EIA REPORT OF M/s. AARTI INDUSTRIES LIMITED, GIDC, DAHEJ, BHARUCH.

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1 CHAPTER -9 EXECUTIVE SUMMARY 1. Basic Information of the Project: i Name & Address of the Project site (Complete details with plot no./survey no., Landmark etc. ) M/s. Aarti Industries Ltd. (Organic Division) Plot 801, 801/23, 806 & 807, Phase-III, GIDC Estate, Pardi, Vapi, Dist.:-Valsad, Gujarat. ii Name of the Applicant Mr. Nimesh Naik, General Manager iii Address for correspondence Plot 801, 801/23, 806 & 807, Phase-III, GIDC Estate, Pardi, Vapi, Dist.:-Valsad, Gujarat. iv Contact no. and ID of the Applicant Mo. no. : premnath.r@aarti-industries.com v Aerial distance of nearest Habitat (KM) Vapi around 4.5 KM vi Longitude & Latitude of the Project Site: (4 corners of the site) Latitude N Longitude E Direction Corners Latitude Longitude S 1 st - Gate 20 21'48.49"N 72 56'29.21"E S 2 nd - Gate 20 21'49.28"N 72 56'32.22"E E 3 nd - Gate 20 21'57.68"N 72 56'35.25"E SW 1 st 20 21'48.36"N 72 56'27.75"E E 2 nd 20 21'55.60"N 72 56'35.28"E NE 3 rd 20 22'0.33"N 72 56'34.69"E WN 4 th 20 21'59.95"N 72 56'30.70"E W 5 th 20 21'54.37"N 72 56'27.15"E vii Total cost of Proposed Project (Rs. in Crores): Existing : Crores Proposed : Crores Total : Crores viii (1) Capital cost for EMS (Environmental Management System): 2.18 Crores. (2) Recurring cost towards the environmental protection measures: 2.90 Crores per Annum. ix Total Plot area ( sq. meter) Existing : 45, 705 sq. meter Proposed: 00 Total : 45, 705 sq. meter x Green belt area,/tree Plantation area ( sq. meter) Existing : sq. meter Proposed: 00 Total : sq. meter (21%) (Unit will take care by creating and developing the green belt in near by GIDC notified area. Also, we will carry out plantation of 1000 trees/year for a period of M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LIMITED, ANKLESHWAR. 267

2 xi xii Category as per the Schedule to the EIA Notification 2006 i.e. 1(d), 2(b), 5(f) etc. Applicability of General Conditions of EIA Notification 2006: i.e. Ensure that I. Protected areas notified under the Wildlife (Protection) Act, 1972; II. CEPI areas III. Eco-sensitive areas and IV. Inter-state boundaries and international boundaries; are not located within 5 km or 10 km (as the case may be) area from the boundary of the proposed site. 5 year in nearby villages (Chanod Colony and Karvad, Tal. Pardi, Dist.: Valsad.). 5 (f) Not Applicable 2. Online application proposal no.: IA/GJ/IND2/64790/2017 & File no.: J-11011/248/2017-IA.II (I) 3. Date of application for EC: 4. Date of MoEF&CC, Delhi meeting for TOR: 24 th EAC meeting on 14 th -16 th June, Date of TOR issued by MoEF&CC, Delhi: 25 th July, Date of Public Hearing (If applicable): Not Applicable 7. Date of presentation for Appraisal: Project status: Expansion 9. Product profile: Name of the Products CAS Quantity Para Nitro Chloro (PNCB) Ortho Nitro Chloro (ONCB) Meta Nitro Chloro (MNCB) 2,5 Dichloro Nitro (2,5 DCNB) 3,4 Dichloro Nitro (3,4 DCNB) 2,3 Dichloro Nitro (2,3 DCNB) 2,4 Dichloro Nitro (2,4 DCNB) Existing Proposed Total (Either/Or) 1500 (Either/Or) End-use of product M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LIMITED, ANKLESHWAR. 268

