SAFETY DATA SHEET Shades Professional Size Summer Flowers Aerosol [400ml x 12]

Transcription

1 Revision Date 27/02/2012 Revision 3-16/09/2008 Product No SAFETY DATA SHEET SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING 1.1. Product identifier Product name Product No Container size 400 ml 1.2. Relevant identified uses of the substance or mixture and uses advised against Identified uses Air freshener 1.3. Details of the supplier of the safety data sheet Supplier Contact Person 1.4. Emergency telephone number SECTION 2: HAZARDS IDENTIFICATION Jeyes Ltd. Jeyes Professional Division Bradkirk Place Walton Summit Preston Lancashire. PR5 8AJ T F technical@jeyes.com Christian Hofner 2.1. Classification of the substance or mixture Classification (1999/45/EEC) Human health Solvent abuse can kill instantly. Physical and Chemical Hazards F+;R12. When sprayed on a naked flame or any incandescent material the aerosol vapours can be ignited. Closed containers can burst violently when heated, due to excess pressure build-up. Extremely flammable 2.2. Label elements Labelling Extremely flammable Risk Phrases Safety Phrases R12 A1 A2 S2 S16 S25 S26 S46 S51 Extremely flammable. Pressurized container: protect from sunlight and do not expose to temperatures exceeding 50 C. Do not pierce or burn, even after use. Do not spray on a naked flame or any incandescent material. Keep out of the reach of children. Keep away from sources of ignition - No smoking. Avoid contact with eyes. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. If swallowed, seek medical advice immediately and show this container or label. Use only in well-ventilated areas. 1 / 6

2 2.3. Other hazards Not applicable. Product No SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.2. Mixtures PROPAN-2-OL 1 - < 2.5% CAS-No.: EC No.: Classification (EC 1272/2008) Flam. Liq. 2 - H225 Eye Irrit. 2 - H319 STOT SE 3 - H336 Classification (67/548/EEC) F;R11 Xi;R36 R67 The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16. SECTION 4: FIRST AID MEASURES 4.1. Description of first aid measures Inhalation In case of inhalation of spray mist: Move person into fresh air and keep at rest. Get medical attention if any discomfort continues. Ingestion Not relevant, due to the form of the product. Skin contact Remove contaminated clothes and rinse skin thoroughly with water. Get medical attention if irritation persists after washing. Eye contact Promptly wash eyes with plenty of water while lifting the eye lids. Continue to rinse for at least 15 minutes and get medical attention Most important symptoms and effects, both acute and delayed Inhalation. Drowsiness, dizziness, disorientation, vertigo. Ingestion Not relevant, due to the form of the product. Skin contact Prolonged contact may cause redness, irritation and dry skin. Eye contact May cause temporary eye irritation Indication of any immediate medical attention and special treatment needed No recommendation given, but first aid may still be required in case of accidental exposure, inhalation or ingestion of this chemical. If in doubt, GET MEDICAL ATTENTION PROMPTLY! SECTION 5: FIREFIGHTING MEASURES 5.1. Extinguishing media Extinguishing media Extinguish with foam, carbon dioxide, dry powder or water fog. Use fire-extinguishing media appropriate for surrounding materials Special hazards arising from the substance or mixture Hazardous combustion products Thermal decomposition or combustion may liberate carbon oxides and other toxic gases or vapours. Unusual Fire & Explosion Hazards Aerosol cans may explode in a fire. Specific hazards Aerosol containers can explode when heated, due to excessive pressure build-up Advice for firefighters Protective equipment for fire-fighters Use protective equipment appropriate for surrounding materials. 2 / 6

3 SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal precautions, protective equipment and emergency procedures For personal protection, see section Environmental precautions Collect and dispose of spillage as indicated in section Methods and material for containment and cleaning up Wear necessary protective equipment. Absorb with sand or other inert absorbent. For waste disposal, see section Reference to other sections For personal protection, see section 8. For waste disposal, see section 13. SECTION 7: HANDLING AND STORAGE 7.1. Precautions for safe handling Read label before use Conditions for safe storage, including any incompatibilities Aerosol cans: Must not be exposed to direct sunlight or temperatures above 50 C. Keep away from heat, sparks and open flame. Keep away from food, drink and animal feeding stuffs. Storage Class Lagerklasse 2 B 7.3. Specific end use(s) The identified uses for this product are detailed in Section 1.2. SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control parameters Name STD TWA - 8 Hrs STEL - 15 Min Notes PROPAN-2-OL WEL 400 ppm 999 mg/m3 500 ppm 1250 mg/m3 WEL = Workplace Exposure Limit Exposure controls Hand protection For prolonged or repeated skin contact use suitable protective gloves. Hygiene measures Wash hands after handling. SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on basic physical and chemical properties Appearance Aerosol. Odour Floral Flammability Limit - Lower(%) 1.4 (Butane) Flammability Limit - Upper(%) 9.4 (Butane) 9.2. Other information Not available. SECTION 10: STABILITY AND REACTIVITY Reactivity There are no known reactivity hazards associated with this product Chemical stability Stable under normal temperature conditions and recommended use. 3 / 6

