Zinc Sulphate Heptahydrate

Transcription

1 Revised edition: Version: 4.0 Identification of the Substance/Mixture and of the Company/Undertaking Product Identifier Page 1 Product Name: Zinc Sulphate Heptahydrate Article No.: Relevant identified Uses of the Substance or Mixture and Uses advised against Identified uses: Chemical for different applications Uses advised against: Details of the Supplier of the Safety Data Sheet Company: Address: Kremer Pigmente GmbH & Co. KG Hauptstr , Aichstetten, Germany Tel./Fax.: Tel , Fax Internet: Emergency No. info@kremer-pigmente.de Emergency No.: (Mon-Fri 8:00-17:00) Hazards Identification Classification of the Substance or Mixture Classification according to EC Regulation 1272/2008 H302 Cat.: 4 H318 Cat.: 1 H400 Cat.: 1 H410 Cat.: 1 Classification according to EC Regulation No. 67/548 or No. 1999/45 Harmful (Xn) R22 Irritating (Xi) R41 Hazardous to the R50 environment (N) R53 Acute toxicity (oral), hazard category 4 Serious eye damage, hazard category 1 Hazardous to the aquatic environment, acute category 1 Chronic aquatic toxicity, category 1 Harmful if swallowed. Causes serious eye damage. Very toxic to aquatic life. Very toxic to aquatic life with long lasting effects. Harmful if swallowed. Risk of serious damage to eyes. Very toxic to aquatic organisms. May cause long-term adverse effects in the aquatic environment. Safety Phrases: Possible Environmental Effects: Label Elements See Section 12. 2

2 2. 2. Page 2 Classification according to EC Regulation 1272/2008 Hazard designation: GHS05-2 GHS07 GHS09 Signal word: Hazard designation: Safety designation: H302 H318 H400 H410 P264 P273 P280 P305+P351+P338 P308+P313 P310 P501 Danger Harmful if swallowed. Causes serious eye damage. Very toxic to aquatic life. Very toxic to aquatic life with long lasting effects. Wash thoroughly after handling. Avoid release to the environment. Wear protective gloves/ clothing/ eye/ face protection. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses and continue rinsing. If exposed or concerned: Get medical advice/attention. Immediately call a poison center or physician. Dispose of contents/ container according to regional, national and international regulations Hazardous components for labelling: Zink sulfate heptahydrate Other Hazards Composition/Information on Ingredients Substance Mixture Chemical Characterization: Hazardous Ingredients: Zink sulfate heptahydrate (Xn,N; R /53; H ); REACH Reg.-Nr <= 100 % CAS-Nr: EINECS-Nr: EC-Nr: Additional information: 3

3 Page First Aid Measures Description of the First Aid Measures General information: After inhalation: After skin contact: After eye contact: Remove contaminated clothes immediately. Take affected person to fresh air. Oxygen therapy in case of impaired breathing. Consult physician immediately. Wash off with plenty of water and soap. Consult a physician if irritation persists. Rinse open eyes with plenty of water for at least 15 minutes. Consult a physician immediately. If possible bring to an eye clinic After ingestion: Most important Symptoms and Effects, both Acute and Delayed Rinse mouth with water and give plenty of water to drink. Consult a physician. Never give anything by mouth to an unconscious person. Do not induce vomiting. In case of spontaneous vomiting, bring unconsciousness person in a stable side position. Symptoms: No further information available Effects: No further information available. Indication of any Immediate Medical Attention and special Treatment needed Treatment: Fire-Fighting Measures Extinguishing Media Suitable extinguishing media: Treat symptomatically. Product itself does not burn. Use extinguishing media for surrounding fire Unsuitable extinguishing media: Special Hazards arising from the Substance or Mixture None known Special hazards: Advice for Firefighters In case of fire: formation of sulfur oxides. Protective equipment: 4

