Product name: ECOSURF BD-405 (75%) Surfactant Issue Date: 03/04/2015 Print Date: 03/10/2015

Transcription

1 SAFETY DATA SHEET ROHM AND HAAS SINGAPORE (PTE) LTD Product name: ECOSURF BD-405 (75%) Surfactant Issue Date: 03/04/2015 Print Date: 03/10/2015 ROHM AND HAAS SINGAPORE (PTE) LTD encourages and expects you to read and understand the entire (M)SDS, as there is important information throughout the document. We expect you to follow the precautions identified in this document unless your use conditions would necessitate other appropriate methods or actions. 1. PRODUCT AND COMPANY IDENTIFICATION Product name: ECOSURF BD-405 (75%) Surfactant Recommended use of the chemical and restrictions on use Identified uses: Coatings product COMPANY IDENTIFICATION ROHM AND HAAS SINGAPORE (PTE) LTD A Subsidiary of The Dow Chemical Company 260 ORCHARD RD, #18-01 THE HEEREN SINGAPORE SINGAPORE Customer Information Number: SDSQuestion@dow.com Fax: EMERGENCY TELEPHONE NUMBER 24-Hour Emergency Contact: Local Emergency Contact: HAZARDS IDENTIFICATION Hazard classification This product is not hazardous per the Globally Harmonized System of Classification and Labelling (GHS). Other hazards 3. COMPOSITION/INFORMATION ON INGREDIENTS This product is a mixture. Component CASRN Concentration Trademark of The Dow Chemical Company ("Dow") or an affiliated company of Dow Page 1 of 8

2 Oxirane, 2-methyl-, polymer with oxirane, mono(2-ethylhexyl) ether >= < 80.0 % 4. FIRST AID MEASURES Description of first aid measures Inhalation: Move to fresh air. Skin contact: Wash affected skin areas thoroughly with soap and water. Consult a physician if irritation persists. Eye contact: Flush eyes with a large amount of water for at least 15 minutes. If eye irritation persists, consult a specialist. Ingestion: Drink 1 or 2 glasses of water. Never give anything by mouth to an unconscious person. Consult a physician. Most important symptoms and effects, both acute and delayed: Aside from the information found under Description of first aid measures (above) and Indication of immediate medical attention and special treatment needed (below), any additional important symptoms and effects are described in Section 11: Toxicology Information. Indication of any immediate medical attention and special treatment needed Notes to physician: Treatment of exposure should be directed at the control of symptoms and the clinical condition of the patient. 5. FIREFIGHTING MEASURES Suitable extinguishing media: Use the following extinguishing media when fighting fires involving this material: polar solvent (alcohol) foam Foam Carbon dioxide (CO2) Water spray Dry chemical Unsuitable extinguishing media: Special hazards arising from the substance or mixture Hazardous combustion products: Unusual Fire and Explosion Hazards: Combustion generates toxic fumes of the following: Carbon oxides Advice for firefighters Fire Fighting Procedures: A solid stream of water can cause frothing. Special protective equipment for firefighters: In the event of fire, wear self-contained breathing apparatus. 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures: Page 2 of 8

3 Environmental precautions: CAUTION: Keep spills of product as supplied out of municipal sewers and open bodies of water. Do not discharge cleaning runoffs directly to open bodies of water. Methods and materials for containment and cleaning up: Floor may be slippery; use care to avoid falling. Contain spills immediately with inert materials (e.g., sand, earth). Transfer liquids and solid diking material to separate suitable containers for recovery or disposal. 7. HANDLING AND STORAGE Precautions for safe handling: Avoid contact with eyes, skin and clothing. Wash thoroughly after handling. Keep container tightly closed. Do not breathe vapors, mist or gas. Conditions for safe storage: Keep container tightly closed. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Control parameters Exposure limits are listed below, if they exist. Exposure controls Engineering controls: Use local exhaust ventilation with a minimum capture velocity of 100 ft/min. (0.5 m/sec.) at the point of vapor evolution. Refer to the current edition of Industrial Ventilation: A Manual of Recommended Practice published by the American Conference of Governmental Industrial Hygienists for information on the design, installation, use, and maintenance of exhaust systems. Protective measures: Facilities storing or utilizing this material should be equipped with an eyewash facility. Individual protection measures Eye/face protection: Eye protection worn must be compatible with respiratory protection system employed. Use chemical splash goggles (ANSI Z87.1 or approved equivalent). Skin protection Hand protection: The glove(s) listed below may provide protection against permeation. (Gloves of other chemically resistant materials may not provide adequate protection): Neoprene gloves Butyl-rubber. Natural rubber Polyethylene Polyvinyl alcohol Polyvinyl chloride Other protection: Use chemically resistant apron or other impervious clothing to avoid prolonged or repeated skin contact. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance Physical state Odor Color Odor Threshold liquid ph Melting point/range Colorless to yellow Page 3 of 8

