SC Johnson Professional Restroom Hard Surface Cleaner Concentrate

Transcription

1 1. PRODUCT AND COMPANY IDENTIFICATION Product information Product name : SC Johnson Professional Restroom Hard Surface Cleaner Concentrate Recommended use : This product is intended to be diluted prior to use. Manufacturer, importer, supplier : S.C. Johnson & Son, Inc Howe Street Racine WI Telephone : Emergency telephone number : 24 Hour Medical Emergency Phone: (866) Hour International Emergency Phone: (703) Hour Transport Emergency Phone: (800) HAZARDS IDENTIFICATION Classification of the substance or mixture Globally Harmonized System (GHS) Classification Hazard classification Hazard category Hazards identification Skin corrosion Category 1 Causes severe skin burns and eye damage. Serious eye damage Category 1 Causes serious eye damage. Labelling Hazard symbols Corrosion Signal word Danger Hazard statements Causes severe skin burns and eye damage. Precautionary statements If medical advice is needed, have product container or label at hand. Keep out of reach of children. Read label before use. 1/13

2 Immediately call a POISON CENTER or doctor/ physician. Specific treatment (see supplemental first aid instructions on this label). IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. IF ON SKIN (or hair): Remove/ Take off immediately all contaminated clothing. Rinse skin with water/ shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. Wash contaminated clothing before reuse. Store locked up. Dispose of contents/ container to an approved incineration plant. Wear protective gloves. Do not breathe dust or mist. Wash hands thoroughly after handling. Other hazards : None identified 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name CAS-No. Weight percent Citric acid Fatty alcohol alkoxylate EO= Lactic Acid Ethoxylated Linear Alcohol 9 EO Benzyl Salicylate The specific chemical identity and/or exact percentage (concentration) of this composition has been withheld as a trade secret. For additional information on product ingredients, see 4. FIRST AID MEASURES Eye contact : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/ physician. Get medical attention immediately. Skin contact : IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. Wash contaminated 2/13

3 clothing before reuse. Immediately call a POISON CENTER or doctor/ physician. Inhalation : IF INHALED: If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing. Ingestion : IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. 5. FIREFIGHTING MEASURES Suitable extinguishing media Specific hazards during firefighting : Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. : Container may melt and leak in heat of fire. Further information : Wear full protective clothing and positive pressure selfcontained breathing apparatus. In case of fire and/or explosion do not breathe fumes. 6. ACCIDENTAL RELEASE MEASURES Personal precautions : Wear personal protective equipment. Wash thoroughly after handling. Environmental precautions Methods and materials for containment and cleaning up : Outside of normal use, avoid release to the environment. : Dike large spills. Clean residue from spill site. 7. HANDLING AND STORAGE Handling Precautions for safe handling : Avoid contact with skin, eyes and clothing. For personal protection see section 8. Use only as directed. KEEP OUT OF REACH OF CHILDREN AND PETS. 3/13

4 Avoid breathing vapours, mist or gas. Wash thoroughly after handling. Advice on protection against fire and explosion Storage Requirements for storage areas and containers : Normal measures for preventive fire protection. : Keep container closed when not in use. Store locked up. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Occupational Exposure Limits ACGIH or OSHA exposure limits have not been established for this product or reportable ingredients unless noted in the table above. Personal protective equipment Respiratory protection : Substantial amounts of mist/vapors can be controlled with local exhaust ventilation or respiratory protection. Hand protection : Rubber gloves Eye protection : Wear splash-resistant Chemical goggles. Skin and body protection : Protective footwear. Hygiene measures : Handle in accordance with good industrial hygiene and safety practice. Wash thoroughly after handling. 9. PHYSICAL AND CHEMICAL PROPERTIES Form : liquid Color : green Odor : pleasant Odour Threshold 4/13

5 ph : 1.94 at (25 C) Melting point/freezing point Initial boiling point and boiling range Flash point : does not flash Evaporation rate Flammability (solid, gas) : The product is not flammable. Upper/lower flammability or explosive limits Vapour pressure Vapour density Relative density : g/cm3 at 20 Cestimated Solubility(ies) : soluble Partition coefficient: n- octanol/water Auto-ignition temperature 5/13

