SAFETY DATA SHEET. 1. Identification. 2. Hazard(s) identification. 3. Composition/information on ingredients

Transcription

1 SAFETY DATA SHEET 1. Identification Product identifier means of identification Recommended use Recommended restrictions ASPLIT PHENOLIC POWDER - CARBON ne known. Manufacturer/Importer/Supplier/Distributor information Manufacturer Company Name Address After hours telephone number rmal work hours telephone number Website Emergency 24-hour telephone number Information on operation hours ErgonArmor, a division of Ergon Asphalt & Emulsions, Inc Lakeland Drive Jackson, MS USA sds@ergon.com CHEMTREC: rth America International :00 a.m. to 5:00 p.m. 2. Hazard(s) identification Physical hazards t classified. Health hazards Serious eye damage/eye irritation Specific target organ toxicity, single exposure Environmental hazards t classified. OSHA defined hazards t classified. Category 2B Category 3 respiratory tract irritation Label elements Signal word Hazard statement Prevention Response Storage Disposal Hazard(s) not otherwise classified (HNOC) Supplemental information Warning Causes eye irritation. May cause respiratory irritation. Observe good industrial hygiene practices. Wash thoroughly after handling. Wear protective gloves/eye protection/face protection. Do not breathe dust/fume/gas/mist/vapors Use only outdoors or in a well-ventilated area. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Call a poison center/doctor if you feel unwell. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. Store in accordance with local/regional/national regulations. Dispose of contents/container to an appropriate treatment and disposal facility in accordance with applicable laws and regulations, and product characteristics at time of disposal. ne known. t applicable. 3. Composition/information on ingredients Mixtures Chemical name Common name and synonyms CAS number % Carbon Coke (petroleum) / 6

2 Chemical name Common name and synonyms CAS number % p-toluenesulfonic acid *Designates that a specific chemical identity and/or percentage of composition has been withheld as a trade secret. 4. First-aid measures Inhalation Skin contact Eye contact Ingestion Most important symptoms/effects, acute and delayed Indication of immediate medical attention and special treatment needed General information Move to fresh air. Call a physician if symptoms develop or persist. Wash off with soap and water. Get medical attention if irritation develops and persists. Rinse with water. Get medical attention if irritation develops and persists. Rinse mouth. Get medical attention if symptoms occur. Direct contact with eyes may cause temporary irritation. Treat symptomatically. Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. 5. Fire-fighting measures Suitable extinguishing media Unsuitable extinguishing media Specific hazards arising from the chemical Special protective equipment and precautions for firefighters Fire-fighting equipment/instructions Specific methods 6. Accidental release measures Personal precautions, protective equipment and emergency procedures Methods and materials for containment and cleaning up Environmental precautions Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2). Do not use water jet as an extinguisher, as this will spread the fire. During fire, gases hazardous to health may be formed. Self-contained breathing apparatus and full protective clothing must be worn in case of fire. Use water spray to cool unopened containers. Use standard firefighting procedures and consider the hazards of other involved materials. Keep unnecessary personnel away. For personal protection, see section 8 of the SDS. Stop the flow of material, if this is without risk. Following product recovery, flush area with water. For waste disposal, see section 13 of the SDS. Avoid discharge into drains, water courses or onto the ground. 7. Handling and storage Precautions for safe handling Conditions for safe storage, including any incompatibilities Avoid prolonged exposure. Observe good industrial hygiene practices. Store in original tightly closed container. Store away from incompatible materials (see Section 10 of the SDS). 8. Exposure controls/personal protection Occupational exposure limits US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR ) PEL 5 mg/m3 Respirable fraction. 15 mg/m3 Total dust. US. OSHA Table Z-3 (29 CFR ) TWA 15 mppcf US. ACGIH Threshold Limit s TWA 2 mg/m3 Respirable fraction. US. NIOSH: Pocket Guide to Chemical Hazards TWA 2.5 mg/m3 Respirable. 2 / 6

3 Biological limit values Appropriate engineering controls biological exposure limits noted for the ingredient(s). Provide adequate ventilation, including appropriate local extraction, to ensure that the defined occupational exposure limit is not exceeded. Individual protection measures, such as personal protective equipment Eye/face protection If contact is likely, safety glasses with side shields are recommended. Hand protection Skin protection Respiratory protection Thermal hazards General hygiene considerations 9. Physical and chemical properties Appearance Odor Physical state Color Odor threshold ph Melting point/freezing point Initial boiling point and boiling range Flash point Evaporation rate Flammability (solid, gas) For prolonged or repeated skin contact use suitable protective gloves. Wear suitable protective clothing. In case of insufficient ventilation, wear suitable respiratory equipment. Wear appropriate thermal protective clothing, when necessary. Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Powder. Solid. Solid. Black. Upper/lower flammability or explosive limits Flammability limit - lower (%) Flammability limit - upper (%) Explosive limit - lower (%) Explosive limit - upper (%) Vapor pressure Vapor density Relative density Solubility(ies) Solubility (water) Partition coefficient (n-octanol/water) Auto-ignition temperature Decomposition temperature Viscosity 10. Stability and reactivity Reactivity Chemical stability Possibility of hazardous reactions Conditions to avoid Incompatible materials Hazardous decomposition products The product is stable and non-reactive under normal conditions of use, storage and transport. Material is stable under normal conditions. Hazardous polymerization does not occur. Avoid temperatures exceeding the flash point. Contact with incompatible materials. Strong acids, alkalies and oxidizing agents. hazardous decomposition products are known. 3 / 6