3 Quantity Name of the Products CAS Existing Proposed Total 2,6 Dichloro Nitro (2,6 DCNB) ,3,4 Trichloro Nitro (2,3,4 TCNB) ,4,5 Trichloro Nitro (2,4,5 TCNB) ,4 Dichloro 3 Fluoro Nitro ,4 Dinitro Chloro (DNCB) (Either/Or) Mono Chloro (MCB) Ortho Dichloro (ODCB) 500 Para Dichloro (PDCB) Meta Dichloro (MDCB) 8000* 3000 (Either/Or) 1,2,4 Tri Chloro (1,2,4 TCB) 1,2,3 Tri Chloro (1,2,3 TCB) Trichloroaniline (TCAN) Ortho Anisidine Para Anisidine Dichloro Aniline ,5 Dichloro Aniline ,4 Dichloro Aniline Ortho Chloro Aniline P-Phenylene diamine O-Phenylene diamine OCPNA/PCONA Ortho Nitro Aniline (ONA) / Para Nitro / End-use of product M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LIMITED, ANKLESHWAR. 269

4 Name of the Products CAS Quantity Existing Proposed Total End-use of product Aniline (PNA) 30 ONCB Para sulphonic acid 31 3,3 Dichloro benzidine sulphate Dilute Sulphuric Acid Basic Chemical Total 13,936 8,200 22, 136 By-Product 1. Sulphuric Acid 70% Basic Chemical 2. Hydrochloric Acid 30% Basic Chemical 3. Aq. Sodium Thio sulphate Basic Chemical Total 9, ,065 19, *NOTE: As such either/or any product will be 8000, but 1, 2, 4 TCB, 1, 2, 3 TCB, TCAN not more than The project falls under Category B of project activity 5(f) as per the schedule of EIA Notification Product wise Raw material consumption: Name of the Product Para Nitro Chloro (PNCB)/ Ortho Nitro Chloro (ONCB) 3. Meta Nitro Chloro (MNCB) 4. 2,5 Dichloro Nitro (2,5 DCNB) 5. 3,4 Di Chloro Nitro (3,4 DCNB) Name of the Raw materials CAS of Raw Total Raw Consumption in Chloro Nitric Acid Sulphuric Acid Spent acid Total Chloro Nitric Acid Sulphuric Acid Spent acid Total ,5 Di chloro Conc. Nitric Acid Sulphuric Acid Spent acid Total ,5 Di chloro Conc. Nitric Acid Sulphuric Acid M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LIMITED, ANKLESHWAR. 270

5 Name of the Product 6. 2,3 Dichloro Nitro (2,3 DCNB) 7. 2,4 Dichloro Nitro (2,4 DCNB) 8. 2,4 Di nitro Chloro (DNCB) 9. 2,6 Di nitro Chloro 10. 2,3,4 Tri chloro Nitro (2,3,4 TCNB) 11. 2,4,5 Tri chloro Nitro (2,4,5 TCNB) Name of the Raw materials CAS of Raw Total Raw Consumption in Spent acid Total ,5 Di chloro Conc. Nitric Acid Sulphuric Acid Spent acid Total ,5 Di chloro Conc. Nitric Acid Sulphuric Acid Spent acid Total PNCB % Conc. Nitric Acid % Conc. Sulphuric Acid Recovered spent acid Total PNCB % Conc. Nitric Acid % Conc. Sulphuric Acid Recovered spent acid Total ,2,4/1,2,3 TCB Nitric Acid Sulphuric Acid Spent Acid Soda Ash Total ,2,4/1,2,3 TCB Nitric Acid Sulphuric Acid Spent Acid Soda Ash Total Crude TCNB 1,2,4/1,2,3 TCB Nitric Acid Sulphuric Acid Spent Acid Soda Ash M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LIMITED, ANKLESHWAR. 271

6 Name of the Product 13. 2,4 Di chloro 3 fluoro Name of the Raw materials CAS of Raw Total Raw Consumption in Total ,2,4/1,2,3 TCB Nitric Acid Sulphuric Acid Soda Ash Total Crude DCNB 2,5 Di chloro Conc. Nitric Acid Sulphuric Acid Spent acid Total Mono Chloro Fresh benzene Recovered benzene Chlorine Total Ortho Di chloro Fresh benzene Recovered benzene Chlorine Total Para Di chloro Fresh benzene Recovered benzene Chlorine Total ,2,4/1,2,3 Tri chloro ODCB Recovered Ortho Di Chloro Chlorine Total Trichloroaniline (TCAN) Aniline Mono Chlorobenzene Rec. Mono Chlorobenzene Hydrogen chloride gas Chlorine Sodium hydroxide Total Ortho Anisidine o-nitroanisole Hydrogen Rec. 30% OA Crude Total Para Anisidine p-nitroanisole M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LIMITED, ANKLESHWAR. 272

