SAFETY DATA SHEET NITOSEAL PU12 CURING AGENT

Transcription

1 Revision Date 10 September 2014 Revision 2 SAFETY DATA SHEET SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING 1.1. Product identifier Product name Product No. A UK Relevant identified uses of the substance or mixture and uses advised against Identified uses Hardener component for two-part isocyanate-based sealant 1.3. Details of the supplier of the safety data sheet Supplier FOSROC Limited Drayton Manor Business Park Coleshill Road Tamworth Staffordshire B78 3XN Tel. +44 (0) Fax. +44 (0) enquiryuk@fosroc.com 1.4. Emergency telephone number +44 (0) (08.30 to 17.00hrs Mon - Thu; to 16.00hrs Fri) SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the substance or mixture Classification (1999/45/EEC) Human health Xn;R22. C;R34. R43. N;R51/53. Corrosive to skin and eyes. The product contains a sensitising substance which may provoke an allergic reaction among sensitive individuals. Contains a substance/a group of substances which may impair fertility. Contains a substance/a group of substances which may cause harm to the unborn child. Environment The product contains a substance which is very toxic to aquatic organisms and which may cause long term adverse effects in the aquatic environment Label elements Contains Labelling ISOPHORONEDIAMINE ORTHO TOLYL BIGUANIDE Risk Phrases Corrosive Harmful Dangerous for the environment R22 R34 R43 Harmful if swallowed. Causes burns. May cause sensitisation by skin contact. 1 / 9

2 Safety Phrases R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S25 S26 S36/37/39 S45 S57 S60 S61 Avoid contact with eyes. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show label where possible). Use appropriate containment to avoid environmental contamination. This material and its container must be disposed of as hazardous waste. Avoid release to the environment. Refer to special instructions/safety data sheets Other hazards Not Classified as PBT/vPvB by current EU criteria. SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.2. Mixtures CALCIUM CARBONATE (STEARATE COATED) 30-60% CAS-No.: EC No.: Not classified. Not classified. BENZYL ALCOHOL 10-30% CAS-No.: EC No.: Registration Number: xxxx Acute Tox. 4 - H302 Acute Tox. 4 - H332 Xn;R20/22 ISOPHORONEDIAMINE 10-30% CAS-No.: EC No.: Registration Number: xxxx Acute Tox. 4 - H302 Acute Tox. 4 - H312 Skin Corr. 1B - H314 Skin Sens. 1 - H317 Aquatic Chronic 3 - H412 C;R34 Xn;R21/22 R43 R52/53 ORTHO TOLYL BIGUANIDE 5-10% CAS-No.: EC No.: Eye Dam. 1 - H318 Skin Sens. 1 - H317 Xi;R41. R43. 2 / 9

3 NONYLPHENOL < 1% CAS-No.: EC No.: Acute Tox. 4 - H302 Skin Corr. 1B - H314 Repr. 2 - H361fd Aquatic Acute 1 - H400 Aquatic Chronic 1 - H410 Repr. Cat. 3;R62,R63 C;R34 Xn;R22 N;R50/53 The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16. SECTION 4: FIRST AID MEASURES 4.1. Description of first aid measures Inhalation Move the exposed person to fresh air at once. Rinse nose and mouth with water. NEVER MAKE AN UNCONSCIOUS PERSON VOMIT OR DRINK FLUIDS! Keep the affected person warm and at rest. Get prompt medical attention. Ingestion DO NOT INDUCE VOMITING! NEVER MAKE AN UNCONSCIOUS PERSON VOMIT OR DRINK FLUIDS! Rinse mouth thoroughly. Provide rest, warmth and fresh air. Get medical attention immediately! Skin contact Remove affected person from source of contamination. Remove contaminated clothing immediately and wash skin with soap and water. Get medical attention promptly if symptoms occur after washing. Eye contact Remove victim immediately from source of exposure. Make sure to remove any contact lenses from the eyes before rinsing. Promptly wash eyes with plenty of water while lifting the eye lids. Continue to rinse for at least 15 minutes and get medical attention Most important symptoms and effects, both acute and delayed General information The severity of the symptoms described will vary dependant of the concentration and the length of exposure. Inhalation Upper respiratory irritation. Coughing, chest tightness, feeling of chest pressure. Ingestion May cause chemical burns in mouth and throat. May cause stomach pain or vomiting. Skin contact Skin irritation. Eye contact Irritating and may cause redness and pain. Profuse watering of the eyes Indication of any immediate medical attention and special treatment needed SECTION 5: FIREFIGHTING MEASURES 5.1. Extinguishing media Extinguishing media Extinguish with alcohol-resistant foam, carbon dioxide, dry powder or water fog. Unsuitable extinguishing media Do not use water jet as an extinguisher, as this will spread the fire Special hazards arising from the substance or mixture Hazardous combustion products In case of fire, toxic gases (CO, CO2, NOx) may be formed. Unusual Fire & Explosion Hazards No unusual fire or explosion hazards noted. 3 / 9