6 Decomposition temperature Viscosity, dynamic Viscosity, kinematic Oxidizing properties Volatile Organic Compounds Total VOC (wt. %)* : 0.9 % - additional exemptions may apply *as defined by US Federal and State Consumer Product Regulations Other information : None identified : 10. STABILITY AND REACTIVITY Possibility of hazardous reactions Possibility of hazardous reactions Conditions to avoid : Stable under recommended storage conditions. : Stable under recommended storage conditions. : Direct sources of heat. Incompatible materials : None known. Hazardous decomposition products : Thermal decomposition can lead to release of irritating gases and vapours. 11. TOXICOLOGICAL INFORMATION Emergency Overview : Danger Acute oral toxicity : NA GHS LD50 Calculated 6/13

7 > 5,000 mg/kg Acute inhalation toxicity : NA GHS LC50 (dust and mist) Calculated > 5.0 mg/l Acute dermal toxicity : NA GHS LD50 > 5,000 mg/kg GHS Properties Classification Routes of entry Acute toxicity No classification proposed Oral Acute toxicity No classification proposed Dermal Acute toxicity No classification proposed Inhalation - Dust and Mist Acute toxicity No classification proposed Inhalation - Vapour Acute toxicity No classification proposed Inhalation - Gas Skin corrosion Category 1 - Serious eye damage Category 1 - Skin sensitisation No classification proposed - Respiratory No classification proposed - sensitisation Germ cell mutagenicity No classification proposed - Carcinogenicity No classification proposed - Reproductive toxicity No classification proposed - Specific target organ toxicity - single exposure Specific target organ toxicity - repeated exposure No classification proposed - No classification proposed - 7/13

8 Aspiration hazard No classification proposed - Aggravated Medical Condition : Individuals with chronic respiratory disorders such as asthma, chronic bronchitis, emphysema, etc. may be more susceptible to irritating effects 12. ECOLOGICAL INFORMATION Product : The product itself has not been tested. Toxicity The ingredients in this formula have been reviewed and no adverse impact to the environment is expected when used according to label directions. Toxicity to fish Components End point Species Value Exposure time Citric acid 440 mg/l 48 h static test LC50 OECD Test Guideline 203 Leuciscus idus (Golden orfe) Fatty alcohol alkoxylate EO=7 LC50 Danio rerio (zebra fish) mg/l 96 h Lactic Acid static test LC50 Oncorhynchus mykiss (rainbow trout) mg/l 96 h Ethoxylated Linear Alcohol 9 EO static test LC50 Pimephales promelas (fathead minnow) mg/l 96 h 8/13

9 Benzyl Salicylate semistatic test LC50 Danio rerio (zebra fish) 1.03 mg/l 96 h Toxicity to aquatic invertebrates Components End point Species Value Exposure time Citric acid EC50 Daphnia magna (Water flea) 1,535 mg/l 24 h Fatty alcohol alkoxylate EO=7 EC50 Daphnia (water flea) mg/l 48 h Lactic Acid static test EC50 Daphnia magna (Water flea) 130 mg/l 48 h Ethoxylated Linear Alcohol 9 EO EC50 Daphnia magna (Water flea) 4.1 mg/l 48 h Benzyl Salicylate static test EC50 Daphnia magna (Water flea) 1.16 mg/l 48 h Toxicity to aquatic plants Components End point Species Value Exposure time Citric acid NOEC Algae 425 mg/l 8 d Fatty alcohol alkoxylate EO=7 EC50 Scenedesmus quadricauda (Green 9/ mg/l 72 h

