Contact Inhalation Ingestion Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a poison center or doctor/physician. Wash with plenty of soap and water. Take off contaminated clothing and wash it before reuse. If skin irritation occurs: Get medical advice/attention. Remove to fresh air. Give two large glasses of water. Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Get medical attention. Most important symptoms and effects Symptoms Causes skin irritation. Causes serious eye damage. May cause an allergic skin reaction. Indication of any immediate medical attention and special treatment needed Notes to Physician Treat symptomatically. 5. FIRE-FIGHTING MEASURES Suitable Extinguishing Media Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Unsuitable Extinguishing Media. Specific Hazards Arising from the Chemical. Hazardous Combustion Products Oxides of carbon. Oxides of nitrogen. Page 2 / 7

3 Protective equipment and precautions for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal Precautions Use personal protective equipment as required. Methods and material for containment and cleaning up Methods for Containment Methods for Clean-Up Prevent further leakage or spillage if safe to do so. Pick up with mop, wet/dry vac, or absorbent material. Rinse area with clean water and dry before permitting traffic. 7. HANDLING AND STORAGE Precautions for safe handling Advice on Safe Handling Handle in accordance with good industrial hygiene and safety practice. Wash face, hands, and any exposed skin thoroughly after handling. Wear protective gloves/protective clothing and eye/face protection. Conditions for safe storage, including any incompatibilities Storage Conditions Incompatible Materials Keep container closed when not in use. Store at room temperature. Do not mix with chlorinated detergents (bleach). 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Exposure Guidelines Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH TWA: 1 ppm Appropriate engineering controls TWA: 1 ppm TWA: 1.4 mg/m 3 (vacated) TWA: 1 ppm (vacated) TWA: 1.4 mg/m 3 IDLH: 75 ppm TWA: 1 ppm TWA: 1.4 mg/m 3 Engineering Controls Maintain adequate ventilation. Individual protection measures, such as personal protective equipment Eye/Face Protection Skin and Body Protection Respiratory Protection Use splash goggles and face shield when eye contact may occur. Wear gloves made of rubber or other impervious material. Normal clothing which covers skin. Wearing of water resistant footwear is suggested. None required. General Hygiene Considerations Wash thoroughly with soap and water after handling. Page 3 / 7

4 Information on basic physical and chemical properties 9. PHYSICAL AND CHEMICAL PROPERTIES Physical State Liquid Appearance Clear liquid Odor Fresh and clean fragrance Color Clear Odor Threshold Property Values Remarks Method ph (Conc.) 4.3 ± 0.2 Melting Point/Freezing Point Boiling Point/Boiling Range 100 C / 212 F Flash Point None Evaporation Rate 1.0 (Water = 1) Flammability (Solid, Gas) Liquid-Not applicable Upper Flammability Limits Not available Lower Flammability Limit Not available Vapor Pressure Vapor Density Specific Gravity Water Solubility Infinite Solubility in other solvents Partition Coefficient Auto-ignition Temperature Decomposition Temperature Kinematic Viscosity Dynamic Viscosity Explosive Properties Oxidizing Properties Density gr/ml Reactivity Not reactive under normal conditions. Chemical Stability Stable under recommended storage conditions. Possibility of Hazardous Reactions None under normal processing. 10. STABILITY AND REACTIVITY Hazardous Polymerization Under normal conditions of storage and use, hazardous polymerization will not occur. Conditions to Avoid Incompatible Materials. Incompatible Materials Do not mix with chlorinated detergents (bleach). Hazardous Decomposition Products Oxides of carbon. Oxides of nitrogen. Information on likely routes of exposure Product Information 11. TOXICOLOGICAL INFORMATION Page 4 / 7

5 Eye Contact Causes serious eye damage. Skin Contact Inhalation Ingestion Causes skin irritation. Do not inhale. Do not ingest. Component Information Chemical Name Oral LD50 Dermal LD50 Inhalation LC50 = 801 mg/kg ( Rat ) = 2000 mg/kg ( Rabbit ) = 4060 = 2 g/m 3 ( Rat ) 4 h mg/kg ( Rat ) Sodium xylenesulfonate = 1000 mg/kg ( Rat ) = 3015 mg/kg ( Rat ) - - Information on physical, chemical and toxicological effects Symptoms Please see section 4 of this SDS for symptoms. Delayed and immediate effects as well as chronic effects from short and long-term exposure Carcinogenicity Nitrate or nitrite ingested under conditions that result in endogenous nitrosation are considered IARC group 2A carcinogens. Chemical Name ACGIH IARC NTP OSHA A3 Group 3 Group 2A X Legend ACGIH (American Conference of Governmental Industrial Hygienists) A3 - Animal Carcinogen IARC (International Agency for Research on Cancer) Group 2A - Probably Carcinogenic to Humans Group 3 IARC components are "not classifiable as human carcinogens" OSHA (Occupational Safety and Health Administration of the US Department of Labor) X - Present Numerical measures of toxicity Ecotoxicity Toxic to aquatic life with long lasting effects. Component Information 12. ECOLOGICAL INFORMATION Chemical Name Algae/aquatic plants Fish Toxicity to microorganisms 2.5: 72 h Chlorella vulgaris 18-56: 96 h Lepomis mg/l EC50 macrochirus mg/l LC50 static : 96 h Oncorhynchus mykiss mg/l LC50 static 16.4: 96 h Pimephales promelas mg/l LC50 Crustacea 18-32: 48 h Daphnia magna mg/l EC50 Static 7.7: 24 h Daphnia magna mg/l EC50 Persistence/Degradability. Page 5 / 7

6 Bioaccumulation. Mobility Other Adverse Effects Waste Treatment Methods 13. DISPOSAL CONSIDERATIONS Disposal of Wastes Contaminated Packaging Disposal should be in accordance with applicable regional, national and local laws and regulations. Disposal should be in accordance with applicable regional, national and local laws and regulations. California Hazardous Waste Status Chemical Name California Hazardous Waste Status Toxic Corrosive Ignitable Reactive Ignitable Reactive 14. TRANSPORT INFORMATION Note DOT IATA IMDG Please see current shipping paper for most up to date shipping information, including exemptions and special circumstances. Not regulated Not regulated Not regulated 15. REGULATORY INFORMATION International Inventories Chemical Name TSCA DSL NDSL EINECS ELINCS ENCS IECSC KECL PICCS AICS Present X Present Present X Present X X Present X Present Present X Present X X Legend: TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances ENCS - Japan Existing and New Chemical Substances IECSC - China Inventory of Existing Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances AICS - Australian Inventory of Chemical Substances Page 6 / 7

7 US Federal Regulations CERCLA Chemical Name Hazardous Substances RQs CERCLA/SARA RQ Reportable Quantity (RQ) 1000 lb SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372 CWA (Clean Water Act) This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR and 40 CFR ) US State Regulations California Proposition 65 This product does not contain any Proposition 65 chemicals. U.S. State Right-to-Know Regulations Chemical Name New Jersey Massachusetts Pennsylvania X X X X X X 16. OTHER INFORMATION NFPA HMIS Health Hazards 1 Health Hazards Flammability 0 Flammability Instability 0 Physical Hazards Special Hazards Personal Protection Issue Date: Revision Date: Revision Note: 31-Mar Mar-2016 ph correction Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. End of Safety Data Sheet Page 7 / 7