INDEX. Laboratory Safety Guide
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1 INDEX A accident reporting, 1, 70, 125 acids, 154 neutralization, strength table, 165 acrylamide, 154 acute toxicity, 31, 313, 314 acute toxicity classes, 32 administrative controls (fume hoods), 95 aerosol cans, 154, 159 air emissions from laboratories law, 71 allergens, 19 anesthetics, 19 animals, working safely with, Chapter 8 animal tissue disposal, 193 caustic digestion, 197 laboratory animal safety, aqueous solutions, 154 asphyxiants, 19 autoclave safety, 117 B bases, 155 neutralization, strengths, table, 166 batteries, 155 benzene, 101 binary mixture hazard, 332 biohazardous waste disposal animals, 195 sharps and glass disposal, 220 biosafety cabinet (BSC), 90, 92, 97 Biosafety Committee, 6 Biological Safety Office, 2 bleeding (emergency), 134 blood toxic agents, 19 bloodborne pathogens, Chapter 9 bloodborne diseases, compliance methods, 207 disinfection, 215 exposure control plan, 206 post exposure evaluation, 211 boiling point, 8 building manager, 1 burns, 134 C carboys, disposal form (green form), 175 guidelines, tag (flammable liquid), 175 white, square, 172 yellow, square, 172 carcinogens, 19, 98, 155 select carcinogen list, Appendix D caustic digestion of animal tissue, 197 centrifuge safety, , 214 (blood) chemical allergy, 19 Chemical and Radiation Protection, 3 chemical carcinogens and mutagens, 98, 122, 155 chemical compatibility, Appendix F chemical waste disposal rules (EPA), 68 Chemical Hygiene Officer, 1 chemical hygiene plan, 24, 60, 303 OSHA Laboratory Standard, Appendix B template, Appendix C chemical release (see spills) Chemical Safety Committee, 5 chemical safety laws, Chapter 3 EPA Hazardous Waste Law, Appendix H OSHA laboratory standard, Appendix B OSHA Particularly Hazardous Substances, Appendix D storage and use of flammable liquids, chemical sharps and glass disposal, 220 chemical spill and release laws, 69 chemical splash, 132, 133 chemical substitution, 146, 144 (table) chemically contaminated animal tissue, 197 chromic acid, 147, 168 chronic toxicity, 33 Clean Air Act, 71 clothing (protective), 87, 135 combustible, 8 compatibility categories chart, Appendix F compressed gases, 14, 109 cylinders, 14, 109, , 185 disposal, flammable, 110 lecture bottles, 110, 185 storage, 109 contact lenses, 87, 133 containment, 329 (Appendix F) contaminated labware, 152, corrosives, 20, 102 Laboratory Safety Guide
2 372 Index Corrosivity (EPA waste), 343 cryogenic liquids, 14, 111, 133 (spills) cyanide salts, 156 D decontamination (spills), , 140 bloodborne, 215 degradation (glove), 89 Department of Transportation (see DOT) disinfection, bloodborne pathogens, 215 disposal (hazardous waste) alphabetical chemical list, Appendix A In-Lab Chemical Management, distillation, 104, 116, 149 E electrical safety, 112 embryotoxin, 22 emergency, Chapter 5 high hazard (major), hydrofluoric, 136 injury, major, mercury, 136 minor, notification, 70, 125 response, 129, 130, 135, 140 empty bottle disposal, 218, 219 empty container, 67 Environmental Health, 5 environmental impact statements, 72 Environmental Protection Agency (see EPA) environmental toxins, 21 EPA hazardous wastes, 65, 343 equipment safety, ethidium bromide, 100, 105, ethylene oxide, 111 explosions, 132 explosive limit, 8 explosives, 13, 158 (disposal) exposure factors, 17 hazard exposure guidelines, reducing, risk assessment, 35, routes of, 15-17, 31 eye protection, 86, 132, 135 animal use, 192 bloodborne pathogens, 208 laser, 283 F fetotoxin, 22, 97 fire, 131 fire extinguishers, 131 first aid, flammable, 8, 83-86, 110 gases, 110 solvent disposal, 158 storage and use, 63, 83-86, 110 flash point, 