10 algae) Lactic Acid static test EC50 Pseudokirchneriella subcapitata (green algae) > 2,800 mg/l 72 h Ethoxylated Linear Alcohol 9 EO Benzyl Salicylate No data available static test EC50 OECD Test Guideline 201 Pseudokirchneriella subcapitata (green algae) 1.29 mg/l 72 h Persistence and degradability Component Biodegradation Exposure Summary time Citric acid 97 % 28 d Readily biodegradable Fatty alcohol alkoxylate EO=7 > 60 % 28 d Readily biodegradable Lactic Acid 67 % 20 d Ethoxylated Linear Alcohol 9 65 % 28 d Readily biodegradable EO Benzyl Salicylate 93 % 28 d Readily biodegradable Bioaccumulative potential Component Bioconcentration factor (BCF) Partition Coefficient n- Octanol/water (log) Citric acid No data available Fatty alcohol alkoxylate EO=7 No data available No data available Lactic Acid No data available Ethoxylated Linear Alcohol 9 No data available < 6.2 EO Benzyl Salicylate 1,136 Read-across (Analogy) 4 10/13

11 Mobility Component End point Value Citric acid No data available Fatty alcohol alkoxylate EO=7 No data available - Lactic Acid log Koc < 1.32 Ethoxylated Linear Alcohol 9 log Koc EO Benzyl Salicylate log Koc 3.75 Measured PBT and vpvb assessment Component Citric acid Fatty alcohol alkoxylate EO=7 Lactic Acid Ethoxylated Linear Alcohol 9 EO Benzyl Salicylate Results Not fulfilling PBT and vpvb criteria Not fulfilling PBT and vpvb criteria Not fulfilling PBT and vpvb criteria Not fulfilling PBT and vpvb criteria Not fulfilling PBT and vpvb criteria Other adverse effects : None known. 13. DISPOSAL CONSIDERATIONS Consumer may discard empty container in trash, or recycle where facilities exist. 14. TRANSPORT INFORMATION Please refer to the Bill of Lading/receiving documents for up-to-date shipping information. 11/13

12 Land transport Sea transport Air transport UN number UN proper shipping name UN3265, Corrosive Liquid, Acidic, Organic, N.O.S. (lactic acid), 8, III UN3265, Corrosive Liquid, Acidic, Organic, N.O.S. (lactic acid), 8, III UN3265, Corrosive Liquid, Acidic, Organic, N.O.S. (lactic acid), 8, III Transport hazard class(es) Packing group III III III Environmental hazards Special precautions for user 15. REGULATORY INFORMATION Limited quantities derogation may be applicable to this product, please check transport documents. Limited quantities derogation may be applicable to this product, please check transport documents. Limited quantities derogation may be applicable to this product, please check transport documents. Notification status : All ingredients of this product are listed or are excluded from listing on the U.S. Toxic Substances Control Act (TSCA) Chemical Substance Inventory. California Prop. 65 : This product is not subject to the reporting requirements under California's Proposition 65. State Right To Know No components are subject to the Massachusetts Right to Know Act. No components are subject to the Minnesota "Right To Know" Act No components are subject to the New Jersey "Right To Know" Act Pennsylvania RTKL Water Citric acid Fatty alcohol alkoxylate EO= Lactic Acid /13

13 16. OTHER INFORMATION HMIS Ratings Health 3 Flammability 0 Reactivity 0 NFPA Ratings Health 3 Fire 0 Reactivity 0 Special - This information is being provided in accordance with the Occupational Safety and Health Administration (OSHA) regulation (29 CFR ). The information supplied is designed for workplaces where product use and frequency of exposure exceeds that established for the labeled consumer use. Further information This document has been prepared using data from sources considered to be technically reliable. It does not constitute a warranty, expressed or implied, as to the accuracy of the information contained herein. Actual conditions of use are beyond the seller's control. User is responsible to evaluate all available information when using product for any particular use and to comply with all Federal, State, Provincial and Local laws and regulations. Prepared by SC Johnson Global Safety Assessment & Regulatory Affairs (GSARA) 13/13