4 5.3. Advice for firefighters Special Fire Fighting Procedures Containers close to fire should be removed immediately or cooled with water. Keep run-off water out of sewers and water sources. Dike for water control. Protective equipment for fire-fighters Self contained breathing apparatus and full protective clothing must be worn in case of fire. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal precautions, protective equipment and emergency procedures Use protective gloves, goggles and suitable protective clothing. Do not breathe vapour Environmental precautions Do not discharge into drains, water courses or onto the ground. Contain spillages with sand, earth or any suitable adsorbent material Methods and material for containment and cleaning up Wear necessary protective equipment. Stop leak if possible without risk. Absorb in vermiculite, dry sand or earth and place into containers. Do not let washing down water contaminate ponds or waterways Reference to other sections For personal protection, see section 8. For waste disposal, see section 13. SECTION 7: HANDLING AND STORAGE 7.1. Precautions for safe handling Provide good ventilation. Avoid contact with skin and eyes. Avoid forming spray/aerosol mists. Do not use in confined spaces without adequate ventilation and/or respirator Conditions for safe storage, including any incompatibilities Store in tightly closed original container in a dry, cool and well-ventilated place. Keep in original container. Storage Class Corrosive storage Specific end use(s) The identified uses for this product are detailed in Section 1.2. SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control parameters Name STD TWA - 8 Hrs STEL - 15 Min Notes CALCIUM CARBONATE (STEARATE COATED) WEL 10 mg/m3 Inhal. Dust 4 mg/m3 Resp. Dust WEL = Workplace Exposure Limit. BENZYL ALCOHOL (CAS: ) DNEL Professional Dermal Long Term 9.5 mg/kg/day Professional Inhalation. Long Term 90 mg/m3 PNEC Freshwater 1 mg/l Marinewater 0.1 mg/l ISOPHORONEDIAMINE (CAS: ) PNEC Freshwater 0.06 mg/l Marinewater mg/l 8.2. Exposure controls 4 / 9

5 Protective equipment Process conditions Provide eyewash, quick drench. Engineering measures Provide adequate general and local exhaust ventilation. Respiratory equipment No specific recommendation made, but respiratory protection must be used if the general level exceeds the recommended occupational exposure limit. Hand protection Use protective gloves made of: Nitrile. Viton rubber (fluor rubber). Polyvinylidene chloride/polyethylene (PVD/PE). Eye protection Wear approved chemical safety goggles where eye exposure is reasonably probable. Hygiene measures Wash hands at the end of each work shift and before eating, smoking and using the toilet. Wash promptly with soap & water if skin becomes contaminated. Promptly remove any clothing that becomes wet. Skin protection Wear apron or protective clothing in case of contact. SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on basic physical and chemical properties Appearance Paste Colour Grey. Odour Amine. Musty (mouldy). Solubility Insoluble in water Initial boiling point and boiling >200 C range ( C) Relative density 1.46 at 20 C Vapour pressure 0.04 kpa ph-value, Conc. Solution approx. 12 Flash point ( C) 131 C Auto Ignition Temperature ( C) >400 C 9.2. Other information Not determined. SECTION 10: STABILITY AND REACTIVITY Reactivity No specific reactivity hazards associated with this product Chemical stability Stable under normal temperature conditions Possibility of hazardous reactions Reacts violently with strong oxidising substances. Hazardous Polymerisation Will not polymerise Conditions to avoid Avoid heat. 5 / 9

6 10.5. Incompatible materials Materials To Avoid Strong acids. Strong oxidising substances. Bases, alkalis (inorganic). Bases, alkalis (organic) Hazardous decomposition products Ammonia or amines. In case of fire, toxic gases (CO, CO2, NOx) may be formed. SECTION 11: TOXICOLOGICAL INFORMATION Information on toxicological effects Inhalation May cause irritation to the respiratory system. May cause sensitisation by inhalation. May cause respiratory allergy. Ingestion Causes burns. May cause chemical burns in mouth and throat. May cause stomach pain or vomiting. Skin contact May cause allergic contact eczema. Acts as a defatting agent on skin. May cause cracking of skin, and eczema. May cause sensitisation by skin contact. Causes burns. Harmful in contact with skin. Eye contact Extreme irritation of eyes and mucous membranes, including burning and tearing. Causes burns. Health Warnings May cause sensitisation by skin contact. Route of entry Inhalation. Ingestion. Skin and/or eye contact. Toxicological information on ingredients. BENZYL ALCOHOL (CAS: ) Acute toxicity: Acute Toxicity (Oral LD50) 1230 mg/kg Rat Acute Toxicity (Dermal LD50) 2000 mg/kg Rabbit ISOPHORONEDIAMINE (CAS: ) Acute toxicity: Acute Toxicity (Oral LD50) 1030 mg/kg Rat Acute Toxicity (Dermal LD50) 1840 mg/kg Rabbit NONYLPHENOL (CAS: ) Acute toxicity: Acute Toxicity (Oral LD50) < 2000 mg/kg Rat Acute Toxicity (Dermal LD50) 2031 mg/kg Rat SECTION 12: ECOLOGICAL INFORMATION 6 / 9

