SAFETY DATA SHEET None. None. The mixture does not meet the criteria for classification.

Transcription

1 SAFETY DATA SHEET 1. Identification Product identifier Other means of identification Brand Code Recommended use Recommended restrictions INSWOOL 3000 SERIES BULK, BLANKETS, AND MODULES 645C, 804A, 805A, 556B, 559A, 552A, 586A, 731A, 689A, 784A, 054B For Industrial Use Only ne known. Manufacturer/Importer/Supplier/Distributor information Manufacturer Company name HarbisonWalker International Address 1305 Cherrington Parkway, Suite 100 Moon Township, Pennsylvania US Telephone General Phone: Website Emergency phone number CHEMTREC 24 HOUR EMERGENCY # Hazard(s) identification Physical hazards Health hazards Environmental hazards OSHA defined hazards Label elements Hazard symbol Signal word Hazard statement Precautionary statement Prevention Response Storage Disposal Hazard(s) not otherwise classified (HNOC) Supplemental information t classified. t classified. t classified. t classified. ne. ne. The mixture does not meet the criteria for classification. Observe good industrial hygiene practices. Wash hands after handling. Store away from incompatible materials. Dispose of waste and residues in accordance with local authority requirements. ne known. ne. 3. Composition/information on ingredients Mixtures Chemical name Common name and synonyms CAS number % Polycrystalline fiber Composition comments Polycrystalline fiber is a reaction product of basic aluminum chloride and silica. Mean fiber diameter: 5-7 µm (non-respirable). The Seventh Annual Report on Carcinogens (1994), prepared by the National Toxicology Program (NTP), classified respirable RCF (another aluminosilicate, but vitreous, fiber product) and glass wool as substances reasonably anticipated to be carcinogens. The International Agency for Research on Cancer (IARC) has classified refractory ceramic fiber as a possible human carcinogen (Group 2B) based on sufficient evidence of carcinogenicity in animals, but insufficient data in humans. There has been no increased incidence of respiratory disease in studies examining occupationally exposed workers. Polycrystalline aluminosilicate fibers have not been specifically classified. Based on a sample analysis of Fraunhofer Institute fur Toxicology and Experimentelle Medizin, Hannover (Certificate dated October 30, 2007) the material does not contain WHO fibers (length >5 µm, diameter 3 µm, relation length/diameter > 3/1). 1 / 6

2 4. First-aid measures Inhalation Skin contact Eye contact Ingestion Most important symptoms/effects, acute and delayed Indication of immediate medical attention and special treatment needed General information 5. Fire-fighting measures Suitable extinguishing media Unsuitable extinguishing media Specific hazards arising from the chemical Special protective equipment and precautions for firefighters 6. Accidental release measures Personal precautions, protective equipment and emergency procedures Methods and materials for containment and cleaning up Environmental precautions 7. Handling and storage Precautions for safe handling Conditions for safe storage, including any incompatibilities Move to fresh air. Call a physician if symptoms develop or persist. Wash off with soap and water. Get medical attention if irritation develops and persists. Rinse with water. Get medical attention if irritation develops and persists. Rinse mouth. Get medical attention if symptoms occur. Treat symptomatically. Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. Use fire-extinguishing media appropriate for surrounding materials. t applicable. 8. Exposure controls/personal protection Occupational exposure limits US. NIOSH: Pocket Guide to Chemical Hazards Components Type Polycrystalline fiber (CAS ) Biological limit values Exposure guidelines Appropriate engineering controls Keep unnecessary personnel away. For personal protection, see section 8 of the SDS. Stop the flow of material, if this is without risk. Following product recovery, flush area with water. For waste disposal, see section 13 of the SDS. Avoid discharge into drains, water courses or onto the ground. Observe good industrial hygiene practices. Store in original tightly closed container. Store away from incompatible materials (see Section 10 of the SDS). Value Form TWA 3 fibers/cm3 Dust. biological exposure limits noted for the ingredient(s). 3 fibers/cm3 Fiber. 5 mg/m3 Fiber, total 5 mg/m3 fibers, total dust This material does not have established exposure limits. OSHA has not established a specific PEL for fibrous glass. It is considered to be a "particulate not otherwise regulated" (PNOR) and is covered under the OSHA nuisance dust PEL's of 5 mg/m3 for the respirable dust fraction and 15 mg/m3 for the total dust fraction for an 8-hr TWA (Time Weighted Average). Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. Individual protection measures, such as personal protective equipment Wear safety glasses with side shields (or goggles). Eye/face protection Skin protection Hand protection Wear appropriate chemical resistant gloves. 2 / 6

3 Other Respiratory protection Thermal hazards Wear suitable protective clothing. Use a NIOSH/MSHA approved respirator if there is a risk of exposure to dust/fume at levels exceeding the exposure limits. Wear appropriate thermal protective clothing, when necessary. General hygiene considerations 9. Physical and chemical properties Appearance Odor Physical state Form Color Odor threshold ph Melting point/freezing point Initial boiling point and boiling range Flash point Evaporation rate Flammability (solid, gas) Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Solid. Solid. Solid. Pressed fibrous material panel, Sheets., Bales., Solid- fiber; White. Odorless F (1823 C) Upper/lower flammability or explosive limits Flammability limit - lower (%) Flammability limit - upper (%) Explosive limit - lower (%) Explosive limit - upper (%) Vapor pressure Vapor density Relative density Solubility(ies) Solubility (water) Partition coefficient (n-octanol/water) Auto-ignition temperature Decomposition temperature Viscosity Other information Bulk density Density Explosive properties Oxidizing properties 10. Stability and reactivity Reactivity Chemical stability 3.30 g/cm3 t explosive. t oxidizing. The product is stable and non-reactive under normal conditions of use, storage and transport. Material is stable under normal conditions. 3 / 6

