MATERIAL SAFETY DATA SHEET. 1. Product and Company Identification

Transcription

1 MATERIAL SAFETY DATA SHEET Product Name CAS # Product use Manufacturer LEGEND HMIS/NFPA Severe Serious Moderate Slight Minimal Product and Company Identification Super Iron Out Multi Surface Mixture Rust Stain Remover Iron Out dba Summit Brands 721 Engle Road Fort Wayne, IN US Phone: Emergency Phone: (CHEMTREC) Health Flammability Physical Hazard Personal Protection * 2 B 2 Hazards Identification 2 Emergency overview Potential short term health effects Routes of exposure Eyes Skin Inhalation Ingestion Target organs Chronic effects Signs and symptoms DANGER -- CORROSIVE Contains a potential reproductive toxin Eye, Skin contact, Inhalation, Ingestion Causes chemical burns May cause blindness Causes chemical burns May cause respiratory tract irritation Harmful if swallowed May cause chemical burns to mouth, throat and stomach Eyes Kidney Respiratory system Skin Prolonged or repeated exposure to dilutions can cause drying, defatting and dermatitis The product causes burns of eyes, skin and mucous membranes 3 Composition / Information on Ingredients Ingredient(s) CAS # Percent First aid procedures Eye contact Skin contact Inhalation Ingestion Notes to physician 4 First Aid Measures Immediately flush with cool water Remove contact lenses, if applicable, and continue flushing for 15 minutes Obtain medical attention immediately Immediately flush with water Wash with soap and water Obtain medical attention if irritation persists If symptoms develop move victim to fresh air If symptoms persist, obtain medical attention Do not induce vomiting Rinse mouth with water, then drink one or two glasses of water Obtain medical attention Never give anything by mouth if victim is unconscious, or is convulsing Symptoms may be delayed #2362 Page 1 of 6

2 General advice If you feel unwell, seek medical advice (show the label where possible) Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves Show this safety data sheet to the doctor in attendance Avoid contact with eyes and skin Keep out of reach of children 5 Fire Fighting Measures Flammable properties Not flammable by WHMIS/OSHA criteria Extinguishing media Suitable extinguishing media Treat for surrounding material Unsuitable extinguishing media Protection of firefighters Specific hazards arising from the chemical Protective equipment for firefighters Hazardous combustion products Explosion data Sensitivity to mechanical impact Sensitivity to static discharge Firefighters should wear full protective clothing including self contained breathing apparatus May include and are not limited to: Oxides of carbon Oxides of nitrogen Ammonia Hydrogen fluoride 6 Accidental Release Measures Personal precautions Methods for containment Methods for cleaning up Handling Storage Keep unnecessary personnel away Do not touch or walk through spilled material Do not touch damaged containers or spilled material unless wearing appropriate protective clothing Keep people away from and upwind of spill/leak Stop leak if you can do so without risk Prevent entry into waterways, sewers, basements or confined areas Before attempting clean up, refer to hazard data given above Small spills may be absorbed with non-reactive absorbent and placed in suitable, covered, labelled containers Prevent large spills from entering sewers or waterways Contact emergency services and supplier for advice Never return spills in original containers for re-use 7 Handling and Storage Use good industrial hygiene practices in handling this material Do not get this material in your eyes, on your skin, or on your clothing Keep out of the reach of children Store in a closed container away from incompatible materials #2362 Page 2 of 6

3 Exposure limits Ingredient(s) 8 Exposure Controls / Personal Protection Exposure Limits TWA: 2 mg/m3 STEL: 6 mg/m3 TWA: 1 mg/m3 STEL: 2 mg/m3 TWA: 1 mg/m3 Engineering controls Personal protective equipment Eye / face protection Hand protection Skin and body protection Respiratory protection Use only under good ventilation conditions or with respiratory protection Wear chemical goggles Rubber gloves Confirm with a reputable supplier first As required by employer code Where exposure guideline levels may be exceeded, use an approved NIOSH respirator General hygiene considerations Use good industrial hygiene practices in handling this material When using do not eat or drink Wash hands before breaks and immediately after handling the product Appearance Color Form Odor Odor threshold Physical state 9 Physical and Chemical Properties Clear Colorless Liquid Lime Liquid ph 8-13 Melting point Freezing point Boiling point Flash point Pour point Evaporation rate Flammability limits in air, lower, % by volume Flammability limits in air, upper, % by volume Vapor pressure Vapor density #2362 Page 3 of 6