7 formaldehyde, 101 frozen glass stoppers, 112 fugitive emissions, 145 fume hoods, 90-95, 97, 114 air flow guidelines, 93 inspection, 92 types of, G gas cylinders, (see compressed gases) gases in aerosol cans (disposal), General Safety, 3 General Safety Committee, 6 generator (waste), 64 glass and plastic disposal, 218, 219 glass stopper, frozen, 112 glassware, 113 clean glass disposal, 218, 219 contaminated, disposal, , glove chemical resistance chart, 88 gloves, H hand protection, 87, 135 Hazard Communication Standard (HAZCOM), 61 hazard exposure guidelines, 33 hazards, binary mixture, 332 hazardous glass and plastic disposal, 218, 219 hazardous material (see hazmat) Hazardous Materials Information System (HMIS) hazardous waste, 65, 343 characteristics (EPA), 65, 161 disposal (prohibited methods), 68, 345 neutralize / treatment, 146 sewer use, 69, 151, sharps / laboratory glass, storage, 344, 345 TCLP, 65, 161, 343, 344 health hazards, University of Wisconsin-Madison Safety Department (608)
3 Index 373 ingestion, 16 inhalation, 15 injection, 17 skin / eye, 16 heating equipment hazards, hepatitis Hepatitis B (Hep B or HBV), 204 Hepatitis C (Hep C or HCB), 205 Hepatitis B immunization, 211 research labs using, 210 hepatoxic agents, 21 high hazard (major) emergency, HMIS, 27, 55 Hospital Safety Office, 5 housekeeping, 79 human carcinogen, 19 Human immunodeficiency virus (HIV), 205 hydrofluoric (HF) acid neutralization, 166 spill, 136 hygiene (in labs), 79 I ignitability (EPA waste), 343 ignition temperature, 8 import and export of hazardous chemicals, 72 incompatibilities, Appendix F acid, , 335 base, 336 strong oxidizer-reducer, toxic gas generation, water reactive, individual generator site, 60 infectious agents in animals, 191 inhalation, 15, 134 (spills) injuries, 134 inorganic chemical disposal, 160 instrument / equipment safety, inventory (chemical), 80, 144 irritants, 21 L labels, 26-29, 82, 288 chemical container, 82, 288 DOT label, 26 NFPA label, 26, 56 HMIS label, 27-29, 55 laboratory animal precautions, clean-outs (disposal), 186 emergency information poster, 127 hygiene, 79, 208 (blood) laboratory safety survey, 78, Appendix E labware, contaminated, lecture bottles disposal, 159 precautions, 110 Less is better! (waste minimization), 142 lethal concentration, 32, 40 lethal dose (acute toxicity), 32, 40 Lifesaving Station, 5 liquid disposal, 163 lung toxic agents, 22 M Madison Energy Recovery, Inc (MERI), 196, 220 Material Safety Data Sheet (see MSDS) medical waste, 219 mercury, 58, 106, 136, 148, 163 disposal, 104, 163 spills, 136, 137 thermometer, 137, 148 waste minimization, 148 metals, toxic, 164 microscale chemical procedures, 142 MSDS, 24, 288 mutagens, 23, 122, 155 (disposal) N 911 (emergency phone #), 1, 125 National Fire Protection Association (see NFPA) needles, 207, 240 nephrotoxic agents, 22 neurotoxic agents, 22 neutralization, 146, acid, base, example calculation, 167 procedures, NFPA, 26, 56 non-point source discharges, 72 normal trash (disposal), , notification, emergency, 125, 127 O Occupational Health, 3 Occupational Health Committee, 6 Occupational Safety & Health Administration (see OSHA) oil disposal, 172 Laboratory Safety Guide
