Report for NIIN: 00N040149

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Julian Wilkinson
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1 DOD Hazardous Materials Information System DoD L AS OF July 1998 FSC: 6810 NIIN: 00N Manufacturer's CAGE: Part No. Indicator: A Part Number/Trade Name: BUTADIENE SULFONE, 98%, General Information Item Name: BUTADIENE SULFONE Company's Name: ALDRICH CHEMICAL CO Company's Street: Company's P. O. Box: 355 Company's City: MILWAUKEE Company's State: WI Company's Country: US Company's Zip Code: Company's Emerg Ph #: Company's Info Ph #: Distributor/Vendor # 1: Distributor/Vendor # 1 Cage: Distributor/Vendor # 2: Distributor/Vendor # 2 Cage: Distributor/Vendor # 3: Distributor/Vendor # 3 Cage: Distributor/Vendor # 4: Distributor/Vendor # 4 Cage: Safety Data Action Code: Safety Focal Point: N Record No. For Safety Entry: 001 Tot Safety Entries This Stk#: 001 Status: SMJ Date MSDS Prepared: 20DEC91 Safety Data Review Date: 22MAR93 Supply Item Manager: MSDS Preparer's Name: Preparer's Company: Preparer's St Or P. O. Box: Preparer's City: Preparer's State: Preparer's Zip Code: Other MSDS Number: MSDS Serial Number: BRZHL Specification Number: Spec Type, Grade, Class: Hazard Characteristic Code: NK Unit Of Issue: Unit Of Issue Container Qty: Type Of Container: Net Unit Weight: NRC/State License Number: Net Explosive Weight: Net Propellant Weight-Ammo: Coast Guard Ammunition Code: Ingredients/Identity Information Page 1

2 Proprietary: NO Ingredient: THIOPENE, 2,5-DIHYDRO-, 1,1-DIOXIDE; (BUTADIENE SULFONE) Ingredient Sequence Number: 01 Percent: 98 Ingredient Action Code: Ingredient Focal Point: N NIOSH (RTECS) Number: XM CAS Number: OSHA PEL: NOT APPLICABLE ACGIH TLV: NOT APPLICABLE Other Recommended Limit: N/K Physical/Chemical Characteristics Appearance And Odor: OFF-WHITE CRYSTALS Boiling Point: N/K Melting Point: 149F,65C Vapor Pressure (MM Hg/70 F): N/K Vapor Density (Air=1): N/K Specific Gravity: N/K Decomposition Temperature: N/K Evaporation Rate And Ref: N/K Solubility In Water: N/K Percent Volatiles By Volume: N/K Viscosity: ph: N/K Radioactivity: Form (Radioactive Matl): Magnetism (Milligauss): Corrosion Rate (IPY): N/K Autoignition Temperature: Fire and Explosion Hazard Data Flash Point: >230F,>110C Flash Point Method: N/P Lower Explosive Limit: N/K Upper Explosive Limit: N/K Extinguishing Media: WATER SPRAY. CARBON DIOXIDE, DRY CHEMICAL POWDER OR APPROPRIATE FOAM. Special Fire Fighting Proc: WEAR NIOSH/MSHA APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT (FP N). Unusual Fire And Expl Hazrds: EMITS TOXIC FUMES UNDER FIRE CONDITIONS. Reactivity Data Stability: YES Cond To Avoid (Stability): NONE SPECIFIED BY MANUFACTURER. Materials To Avoid: STRONG OXIDIZING AGENTS. Hazardous Decomp Products: TOXIC FUMES OF: CARBON MONOXIDE, CARBON DIOXIDE, SULFUR OXIDES. Hazardous Poly Occur: NO Conditions To Avoid (Poly): NOT RELEVANT Health Hazard Data LD50-LC50 Mixture: LD50 (ORAL,RAT): 2830 MG/KG Page 2