7 Name of the Product Name of the Raw materials CAS of Raw Total Raw Consumption in Hydrogen Rec. 30% OA Crude Total Di chloro Aniline Mixture of 2,5 DCNB & 2,6 DCNB Hydrogen Fresh Solvent (Methanol) Recovered solvent Total ,5 Di Chloro Aniline Mixture of 2,5DCNB & ,6 DCNB Hydrogen Fresh Solvent (Methanol) Recovered solvent Total ,4 Di Chloro Aniline Mixture of 2,5DCNB & ,6 DCNB Hydrogen Fresh Solvent (Methanol) Recovered solvent Total Ortho Chloro Aniline ONCB Hydrogen Fresh Solvent (Methanol) Recovered solvent Total PPDA ONA Caustic Sulphur Total OPDA Ortho Nitro aniline Caustic Sulphur Total OCPNA/PCONA 3:4DCNB/2:5DCNB Anhydrous Ammonia Ammonia Solution (32%) M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LIMITED, ANKLESHWAR. 273

8 Name of the Product Name of the Raw materials CAS of Raw Total Raw Consumption in Total ONA/PNA ONCB/ PNCB Anhydrous Ammonia Ammonia Solution (32%) Total ONCB Para Sulfonic Acid MCBPSA Sulphuric acid Nitric acid Potassium chloride Mix Sodium chloride Total :3 Di chloro Benzdine ONCB Sulphate Dichlone Emulsifier Caustic Lye 48% Hydrogen Fresh Toluene Recovered Toluene Hydrochloric acid (3%) Spent Acid (62%) Thiourea Total Total Compliance status of the existing project: Particulars Brief Information/Details Remarks 1 Earlier EC details Unit was established in the year 2003 before EIA - notification issued. Hence, EC is not applicable. Unit has applied EC for the first time. 2 Compliance of EC Not Applicable -- 3 Status of inspection by Not Applicable -- RO-MoEFCC, Bhopal. 4 Status of submission of half yearly return to concern authorities. 5 Compliance of existing CC&A Unit has valid CCA : AWH , Date of issue: 06/09/2017 and its compliance report is -- 6 Legal actions/closure directions/scn etc. issued by GPCB. attached as Annexure-III in EIA report. SCN and its reply are attached as an Annexure- XXI in EIA report. -- M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LIMITED, ANKLESHWAR. 274

9 7 Any Public Complaints No public complaints -- 8 Is there any litigation pending before any court of Law against the Project? No litigation pending Water, Air and Hazardous waste management: Particulars Details no. A Water i Source of Water Supply (GIDC, Bore well, Surface water etc...) GIDC, Vapi Status of permission from the concern authority: Water permission letter from GIDC, Vapi is attached as annexure-ix-a on EIA report. ii Water consumption (KL/day) Category Existing Proposed Total after Remarks KL/day (Additional) KL/day Expansion KL/day (A) Domestic (B) Gardening (C) Industrial Process iii iv Washing Boiler Cooling Others Total (A+B+C) 898 Note: - Waste water generation (KL/day) Category Existing KL/Day Proposed (Additional) KL/day Total after Expansion KL/day Remarks (A) Domestic To STP Plant (B) Industrial Process KLD sent to primary treatment. Washing Sent to ETP Boiler Cooling KLD recycle to CT + 60 KLD send to ETP Others Total Industrial waste water Treatment facility with capacity (ETP, CETP, MEE, STP etc) ETP : 212 KLD (212 KLD to ETP + 60 KLD Recycle from SSF) v Mode of Disposal & Final meeting point Domestic: STP to Gardening Industrial: CETP, Vapi (VGEL) vi Reuse/Recycle details (KL/day) Recycle from SSF : 60 KL/day M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LIMITED, ANKLESHWAR. 275