7 Ecotoxicity Dangerous for the environment if discharged into watercourses Toxicity Acute Fish Toxicity Ecotoxic to fish/daphnia/algae Ecological information on ingredients. Acute Toxicity - Fish LC50 48 hours 645 mg/l LC 50, 96 Hrs, Fish mg/l 110 EC 50, 48 Hrs, Daphnia, mg/l 23 IC 50, 72 Hrs, Algae, mg/l 50 LC 50, 96 Hrs, Fish mg/l EC 50, 48 Hrs, Daphnia, mg/l BENZYL ALCOHOL (CAS: ) ISOPHORONEDIAMINE (CAS: ) NONYLPHENOL (CAS: ) Persistence and degradability Degradability The product is not expected to be biodegradable Bioaccumulative potential Bioaccumulative potential No data available on bioaccumulation. Not expected to be bioaccumulative Ecological information on ingredients. Bioaccumulative potential May accumulate in soil and water systems. NONYLPHENOL (CAS: ) Mobility in soil Mobility: The product is insoluble in water and will sediment in water systems Results of PBT and vpvb assessment This product does not contain any PBT or vpvb substances Other adverse effects None known. SECTION 13: DISPOSAL CONSIDERATIONS General information Waste is classified as hazardous waste. Disposal to licensed waste disposal site in accordance with the local Waste Disposal Authority Waste treatment methods Dispose of waste and residues in accordance with local authority requirements. SECTION 14: TRANSPORT INFORMATION 7 / 9

8 14.1. UN number UN No. (ADR/RID/ADN) 2327 UN No. (IMDG) 2327 UN No. (ICAO) UN proper shipping name Proper Shipping Name TRIMETHYLHEXAMETHYLENEDIAMINES (NONYLPHENOL) Transport hazard class(es) ADR/RID/ADN Class 8 ADR/RID/ADN Class Class 8: Corrosive substances. ADR Label No. 8 IMDG Class 8 ICAO Class/Division 8 Transport Labels CORROSIVE Packing group ADR/RID/ADN Packing group IMDG Packing group ICAO Packing group III III III Environmental hazards Environmentally Hazardous Substance/Marine Pollutant Special precautions for user EMS Emergency Action Code F-A, S-B 2X Hazard No. (ADR) 80 Tunnel Restriction Code (E) Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code Not applicable. SECTION 15: REGULATORY INFORMATION Safety, health and environmental regulations/legislation specific for the substance or mixture 8 / 9

9 Uk Regulatory References The Control of Substances Hazardous to Health Regulations 2002 (S.I 2002 No. 2677) with amendments. Statutory Instruments The Chemicals (Hazard Information and Packaging for Supply) Regulations 2009 (S.I 2009 No. 716). Approved Code Of Practice Classification and Labelling of Substances and Preparations Dangerous for Supply. Guidance Notes Workplace Exposure Limits EH40. Introduction to Local Exhaust Ventilation HS(G)37. CHIP for everyone HSG(108). EU Legislation Dangerous Substance Directive 67/548/EEC. Dangerous Preparations Directive 1999/45/EC. Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16 December 2008 on classification, labelling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006 with amendments Chemical Safety Assessment No chemical safety assessment has been carried out. SECTION 16: OTHER INFORMATION Revision Comments NOTE: Lines within the margin indicate significant changes from the previous revision. Revision Date 10 September 2014 Revision 2 Risk Phrases In Full R34 R20/22 R22 R21/22 R52/53 R43 NC R63 R62 R41 R51/53 R50/53 Hazard Statements In Full H302 H312 H314 H317 H318 H332 H361fd H400 H410 H411 H412 Causes burns. Harmful by inhalation and if swallowed. Harmful if swallowed. Harmful in contact with skin and if swallowed. Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. May cause sensitisation by skin contact. Not classified. Possible risk of harm to the unborn child. Possible risk of impaired fertility. Risk of serious damage to eyes. Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Harmful if swallowed. Harmful in contact with skin. Causes severe skin burns and eye damage. May cause an allergic skin reaction. Causes serious eye damage. Harmful if inhaled. Suspected of damaging fertility or the unborn child. Very toxic to aquatic life. Very toxic to aquatic life with long lasting effects. Toxic to aquatic life with long lasting effects. Harmful to aquatic life with long lasting effects. Disclaimer The information on this data sheet represents our current data and is reliable provided that the product is used under the prescribed conditions and in accordance with the application specified on the packaging and/or in the technical guidance literature. Any other use of the product which involves using the product in combination with any other product or any other process is the responsibility of the user. 9 / 9