1. PRODUCT AND COMPANY IDENTIFICATION

Transcription

1 DUPONT TALENDO FUNGICIDE 1. PRODUCT AND COMPANY IDENTIFICATION Material Identification Product description Recommended use Company details Telephone (09) Fax (09) hour Emergency phone Date of issue May HAZARDS IDENTIFICATION DUPONT TALENDO FUNGICIDE Fungicide Control of powdery mildew in apples, grapes and cucurbits. DuPont (New Zealand) Limited Central Park Corporate Centre Level 2, Building Great South Road Greenlane, Auckland 1051 HSNO Classification Hazards 3.1D (combustible liquid), 6.1E (acute oral toxicant), 6.3A (skin irritant), 8.3A (corrosive-eyes), 6.7B (suspected carcinogen), 6.9A (target organ toxicant), 9.1B (aquatic toxicant) Warning - combustible liquid. Harmful-may be harmful if swallowed, inhaled or absorbed through the skin. May cause skin irritation. Suspected of causing cancer. May cause organ (CNS) damage from repeated oral exposure at high doses. Danger-may cause eye damage. Toxic to aquatic organisms with long lasting effects. 3. COMPOSITION/INFORMATION ON INGREDIENTS Ingredient CAS No. Proportion Proquinazid % Inert ingredients % 4. FIRST AID MEASURES Inhalation Skin contact Eye contact Ingestion If inhaled, remove from exposure and have patient lie down and keep quiet. If patient is not breathing, start artificial respiration immediately. Never give anything by mouth to an unconscious person. Call a physician if necessary. If spilt on the skin, remove contaminated clothing and wash affected areas of skin immediately. If concentrate is splashed in eyes, flush with running water for at least 15 minutes. Take to hospital without delay. For advice contact the National Poisons Centre 0800 POISON ( ) If swallowed, do NOT induce vomiting. For advice, contact the DuPont (New Zealand) Limited Page 1 of 5

2 5. FIRE FIGHTING MEASURES National Poisons Centre 0800 POISON ( ) or call a doctor immediately. Flammable Properties Combustible. Vapour forms explosive mixture with air. Heating can release vapours which can be ignited. Extinguishing Media Water spray, foam, dry chemical, C02. Fire Fighting Instructions Evacuate personnel to a safe area. Keep personnel removed and upwind of fire. Wear self-contained breathing apparatus. Wear full protective equipment Shut off source of fuel, if possible and without risk. Use water spray. Cool tank/container with water spray. Fight fire from maximum distance, use extreme caution as heat may decompose material and rupture containers. Combustion products Hazchem Code 6. ACCIDENTAL RELEASE MEASURES Not known. 3Z This product triggers the Hazardous Substances (Emergency Management) requirement for fire extinguishes whenever it is held in quantities of 500 litres or more, either alone or in aggregate or with other flammable substances Spill precautions Spill containment Spill clean up Use appropriate Personal Protective Equipment during clean up. (See section 8) Dyke spill. Prevent liquid from entering sewers, waterways or low areas. Soak up with sawdust, sand or other absorbent material. Shovel or sweep up. Never return to container for reuse. DO NOT flush to surface water or sanitary sewer system. 7. HANDLING AND STORAGE Handling Storage DO NOT breathe vapour or mist. DO NOT get in eyes, on skin, or on clothing. Wash thoroughly after handling. Wash clothing after use. DO NOT store or consume food, drink or tobacco in areas where they may become contaminated with this material. This product must be under the control of an approved handler during use. Records of use as described in Management of Agrichemicals (NZS8049) must be kept. Store product in original container only, away from other pesticides, fertiliser food or feed and under lock and key. Not for use or storage in or around the home. Stores containing more than 100 litres of this product require secondary containment and are subject to signage. Storage should be in accordance with The New Zealand Standard for the Management of Agrichemicals (NZS 8409) 8. EXPOSURE CONTROLS/PERSONAL PROTECTION DuPont (New Zealand) Limited Page 2 of 5