14 SC Johnson Professional Ready-to-Use Restroom Hard Surface Cleaner Revision Date 06/22/2015 SDS Number PRODUCT AND COMPANY IDENTIFICATION Product information Product name : SC Johnson Professional Ready-to-Use Restroom Hard Surface Cleaner Recommended use : Hard Surface Cleaner Manufacturer, importer, supplier : S.C. Johnson & Son, Inc Howe Street Racine WI Telephone : Emergency telephone number : 24 Hour Medical Emergency Phone: (866) Hour International Emergency Phone: (703) Hour Transport Emergency Phone: (800) HAZARDS IDENTIFICATION Classification of the substance or mixture Globally Harmonized System (GHS) Classification This product does not meet the criteria for classification in any hazard class according to regulation OSHA 29 CFR Labelling Precautionary statements Other hazards : None identified 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name CAS-No. Weight percent Lactic Acid The specific chemical identity and/or exact percentage (concentration) of this composition has been withheld as a trade secret. 1/10

15 SC Johnson Professional Ready-to-Use Restroom Hard Surface Cleaner Revision Date 06/22/2015 SDS Number For additional information on product ingredients, see 4. FIRST AID MEASURES Eye contact : No special requirements Skin contact : No special requirements Inhalation : No special requirements. Ingestion : No special requirements 5. FIREFIGHTING MEASURES Suitable extinguishing media Specific hazards during firefighting : Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. : Container may melt and leak in heat of fire. Further information : Fight fire with normal precautions from a reasonable distance. Standard procedure for chemical fires. Wear full protective clothing and positive pressure self-contained breathing apparatus. 6. ACCIDENTAL RELEASE MEASURES Personal precautions : Wash thoroughly after handling. Environmental precautions Methods and materials for containment and cleaning up : Outside of normal use, avoid release to the environment. : Dike large spills. Clean residue from spill site. 2/10

16 SC Johnson Professional Ready-to-Use Restroom Hard Surface Cleaner Revision Date 06/22/2015 SDS Number HANDLING AND STORAGE Handling Precautions for safe handling Advice on protection against fire and explosion Storage Requirements for storage areas and containers : Avoid contact with skin, eyes and clothing. For personal protection see section 8. KEEP OUT OF REACH OF CHILDREN AND PETS. : Normal measures for preventive fire protection. : Keep container closed when not in use. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Occupational Exposure Limits ACGIH or OSHA exposure limits have not been established for this product or reportable ingredients unless noted in the table above. Personal protective equipment Respiratory protection : No special requirements. Hand protection : No special requirements. Eye protection : No special requirements. Skin and body protection : No special requirements. Hygiene measures : Handle in accordance with good industrial hygiene and safety practice. Wash thoroughly after handling. 9. PHYSICAL AND CHEMICAL PROPERTIES Form : liquid Color : green 3/10

17 SC Johnson Professional Ready-to-Use Restroom Hard Surface Cleaner Revision Date 06/22/2015 SDS Number Odor : pleasant Odour Threshold ph : 2.28 at (25 C) Melting point/freezing point Initial boiling point and boiling range Flash point : does not flash Evaporation rate Flammability (solid, gas) : The product is not flammable. Upper/lower flammability or explosive limits Vapour pressure Vapour density Relative density : g/cm3 at 20 Cestimated Solubility(ies) : soluble Partition coefficient: n- 4/10

18 SC Johnson Professional Ready-to-Use Restroom Hard Surface Cleaner Revision Date 06/22/2015 SDS Number octanol/water Auto-ignition temperature Decomposition temperature Viscosity, dynamic Viscosity, kinematic Oxidizing properties Volatile Organic Compounds Total VOC (wt. %)* : 0.1 % - additional exemptions may apply *as defined by US Federal and State Consumer Product Regulations Other information : None identified : 10. STABILITY AND REACTIVITY Possibility of hazardous reactions Possibility of hazardous reactions Conditions to avoid : Stable under recommended storage conditions. : Stable under recommended storage conditions. : Direct sources of heat. Incompatible materials : None known. Hazardous decomposition products : Thermal decomposition can lead to release of irritating gases and vapours. 5/10

