ANNEXURE - A DETAILS OF PRODUCTS SR. NO. EXISTING PROPOSED TOTAL. 2. Basic Rhodamine B Rhodamine B Base

Transcription

1 ANNEXURE - A DETAILS OF PRODUCTS SR. NO. NAME OF PRODUCTS QUANTITY (MT/MONTH) EXISTING PROPOSED TOTAL 1. Diethyl Meta Amino Phenol (DEMAP) Basic Rhodamine B Rhodamine B Base Metanilic Acid 45% Liquid Liquid Basic Dyes Rhodamine Liquid (Minimum 10% to 40% Maximum) AND / OR Auramine O Liquid (Minimum 20% to 50% Maximum) 6. Drying of WetCake of Dyes Liquid Dyes from WetCake of Dyes Repacking of Dyes and/or Pigments [ Liquid / Dry ] TOTAL

2 M/s Krishna Chemicals, Plot No. 6910/A,6911,G.I.D.C, Ankleshwar,District: Bharuch,Gujarat. ANNEXURE B DETAILS OF RAW MATERIALS CONSUMPTION Sr. No. Name of Raw Material Consumption [ MT/month] Existing Additional Total DIETHYL META AMINO PHENOL 1 Metanilic Acid Ethyl Chloride Caustic Lye Potassium Hydroxide ICE Water BASIC RHODAMINE B 1 Diethyl Meta Amino Phenol 2 Phthalic Anhydride Caustic Lye Hydrochloric Acid Sulphuric Acid ICE Water RHODAMINE B BASE 1 Rhodamine B Caustic Lye Water METANILIC ACID 1 Nitro Benzene Oleum 65% Hydrated Lime Soda Ash Iron Powder (C.I.Powder)

3 M/s Krishna Chemicals, Plot No. 6910/A,6911,G.I.D.C, Ankleshwar,District: Bharuch,Gujarat. 6 Water Hydrochloric Acid Sulphuric Acid RHODAMINE LIQUID (MINIMUM 10% TO 40% MAXIMUM) Minimum 10% Maximum 40 % Minimum 10% Maximum 40 % 1 Rhodamine B/Rhodamine Base 2 Diethylene Glycol Diethylene Glycol Mono Ethyl Ether 4 Stabilizer Acetic Acid/Methanol AURAMINE O LIQUID (MINIMUM 20% TO 50% MAXIMUM) Minimum 20% Maximum 50 % Minimum 20% Maximum 50 % 1 Auramine O Stabilizer Acetic Acid DRYING OF WETCAKE OF DYES 1 Dye Wet Cake LIQUID DYES FROM WETCAKE OF DYES 1 Dye Wet Cake Stabilizer Acetic Acid REPACKING OF DYES AND/OR PIGMENTS [ LIQUID / DRY ] 1 Different types of Dyes and/or Pigments [ Liquid / Dry ]

4 Existing Products : ANNEXURE C MANUFACTURING PROCESS DESCRIPTION 1.] Diethyl Meta Amino Phenol (DEMAP) Process Description: 1. Pressure vessel: Charge in pressure vessel caustic lye/flakes. Metanilic acid and prepare slurry and then charge ethyl chloride under string after complete reaction dump reaction mass to Dumping vessel. 2. Dumping vessel: Dumped materials in dumping vessel & string up to complete crystallization material then transfer to Filter press. 3. Filter press: Do filtration of material by filter press and after filtration transfer to Fusion vessel. 4. Fusion: Take material from Filter press add caustic potassium hydroxide and heat up to c to c under string and after complete fusion reaction, charge water and make slurry of fusion mass and transfer to isolation vessel. 5. Isolation: Take slurry in isolation vessel and isolate material with Ice and slowly add Hydrochloric acid in it to isolate material, after complete isolation do centrifuge and then distil material under distillation vessel or dry in dryer. Now, DEMAP is ready.

5 Process Flow Diagram: Diethyl Meta Amino Phenol (DEMAP)

6 Chemical Reaction of DEMAP:

7 2.] RHODAMINE B Condensation Charge Phthalic anhydride and DEMAP (Diethyl Meta Amino Phenol) in condensation vessel and heat upto c c and charge DEMAP step by step and complete total reaction & after completion, dump in basification vessel. Basicfication Under stirring of water add ice & caustic flakes / lye and dump material of condensation in basification vessel & stirring up to crystallization done. Filtration: After complete basification transfer basification mass to filter nutch or filterpressand do filtration, transfer this material for isolation. Isolation Take material from filtration step& isolation material by addition of Hcl&H 2 SO 4, and after complete isolation, do centrifuge operation and dry material to get Rhodamine B

8 PROCESS FLOW DIAGRAM: RHODAMINE B

9 Chemical Reaction of Rhodamine B:- Rhodamine-B + Phthalic Anhydride M.Wt:148 Condensation Temp: C DEMAP M.wt:165 + M.wt:313 M.wt:165 M.wt:442.5 HCl/Sulphuric Acid Rhodamine B M.wt:478

