MATERIAL SAFETY DATA SHEET

Transcription

1 Page 1 of 5 MATERIAL SAFETY DATA SHEET 1. PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME : ARON OXETANE OXT-101(OXA) GENERAL USE : UV-curable Resin MANUFACTURER : Company Name : TOA GOSEI CO.,LTD. Address : , Nishi Shimbashi, Minato-ku, Tokyo, JAPAN Telephone Number : EMERGENCY TELEPHONE NUMBERS : Importer : Producer : 2. COMPOSITION / INFORMATION ON INGREDIENTS CHEMICAL NAME : 3-Ethyl-3-hydroxymethyloxetane CHEMICAL FORMULA : C6H12O2 STRUCTURAL FORMULA : OH O COMPOSITION : 98% up CAS NUMBER : EC NUMBER : (EINECS) TSCA INVENTORY : included 3. HAZARDS IDENTIFICATION HMIS RATING HEALTH : 1 FLAMMABILITY : 1 PHYSICAL HAZARD : 2 PERSONAL PROTECTION : B

2 Page 2 of 5 HUMAN HEALTH HAZARDS : Irritating to eyes. SAFETY HAZARDS : It may polymerize by contact with acid. ENVIRONMENTAL HAZARDS : Not available 4. FIRST AID MEASURES INHALATION : In case of exposure to high content of vapor / mists, let a sufferer move to outdoors and inhale fresh air. Give artificial respiration if not breathing. Get medical attention. SKIN CONTACT : In case of contact with skin, wash with soap and water fully. Remove contaminated clothing and shoes, wash these wears. Get medical attention if irritation persists after washing. EYE CONTACT : For eye, immediately flush with plenty of water for at least 15 minutes. Get medical attention. INGESTION : If swallowed, and if conscious, induce vomiting to give lot of water and get medical attention. If no conscious, never give anything by mouth and immediately get medical attention. 5. FIRE FIGHTING MEASURES EXTINGUISHING MEDIA Foam, carbon dioxide, dry chemical, dry sand, water spray SPECIAL FIRE FIGHTING PROCEDURES For initial stage, carbon dioxide, dry sand, dry chemical or water spray is available. For advanced stage, foam is available. In case of flowing out, dam up it and keep container away from fire. If the container is immovable, take contents to another tank. SPECIFIC HAZARDS Hazardous materials can generate in case of imperfect combustion or at high temperature. There is much possibility of explosion if contents undergo heating at a closed system. PROTECTIVE EQUIPMENT Full protective clothing and self-contained breathing apparatus. 6. ACCIDENTAL RELEASE MEASURES STEP TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED : Absorb with inert materials (sand etc.) Sweep or scoop up and put in disposal containers. Prevent liquid from entering sewers, watercourses, or lower spaces.

3 Page 3 of 5 7. HANDLING AND STORAGE PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING : When using this substance: (i) Avoid contact with eyes, skin and clothing. Avoid breathing vapor. (ii) Use skin protection. Wash thoroughly after handling. Use with adequate ventilation system. Check for peroxides prior to distillation. Keep in tightly container. Store in a cool, dry, well-ventilated, flammable liquid storage area or cabinet. 8. PERSONAL PROTECTION / EXPOSURE CONTROLS RESPIRATORY PROTECTION : None required in normal use, use air supplied mask if used in confined area. VENTILATION LOCAL EXHAUST : The use of local exhaust ventilation is recommended to control emissions near the source. PROTECTIVE GLOVES : Butyl rubber gloves. Nitrile gloves. EYE PROTECTION : Goggles or side-shield spectacles. OTHER PROTECTIVE CLOTHING OR EQUIPMENT : Eye bath, washing facilities and nonelectric shoes. 9. PHYSICAL AND CHEMICAL PROPERTIES MOLECULAR WEIGHT : APPEARANCE : Clear liquid PHYSICAL STATE : Liquid ODOR : Faint odour BOILING POINT : 105 (0.93kPa) MELTING POINT : < -37 SPECIFIC GRAVITY (H2O=1) : 1.02(20 ) VAPOR PRESSURE : 2.0Pa(20 ) SOLUBILITY IN WATER : Easily soluble in cold water and hot water. SOLUBILITY : Soluble in methanol, acetone. EVAPORATION RATE : Not available FLASH POINT : 110 (OPEN CUP) AUTO-IGNITION TEMP. : Not available VISCOSITY : mpa s(25 ) EXPLOSIVE PROPERTIES : Predicted negative

4 Page 4 of STABILITY AND REACTIVITY CHEMICAL STABILITY : This product is considered as a stable material under normal and anticipated storage and handling conditions. May form explosive peroxides on exposure to air. CONDITIONS TO AVOID : Heat, light, impact, friction, sparks, and electrostatic charges. MATERIALS TO AVOID : Strong oxidizing agents, acidic compounds. HAZARDOUS DECOMPOSITION : Carbon monoxide, Carbon dioxide HAZARDOUS POLYMERIZATION : It may polymerize by contact with acid. 11. TOXICOLOGICAL INFORMATION ACUTE TOXICITY : LD50(oral-rat) >2,000mg/kg SUBACUTE TOXICITY : Not available SKIN IRRITATION : Primary Irritation Index (P.I.I.) is 0.2 EYE IRRITATION : Irritating to eyes SENSITIZATION : Non-sensitizer MUTAGENIC EFFECTS : Ames test: Negative SIGNS AND SYMPZTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. 12. ECOLOGICAL INFORMATION ECOLOGICAL EFFECTS : 28-Day Biodegradation Study: BOD = 37mg O2/g Bioaccumulative potential: log Pow < 1 Bioconcentration Study with Corp: Not available Acute toxicity for fish: Not available Acute toxicity for daphnia: Not available Growth inhibition test of algae: Not available 13. DISPOSAL INFORMATION WASTE DISPOSAL METHOD : Incineration is recommended. (Dispose in accordance with all applicable federal, state and local environmental regulations. Do not dump this product into sewers, on the ground or into any body of water.)

5 Page 5 of TRANSPORT INFORMATION TRANSPORTATION INFORMATION : US DEPARTMENT OF TRANSPORTATION (DOT) Hazardous Materials : SEA TRANSPORT IMDG Class: Packing Group (PG) : UN Number : Proper Shipping Name : Marine Pollutant : AIR TRANSPORT ICAO/IATA Class: Packing Group (PG) : UN Number : Proper Shipping Name : 15. REGULATORY INFORMATION REGULATORY INFORMATION : TSCA inventory : included 16. OTHER INFORHATION OTHER INFORMATION : To the best of our knowledge, the information contained herein is accurate. However, neither Toagosei Co., Ltd. nor any of its subsidiaries any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards which exist.