Material Safety Data Sheet

Transcription

1 Material Safety Data Sheet KODAK PMT 3 Activator 1. Chemical Product and Company Identification Common Name KODAK PMT 3 Activator MSDS# 131 Synonym Catalog number Area of Application KAN ; PCD 533; A ; ; ; ; ; Industrial applications. Graphic Arts Imaging. Version 2.7 Validation Date Responsible Name Kodak Polychrome Graphics Supplier Kodak Polychrome Graphics 41 Merrit 7 Norwalk, CT 6851 USA Tel. (23) 8457 KPG# Emergency telephone number In Case of Emergency (medical/roadside) (24hrs) CALL For other EHS Information Kodak Polychrome Graphics, Environmental Solutions Department; Johns Creek Parkway, #26, Duluth, GA 397; USA Phone ext. 511, Additional phone (77) PEP@kpgraphics.com, Fax (77) ; 2. Composition, Information on Ingredients Name CAS # % by Weight Exposure Limits 1) Water Not available. 2) Sodium sulfite Not available. 3) Sodium thiosulfate Not available. 4) 2Methylaminoethanol Not available. 5) Glycerol TWA 1 (mg/m 3 ) 6) Hydroquinone <1 TWA 2 (mg/m 3 ) STEL 4 (mg/m 3 ) 3. Hazards Identification Physical State and Appearance Emergency Overview Routes of Entry Liquid. WARNING! CAUSES SKIN AND EYE IRRITATION. MAY CAUSE ALLERGIC SKIN REACTION. MAY BE HARMFUL IF SWALLOWED. Do not get in eyes. Avoid contact with eyes, skin and clothing. Avoid breathing vapor or mist. Keep container closed. Use only with adequate ventilation. Wash thoroughly after handling. Absorbed through skin. Eye contact. Potential Acute Health Effects Eyes Hazardous in case of eye contact (irritant) Skin Inhalation Ingestion Potential Chronic Health Effects Medical Conditions Aggravated by Overexposure Hazardous in case of skin contact (irritant). Skin inflammation is characterized by itching, scaling, reddening, or, occasionally, blistering. May cause allergic skin reactions with repeated exposure. May be harmful if swallowed. CARCINOGENIC EFFECTS Classified None. by OSHA [Sodium sulfite]. Classified None. by OSHA [2Methylaminoethanol]. Classified 3 (Not classifiable for human.) by IARC [Hydroquinone]. MUTAGENIC EFFECTS Not available. TERATOGENIC EFFECTS Not available. Repeated or prolonged exposure is not known to aggravate medical condition.

2 KODAK PMT 3 Activator Page 2/6 Overexposure /Signs/Symptoms See Toxicological Information (section 11) 4. First Aid Measures Eye Contact Skin Contact Inhalation Check for and remove any contact lenses. In case of contact with eyes, rinse immediately with plenty of water. Seek medical attention. In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. If irritation persists, seek medical attention. Wash contaminated clothing before reuse. Allow the victim to rest in a wellventilated area. If irritation persists, seek medical attention. Ingestion DO NOT induce vomiting. Have conscious person drink several glasses of water or milk. Seek medical attention. 5. Fire Fighting Measures Flammability of the Product AutoIgnition Temperature Hazardous thermal (de)composition products Fire Hazards in Presence of Various Substances Explosion Hazards in Presence of Various Substances Fire Fighting Media and Instructions Protective Clothing (Fire) Special Remarks on Fire Hazards Special Remarks on Explosion Hazards Nonflammable. These products are carbon oxides (CO, CO2), sulfur oxides (SO2, SO3...). Use DRY chemicals, CO2, water spray or foam. Be sure to use an approved/certified respirator or equivalent. None. 6. Accidental Release Measures Small Spill and Leak Large Spill and Leak 7. Handling and Storage Dilute with water and mop up, or absorb with an inert dry material and place in an appropriate waste disposal container. If necessary Neutralize the residue with a dilute solution of acetic acid. Finish cleaning by spreading water on the contaminated surface and dispose of according to local and regional authority requirements. Absorb with an inert material and put the spilled material in an appropriate waste disposal. Neutralize the residue with a dilute solution of acetic acid. Finish cleaning by spreading water on the contaminated surface and dispose of according to local and regional authority requirements. Handling Storage Avoid breathing vapors or spray mists. Avoid contact with skin and clothing. Do not get in eyes. Keep container closed. Use only with adequate ventilation. Wash thoroughly after handling. Store at room temperature 25 C (77 F) or lower. Prevent from freezing

3 KODAK PMT 3 Activator Page 3/6 8. Exposure Controls, Personal Protection Engineering Controls Personal Protection Eyes Body Respiratory Protective Clothing (Pictograms) Hands Feet Use good general ventilation(>1 air changes/hour) and engineering controls (local exhaust, filter's, process enclosures if necessary) to maintain airborne levels below ACGIH Threshold Limit Values (TLV) and OSHA Permissible Exposure Limits(PEL). Ensure that eyewash station and safety shower is proximal to the workstation location. Safety glasses. Wear appropriate respirator when ventilation is inadequate. Gloves (impervious). Personal Protection in Case of a Large Spill Product Name Splash goggles. Lab coat. Gloves (impervious). Ventilation is normally required when handling or using this product. Exposure Limits 1) Water Not available. 2) Sodium sulfite Not available. 3) Sodium thiosulfate Not available. 4) 2Methylaminoethanol Not available. 5) Glycerol TWA 1 (mg/m 3 ) 6) Hydroquinone TWA 2 (mg/m 3 ) STEL 4 (mg/m 3 ) Consult local authorities for acceptable exposure limits. 9. Physical and Chemical Properties Physical State and Appearance Liquid. Odor Odorless. Color Orange. (Light.) ph 11 [Basic.] Boiling/Condensation Point >1 C (212 F) Melting/Freezing Point < C (32 F) Density Specific Gravity 1.76 (Water = 1) Vapor Pressure 2.4 kpa (@ 2 C) Vapor Density.6 (Air = 1) Volatility 95% (w/w). VOC Calculated g/l (.988 lbs/gal.). Ionicity (in Water) Dispersion Properties See solubility in cold water Solubility Easily soluble in cold water

