SAFETY DATA SHEET PEPPERMINT ARVENSIS ORGANIC OIL

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1 SAFETY DATA SHEET SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING 1.1. Product identifier Product name Product No. Synonyms, Trade Names CAS-No. EC No. Alternative Cas OCPEPPARVE Mentha Arvensis Herb Oil, Mint / Cornmint Relevant identified uses of the substance or mixture and uses advised against Identified uses Aromatherapy, pharmaceuticals 1.3. Details of the supplier of the safety data sheet Supplier Telephone Approved Sellers MADAR Corporation Limited Sandleheath Industrial Estate Fordingbridge Hampshire SP6 1PA Cosmetic Butters, Mystic Moments, New Directions, World of Moulds 1.4. Emergency telephone number SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the substance or mixture Classification (1999/45/EEC) Human health Skin irritant and harmful if swallowed Environment Xn;R22. Xi;R38. R43. N;R51/53. The product contains a substance which is toxic to aquatic organisms and which may cause long term adverse effects in the aquatic environment Label elements EC No Contains Labelling Limonene Menthones pinenes Harmful Dangerous for the environment Risk Phrases R22 R43 Harmful if swallowed. May cause sensitisation by skin contact. R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. BiOrigins, Sandleheath Industrial Estat e, Fordingbridge, Hampshire, SP6 1PA, UK Page 1 of 7

2 Safety Phrases 2.3. Other hazards R38 S24 S37 S36 S61 Irritating to skin. Avoid contact with skin. Wear suitable gloves. Wear suitable protective clothing. Avoid release to the environment. Refer to special instructions/safety data sheets. SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.2. Mixtures Limonene 5-10% CAS-No.: EC No.: Flam. Liq. 3 - H226 Skin Irrit. 2 - H315 Skin Sens. 1 - H317 Asp. Tox. 1 - H304 Aquatic Acute 1 - H400 Aquatic Chronic 1 - H410 Xi;R38. N;R50/53. R10,R43. MENTHOLS 30-60% CAS-No.: EC No.: Skin Irrit. 2 - H315 Xi;R38. Menthones 30-60% CAS-No.: EC No.: Flam. Liq. 3 - H226 Acute Tox. 4 - H302 Eye Irrit. 2 - H319 Skin Sens. 1 - H317 Aquatic Chronic 3 - H412 Xn;R22. Xi;R36. R10,R43,R52/53. Menthyl Acetate 1-5% CAS-No.: EC No.: Aquatic Chronic 2 - H411 N;R51/53. pinenes 1-5% CAS-No.: EC No.: Page 2 of 7

3 Flam. Liq. 3 - H226 Skin Irrit. 2 - H315 Skin Sens. 1 - H317 Asp. Tox. 1 - H304 Xn;R65. Xi;R38.. R43. Pulegones 1-5% CAS-No.: EC No.: Acute Tox. 4 - H302 Acute Tox. 5 - H313 Skin Irrit. 3 - H316 Xn;R22. The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16. CAS-No EC No Hydrocarbon Content % <10% SECTION 4: FIRST AID MEASURES 4.1. Description of first aid measures Inhalation Move the exposed person to fresh air at once. Get medical attention if any discomfort continues. Ingestion Immediately rinse mouth and provide fresh air. Get medical attention. Skin contact Remove affected person from source of contamination. Remove contaminated clothing. Wash the skin immediately with soap and water. Get medical attention if any discomfort continues. Eye contact Promptly wash eyes with plenty of water while lifting the eye lids. Continue to rinse for at least 15 minutes and get medical attention Most important symptoms and effects, both acute and delayed 4.3. Indication of any immediate medical attention and special treatment needed SECTION 5: FIREFIGHTING MEASURES 5.1. Extinguishing media Extinguishing media Use as appropriate: Carbon dioxide (CO2), dry chemical or foam. Unsuitable extinguishing media Do not use direct water jet on burning material Special hazards arising from the substance or mixture Specific hazards When heated to decomposition, it emits acrid smoke as well as carbonmonoxide and carbondioxide Advice for firefighters Special Fire Fighting Procedures Avoid breathing fire vapours. Keep away from sources of heat, sparks and flames. Cool endangered drums with water. Protective equipment for fire-fighters Wear: Self-contained breathing apparatus. Wear chemical protective clothing. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal precautions, protective equipment and emergency procedures Avoid inhalation and direct contact with skin and eyes. Use individual protective equipment (safety glasses, waterproof boots, suitable protective clothing) in case of major spillages. Page 3 of 7

4 6.2. Environmental precautions Do not discharge into drains, water courses or onto the ground Methods and material for containment and cleaning up Remove all potential ignition sources. Contain spilled material. Cover with an inert or non-combustible inorganic absorbent material, sweep up and remove to an approved disposal container. Observe state, federal & local regulations Reference to other sections Wear protective clothing as described in Section 8 of this safety data sheet. SECTION 7: HANDLING AND STORAGE 7.1. Precautions for safe handling Apply good manufacturing practise and industrial hygiene practises, ensuring proper ventilation. Observe good personal hygiene and do not eat, drink or smoke whilst handling Conditions for safe storage, including any incompatibilities Store in tightly closed original containers, in a cool, dry area away from heat sources and protected from light. Keep air contact to a minimum Specific end use(s) SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control parameters Ingredient Comments No exposure limits noted for ingredient(s) Exposure controls Protective equipment Engineering measures Provide adequate general and local exhaust ventilation. Respiratory equipment If ventilation is insufficient, suitable respiratory protection must be provided. Hand protection Use suitable protective gloves if risk of skin contact. Eye protection Wear approved safety goggles. Other Protection Provide eyewash station. Hygiene measures Remove contaminated clothing and wash the skin thoroughly with soap and water after work. Good personal hygiene practices are always advisable, especially when working with chemicals. Personal protection Avoid inhalation and contact with skin and eyes. Skin protection Wear apron or protective clothing in case of splashes. SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on basic physical and chemical properties Appearance Colour Odour Mobile Liquid Colourless or pale yellow to greenish yellow Characteristic. Page 4 of 7

5 Relative density c 9.2. Other information Refractive Index Optical Rotation -19 to -25 SECTION 10: STABILITY AND REACTIVITY Reactivity It presents no significant reactivity hazards, by itself or in contact with water Chemical stability Stable under normal temperature conditions and recommended use Possibility of hazardous reactions Conditions to avoid Avoid heat, flames and other sources of ignition Incompatible materials Materials To Avoid Strong acids, alkali or oxidising agents Hazardous decomposition products Liable to cause smoke and acrid fumes during combustion: carbon monoxide, carbon dioxide and other non identified organic compounds may be formed. SECTION 11: TOXICOLOGICAL INFORMATION Information on toxicological effects Toxicological information To the best of our knowledge, the chemical/physical/toxicological properties have not been thoroughly investigated. Inhalation May be harmful if inhaled. Ingestion May be harmful if swallowed. Skin contact May cause skin irritation/eczema. Eye contact May cause eye irritation. SECTION 12: ECOLOGICAL INFORMATION Ecotoxicity The product contains a substance which is very toxic to aquatic organisms and which may cause long term adverse effects in the aquatic environment Toxicity Persistence and degradability Bioaccumulative potential Mobility in soil Results of PBT and vpvb assessment Other adverse effects Page 5 of 7

6 SECTION 13: DISPOSAL CONSIDERATIONS General information When handling waste, consideration should be made to the safety precautions applying to handling of the product Waste treatment methods Dispose of in compliance with all local and national regulations. SECTION 14: TRANSPORT INFORMATION Air Transport Notes Packing Instruction: UN number UN No. (ADR/RID/ADN) 3082 UN No. (IMDG) 3082 UN No. (ICAO) UN proper shipping name Proper Shipping Name ENVIRONMENTALLY HAZARD SUBSTANCE LIQUID, N.O.S Transport hazard class(es) ADR/RID/ADN Class 3082 ADR/RID/ADN Class Class 9: Miscellaneous dangerous substances and articles. IMDG Class 9 ICAO Class/Division 9 Transport Labels MISCELLANEOUS DANGEROUS GOODS Packing group ADR/RID/ADN Packing group IMDG Packing group ICAO Packing group III III III Environmental hazards Environmentally Hazardous Substance/Marine Pollutant Special precautions for user EMS Hazard No. (ADR) Tunnel Restriction Code F-A-S-F 90 Environmentally hazardous substance; miscellaneous dangerous substances. (E) Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code Tariff Number Page 6 of 7

7 SECTION 15: REGULATORY INFORMATION Safety, health and environmental regulations/legislation specific for the substance or mixture Statutory Instruments The Chemicals (Hazard Information and Packaging for Supply) Regulations 2009 (S.I 2009 No. 716). Approved Code Of Practice Classification and Labelling of Substances and Preparations Dangerous for Supply. Guidance Notes Workplace Exposure Limits EH40. CHIP for everyone HSG(108). EU Legislation Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European Chemicals Agency, amending Directive 1999/45/EC and repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC) No 1488/94 as well as Council Directive 76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and 2000/21/EC, including amendments Chemical Safety Assessment SECTION 16: OTHER INFORMATION SDS No Date 09/10/2014 Risk Phrases In Full R10 Flammable. R22 Harmful if swallowed. R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R65 Harmful: may cause lung damage if swallowed. R36 Irritating to eyes. R38 Irritating to skin. R43 May cause sensitisation by skin contact. R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Hazard Statements In Full H316 Causes mild skin irritation. H319 Causes serious eye irritation. H315 Causes skin irritation. H226 Flammable liquid and vapour. H302 Harmful if swallowed. H412 Harmful to aquatic life with long lasting effects. H304 May be fatal if swallowed and enters airways. H313 May be harmful in contact with skin. H317 May cause an allergic skin reaction. H411 Toxic to aquatic life with long lasting effects. H401 Toxic to aquatic life. H410 Very toxic to aquatic life with long lasting effects. H400 Very toxic to aquatic life. Disclaimer This information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process. Such information is, to the best of the company's knowledge and belief, accurate and reliable as of the date indicated. However, no warranty guarantee or representation is made to its accuracy, reliability or completeness. It is the user's responsibility to satisfy himself as to the suitability of such information for his own particular use. Page 7 of 7