4 11. Toxicological information Information on likely routes of exposure Ingestion Inhalation Skin contact Eye contact Symptoms related to the physical, chemical and toxicological characteristics Information on toxicological effects Acute toxicity Product Expected to be a low ingestion hazard. Prolonged inhalation may be harmful. Inhalation of dusts may cause respiratory irritation. May be irritating to the skin. adverse effects due to skin contact are expected. Causes eye irritation. t classified. Species ASPLIT PHENOLIC POWDER - CARBON (CAS Mixture) Acute Oral Acute Oral p-toluenesulfonic acid (CAS ) Acute Oral Mouse Species Mouse Mouse * Estimates for product may be based on additional component data not shown. Skin corrosion/irritation Serious eye damage/eye irritation Respiratory or skin sensitization Respiratory sensitization Skin sensitization Germ cell mutagenicity Carcinogenicity Causes eye irritation. This product is not expected to cause skin sensitization. Test Results mg/kg estimated mg/kg estimated mg/kg estimated Test Results > mg/kg 440 mg/kg 400 mg/kg 160 mg/kg 70 mg/kg available to indicate product or any components present at greater than 0.1% are mutagenic or genotoxic. This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA. US. OSHA Specifically Regulated Substances (29 CFR ) Reproductive toxicity Specific target organ toxicity - single exposure Specific target organ toxicity - repeated exposure Aspiration hazard Chronic effects This product is not expected to cause reproductive or developmental effects. Respiratory tract irritation. t classified. Prolonged inhalation may be harmful. t expected to be hazardous by OSHA criteria. 4 / 6

5 12. Ecological information Ecotoxicity Persistence and degradability Bioaccumulative potential Mobility in soil adverse effects 13. Disposal considerations Disposal instructions Local disposal regulations Hazardous waste code Waste from residues / unused products Contaminated packaging 14. Transport information DOT t regulated as dangerous goods. IATA t regulated as dangerous goods. IMDG t regulated as dangerous goods. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code 15. Regulatory information US federal regulations The product is not classified as environmentally hazardous. However, this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment. is available on the degradability of this product. available. available. other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component. When this product as supplied is to be discarded as waste, it does not meet the definition of a RCRA waste under 40 CFR 261. Dispose in accordance with all applicable regulations. The waste code should be assigned in discussion between the user, the producer and the waste disposal company. Dispose of in accordance with local regulations. Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe manner (see: Disposal instructions). Empty containers should be taken to an approved waste handling site for recycling or disposal. Since emptied containers may retain product residue, follow label warnings even after container is emptied. t applicable. All components are on the U.S. EPA TSCA Inventory List. TSCA Section 12(b) Export tification (40 CFR 707, Subpt. D) CERCLA Hazardous Substance List (40 CFR 302.4) US. OSHA Specifically Regulated Substances (29 CFR ) Superfund Amendments and Reauthorization Act of 1986 (SARA) Hazard categories Immediate Hazard - Delayed Hazard - Fire Hazard - Pressure Hazard - Reactivity Hazard - SARA 302 Extremely hazardous substance SARA 311/312 Hazardous chemical SARA 313 (TRI reporting) federal regulations Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR ) 5 / 6

6 Safe Drinking Water Act (SDWA) US state regulations US. Massachusetts RTK - Substance List p-toluenesulfonic acid (CAS ) US. New Jersey Worker and Community Right-to-Know Act US. Pennsylvania RTK - Hazardous Substances p-toluenesulfonic acid (CAS ) US. Rhode Island RTK US. California Proposition 65 California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): This material is not known to contain any chemicals currently listed as carcinogens or reproductive toxins. International Inventories Country(s) or region Inventory name On inventory (yes/no)* Australia Australian Inventory of Chemical Substances (AICS) Canada Canada China Europe Europe Japan Korea New Zealand Philippines United States & Puerto Rico Domestic Substances List (DSL) n-domestic Substances List (NDSL) Inventory of Existing Chemical Substances in China (IECSC) European Inventory of Existing Commercial Chemical Substances (EINECS) European List of tified Chemical Substances (ELINCS) Inventory of Existing and New Chemical Substances (ENCS) Existing Chemicals List (ECL) New Zealand Inventory Philippine Inventory of Chemicals and Chemical Substances (PICCS) Toxic Substances Control Act (TSCA) Inventory *A "" indicates that all components of this product comply with the inventory requirements administered by the governing country(s) A "" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing country(s). 16. information, including date of preparation or last revision Issue date Revision date Version # 02 Disclaimer Revision Information The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. Product and Company Identification: Product and Company Identification Physical & Chemical Properties: Multiple Properties 6 / 6