19 SC Johnson Professional Ready-to-Use Restroom Hard Surface Cleaner Revision Date 06/22/2015 SDS Number TOXICOLOGICAL INFORMATION Emergency Overview : This product does not meet the criteria for classification in any hazard class according to regulation OSHA 29 CFR Acute oral toxicity : NA GHS LD50 Calculated > 5,000 mg/kg Acute inhalation toxicity : NA GHS LC50 (dust and mist) Calculated > 5.0 mg/l Acute dermal toxicity : NA GHS LD50 Calculated > 5,000 mg/kg GHS Properties Classification Routes of entry Acute toxicity No classification proposed Oral Acute toxicity No classification proposed Dermal Acute toxicity No classification proposed Inhalation - Dust and Mist Acute toxicity No classification proposed Inhalation - Vapour Acute toxicity No classification proposed Inhalation - Gas Skin corrosion/irritation No classification proposed - Serious eye No classification proposed - damage/eye irritation Skin sensitisation No classification proposed - Respiratory No classification proposed - sensitisation Germ cell mutagenicity No classification proposed - 6/10

20 SC Johnson Professional Ready-to-Use Restroom Hard Surface Cleaner Revision Date 06/22/2015 SDS Number Carcinogenicity No classification proposed - Reproductive toxicity No classification proposed - Specific target organ No classification proposed - toxicity - single exposure Specific target organ No classification proposed - toxicity - repeated exposure Aspiration hazard No classification proposed - Aggravated Medical Condition : None known. 12. ECOLOGICAL INFORMATION Product : The product itself has not been tested. Toxicity The ingredients in this formula have been reviewed and no adverse impact to the environment is expected when used according to label directions. Toxicity to fish Components End point Species Value Exposure time Lactic Acid 96 h static test LC50 Oncorhynchus mykiss (rainbow trout) mg/l Toxicity to aquatic invertebrates Components End point Species Value Exposure time Lactic Acid 130 mg/l 48 h static test EC50 Daphnia magna (Water flea) 7/10

21 SC Johnson Professional Ready-to-Use Restroom Hard Surface Cleaner Revision Date 06/22/2015 SDS Number Toxicity to aquatic plants Components End point Species Value Exposure time Lactic Acid 72 h static test EC50 Pseudokirchneriella subcapitata (green algae) > 2,800 mg/l Persistence and degradability Component Biodegradation Exposure time Lactic Acid 67 % 20 d Summary Bioaccumulative potential Component Bioconcentration Partition Coefficient n- factor (BCF) Octanol/water (log) Lactic Acid No data available Mobility Component End point Value Lactic Acid log Koc < 1.32 PBT and vpvb assessment Component Lactic Acid Results Not fulfilling PBT and vpvb criteria Other adverse effects : None known. 8/10

22 SC Johnson Professional Ready-to-Use Restroom Hard Surface Cleaner Revision Date 06/22/2015 SDS Number DISPOSAL CONSIDERATIONS Consumer may discard empty container in trash, or recycle where facilities exist. 14. TRANSPORT INFORMATION Please refer to the Bill of Lading/receiving documents for up-to-date shipping information. Land transport Not classified as dangerous in the meaning of transport regulations. Sea transport Not classified as dangerous in the meaning of transport regulations. Air transport Not classified as dangerous in the meaning of transport regulations. 15. REGULATORY INFORMATION Notification status : All ingredients of this product are listed or are excluded from listing on the U.S. Toxic Substances Control Act (TSCA) Chemical Substance Inventory. California Prop. 65 : This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm. 9/10

23 SC Johnson Professional Ready-to-Use Restroom Hard Surface Cleaner Revision Date 06/22/2015 SDS Number OTHER INFORMATION HMIS Ratings Health 0 Flammability 0 Reactivity 0 NFPA Ratings Health 0 Fire 0 Reactivity 0 Special - This information is being provided in accordance with the Occupational Safety and Health Administration (OSHA) regulation (29 CFR ). The information supplied is designed for workplaces where product use and frequency of exposure exceeds that established for the labeled consumer use. Further information This document has been prepared using data from sources considered to be technically reliable. It does not constitute a warranty, expressed or implied, as to the accuracy of the information contained herein. Actual conditions of use are beyond the seller's control. User is responsible to evaluate all available information when using product for any particular use and to comply with all Federal, State, Provincial and Local laws and regulations. Prepared by SC Johnson Global Safety Assessment & Regulatory Affairs (GSARA) 10/10