4 Freezing point Boiling point (760 mmhg) Flash point Evaporation Rate (Butyl Acetate = 1) Flammability (solid, gas) Lower explosion limit Upper explosion limit Vapor Pressure Relative Vapor Density (air = 1) >1 Relative Density (water = 1) Water solubility Partition coefficient: n- octanol/water Auto-ignition temperature Decomposition temperature Kinematic Viscosity Explosive properties Oxidizing properties Molecular weight 288 C closed cup Not Applicable <0.01 mmhg soluble NOTE: The physical data presented above are typical values and should not be construed as a specification. 10. STABILITY AND REACTIVITY Reactivity: Chemical stability: Possibility of hazardous reactions: Stable under normal conditions. Product will not undergo polymerization. Conditions to avoid: high temperatures Incompatible materials: Avoid contact with the following: Strong acids Strong bases Strong oxidizers Hazardous decomposition products: 11. TOXICOLOGICAL INFORMATION Page 4 of 8

5 Toxicological information on this product or its components appear in this section when such data is available. Acute toxicity Acute oral toxicity LD50, Rat, female, > 2,000 mg/kg Acute dermal toxicity LD50, Rabbit, > 2,000 mg/kg No deaths occurred at this concentration. Acute inhalation toxicity Skin corrosion/irritation practically non-irritating Serious eye damage/eye irritation May cause transient irritation. Sensitization Did not cause sensitisation on laboratory animals. Specific Target Organ Systemic Toxicity (Single Exposure) Specific Target Organ Systemic Toxicity (Repeated Exposure) Carcinogenicity Teratogenicity Reproductive toxicity Mutagenicity Aspiration Hazard COMPONENTS INFLUENCING TOXICOLOGY: Acute inhalation toxicity As product: The LC50 has not been determined. Specific Target Organ Systemic Toxicity (Repeated Exposure) Relevant data not available. Page 5 of 8

6 Carcinogenicity Relevant data not available. Teratogenicity Relevant data not available. Reproductive toxicity Relevant data not available. Mutagenicity One material tested in this family was negative in the Ames test. Aspiration Hazard Based on physical properties, not likely to be an aspiration hazard. 12. ECOLOGICAL INFORMATION Ecotoxicological information on this product or its components appear in this section when such data is available. General Information Material is not classified as dangerous to aquatic organisms (LC50/EC50/IC50/LL50/EL50 greater than 100 mg/l in most sensitive species). Ecotoxicity Acute toxicity to aquatic invertebrates EC50, Daphnia (water flea), static test, 48 Hour, > 100 mg/l Acute toxicity to algae/aquatic plants ErC50, Algae (Desmodesmus subspicatus), static test, 72 Hour, Growth rate, > 100 mg/l, OECD Test Guideline 201 or Equivalent Persistence and degradability Biodegradability: 10-day Window: Pass Biodegradation: > 60 % Exposure time: 28 d Method: OECD Test Guideline 301F or Equivalent Bioaccumulative potential Bioaccumulation: No relevant data found. Mobility in Soil No relevant data found. Results of PBT and vpvb assessment Page 6 of 8

7 This substance has not been assessed for persistence, bioaccumulation and toxicity (PBT). Other adverse effects This substance is not in Annex I of Regulation (EC) No 1005/2009 on substances that deplete the ozone layer. 13. DISPOSAL CONSIDERATIONS Disposal methods: For disposal, incinerate this material at a facility that complies with local, state, and federal regulations. 14. TRANSPORT INFORMATION Classification for ROAD and Rail transport: Not regulated for transport Classification for SEA transport (IMO-IMDG): Not regulated for transport Transport in bulk Consult IMO regulations before transporting ocean bulk according to Annex I or II of MARPOL 73/78 and the IBC or IGC Code Classification for AIR transport (IATA/ICAO): Not regulated for transport This information is not intended to convey all specific regulatory or operational requirements/information relating to this product. Transportation classifications may vary by container volume and may be influenced by regional or country variations in regulations. Additional transportation system information can be obtained through an authorized sales or customer service representative. It is the responsibility of the transporting organization to follow all applicable laws, regulations and rules relating to the transportation of the material. 15. REGULATORY INFORMATION Workplace Classification This product is not classified as hazardous according to Singapore Standards, Act and Regulations. : Page 7 of 8

8 16. OTHER INFORMATION Revision Identification Number: / 1897 / Issue Date: 03/04/2015 / Version: 2.0 Most recent revision(s) are noted by the bold, double bars in left-hand margin throughout this document. Information Source and References This SDS is prepared by Product Regulatory Services and Hazard Communications Groups from information supplied by internal references within our company. ROHM AND HAAS SINGAPORE (PTE) LTD urges each customer or recipient of this (M)SDS to study it carefully and consult appropriate expertise, as necessary or appropriate, to become aware of and understand the data contained in this (M)SDS and any hazards associated with the product. The information herein is provided in good faith and believed to be accurate as of the effective date shown above. However, no warranty, express or implied, is given. Regulatory requirements are subject to change and may differ between various locations. It is the buyer's/user's responsibility to ensure that his activities comply with all federal, state, provincial or local laws. The information presented here pertains only to the product as shipped. Since conditions for use of the product are not under the control of the manufacturer, it is the buyer's/user's duty to determine the conditions necessary for the safe use of this product. Due to the proliferation of sources for information such as manufacturerspecific (M)SDSs, we are not and cannot be responsible for (M)SDSs obtained from any source other than ourselves. If you have obtained an (M)SDS from another source or if you are not sure that the (M)SDS you have is current, please contact us for the most current version. Page 8 of 8