4 10.3. Possibility of hazardous reactions There are no known reactivity hazards associated with this product Conditions to avoid Avoid exposing aerosol containers to high temperatures or direct sunlight. Avoid heat, flames and other sources of ignition Incompatible materials Materials To Avoid No specific, or groups of materials are likely to react to produce a hazardous situation Hazardous decomposition products None under normal conditions. SECTION 11: TOXICOLOGICAL INFORMATION Information on toxicological effects Aspiration hazard: Inhalation High concentrations of vapours may irritate respiratory system and lead to headache, fatigue, nausea and vomiting. Solvent abuse can kill instantly. Ingestion Not relevant, due to the form of the product. Skin contact Prolonged contact may cause redness and irritation. Eye contact May cause temporary eye irritation. SECTION 12: ECOLOGICAL INFORMATION Ecotoxicity The product is not expected to be toxic to aquatic organisms Toxicity Acute Fish Toxicity Not considered toxic to fish Persistence and degradability Degradability There are no data on the degradability of this product Bioaccumulative potential Bioaccumulative potential No data available on bioaccumulation Mobility in soil Mobility: The product contains volatile organic compounds (VOC) which will evaporate easily from all surfaces Results of PBT and vpvb assessment This product does not contain any PBT or vpvb substances Other adverse effects Not known. SECTION 13: DISPOSAL CONSIDERATIONS General information When handling waste, consideration should be made to the safety precautions applying to handling of the product Waste treatment methods Dispose of waste and residues in accordance with local authority requirements. 4 / 6

5 SECTION 14: TRANSPORT INFORMATION General LIMITED QUANTITIES for ADR/RID/IMDG (Not assessed for transportation via air (ICAO/IATA) under limited quantities) UN number UN No. (ADR/RID/ADN) 1950 UN No. (IMDG) 1950 UN No. (ICAO) UN proper shipping name Proper Shipping Name AEROSOLS Transport hazard class(es) ADR/RID/ADN Class 2.1 ADR/RID/ADN Class Class 2: Gases ADR Label No. 2.1 IMDG Class 2.1 ICAO Class/Division 2.1 Transport Labels FLAMMABLE GAS Packing group ADR/RID/ADN Packing group # IMDG Packing group # ICAO Packing group # Environmental hazards Environmentally Hazardous Substance/Marine Pollutant No Special precautions for user EMS Tunnel Restriction Code F-D, S-U (D) Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code Not relevant SECTION 15: REGULATORY INFORMATION Safety, health and environmental regulations/legislation specific for the substance or mixture EU Legislation Dangerous Preparations Directive 1999/45/EC. Dangerous Substance Directive 67/548/EEC. Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European Chemicals Agency, amending Directive 1999/45/EC and repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC) No 1488/94 as well as Council Directive 76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and 2000/21/EC, including amendments. Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16 December 2008 on classification, labelling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006 with amendments. 5 / 6

6 National Regulations The Aerosol Dispensers (EEC Requirements)(Amendment) Regulations 1996 (S.I 1996 No. 2421). Authorisations (Title VII Regulation 1907/2006) No specific authorisations are noted for this product. Restrictions (Title VIII Regulation 1907/2006) No specific restrictions of use are noted for this product Chemical Safety Assessment No chemical safety assessment has been carried out. SECTION 16: OTHER INFORMATION Revision Comments Change of format and content according to REACH Annex II. Issued By Christian Hofner Revision Date 27/02/2012 Revision 3-16/09/2008 Safety Data Sheet Status Risk Phrases In Full R12 R11 R36 R67 Hazard Statements In Full H224 H225 H319 H336 Approved. Extremely flammable. Highly flammable Irritating to eyes. Vapours may cause drowsiness and dizziness. Extremely flammable liquid and vapour. Highly flammable liquid and vapour. Causes serious eye irritation. May cause drowsiness or dizziness. Disclaimer This information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process. Such information is, to the best of the company's knowledge and belief, accurate and reliable as of the date indicated. However, no warranty guarantee or representation is made to its accuracy, reliability or completeness. It is the user's responsibility to satisfy himself as to the suitability of such information for his own particular use. 6 / 6