4 Possibility of hazardous reactions Conditions to avoid Incompatible materials Hazardous decomposition products 11. Toxicological information dangerous reaction known under conditions of normal use. Contact with incompatible materials. Strong oxidizing agents. Incompatibility is based strictly upon potential theoretical reactions between chemicals and may not be specific to industrial application exposure. hazardous decomposition products are known. Information on likely routes of exposure Inhalation adverse effects due to inhalation are expected. Skin contact Eye contact Ingestion Symptoms related to the physical, chemical and toxicological characteristics Information on toxicological effects Acute toxicity Skin corrosion/irritation Serious eye damage/eye irritation Respiratory or skin sensitization Respiratory sensitization Skin sensitization Germ cell mutagenicity Carcinogenicity adverse effects due to skin contact are expected. Expected to be a low ingestion hazard. Prolonged skin contact may cause temporary irritation. t a respiratory sensitizer. This product is not expected to cause skin sensitization. IARC Monographs. Overall Evaluation of Carcinogenicity data available to indicate product or any components present at greater than 0.1% are mutagenic or genotoxic. Possible cancer hazard - may cause cancer based on animal data. t listed. US. National Toxicology Program (NTP) Report on Carcinogens Polycrystalline fiber (CAS ) Reasonably Anticipated to be a Human Carcinogen. US. OSHA Specifically Regulated Substances (29 CFR ) t regulated. Reproductive toxicity Specific target organ toxicity - single exposure Specific target organ toxicity - repeated exposure Aspiration hazard 12. Ecological information Ecotoxicity Persistence and degradability Bioaccumulative potential Mobility in soil Other adverse effects 13. Disposal considerations Disposal instructions This product is not expected to cause reproductive or developmental effects. t classified. t classified. t an aspiration hazard. The product is not classified as environmentally hazardous. However, this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment. data is available on the degradability of this product. data available. data available. other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component. This product, in its present state, when discarded or disposed of, is not a hazardous waste according to Federal regulations (40 CFR (b)(4)). Under RCRA, it is the responsibility of the user of the product to determine, at the time of disposal, whether the product meets RCRA criteria for hazardous waste. 4 / 6

5 Hazardous waste code Waste from residues / unused products Contaminated packaging 14. Transport information DOT t regulated as dangerous goods. IATA t regulated as dangerous goods. IMDG t regulated as dangerous goods. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code 15. Regulatory information US federal regulations Since this product is used in several industries, no Waste Code can be provided by the supplier. The Waste Code should be determined in arrangement with your waste disposal partner or the responsible authority. t applicable. Toxic Substances Control Act (TSCA) Section 12(b) - This product has been assigned a CAS number; however, it is an "article" under TSCA and therefore exempt from listing on the TSCA inventory. This product is not known to be a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR TSCA Section 12(b) Export tification (40 CFR 707, Subpt. D) t regulated. CERCLA Hazardous Substance List (40 CFR 302.4) t listed. SARA 304 Emergency release notification t regulated. US. OSHA Specifically Regulated Substances (29 CFR ) t regulated. Superfund Amendments and Reauthorization Act of 1986 (SARA) Hazard categories Immediate Hazard - Delayed Hazard - Fire Hazard - Pressure Hazard - Reactivity Hazard - SARA 302 Extremely hazardous substance t listed. SARA 311/312 Hazardous chemical SARA 313 (TRI reporting) t regulated. Other federal regulations Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List t regulated. Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR ) t regulated. Safe Drinking Water Act (SDWA) US state regulations t regulated. WARNING: This product contains a chemical known to the State of California to cause cancer. US - California Proposition 65 - CRT: Listed date/carcinogenic substance International Inventories Polycrystalline fiber (CAS ) Listed: July 1, 1990 Country(s) or region Inventory name On inventory (yes/no)* Australia Australian Inventory of Chemical Substances (AICS) Canada Domestic Substances List (DSL) 5 / 6

6 Country(s) or region Inventory name On inventory (yes/no)* Canada n-domestic Substances List (NDSL) China Europe Europe Japan Korea New Zealand Philippines Inventory of Existing Chemical Substances in China (IECSC) European Inventory of Existing Commercial Chemical Substances (EINECS) European List of tified Chemical Substances (ELINCS) Inventory of Existing and New Chemical Substances (ENCS) Existing Chemicals List (ECL) New Zealand Inventory Philippine Inventory of Chemicals and Chemical Substances (PICCS) United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory *A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s) A "" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing country(s). 16. Other information, including date of preparation or last revision Issue date Version # 01 Disclaimer Revision information This information is based on our present knowledge on creation date. However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. This document has undergone significant changes and should be reviewed in its entirety. 6 / 6