: DOBECKAN PE820DP2-20 KG

Transcription

1 1. Identification of the substance/mixture and of the company/undertaking 1.1 Product identifier Trade name : 1.2 Relevant identified uses of the substance or mixture and uses advised against Use of the : Insulating resin Substance/Mixture 1.3 Details of the supplier of the safety data sheet Company : ELANTAS Italia S.r.l. Strada Antolini Collecchio Italy Telephone : Telefax : address : msds.elantas.italia@altana.com 1.4 Emergency telephone number +39 (0) (8-17 h) 2. Hazards identification 2.1 Classification of the substance or mixture Classification (67/548/EEC, 1999/45/EC) Harmful Sensitising Dangerous for the environment R22: Harmful if swallowed. R43: May cause sensitization by skin contact. R50/53: Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. 2.2 Label elements Labelling (REGULATION (EC) No 1272/2008) Labelling according to EC Directives (1999/45/EC) Hazard pictograms : Harmful Dangerous for the environment R-phrase(s) : R22 Harmful if swallowed. R43 May cause sensitization by skin contact. R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. 1 / 8

2 S-phrase(s) : S24 Avoid contact with skin. S37 Wear suitable gloves. S57 Use appropriate container to avoid environmental contamination. S60 This material and its container must be disposed of as hazardous waste. Hazardous components which must be listed on the label: diallyl phthalate hydroxyethyl methacrylate 3. Composition/information on ingredients 3.2 Mixtures Chemical nature : Unsaturated Polyester Resin Solution Hazardous components Chemical Name CAS-No. EC-No. Registration number diallyl phthalate Classification (67/548/EEC) Xn; R22 N; R50-R53 Classification (REGULATION (EC) No 1272/2008) Acute Tox. 4; H302 Aquatic Acute 1; H400 Aquatic Chronic 1; H410 Concentration [%] >= 30 - < 50 2-hydroxyethyl methacrylate / Xi; R36/38 R43 Eye Irrit. 2; H319 Skin Irrit. 2; H315 Skin Sens. 1; H317 >= 10 - < 12,5 bis (#,#-dimethylbenzyl) peroxide O; R 7 Xi; R36/38 N; R51-R53 Org. Perox. F; H242 Eye Irrit. 2; H319 Skin Irrit. 2; H315 Aquatic Chronic 2; H411 >= 1 - < 2,5 For the full text of the R-phrases mentioned in this Section, see Section 16. For the full text of the H-Statements mentioned in this Section, see Section First aid measures 4.1 Description of first aid measures General advice : Do not leave the victim unattended. If inhaled : If unconscious place in recovery position and seek medical advice. If symptoms persist, call a physician. 2 / 8

3 In case of skin contact In case of eye contact If swallowed : Take off contaminated clothing and shoes immediately. Wash off immediately with plenty of water for at least 15 minutes. Use a mild soap if available. Wash contaminated clothing before re-use. : Remove contact lenses. Protect unharmed eye. If eye irritation persists, consult a specialist. : Keep respiratory tract clear. Do not give milk or alcoholic beverages. Never give anything by mouth to an unconscious person. If symptoms persist, call a physician. 5. Firefighting measures 5.1 Extinguishing media Suitable extinguishing media : Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. Unsuitable extinguishing : High volume water jet media 5.2 Special hazards arising from the substance or mixture Specific hazards during firefighting : Warning: water promotes the spread of fire. Cool containers / tanks with water spray. The pressure in sealed containers can increase under the influence of heat. 5.3 Advice for firefighters Special protective equipment for firefighters Further information : Wear self contained breathing apparatus for fire fighting if necessary. : Standard procedure for chemical fires. Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. 6. Accidental release measures 6.1 Personal precautions, protective equipment and emergency procedures 6.2 Environmental precautions Environmental precautions : If the product contaminates rivers and lakes or drains inform respective authorities. 6.3 Methods and materials for containment and cleaning up Methods for cleaning up : Wipe up with absorbent material (e.g. cloth, fleece). Keep in suitable, closed containers for disposal. 3 / 8