10 B i ii Water going with HCl: 308 KL/Day Air [Existing & Proposed] Flue gas emission details: of Boilers/TFH/Furnaces/DG sets etc. with capacities viz. TPH, Kcal/hr, MT/hr, KVA etc. Source of NAAQS Quantity emission Stack Nam Type of (National of Fuel SR. With Height e of emissions Ambient MT/hr APCM no. Capacity (meter the i.e. Air Air Quality & e.g. Boiler ) fuel Pollutants Standards) MT/Day (8 TPH) Existing 1 2 D.G. set (1 no. 625KVA) D.G. set (1 no. 750 KVA) Dies el Dies el 0.1 MT/hr MT/hr PM SO 2 NO X PM SO 2 NO X Adequate stack height & acoustic enclosure Proposed D.G. set PM (1 no. Dies SO 1100 el MT/hr 2 Adequate NO KVA) X stack height Thermo & acoustic PM pack Dies 0.20MT/ enclosure SO 1,00,000 el hr 2 NO K Cal X Note: DG sets will be run only in case of electricity failure. Process gas i.e. Type of pollutant gases (SO 2, HCl, NH 3, Cl 2, NO x etc.) [Existing & Proposed] no. Existing 1 2 Source of emission Chlorinator for MCB plant Nitrator of NCB plant Type of emission HCl Cl 2 18 NO X 12 Stack/ Vent Height (meter) APCM Two stage water scrubber + Caustic scrubber Two Stage Caustic scrubber 150mg/ Nm ppm 50ppm 150mg/ Nm ppm 50ppm 150mg/ Nm ppm 50ppm 150mg/ Nm ppm 50ppm NAAQS (National Ambient Air Quality Standards) 20 mg/nm 3 9 mg/nm 3 25 mg/nm 3 Proposed 3. Connected to HCl Two stage water HCl 11 storage tank scrubber 20 mg/nm 3 4. Connected to GLV 25 mg/nm 3 NO NCB X 11 Caustic scrubber 5. Spent acid 25 mg/nm 3 NO Concentration plant X 11 Caustic scrubber 6. Batch Nitration plant NO X 11 Caustic scrubber 25 mg/nm 3 7. DNCB Plant NO X 11 Water scrubber 25 mg/nm 3 M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LIMITED, ANKLESHWAR. 276

11 v C i followed by Caustic scrubber Fugitive emission details with its mitigation measures. [Existing & Proposed] Details are provided in chapter-8 in table no: 8.3 from page no.:237 to 239. Hazardous waste (as per the Hazardous and Other Wastes (Management and Transboundary Movement) Rules [Existing & Proposed] Disposal Method no. Type/ Name of Hazardou s waste Source of generatio n Category and Schedule as per HW Rules. Quantit y (MT/ Annum) 1. ETP waste ETP Collection, Storage, Transportation, disposal to TSDF site. 2. MEE salt Effluent Collection, Storage, Transportation, disposal to TSDF site. 3. Distillation Residue 4. Spent carbon 5. Discarded (plastic bags, Drums) Process Collection, Storage, Transportation, disposal to CHWIF. Process Collection, Storage, Transportation disposal to CHWIF. Raw 33.1 What so ever 6. Used Oil Plant Lit/year 7. a. Dilute H 2 SO 4 b. Dilute H 2 SO 4 8. Sulfuric Acid Process B15 a b Collection, Storage, Transportation disposal entire quantity reuse for filling the sludge and drums for filling residue & ETP waste/ Sale to authorized recycler. Collection, Storage, Transportation disposal by reuse in plant & machinery for lubricating purpose. M/s. Aarti Industries Ltd. (Alchemie organic Div.) & M/s. Apex Pharma Chem Pvt. Ltd.) Reception/ collection/ Storage/ Reuse. Process B15 79, 848 Collection, storage, Transportation and sale to authorized industry having permission under rule-9 of Hazardous & other wastes (Management & M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LIMITED, ANKLESHWAR. 277

12 ii ii D i ii 9. Hydrochlor ic Acid 10. Aq. Sodium Thio sulphate (Thio Liquor) Process B15 1, 58, 436 Transbouandry Movement) rule-2016 OR inhouse treatment. Collection, storage, Transportation and sale to authorized industry having permission under rule-9 of Hazardous & other wastes (Management & Transbouandry Movement) rule-2016 OR inhouse treatment. Process Collection, storage, Transportation and sale to authorized industry having permission under rule-9 of Hazardous & other wastes (Management & Transbouandry Movement) rule-2016 OR inhouse treatment. NON- HAZARDOUS WASTE GENERATION 8. Insulation waste Plant Collection, Storage, Transportation and disposal to TSDF, Vapi. Quantity of discarded containers must be in MT/Annum. Membership details of CETP, TSDF, Membership Certificates are attached as annexure CHWIF, Common MEE etc. XIII-A-B-C in EIA report. Details of Non-Hazardous waste & its Insulation waste : 7 disposal [Collection, Storage, Transportation and disposal (MSW and others) to TSDF, Vapi.] Solvent management (If any) Details of Solvent recovery (As per respective ToR) VOC emission sources and its mitigation measures Details of solvent recovery are given in chapter-2 in section 2.6. Details are provided in chapter-8 in table no: Details of Environmental Consultants: Particulars Details no. i Name of the Consultant Jyoti Om Chemical Research Centre Pvt. Ltd. ii Validity of Certificate of High court stay order accreditation issued by the NABET, QCI iii Accreditation for the categories -- iv Any other details -- M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LIMITED, ANKLESHWAR. 278