3 Engineering Controls Exposure Limits Personal Protection Use only with adequate ventilation. Keep container tightly closed. Wear safety goggles or face shield, rubber gloves, long sleeved shirt and long pants. 9. PHYSICAL AND CHEMICAL PROPERTIES Form Liquid Colour Brown Odour Slightly aromatic. Flash Point 74 C Corrosivity Non-corrosive Oxidisation Not an oxidiser ph 6.5 (Also,see sections 5 &10) 10. STABILITY AND REACTIVITY Stability Incompatible materials Decomposition Polymerisation Stable at normal temperatures and storage conditions. No incompatibilities reasonably foreseeable. Decomposes with heat. Polymerisation will not occur. 11. TOXICOLOGICAL INFORMATION Acute Effects Eye Skin Inhalation Ingestion Toxicity Data Severe eye irritant. Will irritate skin. Moderate skin irritant, but not a skin sensitiser. Harmful by inhalation. Low level of toxicity by ingestion. Acute Oral LD 50(rat) >5,000 mg/kg Acute dermal LD 50(rat) >5,000 mg/kg Inhalation LC 50 (4 hr) rat > 5.2 mg/l (proquinazid) 12. ECOLOGICAL INFORMATION Proquinazid Fish LC50(96hr) rainbow trout mg/l. Daphnia EC50 (48hr) mg/l. Algae EC50 (72hr) >0.740 mg/l. Birds LC50/8days bobwhite quail >2,250 mg/kg; > 5620 mg/kg mallard duck. Soil life DT50 average 30 days. Kfoc =10296 ml/g Bees LD50(48hr) oral >125 µg/bee. Contact >197 µg/bee. Earthworms 14 day LC50 NOEC > 1,000 mg/kg 13. DISPOSAL CONSIDERATION Triple rinse empty container and add to spray tank. If recycling, replace DuPont (New Zealand) Limited Page 3 of 5

4 14. TRANSPORT INFORMATION cap and return clean to containers to recycler or designated collection point. Puncture container and dispose of at an approved landfill. Disposal must be in accordance with applicable local regulations. Dispose of product by using in accordance with label instructions. DO NOT flush to surface water or sanitary sewer system. DO NOT reuse containers. Proper Shipping Name Environmentally Hazardous Substance, Liquid, N.O.S. (Proquinazid) D.G. Class 9 UN Number 3082 Hazchem 3Z Pack Group III Trade names DuPont Talendo fungicide 15. REGULATORY INFORMATION HSNO Approval Code HSNO Controls (inc. Tracking and Record Keeping): Approved handler ACVM Registration: ACVM Controls: HSR See for controls. This product must be under the control of an approved handler during use. DuPont Talendo fungicide is registered pursuant to the ACVM Act 1997 No. P.8381 See for registration conditions. DuPont (New Zealand) Limited Page 4 of 5

5 16. OTHER INFORMATION Glossary ACGIH DT50 EC50 EEL ERMA HSNO IARC Koc LC50 LD50 NOEL OSHA Pow TEL TLV WES Miscellaneous Responsibility for MSDS American Conference of Governmental Industrial Hygienists. Time(days) for 50%loss. Median effective concentration. Environmental Exposure Limit. Environmental Risk Management Authority Hazardous Substances and New Organisms. International Agency for Research on Cancer. Organic carbon partition coefficient (ml soil water/g organic carbon) Lethal concentration that will kill 50% of the test organisms inhaling or ingesting it. Lethal dose to kill 50% of test animals/organisms. No observable effect level. American Occupational Safety and Health Administration. The octanol-water partition coefficient is the ratio of the concentration of a chemical in octanol and in water at equilibrium at a specified temperature. Tolerable Exposure Limit. Threshold Limit Value-an exposure limit set by responsible authority. Workplace Exposure Limit The data in this Material Safety Data Sheet relates only to the specific material designated herein and does not relate to use in combination with any other material or in any process DuPont (New Zealand) Limited For further information Phone (09) DuPont (New Zealand) Limited Page 5 of 5