4 Page 4 Wear self-contained respiratory protective device. Wear suitable protective clothing Further information: Accidential Release Measures Personal Precautions, Protective Equipment and Emergency Procedures Collect contaminated extinguishing water and debris separately; avoid contamination of sewage system. Contaminated extinguishing water and debris should be disposed of according to local regulations Personal precautions: Environmental Precautions Wear protective clothing. Ensure adequate ventilation. Avoid contact with eyes and skin Environmental precautions: Methods and Material for Containment and Cleaning Up Prevent contamination of soils, drains and surface water. Contact local authorities if product pollutes soil or vegetation Methods and material: Reference to other Sections Handling and Storage Precautions for Safe Handling Instructions on safe handling: Take up mechanically and collect in suitable containers for disposal. Protective clothing, see Section 8. Avoid formation of dust. Provide adequate ventilation. Avoid contact with eyes, skin and clothing Hygienic measures: Conditions for Safe Storage, including any Incompatibilities Keep away from foodstuffs and drinks. Do not eat, drink or smoke during work. Wash hands before breaks and at the end of work. A nearby eyewash facility should be available for emergencies. Storage conditions: Requirements for storage areas and containers: Information on fire and explosion protection: Store in tightly sealed containers in a dry room. Storage: In the original container. Product is not combustible. Do not store together with: foodstuffs, beverages and feed. Do not store together with: strong oxidants and acids. 5

5 Storage class (VCI): Page Further Information: Specific End Use(s) Further information: Exposure Controls/Personal Protection Parameters to be Controlled Parameters to be controlled (DE): none known Parameters to be controlled (EC): Derived No-Effect Level (DNEL): Predicted No-Effect Concentration (PNEC): No values available. No values available Additional Information: Exposure Controls Technical protective measures: No further measures, see Section 7. Personal Protection General protective measures: Respiratory protection: Hand protection: Protective glove material: Eye protection: Body protection: Keep away from foodstuffs and drinks. Do not eat, drink or smoke during work. Wash hands before breaks and at the end of work. Dust mask recommended when very dusty (with particle filter P2/P3; EN 143). Protective gloves (EN 374) Natural rubber (480 min, 0.5 mm) Chloroprene rubber (> 480 min; > 0.5 mm). Nitrile rubber (480 min, 0.35 mm) Butyl rubber (480 min; 0.5 mm). Fluoro carbon rubber -FKM (480 min; 0.4 mm). Polyvinyl chloride (> 480 min; > 0.5 mm) Safety glasses with protective shields (EN 166). Protective clothing. Environmental precautions: Prevent contamination of open water ways and sewage system. 6

6 Avoid contamination of ground water. 9. Physical and Chemical Properties Information on Basic Physical and Chemical Properties Page 6 Form: Color: Odor: Odor threshold: ph-value: Melting temperature: Boiling temperature: Flash point: Evaporation rate: Flammability (solid, gas): Upper explosion limit: Lower explosion limit: Vapor pressure: Vapor density: Density: Solubility in water: Coefficient of variation (n- Octanol/Water): Auto-ignition temperature: solid blue violet odorless (50 g/l; 20 C) not available not available not available no information available no information available not available 960 g/l (20 C) no information available Decomposition temperature: 39 C Viscosity, dynamic: Explosive properties: Product is not explosive. 7

7 Oxidizing properties: none Page Bulk density: Further Information Solubility in solvents: Viscosity, kinematic Burning class: Solvent content: Solid content: Particle size: Other information: Stability and Reactivity Reactivity Chemical Stability Possibility of Hazardous Reactions Conditions to Avoid Conditions to avoid: Thermal decomposition: Imcompatible Materials Hazardous Decomposition Products Further Information Toxicological Information Information on Toxicological Effects Acute Toxicity LD50, oral: LD50, dermal: LC50, inhalation: Primary effects ca. 980 kg/m3 (20 C) No further information. Stable if used according to specifications. Reacts with strong oxidants. Avoid heat. Avoid heat. Strong oxidizing agents. In case of fire: formation of sulphur oxides, zinc oxide mg/kg (rat) May cause respiratory irritation. Irritant effect on skin: 8