13 14. Details regarding EIA report: no. a b c d e f g Particulars Details Page no. of EIA report Ensure that there is no 1) Page no.: change in EIA report 2. compared to ToR application i.e. Form-1 & PFR. Baseline environmental monitoring period Baseline study area (5 km or 10 km) of AAQM stations including project site Parameters considered for AAQM & ensure that project specific parameters are considered. Conclusion of the Monitoring (Baseline study) Air, Water & Land Parameters considered for AAQM including project specific parameters. Parameters no. 1. PM PM SO NOx CO Cl 2 BDL 7. HCl BDL 8. VOCs ) As per TOR application, Existing plot area of the unit is 45, 477 sq. meters. But actual GIDC plot allotment letter plot area of the unit is 45, 705 sq. meters. 2) As per ToR application, Total water requirement will be 958 KLD. Now, In EC application, Total water requirement will be reducing to 898 KLD. 3) As per ToR application, Total waste water generation will be 272 KLD (Industrial). Now, In EC application, Waste water generation will be reducing to 212 KLD (Industrial). Installing side stream filter. So, the water consumption & waste water generation will be reducing by 6.3% compare to the Terms of Reference. March-2017 to May KM -- 2) Page no:78 3) Page no: 9 of AAQM stations PM 2.5, PM 10, SO 2, NO X, CO, Cl 2, HCl and VOC Acceptable -- PM 2.5, PM 10, SO 2, NO X, CO, Cl 2, HCl and VOC. Range of Concentrations (μg/m 3 ) Remarks M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LIMITED, ANKLESHWAR. 279

14 h i j k Whether the results of AAQM are within the norms prescribed in NAAQS? Comments for AAQM results w.r.t. NAAQS Software used for the mathematical Modeling for anticipated incremental GLCs (Ground Level Concentrations) The resultant concentrations w.r.t. NAAQS and its conclusion. l Suggested mitigation measures w.r.t. Air m Conclusion of the Monitoring during baseline study of water n Suggested mitigation measures w.r.t. Water o Conclusion of the Monitoring during baseline study of Land p Suggested mitigation measures w.r.t. Land q Conclusion of the Monitoring during baseline study of Noise Yes Industrial Source Complex Short Term (ISC-ST3) 145 From the dispersion modeling 153 studies conducted, it was observed that the maximum ground level concentration occurs in the East direction. The maximum incremental increase in concentration for PM, SO 2 and NO x is 0.52 µg/m 3, 0.4 µg/m 3 and 0.31 µg/m 3 respectively at a distance of about 1 km in the East direction, whereas, the maximum incremental increase in concentration for HCl and Cl 2 is µg/m 3 and µg/m 3 respectively at a distance of about 1 km in the East direction. Details are covered under Chapter Details are covered under Chapter- 99 & The noise levels during daytime varied from db (A) Leq to db (A) Leq in the study area. The noise level in the study area is within the permissible Limits as per Noise rules The night time noise level in the study area is in the range of db (A) Leq to db (A) Leq. The night time noise was also 104 M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LIMITED, ANKLESHWAR. 280

15 r Suggested mitigation measures w.r.t. Noise s Main issues in Public hearing (If applicable) t Brief description of Public hearing Main Issues raised by stake holders within stipulated standards of CPCB Not applicable -- Commitments by Project proponent and action plan u Major hazardous chemicals and worst Details are covered under Chapter case scenario considered in Risk Analysis report. Comments/Suggestions/mitigation measures in brief. v An undertaking by the Project Proponent Undertaking from project -- on the ownership of the EIA report as per proponent is attached as an the OM of MoEF&CC dated 05/10/2011 Annexure-XXIV in EIA and an undertaking by the Consultant report. regarding the prescribed TORs have been complied with and the data submitted is factually correct as per the OM of Undertaking from consultant is attached as an Annexure- XXIII in EIA report. MoEF&CC dated 04/08/2009. w Any other details: M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LIMITED, ANKLESHWAR. 281