10 3.] Rhodamine B Base : Under stirring of water charge Rhodamine b then charge Caustic lye in the vessel &heat up to 70 C, then do cooling under stirring up to crystallization, then do centrifuge and do drying operation, Final product isrhodamine b base. PROCESS FLOW DIAGRAM: RHODAMINE B BASE Chemical Reaction of Rhodamine B Base:-

11 PROPOSED PRODUCTS : 1.] METANILIC ACID 45% SOLUTION 1. SULFONATION Take nitrobenzene in the reactor, start cooling in jacket. Add oleum (65%) in 9 to 10 steps then maintain temperature 55 0 C to 75 0 C. then do stirring on 65 0 C to 75 0 C temperature. for half an hour. Then drain jacket and heat it upto 110 C temperature. Maintain C to C for 2 hours. Take out sample from reactor and do inprocess testing. once reaction is completed transfer reaction mass to next step. 2. SEPERATION Take reaction mass of sulfonation and add Hydrated lime in it slowly within 2 hours. Then adjust ph 7.0 by adding further hydrated lime. See ph 7.0 to 7.5. then filter it on filter nutsche or filter press and then wash out calcium sulphatedihydrate with 100 to 115 liter water washing. Reject calcium sulphatedehydrate and take filtrate for next step. 3. REDUCTION Take liquid from Seperation step for reduction it, at 70 C temperature add iron powder 60 to 150 mesh size and Hcl 30-35% slowly and maintaining temperature 95 0 C to C. do inprocess sample and complete reduction reaction. 2 nd ph if test not o.k. add some iron and Hcl and make spot test o.k. then adjust ph by soda ash seeing iron sludge with boil water and reject iron sludge. Filtrate is Metanilic Acid 45% Solution.

12 PROCESS FLOW DIAGRAM: METANILIC ACID 45% SOLUTION

13 Chemical Reaction of Metanilic Acid 45% Solution:-

14 4.] Rhodamine Liquid(Minimum 10% to 40% Maximum) Under stirring charge Diethylene Glycol or Acetic acid or Methanol and stabilizer then heat the mixture up to 60 C now slowly charge Rhodamine B & Rhodamine Base and dissolve it under stirring for 2 to 3 hours. Do in process test and once QC department approve quality of product cool down to room temperature and do filtration and packing, finished product isrhodamine Liquid. PROCESS FLOW DIAGRAM: Rhodamine Liquid (Minimum 10% to 40% Maximum)

15 5.] AuramineO Liquid (Minimum 20% to 50% Maximum) Under stirring charge Acetic acid and stabilizer then heat the mixture up to 60 C now slowly charge Auramine O and dissolve it under stirring for 2 to 3 hours. Do in process test and once QC department approve quality of product, cool down to room temperature and do filtration and packing, finished product is Auramine O Liquid. PROCESS FLOW DIAGRAM: Auramine Liquid (Minimum 20% to 50% Maximum)

16 6.] Dye Wet Cake Drying : Take Dye wet cake and dry it at 105 C in tray dryer or other suitable dryer. After 4 to 5 hours of drying, Do in process test and once QC department approve quality of product, do packing, finished product isdye Powder. PROCESS FLOW DIAGRAM: Dye Wet Cake Drying 7.] Liquid Dye from Wet Cake Under stirring charge Acetic acid and stabilizer then heat the mixture up to 60 C now slowly charge Wet Cake Dye and dissolve it under stirring for 2 to 3 hours. Do in process test and once QC department approve quality of product, cool down to room temperature and do filtration and packing, finished product is Liquid Dye. PROCESS FLOW DIAGRAM: Liquid Dye From Wet Cake:

17 8.] Repacking of Dyes and/or Pigments [ Liquid / Dry ] : The Dyes or pigments in Liquid / dry form, will be mixed and blended as per requirement And packed in the bags / drums packing as per client requirement. Also, the dyes / pigment in liquid / dry form will be repacked in the small packings as per client requirement. Different types of dyes / pigments Mixing / blending Packing as per desired quantity Sold to the customers

18 ANNEXURE D DETAILS OF WATER CONSUMPTION AND WASTE WATER GENERATION DETAILS OF WATER CONSUMPTION : Sr. no. PURPOSE Consumption, KL/day Existing Proposed Total After Proposed expansion 1. Domestic Industrial a. Process b. Boiler make up c. Cooling make up d. Washing water e. Any other scrubbing f. Gardening TOTAL [2] TOTAL [1+2]

19 DETAILS OF WASTE WATER GENERATION : Sr. no. PURPOSE Generation, KL/day Existing Proposed Total after proposed expansion 1. Domestic Industrial a. Process b. Boiler blow down* * c. Cooling bleed off* * d. Washing water e. Any other scrubbing TOTAL [2] TOTAL [1+2] Note - * - The generated boiler blow down and cooling bleed off will be mixed with raw water and reused within the plant premises. Hence, there will not be any additional waste water discharged from the plant premises because of the proposed expansion project. Therefore, there will not be any change in the consented waste water generation quantity, because of proposed expansion project.

