: Tempilink Sterilization Process Indicating Ink ETO Blue/Brown 564A

Transcription

1 Date of issue: 03/09/2015 Version: 1.0 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form Trade name : Mixture : Tempilink Sterilization Process Indicating Ink ETO Blue/Brown 1.2. Relevant identified uses of the substance or mixture and uses advised against Use of the substance/mixture : Ink Details of the supplier of the safety data sheet LA-CO Industries, Inc Pratt Boulevard Elk Grove Village, IL Phone: (847) Fax: (847) customer_service@laco.com 1.4. Emergency telephone number Emergency number : 24-hour emergency: CHEMTREC- U.S. : International: SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification in accordance with the Globally Harmonized Standard Eye Irrit. 2A H319 Full text of H-phrases: see section Label elements GHS-US labelling Hazard pictograms (GHS-US) : Signal word (GHS-US) Hazard statements (GHS-US) Precautionary statements (GHS-US) GHS07 : Warning : H319 - Causes serious eye irritation : P264 - Wash hands thoroughly after handling P280 - Wear eye protection, protective gloves P305+P351+P338 - If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P337+P313 - If eye irritation persists: Get medical advice/attention 2.3. Other hazards SECTION 3: Composition/information on ingredients 3.1. Substance 3.2. Mixture Name Product identifier % (w/w) GHS-US classification nicotinamide (CAS No) Eye Irrit. 2A, H319 isoniazid (CAS No) Acute Tox. 4 (Oral), H302 Full text of H-phrases: see section 16 09/03/2015 EN (English) SDS Ref.: LACO /7

2 SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures general First-aid measures after inhalation First-aid measures after skin contact First-aid measures after eye contact First-aid measures after ingestion : Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible). : Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/physician if you feel unwell. : Wash with plenty of soap and water. : Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. : Do NOT induce vomiting. Call a POISON CENTER or doctor/physician if you feel unwell Most important symptoms and effects, both acute and delayed Symptoms/injuries after eye contact : Causes serious eye irritation Indication of any immediate medical attention and special treatment needed All treatments should be based on observed signs and symptoms of distress in the patient. SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media Unsuitable extinguishing media : Carbon dioxide. Dry powder. Foam. : None known Special hazards arising from the substance or mixture Fire hazard : No particular fire or explosion hazard. Reactivity : No dangerous reactions known Advice for firefighters Firefighting instructions Protection during firefighting : Exercise caution when fighting any chemical fire. Do not allow run-off from fire fighting to enter drains or water courses. Cool adjacent structures and containers with water spray to protect and prevent ignition. : Do not enter fire area without proper protective equipment, including respiratory protection. Wear a self contained breathing apparatus. Wear fire/flame resistant/retardant clothing. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures General measures : Avoid contact with skin and eyes For non-emergency personnel Protective equipment Emergency procedures For emergency responders Protective equipment Emergency procedures : Chemical goggles or safety glasses. Wear suitable gloves. : Evacuate unnecessary personnel. : Chemical goggles or safety glasses. Wear suitable gloves. : Ventilate area. Stop leak if safe to do so Environmental precautions Avoid release to the environment. Do not discharge into drains or the environment Methods and material for containment and cleaning up For containment Methods for cleaning up 6.4. Reference to other sections : Absorb and/or contain spill with inert material, then place in suitable container. : Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Take up in non-combustible absorbent material and shove into container for disposal. Section 13: disposal information. Section 7: safe handling. Section 8: personal protective equipment. 09/03/2015 EN (English) SDS Ref.: LACO /7

3 SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling Hygiene measures : Avoid contact with skin and eyes. : Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Do not eat, drink or smoke when using this product Conditions for safe storage, including any incompatibilities Storage conditions Incompatible products Prohibitions on mixed storage : Keep container tightly closed. Keep away from combustible material. Keep only in the original container in a cool well ventilated place. : Alkali. Strong oxidizers. : Incompatible materials Specific end use(s) Ink. SECTION 8: Exposure controls/personal protection 8.1. Control parameters Tempilink Sterilization Process Indicating Ink ETO Blue/Brown ACGIH OSHA ACGIH OSHA ACGIH OSHA 8.2. Exposure controls Appropriate engineering controls Personal protective equipment Hand protection Eye protection Respiratory protection Other information : Avoid creating mist or spray. Avoid splashing. Provide local exhaust ventilation of closed transfer systems to minimize exposures. : Avoid all unnecessary exposure. : It is a good industrial hygiene practice to minimize skin contact. Wear suitable gloves. rubber. : Eye protection should only be necessary where liquid could be splashed or sprayed. : Where exposure through inhalation may occur from use, respiratory protection equipment is recommended. Use an approved respirator equipped with oil/mist cartridges. : Do not eat, drink or smoke when using this product. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Liquid Appearance : Opaque liquid. Colour : Blue. brown. Odour : Solvent. Odour threshold ph Relative evaporation rate (butyl acetate=1) Melting point Freezing point Boiling point : 100 C Flash point : > 93.3 C Auto-ignition temperature Decomposition temperature Flammability (solid, gas) 09/03/2015 EN (English) SDS Ref.: LACO /7