3 Route Of Entry - Inhalation: YES Route Of Entry - Skin: YES Route Of Entry - Ingestion: YES Health Haz Acute And Chronic: ACUTE: MAY BE HARMFUL BY INHALATION, INGESTION, OR SKIN ABSORPTION. CAUSES SEVERE EYE IRRITATION. TO THE BEST OF MFR KNOWLEDGE, THE CHEMICAL, PHYSICAL, AND TOXICOLOGICAL PROPERTIES HAVE NOT BEEN THOROUGHLY INVESTIGATED. Carcinogenicity - NTP: NO Carcinogenicity - IARC: NO Carcinogenicity - OSHA: NO Explanation Carcinogenicity: NOT RELEVANT Signs/Symptoms Of Overexp: SEE HEALTH HAZARDS. Med Cond Aggravated By Exp: NONE SPECIFIED BY MANUFACTURER. Emergency/First Aid Proc: EYES: FLUSH EYES WITH COPIOUS AMOUNTS OF WATER FOR AT LEAST 15 MIN. SKIN: IMMED WASH SKIN WITH SOAP AND COPIOUS AMOUNTS OF WATER. INHAL: REMOVE TO FRESH AIR. IF NOT BREATHING GIVE ARTF RESP. IF BREATHING IS DIFFICULT, GIVE OXYGEN. INGEST: WASH OUT MOUTH WITH WATER PROVIDED PERSON IS CONSCIOUS. CALL MD. WASH CONTAMINATED CLOTHING BEFORE REUSE. Precautions for Safe Handling and Use Steps If Matl Released/Spill: WEAR NIOSH/MSHA APPROVED SCBA, RUBBER BOOTS AND HEAVY RUBBER GLOVES. SWEEP UP, PLACE IN A BAG AND HOLD FOR WASTE DISPOSAL. AVOID RAISING DUST. VENTILATE AREA AND WASH SPILL SITE AFTER MATERIAL PICKUP IS COMPLETE. Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER. Waste Disposal Method: DISSOLVE OR MIX THE MATERIAL WITH A COMBUSTIBLE SOLVENT AND BURN IN A CHEMICAL INCINERATOR EQUIPPED WITH AN AFTERBURNER AND SCRUBBER. Precautions-Handling/Storing: AVOID CONTACT AND INHALATION. DO NOT GET IN EYES, ON SKIN, ON CLOTHING. SEVERE EYE IRRITANT. KEEP TIGHTLY CLOSED. STORE IN A COOL DRY PLACE. Other Precautions: NONE SPECIFIED BY MANUFACTURER. Control Measures Respiratory Protection: NIOSH/MSHA APPROVED RESPIRATOR. Ventilation: MECHANICAL EXHAUST REQUIRED. Protective Gloves: RUBBER GLOVES. Eye Protection: CHEMICAL SAFETY GOGGLES. Other Protective Equipment: SAFETY SHOWER AND EYE BATH. Work Hygienic Practices: WASH THOROUGHLY AFTER HANDLING. Suppl. Safety & Health Data: NONE SPECIFIED BY MANUFACTURER. Transportation Data Transportation Action Code: Transportation Focal Point: Trans Data Review Date: DOT PSN Code: DOT Symbol: DOT Proper Shipping Name: DOT Class: DOT ID Number: DOT Pack Group: DOT Label: DOT/DoD Exemption Number: Page 3

4 IMO PSN Code: IMO Proper Shipping Name: IMO Regulations Page Number: IMO UN Number: IMO UN Class: IMO Subsidiary Risk Label: IATA PSN Code: IATA UN ID Number: IATA Proper Shipping Name: IATA UN Class: IATA Subsidiary Risk Class: IATA Label: AFI PSN Code: AFI Symbols: AFI Prop. Shipping Name: AFI Class: AFI ID Number: AFI Pack Group: AFI Label: AFI Special Prov: AFI Basic Pac Ref: MMAC Code: N.O.S. Shipping Name: Additional Trans Data: Disposal Data Disposal Data Action Code: Disposal Data Focal Point: Disposal Data Review Date: Rec # For This Disp Entry: Tot Disp Entries Per NSN: Landfill Ban Item: Disposal Supplemental Data: 1st EPA Haz Wst Code New: 1st EPA Haz Wst Name New: 1st EPA Haz Wst Char New: 1st EPA Acute Hazard New: 2nd EPA Haz Wst Code New: 2nd EPA Haz Wst Name New: 2nd EPA Haz Wst Char New: 2nd EPA Acute Hazard New: 3rd EPA Haz Wst Code New: 3rd EPA Haz Wst Name New: 3rd EPA Haz Wst Char New: 3rd EPA Acute Hazard New: Label Data Label Required: YES Technical Review Date: 22MAR93 Label Date: 26FEB93 MFR Label Number: Label Status: G Common Name: BUTADIENE SULFONE, 98%, Chronic Hazard: NO Signal Word: WARNING! Acute Health Hazard-None: Page 4

5 Acute Health Hazard-Slight: X Acute Health Hazard-Moderate: Acute Health Hazard-Severe: Contact Hazard-None: Contact Hazard-Slight: Contact Hazard-Moderate: X Contact Hazard-Severe: Fire Hazard-None: Fire Hazard-Slight: X Fire Hazard-Moderate: Fire Hazard-Severe: Reactivity Hazard-None: X Reactivity Hazard-Slight: Reactivity Hazard-Moderate: Reactivity Hazard-Severe: Special Hazard Precautions: AVOID CONTACT AND INHALATION. DO NOT GET IN EYES, ON SKIN, ON CLOTHING. STORE IN A COOL, DRY PLACE. ACUTE: MAY BE HARMFUL BY INHALATION, INGESTION OR SKIN ABSORPTION. CAUSES SEVERE EYE IRRITATION. TO THE BEST OF MFR KNOWLEDGE, THE CHEMICAL, PHYSICAL, AND TOXICOLOGICAL PROPERTIES HAVE NOT BEEN THOROUGHLY INVESTIGATED. CHRONIC: NONE LISTED BY MANUFACTURER. Protect Eye: Y Protect Skin: Y Protect Respiratory: Y Label Name: ALDRICH CHEMICAL CO Label Street: Label P.O. Box: 355 Label City: MILWAUKEE Label State: WI Label Zip Code: Label Country: US Label Emergency Number: Year Procured: Page 5

Report for NIIN: 00F010059

Report for NIIN: 00F010059 DOD Hazardous Materials Information System DoD 6050.5-L AS OF July 1998 FSC: 7930 NIIN: 00F010059 Manufacturer's CAGE: 86874 Part No. Indicator: A Part Number/Trade Name: EXPO WHITE BOARD CLEANER,CLEAR