20 M/s Krishna Chemicals, Plot No. 6910/A, 6911, G.I.D.C, Ankleshwar,District: Bharuch,Gujarat ANNEXURE E DETAILS OF HAZARDOUS WASTE GENERATION AND ITS DISPOSAL Sr. No. Name of Hazardous Waste Category as per HWM, Used Oil KL/year 2. Discarded containers 3. Filter & Filter bags from centrifuge MT/year Generation Per year Consented Additional Total nos/year KL/year 1.2 MT/year nos/year KL/year 2.4 MT/year nos/year Remarks Collection, Storage, Transportation and sold to authorized Recyclers. Collection, Storage, Decontamination or sold to authorized recycler. Reused or sale to GPCB authorized recycler. 4. Process waste [ Gypsum] 5. Process waste [ Iron sludge] MT/year 1284 MT/year Mt/year 1920 MT/year MT/year 2016 MT/year Collection, Storage, Transportation and sent to Co-process / TSDF site. Collection, Storage, Transportation and sent to Co-process / TSDF site.

21 M/s Krishna Chemicals,Plot No. 6910/A,6911,G.I.D.C, Ankleshwar,District: Bharuch,Gujarat. ANNEXURE F DETAILS OF AIR POLLUTION CONTROL MEASURES DETAILS OF FLUE GAS EMISSION Sr. No. Stack Attached to Name of fuel & its consumption Stack Height Air pollution Control System For Consented Production Capacity Parameters 1. Baby Boiler Natural 40 Nm3/day 10 m ---- PM < 150 mg/nm3 SO2 < 100 ppm NOx< 50 ppm For Proposed additional production capacity 1. Baby Boiler Natural 400 Nm3/day 10 m ---- PM < 150 mg/nm3 SO2 < 100 ppm NOx< 50 ppm Sr. No. Stack Attached to 1. Sulphonator Vessel DETAILS OF PROCESS GAS EMISSION : Stack Height Air pollution Control System For Proposed additional production capacity 3 m Two stage Caustic scrubber Parameters SO2 < 40 mg/nm3 2. Blender 3 m Bag filter PM < 150 mg/nm 3

22 M/s Krishna Chemicals, Plot No. 6910/A, 6911, G.I.D.C Estate, Ankleshwar,District: Bharuch,Gujarat ANNEXURE G PLANT LAY OUT

23

24

25

26 . GUJARAT INDUSTRIAL DEVELOPMENT CORPORATION (A GOVERNMENT OF GUJARAT TJNDERTAKING) On ol towards West : possessron rakst g.yfbnby, lt:.;t; r,.-s Shri >N-h^ - h'8' Dr{JA&t' o"". E$i.b'oolt afi hlrntv - COPY TO : tl'tn o.",-aa-f Place : GIDC / Ankleshwar Dt + ts/03 :/a NO. cldc : DEE : lllank:5d(d Office ofthe Dy. Ex. Engineer (lll) G. I. D. C. ANK n+r. F-r / dtn\ ","'..+,J'-...) Ret : (1) Allotment order No. : GIDC/RM/ANI(ALI i +43 Dr d"lj lk l[3 (2) Poss. Advice No. : crdc/rm/anrvalr...lg.&i...dt..*\s\$3 (3) EXTN, LETTER NO, : GIDC/RM/ANruALT F I POSSESSTON RECETPT I 4a r r., ln In pursuance of Allotment of Indl.l@orrrtrt.F+e#H gf. PlbfNo./H g l+-n,rsn rl-fltr. r,, \-,,, pl nomeasunns 4qQ r 31 iq. t'ttr. situala inrthe Housins oil]" -' ' GIDC Industrial estate Ank. is handed over to today i.". on 4I LA in good condition. THIS SAID PREMISES ARE BOUNDED AS On or towards North by : On or towards South by : On or towards East : Place : GIDC / Ankleshwar Dt.+ ts;t O\ POSSESSION HANDED OVER BY: a (2) The R. M. GIDC / ANK (3) Account Officer GIDC / ANK (4) The Ex. Engineer GIDC /ANK (5) Dy. Ex. Engineer (1) GlDc / ANK Note : (1) Infrastructure facilities like Roads, W/s, Power, Available / Not Avajlable. (2) cujarat INDUSTRIAL DEVELOPMENT CORPORATION has allotted the land / property on :AS ls V\+IERE ls BASIS hence due to this, there is no changes in rates & no any

27

28

29

30

31

32

33