4 374 Index On-Site Hazardous Materials Management Service, 172, OPIM, Chpater 9 (bloodborne pathogens) organic solvents (disposal), distillation, 104, 149 disposal, organic chemical disposal, 172 organic solvent carboy collection, OSHA Lab Standard, 59, Appendix B Chemical Hygiene Plan, 24, Appendix C employer responsibilities, 59, 76 standards for specific chemicals, 61 statute 29 CFR , Appendix B OSHA-regulated chemicals, 61, 101, Appendix B osmium tetroxide, 102, 176 (disposal) Other Potential Infectious Material (see OPIM) overexposure, chemical, 31 oxidizers, 9, 103, P particularly hazardous substances, 24, 61, 95-97, Appendix D permeation (gloves), 89 peroxide-forming chemicals, 12, distillation, 104 formation, 12, 103 testing, 104 personal protective equipment (PPE), 86-90, 131 animal handling, 192 bloodborne pathogens, 208 (for) spill clean-up, 135 personal risk analysis, 22, pesticides, 62 physical hazard, 7 plants suitable for incineration, 199 poisons, 100 pollution prevention, polychlorinated biphenyls (PCBs), 69, pressurized system hazards, 114 primary anesthetic, 19 product substitution, prohibited disposal methods, 68, 145, 178, 345 protection, spills, 135 pyrophoric chemicals, 11, 103 R radiation safety, Chapter 11 Radiation Safety Committee, 6 radioactive waste disposal animal tissue disposal, 197 sharps / glass, 220 radioactive material in animals, 191 reactive, 10, 102 water reactive, 10, reactivity (EPA waste), 343 recombinant DNA in animals, 191 recycling of chemicals, 149 redistribution of surplus chemicals, 143, 149, 185 refrigerators, flammable liquid, refrigerator / freezer considerations, 116 reproductive health hazards, 22, 23, 97, 98, 312 mutagen, 23, 98 teratogen, 23 reproductive toxins, 22, 97, 312, 313 Research Animal Resources Committee, 189 respirator, 16, 43, 87 respiratory protection, 87 Resource Conservation & Recovery Act (RCRA), responsibilities for safety, employees, 76 faculty, 76 instructors, 76 Safety Department, risk assessment, 22, 35, 41, Risk Management and Property Control, 5 S safe laboratory practices, 77-78, , 333 Safety Department, 2, 76 sanitary sewer, 67, 69, 151, disposal procedures, satellite accumulation, 67 select carcinogens, 24, 61, , 122, , sensitizer, 19 sewer disposal, 67, 69, , 198 sharps disposal, 216, 217 biohazardous, 220 chemically contaminated, 220 collection containers, 217, 220 radioactive, 220 shock-sensitive, 13, 103, 355 sites of action, 31 skin contamination, 132 skin protection, 87-90, 135 smoke inhalation, 134 solids disposal, 182 solvents, collection, 172, 186 University of Wisconsin-Madison Safety Department (608)
5 Index 375 source reduction (chemical), 142 spills, 65-67, , 140 assessing, 129 cleanup, 67, 135, 140 clothing, 135 cryogenic material, 133 eye splash, 133 human blood, 223 hydrofluoric (HF) acid, 136 major (high hazard), mercury, 106, 136, 137 personal protective equipment, 135 prevention & countermeasures (SPCC), 69, 74 preparation, skin, simple, 134, 135 storage, 81-83, cabinets, 330 chemical, 81, 330 combustible, 63, 83-86, 330 corrosives, 102, flammable, 63, 83-86, 330 liquids, 330 stormwater, 73 substitution of safer chemicals, surplus chemicals, 143, 345 Surplus Chemical Form, 184 surveys / audits, 78, Appendix E syringe safety, 207 systemic effects, 31 T teratogen, 23 thermometers, broken, mercury, 137, 163 toxic chemicals in animals, 190 Toxic Substances Control Act (TSCA), 72 toxicity, acute, 31 chronic, 33 Toxicity Characteristic Leaching Procedure (TCLP), 65-66, 161, 343, 344 toxicology, exposure routes, 31 site of action, 31 toxins environmental, 21 reproductive, 22, 97 training, 397, Appendix G bloodborne pathogens, 203, 212 transportation, 80 live animals, 193 treatment (chemical waste), 70, 150, 154 U unknowns (disposal), 182 UN number, 304 V vacuum system hazards, 115 volatile organic compounds (VOCs), 71 W waste animal tissue disposal, 193 disposal (EPA), 68, 69 waste minimization, 68, 149, 149 water-reactive, 10, 103 weighing toxic chemicals, work practices, controls, 95 Laboratory Safety Guide
6 376 Index University of Wisconsin-Madison Safety Department (608)
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