Nitrate removal by Chesapeake watershed riparian buffers and potential additional removal from buffer restoration

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1 Nitrate removal by Chesapeake watershed riparian buffers and potential additional removal from buffer restoration Donald E. Weller, Matthew E. Baker, and Thomas E. Jordan Smithsonian Environmental Research Center CBP STAC Healthy Watersheds Workshop March 7, 2012

2 Strong evidence for buffer nutrient nitrate removal comes mainly from transect-scale studies Nitrate Concentration (mg N/l) Distance from Field toward Stream (m) Lowrance et al Env. Mgt. 21:

3 but, some studies report low removal Nitrate Removal (%) sites 16 > 80% 6 < 50% 3 negative Forest & Wetland Width (m) Mayer et al JEQ 36:

4 and, buffer prevalence varies widely

5 Common buffer metrics have limited efforts to scale up from transects to watersheds Complete buffering NO buffering Crop (source) Forest (sink) Neutral Land use proportions identical Both have 50% forest in 100 ft buffer

6 Functional riparian metrics Cropland Riparian forest Other Baker et al Land. Ecol. 21:

7 Functional riparian metrics Cropland Metrics consider source-stream paths only Buffer prevalence along transport paths Unites transect and watershed scales Riparian forest Other Baker et al Land. Ecol. 21:

8 SERC watershed study Sampling design 321 watersheds 3 physiographic provinces 12 clusters Mostly rural watersheds Measured baseflow nitrate concentration Liu et al JAWRA 36:

9 Spatial data and analysis National Land Cover Dataset 1990 (30 m pixels) Cropland Forest/wetland (buffers) 1:24K topography (DEM) 1:24K stream maps Flow path metrics Width metrics need finer resolution land cover Buffer gaps below cropland distinguish buffered and unbuffered cropland Baker et al Land. Ecol. 21:

10 The gory statistical details... Land proportion Buffer where N is nitrate concentration; C, G, and D are the proportions of cropland, grassland, and developed land; β values are fitted model coefficients; ε is error; the subscript u designates coefficients β for unbuffered cropland, and P p and P a are dummy variables representing the categorical variable physiographic province. P p = 1 for the Piedmont province and zero otherwise, whereas P a = 1 for the Appalachian Mountain province and zero otherwise. For the Coastal Plain, both P p and P a are zero. The first subscript on a coefficient β represents the land cover to which that coefficient applies (c, g, or d for cropland, grassland, or developed land). If present, the second subscript represents the dummy variable for physiographic province to which the coefficient applies (p or a for P p or P a ). Weller et al Ecol. Applic. 23:

11 Bare bones model summary Resolves buffered from unbuffered cropland NO = β + β C+ β C 3 0 c u u Separate βs for 3 physiographic provinces Developed and grassland coefficients not significant (Careful!) Model demonstrated significance of buffers and quantified effects on nitrate concentration

12 Model parameters estimate nitrate source and removal potentials Model Coefficient (mg N/l) β c = + + NO3 β0 βcc βucu β c +β u Lost from cropland Removed by buffer Lost through buffer -10 CP PD AM Physiographic Province

13 Potentials differ among provinces 40 β c Edge-of-field loss ~3X CP Model Coefficient (mg N/l) β c +β u Removal in mg/l similar Leakage through buffers differs -10 CP PD AM Physiographic Province Weller et al Ecol. Applic. 23:

14 Scenario predictions quantify cropland nitrate components for any watershed Stream Nitrate from Cropland (mg N/l) no buffers current buffers restored buffers current buffer removal restored buffer removal buffer leakage Weller et al Ecol. Applic. 23:

15 321 study watersheds Extrapolating to predict watershedwide effects on cropland nitrate ~2000 HUC12s ~83 km 2 each Assume AM parameters apply to AP

16 Cropland and riparian buffer gaps

17 Cropland and riparian buffer gaps 15 Percent of Watershed Area % 36% 25% Unbuffered Buffered 46% 0 CP PD AM AP Physiographic Province

18 Mean annual stream flow model!!! Qm = APT e a b c d Vogel et al J. Irrig. Drainage Engin. 125:

19 Predicted annual stream flow cm 40 Mean Annual Flow (cm) CP PD AM AP Physiographic Province PRISM climate data (

20 Combining models estimates components of cropland nitrate yield kg/ha ~ lb/ac Nitrate Yield (kg N/ha of watershed) current buffer restored buffer removal buffer leakage PD 21% AM 36% CP 18% AP 24% CP PD AM AP Physiographic Province

21 and the components of nitrate load 1 Gg ~ 2 million lbs 1000 tons Nitrate Load (Gg N) 20 current buffer restored buffer removal buffer leakage 0 CP PD AM AP Physiographic Province

22 Watershed-wide annual benefits 1 Gg ~ 2 million lbs 1000 tons Cropland Nitrate Load (Gg N) current buffer restored buffer removal buffer leakage +25% 13 Gg 37% 19 Gg 63% 32 Gg an upper limit... 0 Entire Watershed

23 Cautions Current means circa 1990 Results apply to buffers detectable in 30 m data (but method can and should be applied to higher resolution data) Restoration refers to buffer gaps below cropland Restoration sites NOT the same as current buffers (actual results may vary)

24 Applications... Use Landsat data (NLCD) & flow path analysis to quantify buffer prevalence Separate buffered & unbuffered cropland in other models Use flow path analysis to target buffer preservation and restoration

25 Acknowledgements (recent) EaGLe Atlantic Slope Consortium EPA Estuarine & Great Lakes Indicators Program R EPA Watershed Classification Program R The Cooperative Institute for Coastal and Estuarine Environmental Technology