4 Vapour pressure Relative vapour density at 20 C Relative density Solubility Log Pow Log Kow Viscosity, kinematic Viscosity, dynamic Explosive properties Oxidising properties Explosive limits 9.2. Other information VOC content : 0.5 % SECTION 10: Stability and reactivity Reactivity No dangerous reactions known Chemical stability Stable under normal conditions Possibility of hazardous reactions Hazardous polymerization will not occur Conditions to avoid Avoid excessive heat or cold Incompatible materials Alkali. Strong oxidizers Hazardous decomposition products Burning produces irritating, toxic and noxious fumes. Carbon oxides. metallic oxides. SECTION 11: Toxicological information Information on toxicological effects Acute toxicity LD50 oral rat ATE CLP (oral) LD50 oral rat LD50 dermal rabbit LC50 inhalation rat (mg/l) Skin corrosion/irritation Serious eye damage/irritation Respiratory or skin sensitisation Germ cell mutagenicity Carcinogenicity Reproductive toxicity Specific target organ toxicity (single exposure) Specific target organ toxicity (repeated exposure) 1250 mg/kg mg/kg bodyweight > 2500 mg/kg No mortality observed > 2000 mg/kg No mortality observed > 3.8 mg/l/4h No mortality observed : Causes serious eye irritation.. Aspiration hazard Potential adverse human health effects and symptoms Symptoms/injuries after eye contact : Causes serious eye irritation. Likely routes of exposure : Skin and eye contact;inhalation 09/03/2015 EN (English) SDS Ref.: LACO /7

5 SECTION 12: Ecological information 12.1 Toxicity LC50 fish 1 EC50 Daphnia 1 > 1000 mg/l 96 h 1000 mg/l 24 h Persistence and degradability Persistence and degradability Biodegradation Readily biodegradable. 96 % 14 d Bioaccumulative potential Log Pow Mobility in soil Other adverse effects SECTION 13: Disposal considerations 13.1 Waste treatment methods Sewage disposal recommendations Waste disposal recommendations : Do not dispose of waste into sewer. : Dispose in a safe manner in accordance with local/national regulations. SECTION 14: Transport information In accordance with DOT and TDG Not considered a dangerous good for transport regulations Proper Shipping Name (ADR) : Transport by sea Air transport SECTION 15: Regulatory information US Federal regulations Listed on the United States TSCA (Toxic Substances Control Act) inventory Listed on the United States TSCA (Toxic Substances Control Act) inventory International regulations CANADA Listed on the Canadian DSL (Domestic Substances List) inventory. Listed on the Canadian DSL (Domestic Substances List) inventory. EU-Regulations Listed on the EEC inventory EINECS (European Inventory of Existing Commercial Chemical Substances) 09/03/2015 EN (English) SDS Ref.: LACO /7

6 Listed on the EEC inventory EINECS (European Inventory of Existing Commercial Chemical Substances) National regulations Tempilink Sterilization Process Indicating Ink ETO Blue/Brown All components are listed on the EEC inventory European Inventory of Existing Commercial Chemical Substances (EINECS). All ingredients are listed in the Toxic Substances Control Act (TSCA). All ingredients are listed on the Canadian Domestic Substances List (DSL) or Non-Domestic Substances List (NDSL) US State regulations SECTION 16: Other information Indication of changes : Original Document. Data sources : ACGIH Abbreviations and acronyms Other information Canadian Centre for Occupational Health and Safety. Accessed at: ESIS (European chemincal Substances Information System; accessed at: European Chemicals Agency (ECHA) Registered Substances list. Accessed at Krister Forsberg and S.Z. Mansdorf, "Quick Selection Guide to Chemical Protective Clothing", Fifth Edition. National Fire Protection Association; Fire Protection Guide to Hazardous Materials; 10th edition. OSHA 29CFR Hazard Communication Standard. REGULATION (EC) No 1272/2008 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL of 16 December 2008 on classification, labelling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006. TSCA Chemical Substance Inventory. Accessed at : ACGIH (American Conference of Governement Industrial Hygienists). ATE: Acute Toxicity Estimate. CAS (Chemical Abstracts Service) number. CLP: Classification, Labelling, Packaging. EC50: Environmental Concentration associated with a response by 50% of the test population. GHS: Globally Harmonized System (of Classification and Labeling of Chemicals). LD50: Lethal Dose for 50% of the test population. OSHA: Occupational Safety & Health Administration. PBT: Persistent, Bioaccumulative, Toxic. STEL: Short Term Exposure Limits. TSCA: Toxic Substances Control Act. TWA: Time Weight Average. : None. NFPA health hazard NFPA fire hazard NFPA reactivity : 1 - Exposure could cause irritation but only minor residual injury even if no treatment is given. : 1 - Must be preheated before ignition can occur. : 0 - Normally stable, even under fire exposure conditions, and not reactive with water. Full text of H-phrases: Acute Tox. 4 (Oral) Acute toxicity (oral), Category Eye Irrit. 2A Serious eye damage/eye irritation, Category 2A H302 Harmful if swallowed H319 Causes serious eye irritation SDS Prepared by: The Redstone Group, LLC 09/03/2015 EN (English) SDS Ref.: LACO /7

7 6397 Emerald Pkwy. Suite 200 Dublin, OH USA T LACO NA GHS SDS This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product 09/03/2015 EN (English) SDS Ref.: LACO /7