8 Irritating (rabbit) Page 8 Irritant effect on eyes: Inhalation: Ingestion: Sensitization: Mutagenicity: Reproductive toxicity: Cancerogenity: Teratogenicity: Specific target organ toxicity (STOT): Intensive irritation. Can damage eye (rabbit). No information available Not sensitizing (mouse). No data available. No data available. No data available. No data available Additional toxicological information: Ecological Information Aquatic Toxicity Fish toxicity: Daphnia toxicity: Bacteria toxicity: Algae toxicity: Persistency and Degradability Bioaccumulation Moblity Results of PBT- und vpvp Assessment LC50: 17 mg/l (96h, Pimephales promelas) EC50: 1.86 mg/l (48h, Daphnia magna) EC50: mg/l (0.5h, Photobacterium phosphoreum) EC50: 0.52 mg/l (120h, Scenedesmus quadricauda) Methods for the evaluation of the biological degradability are not applicable for inorganic substances. Water soluble. Product is mobile in aqueous environment. Not applicable. 9

9 Other Adverse Effects Page 9 Water hazard class: 3, hazardous Danger to drinking water even if small quantities leak into the ground. Behaviour in sewage systems: Further ecological effects: Avoid subsoil penetration. Prevent product from entering drains. Do not contaminate surface water. Very toxic for water organisms. May cause long-term adverse effects in the aquatic environment AOX Value: Disposal Considerations Waste Treatment Methods Product: Must not be disposed together with household garbage. Special disposal required according to local regulations. Do not let product enter water systems. European Waste Code (EWC): Uncleaned packaging: Uncontaminated packaging may be recycled. Completely empty packaging can be disposed of with the regular waste. Packaging may be disposed of in the same manner as the product Waste Code No.: Transport Information UN Number ADR, IMDG, IATA 3077 UN Proper Shipping Name ADR/RID: IMDG/IATA: Transport Hazard Classes UMWELTGEFÄHRDENDER STOFF FEST, N.A.G. (Zinksulfatheptahydrat) ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (Zinc sulfate heptahydrate) ADR Class: 9 Hazard no.: 9 Classification code: Tunnel no.: M7 E IMDG Class (sea): 9 Hazard no.: 9 EmS No.: F-A, S-F 10

10 Page 10 IATA Class: 9 Hazard no.: Packaging Group ADR/RID: IMDG: IATA: Environmental Hazards Special Precautions for User III III III Labelling according ADR/RID: fish and tree Labelling according IMDG: fish and tree Classification as hazardous according IMDG: yes Labelled with "P" according 2.10 IMDG: no Transportation in Bulk according to Annex II of MARPOL 73/78 and IBC-Code IMDG: Further Information Regulatory Information Safety, Health and Environmental Regulations/Legislation specific for the Substance or Mixture Water hazard class: Local regulations on chemical accidents: Employment restrictions: 3, very hazardous for water Underlies the Accident Ordinance 9a The employment restrictions for young workers in accordance with the Youth Employment Protection Law (94/33/EC) are to be observed. The employment restrictions for expectant and nursing mothers in accordance with the Maternity Protection Guideline (94/85/EEC) are to be observed Restriction and prohibition of application: Technical instructions on air quality: Chemical Safety Assessment Further Information Other Information Listed in: EINECS ( ), AICS (AUS), DSL/INV (CA; G-3078), ISHL (JP; 1-(3)-223), ENCS (JP; (1)-542), PICCS (PH) This product should be stored, handled and used in accordance with good hygiene practices and in conformity with any legal regulations. This information contained herein is based on the present state of knowledge and is intended to describe our product from the point of view of safety requirements. It should be therefore not be construed as guaranteeing specific properties.