4 7. Handling and storage 7.1 Precautions for safe handling Advice on safe handling : For personal protection see section 8. Smoking, eating and drinking should be prohibited in the application area. Advice on protection against : Normal measures for preventive fire protection. fire and explosion 7.2 Conditions for safe storage, including any incompatibilities Requirements for storage areas and containers : Electrical installations / working materials must comply with the technological safety standards. Advice on common storage Other data : No materials to be especially mentioned. : No decomposition if stored and applied as directed. 8. Exposure controls/personal protection 8.1 Control parameters Components CAS-No. Value Control parameters Update Basis diallyl TWA 5 mg/m GB EH40 phthalate Further information : 2: Where no specific short-term exposure limit is listed, a figure three times the long-term exposure should be used 8.2 Exposure controls Engineering measures Use only appropriately classified electrical equipment and powered industrial trucks. Personal protective equipment Respiratory protection : No personal respiratory protective equipment normally required. Hand protection : Protective gloves complying with EN 374. Eye protection Skin and body protection Hygiene measures : Safety glasses : Protective suit : General industrial hygiene practice. 4 / 8

5 Protective measures : Ensure that eye flushing systems and safety showers are located close to the working place. Do not wear contact lenses. Environmental exposure controls General advice : If the product contaminates rivers and lakes or drains inform respective authorities. 9. Physical and chemical properties 9.1 Information on basic physical and chemical properties Appearance : liquid Colour : light yellow Odour : characteristic Flash point : 104 C : C Density : g/l at 20 C 10. Stability and reactivity 10.1 Reactivity 10.2 Chemical stability 10.3 Possibility of hazardous reactions Hazardous reactions : Stable under recommended storage conditions., No hazards to be specially mentioned Conditions to avoid Conditions to avoid 10.5 Incompatible materials Materials to avoid : Strong acids and strong bases Strong oxidizing agents Strong reducing agents Alkali metals Alkaline earth metals 10.6 Hazardous decomposition products Hazardous decomposition products : Stable under recommended storage conditions. Heating can release vapours which can be ignited. Burning produces noxious and toxic fumes. 5 / 8

6 : Carbon dioxide (CO2), carbon monoxide (CO), oxides of nitrogen (NOx), dense black smoke. 11. Toxicological information 11.1 Information on toxicological effects Acute toxicity Acute oral toxicity Skin corrosion/irritation Skin irritation Serious eye damage/eye irritation Eye irritation Respiratory or skin sensitization Sensitisation Target Organ Systemic Toxicant - Repeated exposure Further information 12. Ecological information 12.1 Toxicity Toxicity to fish : no data available Toxicity to daphnia and other aquatic invertebrates 12.2 Persistence and degradability Biodegradability 12.3 Bioaccumulative potential Bioaccumulation 12.4 Mobility in soil 12.5 Results of PBT and vpvb assessment 12.6 Other adverse effects 6 / 8

7 Additional ecological information 13. Disposal considerations 13.1 Waste treatment methods Product Contaminated packaging : Dispose of in accordance with the European Directives on waste and hazardous waste. Do not dispose of with domestic refuse. The product should not be allowed to enter drains, water courses or the soil. Container hazardous when empty. : Empty containers should be taken to an approved waste handling site for recycling or disposal. 14. Transport information Land transport ADR / RID: Class: 9 Packaging group: III UN number: 3082 ADR/RID-Labels: 9 Description of the goods: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (diallyl phthalate) Sea transport IMDG: Class: 9 Packaging group: III UN number: 3082 Labels: 9 EmS: F-A S-F Description of the goods: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (diallyl phthalate) Marine Pollutant Air transport IATA-DGR : Class: 9 Packaging group: III UN/ID No.: UN 3082 Labels: 9 7 / 8

8 Description of the goods: Environmentally hazardous substance, liquid, n.o.s. (diallyl phthalate) 15. Regulatory information 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture Major Accident Hazard Legislation : 96/82/EC Update: 2003 Dangerous for the environment 9a Quantity 1: 100 t Quantity 2: 200 t 15.2 Chemical Safety Assessment 16. Other information Full text of R-phrases referred to under sections 2 and 3 R 7 May cause fire. R22 Harmful if swallowed. R36/38 Irritating to eyes and skin. R43 May cause sensitization by skin contact. R50 Very toxic to aquatic organisms. R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R51 Toxic to aquatic organisms. R53 May cause long-term adverse effects in the aquatic environment. Full text of H-Statements referred to under sections 2 and 3. H242 Heating may cause a fire. H302 Harmful if swallowed. H315 Causes skin irritation. H317 May cause an allergic skin reaction. H319 Causes serious eye irritation. H400 Very toxic to aquatic life. H410 Very toxic to aquatic life with long lasting effects. H411 Toxic to aquatic life with long lasting effects. Further information Training advice : Provide adequate information, instruction and training for operators. The information contained herein is based on the present state of our knowledge and does therefore not guarantee certain properties. 8 / 8