: Starch-Iodide Solution

Transcription

1 Date of issue: 05/08/2015 Revision date: 04/25/2018 Supersedes: 05/08/2015 Version: 1.1 SECTION 1: Identification 1.1. Identification Product form Product name Product code : Mixtures : Starch-Iodide Solution : LC Recommended use and restrictions on use Use of the substance/mixture Recommended use Restrictions on use 1.3. Supplier : For laboratory and manufacturing use only. : Laboratory chemicals : Not for food, drug or household use LabChem Inc Jackson's Pointe Commerce Park Building 1000, 1010 Jackson's Pointe Court Zelienople, PA USA T F info@labchem.com Emergency telephone number Emergency number : CHEMTREC: or SECTION 2: Hazard(s) identification 2.1. Classification of the substance or mixture GHS-US classification Not classified 2.2. GHS Label elements, including precautionary statements Not classified as a hazardous chemical. Other hazards not contributing to the classification 2.4. Unknown acute toxicity (GHS US) : None. SECTION 3: Composition/Information on ingredients 3.1. Substances 3.2. Mixtures Name Product identifier % GHS-US classification Water (CAS-No.) Not classified Starch, Soluble (CAS-No.) Not classified Salicylic Acid (CAS-No.) Acute Tox. 4 (Oral), H302 Aquatic Acute 3, H402 Aquatic Chronic 3, H412 Potassium Iodide (CAS-No.) Aquatic Acute 2, H401 Full text of hazard classes and H-statements : see section 16 SECTION 4: First-aid measures 4.1. Description of first aid measures First-aid measures general First-aid measures after inhalation First-aid measures after skin contact First-aid measures after eye contact First-aid measures after ingestion : Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible). : Allow victim to breathe fresh air. Allow the victim to rest. : Remove affected clothing and wash all exposed skin area with mild soap and water, followed by warm water rinse. : Rinse immediately with plenty of water. Obtain medical attention if pain, blinking or redness persists. : Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention. 04/25/2018 EN (English US) Page 1

2 4.2. Most important symptoms and effects (acute and delayed) Symptoms/effects Symptoms/effects after inhalation Symptoms/effects after skin contact Symptoms/effects upon intravenous administration Chronic symptoms : Not expected to present a significant hazard under anticipated conditions of normal use. : None under normal use.. : Not available. : No specific information available Immediate medical attention and special treatment, if necessary None. SECTION 5: Fire-fighting measures 5.1. Suitable (and unsuitable) extinguishing media Suitable extinguishing media Unsuitable extinguishing media 5.2. Specific hazards arising from the chemical Fire hazard Explosion hazard Reactivity : Foam. Dry powder. Carbon dioxide. Water spray. Sand. : Do not use a heavy water stream. : Not flammable. :. : None Special protective equipment and precautions for fire-fighters Firefighting instructions Protection during firefighting Other information SECTION 6: Accidental release measures : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Prevent fire-fighting water from entering environment. : Do not enter fire area without proper protective equipment, including respiratory protection. : Personal precautions, protective equipment and emergency procedures For non-emergency personnel Emergency procedures For emergency responders Protective equipment Emergency procedures : Evacuate unnecessary personnel. : Equip cleanup crew with proper protection. : Ventilate area Environmental precautions Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters Methods and material for containment and cleaning up Methods for cleaning up 6.4. Reference to other sections See Heading 8. Exposure controls and personal protection. SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling 7.2. Conditions for safe storage, including any incompatibilities Storage conditions Incompatible products Incompatible materials : Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Collect spillage. Store away from other materials. : Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Provide good ventilation in process area to prevent formation of vapor. : Keep container closed when not in use. : Strong bases. Strong acids. : Sources of ignition. Direct sunlight. SECTION 8: Exposure controls/personal protection 8.1. Control parameters 04/25/2018 EN (English US) 2/7

3 Starch, Soluble ( ) ACGIH ACGIH TWA (mg/m³) 10 mg/m³ OSHA OSHA PEL (TWA) (mg/m³) 5 mg/m³ NIOSH NIOSH REL (TWA) (mg/m³) 5 mg/m³ ACGIH ACGIH TWA (ppm) 0.01 ppm Inhalable fraction 8.2. Appropriate engineering controls Appropriate engineering controls : Emergency eye wash fountains should be available in the immediate vicinity of any potential exposure Individual protection measures/personal protective equipment Personal protective equipment: Safety glasses. Hand protection: Wear protective gloves. Eye protection: Chemical goggles or safety glasses Respiratory protection: Respiratory protection not required in normal conditions Other information: Do not eat, drink or smoke during use. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Liquid Color : milky Odor : odorless Odor threshold ph Melting point Freezing point Boiling point Flash point Relative evaporation rate (butyl acetate=1) Flammability (solid, gas) : Non flammable. Vapor pressure Relative vapor density at 20 C Relative density 04/25/2018 EN (English US) 3/7