4 KODAK PMT 3 Activator Page 4/6 1. Stability and Reactivity Stability and Reactivity Conditions of Instability The product is stable. Incompatibility with Various Substances Hazardous Decomposition Products Hazardous Polymerization Incompatible with some strong acids. These products are carbon oxides (CO, CO2), sulfur oxides (SO2, SO3...). Will not occur. 11. Toxicological Information Toxicity to Animals Chronic Effects on Humans Other Toxic Effects on Humans Water ORAL (LD5) Acute >9 mg/kg [Rat]. Sodium sulfite ORAL (LD5) Acute 64 mg/kg [Rat]. Sodium thiosulfate ORAL (LD5) Acute >5 mg/kg [Rat]. 2Methylaminoethanol ORAL (LD5) Acute 234 mg/kg [Rat]. Glycerol ORAL (LD5) Acute 126 mg/kg [Rat]. DERMAL (LD5) Acute >1 mg/kg [Rabbit]. Hydroquinone ORAL (LD5) Acute 32 mg/kg [Rat]. DERMAL (LD5) Acute 9 mg/kg [Rat, Rabbit]. CARCINOGENIC EFFECTS Classified None. by OSHA [Sodium sulfite]. Classified None. by OSHA [2Methylaminoethanol]. Classified 3 (Not classifiable for human.) by IARC [Hydroquinone]. Hazardous in case of skin contact (irritant). of eye contact (irritant) 12. Ecological Information Biodegradable/OECD BOD5 and COD Ecotoxicity Toxicity of the Products of Biodegradation Not available. Ecotoxicity in water (LC5) 26 mg/l 96 hours [Fish]. 69 mg/l 48 hours [Daphnia]. (Sodium sulfite). 1 mg/l 96 hours [Fish]. (2Methylaminoethanol). The product itself and its products of degradation are not toxic. 13. Disposal Considerations Waste Information Waste must be disposed of in accordance with federal, state and local environmental control regulations. Consult your local or regional authorities. 14. Transport Information DOT Classification Not a DOT controlled material (United States). Marine Pollutant Hazardous Substances Reportable Quantity

5 KODAK PMT 3 Activator Page 5/6 Special Provisions for Transport TDG Classification ADR/RID Classification IMO/IMDG Classification ICAO/IATA Classification Not controlled under TDG (Canada). Not controlled under ADR (Europe). Not controlled under IMDG. Not controlled under IATA. 15. Regulatory Information HCS Classification U.S. Federal Regulations International Regulations WHMIS (Canada) CLASS Irritating substance. TSCA 8(b) inventory Water; Sodium sulfite; Sodium thiosulfate; 2Methylaminoethanol; Glycerol; Hydroquinone SARA 32/34/311/312 extremely hazardous substances No products were found. SARA 32/34 emergency planning and notification Hydroquinone SARA 32/34/311/312 hazardous chemicals No products were found. SARA 311/312 MSDS distribution chemical inventory hazard identification Sodium sulfite immediate health hazard, delayed health hazard; 2Methylaminoethanol fire, immediate health hazard; Hydroquinone immediate health hazard, delayed health hazard SARA 313 toxic chemical notification and release reporting Hydroquinone.9% Clean Water Act (CWA) 37 No products were found. Clean Water Act (CWA) 311 No products were found. Clean air act (CAA) 112 accidental release prevention No products were found. Clean air act (CAA) 112 regulated flammable substances No products were found. Clean air act (CAA) 112 regulated toxic substances No products were found. CLASS D2B Material causing other toxic effects (TOXIC). This product has been classified in accordance with hazard criteria of the Controlled Products Regulations and the MSDS contains all the information required by the Controlled Products Regulations. DSCL (EEC) International Lists State Regulations CEPA DSL Water; Sodium sulfite; Sodium thiosulfate; 2Methylaminoethanol; Glycerol; Hydroquinone R36/37/38 Irritating to eyes, respiratory system and skin. No products were found. California prop. 65 No products were found. 16. Other Information Label Requirements CAUSES SKIN AND EYE IRRITATION. MAY CAUSE ALLERGIC SKIN REACTION. MAY BE HARMFUL IF SWALLOWED. Hazardous Material Information System (U.S.A.) Health Fire Hazard Reactivity Personal Protection 2 B National Fire Protection Association (U.S.A.) Health 1 Fire Hazard Reactivity Specific Hazard References Other Special Considerations Not available. Not available. Validated by Kodak Polychrome Graphics on In Case of Emergency CALL Verified by Kodak Polychrome Graphics. Printed

6 KODAK PMT 3 Activator Page 6/6 Notice to Reader To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor any of its subsidiaries assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist.