TIGFAC160: TEMPILINK ETO BLU/BRN 160

Transcription

1 Date of issue: 05/05/2015 Version: 1.0 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form : Mixture Trade name : TIGFAC160: TEMPILINK ETO BLU/BRN Relevant identified uses of the substance or mixture and uses advised against Use of the substance/mixture : Ink Details of the supplier of the safety data sheet LA-CO Industries, Inc Pratt Boulevard Elk Grove Village, IL Phone: (847) Fax: (847) customer_service@laco.com 1.4. Emergency telephone number Emergency number : 24-hour emergency: CHEMTREC- U.S. : International: SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification in accordance with the Globally Harmonized Standard Flam. Liq. 2 H225 Eye Dam. 1 H318 STOT SE 3 H336 Full text of H-phrases: see section Label elements GHS-US labelling Hazard pictograms (GHS-US) : Signal word (GHS-US) Hazard statements (GHS-US) : Danger GHS02 GHS05 GHS07 : H225 - Highly flammable liquid and vapour H318 - Causes serious eye damage H336 - May cause drowsiness or dizziness Precautionary statements (GHS-US) : P210 - Keep away from open flames, sparks. - No smoking P233 - Keep container tightly closed P240 - Ground/bond container and receiving equipment P241 - Use explosion-proof electrical, lighting, ventilating equipment P242 - Use only non-sparking tools P243 - Take precautionary measures against static discharge P261 - Avoid breathing mist, vapours P271 - Use only outdoors or in a well-ventilated area P280 - Wear eye protection, protective gloves P303+P361+P353 - If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower P304+P340 - If inhaled: Remove person to fresh air and keep comfortable for breathing P305+P351+P338 - If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P310 - Immediately call a doctor P370+P378 - In case of fire: Use carbon dioxide (CO2), dry extinguishing powder, foam to extinguish P403+P233 - Store in a well-ventilated place. Keep container tightly closed P403+P235 - Store in a well-ventilated place. Keep cool P405 - Store locked up 05/05/2015 EN (English) SDS Ref.: LACO /1

2 2.3. Other hazards P501 - Dispose of contents/container to an authorised waste collection point 2.4 Unknown acute toxicity (GHS-US) 2.6 percent of the mixture consists of ingredient(s) of unknown acute toxicity (Oral) 2.6 percent of the mixture consists of ingredient(s) of unknown acute toxicity (Dermal) 2.6 percent of the mixture consists of ingredient(s) of unknown acute toxicity (Inhalation (Dust/Mist)) SECTION 3: Composition/information on ingredients 3.1. Substance 3.2. Mixture Name Product identifier % (w/w) GHS-US classification propyl acetate (CAS No) Flam. Liq. 2, H225 Eye Irrit. 2A, H319 STOT SE 3, H336 propan-1-ol (CAS No) Flam. Liq. 2, H225 Eye Dam. 1, H318 STOT SE 3, H336 1-Methoxy-2-propanol (CAS No) Flam. Liq. 3, H226 STOT SE 3, H336 nicotinamide (CAS No) Eye Irrit. 2A, H319 Isopropanol (CAS No) Flam. Liq. 2, H225 Eye Irrit. 2A, H319 STOT SE 3, H336 Full text of H-phrases: see section 16 SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures general First-aid measures after inhalation First-aid measures after skin contact First-aid measures after eye contact First-aid measures after ingestion : Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible). : Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/physician if you feel unwell. : Rinse skin with water/shower. Remove/Take off immediately all contaminated clothing. Repeated exposure may cause skin dryness or cracking. : Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. : Do NOT induce vomiting. Call a POISON CENTER or doctor/physician if you feel unwell Most important symptoms and effects, both acute and delayed Symptoms/injuries after inhalation : May cause drowsiness or dizziness. Symptoms/injuries after eye contact : Causes serious eye damage Indication of any immediate medical attention and special treatment needed All treatments should be based on observed signs and symptoms of distress in the patient. SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media Unsuitable extinguishing media : Carbon dioxide. Dry powder. Foam. : None known Special hazards arising from the substance or mixture Fire hazard : Highly flammable liquid and vapour. Explosion hazard : May form flammable/explosive vapour-air mixture. Reactivity : No dangerous reactions known Advice for firefighters Firefighting instructions Protection during firefighting : Exercise caution when fighting any chemical fire. Do not allow run-off from fire fighting to enter drains or water courses. Cool adjacent structures and containers with water spray to protect and prevent ignition. : Do not enter fire area without proper protective equipment, including respiratory protection. Wear a self contained breathing apparatus. Wear fire/flame resistant/retardant clothing. 05/05/2015 EN (English) SDS Ref.: LACO /1

3 SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures General measures : Remove ignition sources. Use special care to avoid static electric charges. No open flames. No smoking. Avoid all eye and skin contact and do not breathe vapour and mist For non-emergency personnel Protective equipment Emergency procedures For emergency responders Protective equipment Emergency procedures : Chemical goggles or safety glasses. Wear suitable gloves. : Evacuate unnecessary personnel. : Chemical goggles or safety glasses. Wear suitable gloves. : Ventilate area. Stop leak if safe to do so Environmental precautions Avoid release to the environment Methods and material for containment and cleaning up For containment Methods for cleaning up : Absorb and/or contain spill with inert material, then place in suitable container. : Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Take up in non-combustible absorbent material and shove into container for disposal Reference to other sections Section 13: disposal information. Section 7: safe handling. Section 8: personal protective equipment. SECTION 7: Handling and storage 7.1. Precautions for safe handling Additional hazards when processed Precautions for safe handling Hygiene measures : Handle empty containers with care because residual vapours are flammable. : No open flames. No smoking. Use only non-sparking tools. Avoid all eye and skin contact and do not breathe vapour and mist. Use only outdoors or in a well-ventilated area. : Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Do not eat, drink or smoke when using this product Conditions for safe storage, including any incompatibilities Technical measures Storage conditions Incompatible products Incompatible materials Heat and ignition sources Prohibitions on mixed storage Storage area : Proper grounding procedures to avoid static electricity should be followed. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/ equipment. : Keep container closed when not in use. Keep in fireproof place. : Alkali. Strong oxidizers. : Heat sources. Direct sunlight. : Keep away from heat, sparks and flame. : Incompatible materials. : Store in dry, cool, well-ventilated area Specific end use(s) Ink. SECTION 8: Exposure controls/personal protection 8.1. Control parameters TIGFAC160: TEMPILINK ETO BLU/BRN 160 ACGIH OSHA ACGIH ACGIH TWA (mg/m³) 490 mg/m³ ACGIH ACGIH TWA (ppm) 200 ppm ACGIH ACGIH STEL (mg/m³) 960 mg/m³ ACGIH ACGIH STEL (ppm) 400 ppm ACGIH Remark (ACGIH) Eye & URT irr; CNS impair OSHA OSHA PEL (TWA) (mg/m³) 980 mg/m³ 05/05/2015 EN (English) SDS Ref.: LACO /1

4 OSHA OSHA PEL (TWA) (ppm) 400 ppm Canada (Quebec) VECD (mg/m³) 1230 mg/m³ Canada (Quebec) VECD (ppm) 500 ppm Canada (Quebec) VEMP (mg/m³) 983 mg/m³ Canada (Quebec) VEMP (ppm) 400 ppm ACGIH ACGIH TWA (mg/m³) 369 mg/m³ ACGIH ACGIH TWA (ppm) 50 ppm ACGIH ACGIH STEL (mg/m³) 553 mg/m³ ACGIH ACGIH STEL (ppm) 100 ppm ACGIH Remark (ACGIH) Eye irr; CNS impair; A4 OSHA Canada (Quebec) VECD (mg/m³) 553 mg/m³ Canada (Quebec) VECD (ppm) 150 ppm Canada (Quebec) VEMP (mg/m³) 369 mg/m³ Canada (Quebec) VEMP (ppm) 100 ppm ACGIH ACGIH TWA (mg/m³) 835 mg/m³ ACGIH ACGIH TWA (ppm) 200 ppm ACGIH ACGIH STEL (mg/m³) 1040 mg/m³ ACGIH ACGIH STEL (ppm) 250 ppm ACGIH Remark (ACGIH) Eye & URT irr OSHA OSHA PEL (TWA) (mg/m³) 840 mg/m³ OSHA OSHA PEL (TWA) (ppm) 200 ppm Canada (Quebec) VECD (mg/m³) 1040 mg/m³ Canada (Quebec) VECD (ppm) 250 ppm Canada (Quebec) VEMP (mg/m³) 835 mg/m³ Canada (Quebec) VEMP (ppm) 200 ppm ACGIH ACGIH TWA (ppm) 100 ppm ACGIH Remark (ACGIH) Eye & URT irr OSHA OSHA PEL (TWA) (mg/m³) 500 mg/m³ OSHA OSHA PEL (TWA) (ppm) 200 ppm Canada (Quebec) VECD (mg/m³) 615 mg/m³ Canada (Quebec) VECD (ppm) 250 ppm Canada (Quebec) VEMP (mg/m³) 492 mg/m³ Canada (Quebec) VEMP (ppm) 200 ppm Canada (Quebec) Notations and remarks (Peau) ACGIH OSHA 8.2. Exposure controls Appropriate engineering controls Personal protective equipment Hand protection Eye protection Respiratory protection : Avoid creating mist or spray. Avoid splashing. Provide local exhaust ventilation of closed transfer systems to minimize exposures. : Avoid all unnecessary exposure. : It is a good industrial hygiene practice to minimize skin contact. Wear suitable gloves. rubber. : Chemical goggles or safety glasses. : Where exposure through inhalation may occur from use, respiratory protection equipment is recommended. Use an approved respirator equipped with oil/mist cartridges. 05/05/2015 EN (English) SDS Ref.: LACO /1

5 SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Liquid Colour Odour Odour threshold ph Relative evaporation rate (butyl acetate=1) Melting point Freezing point Boiling point : 82 C Flash point : 2 C Auto-ignition temperature Decomposition temperature Flammability (solid, gas) Vapour pressure Relative vapour density at 20 C Relative density Solubility Log Pow Log Kow Viscosity, kinematic Viscosity, dynamic Explosive properties Oxidising properties Explosive limits 9.2. Other information VOC content : 68.1% SECTION 10: Stability and reactivity Reactivity No dangerous reactions known Chemical stability Highly flammable liquid and vapour. May form flammable/explosive vapour-air mixture Possibility of hazardous reactions Hazardous polymerization will not occur Conditions to avoid Open flame. Direct sunlight. Keep away from sources of ignition Incompatible materials Alkali. Strong oxidizers Hazardous decomposition products Burning produces irritating, toxic and noxious fumes. Carbon oxides (CO, CO2). metallic oxides. May release flammable gases. SECTION 11: Toxicological information Information on toxicological effects Acute toxicity LD50 dermal rabbit LC50 inhalation rat (ppm) ATE CLP (oral) LD50 dermal rat 5840 mg/kg 16.4 ml/kg > ppm/4h mg/kg bodyweight 4016 mg/kg bodyweight > 2000 mg/kg bodyweight 05/05/2015 EN (English) SDS Ref.: LACO /1

6 LC50 inhalation rat (ppm) ATE CLP (oral) LD50 dermal rabbit LC50 inhalation rat (mg/l) ATE CLP (oral) ATE CLP (vapours) ATE CLP (dust,mist) LD50 dermal rabbit LC50 inhalation rat (mg/l) ATE CLP (oral) ATE CLP (dermal) LD50 dermal rabbit LC50 inhalation rat (mg/l) Skin corrosion/irritation Serious eye damage/irritation Respiratory or skin sensitisation Germ cell mutagenicity Carcinogenicity IARC group Reproductive toxicity Specific target organ toxicity (single exposure) Specific target organ toxicity (repeated exposure) > 7000 ppm 6 hr mg/kg bodyweight 8700 mg/kg > mg/kg 32 mg/l/4h mg/kg bodyweight mg/l/4h mg/l/4h 5400 mg/kg 4032 mg/kg > 33.8 mg/l/4h mg/kg bodyweight mg/kg bodyweight > 2500 mg/kg No mortality observed > 2000 mg/kg No mortality observed > 3.8 mg/l/4h No mortality observed : Causes serious eye damage. 3 - Not classifiable : May cause drowsiness or dizziness. Aspiration hazard Potential adverse human health effects and symptoms Symptoms/injuries after inhalation : May cause drowsiness or dizziness. Symptoms/injuries after eye contact : Causes serious eye damage. SECTION 12: Ecological information 12.1 Toxicity EC50 Daphnia 1 ErC50 (algae) EC50 Daphnia 1 EC50 Daphnia 1 EC50 Daphnia mg/l mg/l mg/l > 1000 mg/l 60 mg/l 96 h 91.5 mg/l 48 h 4555 mg/l 96 h 1000 mg/l 48 h > 1000 mg/l 96 h 1000 mg/l 24 h /05/2015 EN (English) SDS Ref.: LACO /1

7 Biodegradation Biodegradation Biodegradation Biodegradation 96 % 28 d 62 % 5 d 75 % 20 d 96 % 14 d Bioaccumulative potential Bioaccumulative potential Bioaccumulative potential Not expected to bioaccumulate. Not expected to bioaccumulate. Log Pow 1.23 BCF fish Log Pow 0.2 Log Pow Mobility in soil No additional information available Other adverse effects No additional information available SECTION 13: Disposal considerations 13.1 Waste treatment methods Sewage disposal recommendations Waste disposal recommendations Additional information : Do not dispose of waste into sewer. : Dispose in a safe manner in accordance with local/national regulations. : Handle empty containers with care because residual vapours are flammable. SECTION 14: Transport information In accordance with DOT and TDG Transport document description UN-No.(DOT) Proper Shipping Name (DOT) Transport hazard class(es) (DOT) Packing group (DOT) ADR Transport document description Proper Shipping Name (ADR) Packing group (ADR) Class (ADR) : UN1210 Printing ink, flammable (including printing ink thinning or reducing compound), flammable, 3, II : UN1210 : Printing ink, flammable (including printing ink thinning or reducing compound), flammable : 3 - Flammable liquid : II - Medium Danger : UN 1210 PRINTING INK, 3, II, (D/E) : PRINTING INK : II : 3 - Flammable liquid Transport by sea UN-No. (IMDG) : UN 1210 Proper Shipping Name (IMDG) : PRINTING INK Class (IMDG) : 3 - Flammable liquids Packing group (IMDG) : II 05/05/2015 EN (English) SDS Ref.: LACO /1

8 Air transport UN-No. (IATA) : UN 1210 Proper Shipping Name (IATA) Class (IATA) Packing group (IATA) : Printing ink : 3 - Flammable Liquids : II SECTION 15: Regulatory information US Federal regulations SARA Section 311/312 Hazard Classes Fire hazard International regulations CANADA EU-Regulations National regulations TIGFAC160: TEMPILINK ETO BLU/BRN 160 All components are listed on the EEC inventory European Inventory of Existing Commercial Chemical Substances (EINECS). All ingredients are listed in the Toxic Substances Control Act (TSCA). All ingredients are listed on the Canadian Domestic Substances List (DSL) or Non-Domestic Substances List (NDSL) US State regulations U.S. - Minnesota - Hazardous Substance List U.S. - New Jersey - Right to Know Hazardous Substance List 05/05/2015 EN (English) SDS Ref.: LACO /1

9 U.S. - Minnesota - Hazardous Substance List U.S. - New Jersey - Right to Know Hazardous Substance List U.S. - New York - Right to Know List of Hazardous Chemicals U.S. - New Jersey - Right to Know Hazardous Substance List U.S. - Minnesota - Hazardous Substance List U.S. - New Jersey - Right to Know Hazardous Substance List U.S. - New York - Right to Know List of Hazardous Chemicals SECTION 16: Other information Indication of changes Data sources Abbreviations and acronyms Other information : Original Document. : ACGIH (American Conference of Governement Industrial Hygienists). European Chemicals Agency (ECHA) C&L Inventory database. Accessed at Krister Forsberg and S.Z. Mansdorf, "Quick Selection Guide to Chemical Protective Clothing", Fifth Edition. National Fire Protection Association. Fire Protection Guide to Hazardous Materials; 10th edition. OSHA 29CFR Hazard Communication Standard. TSCA Chemical Substance Inventory. Accessed at : ATE: Acute Toxicity Estimate. CAS (Chemical Abstracts Service) number. CLP: Classification, Labelling, Packaging. EC50: Environmental Concentration associated with a response by 50% of the test population. GHS: Globally Harmonized System (of Classification and Labeling of Chemicals). LD50: Lethal Dose for 50% of the test population. OSHA: Occupational Safety & Health Administration. PBT: Persistent, Bioaccumulative, Toxic. TWA: Time Weight Average. TSCA: Toxic Substances Control Act. : None. NFPA health hazard NFPA fire hazard NFPA reactivity : 2 - Intense or continued exposure could cause temporary incapacitation or possible residual injury unless prompt medical attention is given. : 4 - Will rapidly or completely vaporize at normal pressure and temperature, or is readily dispersed in air and will burn readily. : 0 - Normally stable, even under fire exposure conditions, and not reactive with water. Full text of H-phrases: Eye Dam. 1 Serious eye damage/eye irritation, Category Eye Irrit. 2A Serious eye damage/eye irritation, Category 2A Flam. Liq. 2 Flammable liquids, Category Flam. Liq. 3 Flammable liquids, Category STOT SE 3 Specific target organ toxicity Single exposure, Category 3, Narcosis H225 Highly flammable liquid and vapour H226 Flammable liquid and vapour H318 Causes serious eye damage H319 Causes serious eye irritation H336 May cause drowsiness or dizziness SDS Prepared by: The Redstone Group, LLC 6077 Frantz Rd. Suite 206 Dublin, OH USA T LACO NA GHS SDS This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product 05/05/2015 EN (English) SDS Ref.: LACO /1