4 Specific gravity / density : 1 Solubility Log Pow Auto-ignition temperature Decomposition temperature Viscosity, kinematic Viscosity, dynamic Explosion limits Explosive properties Oxidizing properties 9.2. Other information No additional information available SECTION 10: Stability and reactivity Reactivity None Chemical stability Possibility of hazardous reactions Conditions to avoid Direct sunlight. Extremely high or low temperatures Incompatible materials Strong acids. Strong bases Hazardous decomposition products fume. Carbon monoxide. Carbon dioxide. SECTION 11: Toxicological information Information on toxicological effects : Soluble in water. Likely routes of exposure Acute toxicity LD50 oral rat LD50 dermal rat LD50 dermal rabbit ATE US (oral) LD50 oral rat ATE US (oral) Skin corrosion/irritation Serious eye damage/irritation Respiratory or skin sensitization Germ cell mutagenicity Carcinogenicity : Skin and eye contact 891 mg/kg body weight (OECD 401: Acute Oral Toxicity, Rat, Male, Experimental value) > 2000 mg/kg (Rat) > mg/kg (Rabbit) 891 mg/kg body weight mg/kg mg/kg body weight Based on available data, the classification criteria are not met Reproductive toxicity Specific target organ toxicity single exposure Based on available data, the classification criteria are not met 04/25/2018 EN (English US) 4/7

5 Specific target organ toxicity repeated exposure Aspiration hazard Potential Adverse human health effects and symptoms Symptoms/effects after inhalation Symptoms/effects after skin contact Symptoms/effects upon intravenous administration Chronic symptoms : Based on available data, the classification criteria are not met. : None under normal use.. : Not available. : No specific information available. SECTION 12: Ecological information Toxicity LC50 fish 1 EC50 Daphnia 1 LC50 fish 1 EC50 Daphnia 1 90 mg/l (DIN , 48 h, Leuciscus idus, Static system, Fresh water, Experimental value) 870 mg/l (Equivalent or similar to OECD 202, 48 h, Daphnia magna, Static system, Fresh water, Experimental value) 3200 mg/l 120 h 2.7 mg/l 24 h Starch-Iodide Solution Biochemical oxygen demand (BOD) Chemical oxygen demand (COD) ThOD Biodegradable in the soil. Readily biodegradable in water g O₂/g substance 1.58 g O₂/g substance g O₂/g substance BOD (% of ThOD) Bioaccumulative potential Starch-Iodide Solution Bioaccumulative potential Log Pow 2.25 (Experimental value, Equivalent or similar to OECD 117, 25 C) Bioaccumulative potential Low potential for bioaccumulation (Log Kow < 4). Bioaccumulative potential Bioaccumulative potential Mobility in soil No additional information available Other adverse effects 04/25/2018 EN (English US) 5/7

6 Other information : Avoid release to the environment. SECTION 13: Disposal considerations Disposal methods Waste disposal recommendations : Dispose in a safe manner in accordance with local/national regulations. Ecology - waste materials : Avoid release to the environment. SECTION 14: Transport information Department of Transportation (DOT) In accordance with DOT Not regulated SECTION 15: Regulatory information US Federal regulations All components of this product are listed, or excluded from listing, on the United States Environmental Protection Agency Toxic Substances Control Act (TSCA) inventory SARA Section 311/312 Hazard Classes Immediate (acute) health hazard Delayed (chronic) health hazard International regulations CANADA Starch, Soluble ( ) Listed on the Canadian DSL (Domestic Substances List) Listed on the Canadian DSL (Domestic Substances List) Listed on the Canadian DSL (Domestic Substances List) EU-Regulations No additional information available National regulations Listed on the Canadian IDL (Ingredient Disclosure List) Listed on the Canadian IDL (Ingredient Disclosure List) US State regulations California Proposition 65 - This product does not contain any substances known to the state of California to cause cancer, developmental and/or reproductive harm SECTION 16: Other information Revision date : 04/25/2018 Other information : None. 04/25/2018 EN (English US) 6/7

7 Full text of H-phrases: see section 16: H302 H401 H402 H412 NFPA health hazard NFPA fire hazard NFPA reactivity Harmful if swallowed Toxic to aquatic life Harmful to aquatic life Harmful to aquatic life with long lasting effects : 0 - Materials that, under emergency conditions, would offer no hazard beyond that of ordinary combustible materials. : 0 - Materials that will not burn under typical fire conditions, including intrinsically noncombustible materials such as concrete, stone, and sand. : 0 - Material that in themselves are normally stable, even under fire conditions. Hazard Rating Health Flammability Physical Personal protection : 0 Minimal Hazard - No significant risk to health : 0 Minimal Hazard - Materials that will not burn : 0 Minimal Hazard - Materials that are normally stable, even under fire conditions, and will NOT react with water, polymerize, decompose, condense, or self-react. Non-Explosives. : A A - Safety glasses SDS US LabChem Information in this SDS is from available published sources and is believed to be accurate. No warranty, express or implied, is made and LabChem Inc assumes no liability resulting from the use of this SDS. The user must determine suitability of this information for his application. 04/25/2018 EN (English US) 7/7