4 Specific gravity Octanol/water coefficient Auto-ignition temperature Percent volatile C 1 Stability and Reactivity Chemical stability Conditions to avoid Incompatible materials Stable under recommended storage conditions Do not mix with other chemicals Reacts violently with alkaline material Acids Oxidizers Reducing agents Caustics Hazardous decomposition products May include and are not limited to: Oxides of carbon Oxides of nitrogen Ammonia Hydrogen fluoride when heated to decomposition Possibility of hazardous reactions Hazardous polymerization does not occur 11 Toxicological Information Component analysis - LC5 Ingredient(s) Component analysis - Oral LD5 Ingredient(s) LC5 345 mg/kg mouse LD5 Effects of acute exposure Eye Skin Inhalation Ingestion Sensitization Chronic effects Carcinogenicity 13 mg/kg rat 266 mg/kg rat 375 mg/kg rat 1121 mg/kg rat Causes chemical burns May cause blindness Causes chemical burns May cause respiratory tract irritation Harmful if swallowed May cause chemical burns to mouth, throat and stomach Not classified or listed by IARC, NTP, OSHA and ACGIH Not classified or listed by IARC, NTP, OSHA and ACGIH Not classified or listed by IARC, NTP, OSHA and ACGIH ACGIH - Threshold Limit Values - Carcinogens A4 - Not Classifiable as a Human Carcinogen Mutagenicity Not classified or listed by IARC, NTP, OSHA and ACGIH Reproductive effects Teratogenicity Synergistic Materials Ecotoxicity may cause developmental changes based on published data, at doses many times in excess of those that could occur through inhalation of dust in occupational settings Not classified or listed by IARC, NTP, OSHA and ACGIH 12 Ecological Information Because of the low ph of this product, it would be expected to produce significant ecotoxicity upon exposure to aquatic organisms and aquatic systems Ecotoxicity - Freshwater Fish Species Data Hr LC5 Carassius auratus: 12 mg/l [flow-through] Hr LC5 Lepomis macrochirus: 4 mg/l [static] Ecotoxicity - Water Flea Data Hr EC5 Daphnia magna: mg/l Hr EC5 Daphnia magna: mg/l [Static] #2362 Page 4 of 6

5 Environmental effects Aquatic toxicity Persistence / degradability Bioaccumulation / accumulation Partition coefficient Mobility in environmental media Chemical fate information Other adverse effects Waste codes Disposal instructions Waste from residues / unused products Contaminated packaging 13 Disposal Considerations Review federal, provincial, and local government requirements prior to disposal 14 Transport Information US Department of Transportation (DOT) Basic shipping requirements: Proper shipping name Corrosive liquids, nos (UREA, MONOHYDROCHLORIDE) Hazard class UN number Packing group Additional information: Special provisions Packaging exceptions ERG number 8 UN176 II B2, IB2, T11, TP2, TP Transportation of Dangerous Goods (TDG - Canada) Basic shipping requirements: Proper shipping name CORROSIVE LIQUID, NOS (UREA, MONOHYDROCHLORIDE) Hazard class UN number Packing group Additional information: Special provisions UN176 II Regulatory Information Canadian federal regulations This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all the information required by the Controlled Products Regulations Canada - WHMIS - Ingredient Disclosure List % % US Federal regulations This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR All components are on the US EPA TSCA Inventory List #2362 Page 5 of 6

6 Occupational Safety and Health Administration (OSHA) 29 CFR hazardous Yes chemical CERCLA (Superfund) reportable quantity : 1 Superfund Amendments and Reauthorization Act of 1986 (SARA) Hazard categories Immediate Hazard - Yes Delayed Hazard - Yes Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No Section 32 extremely No hazardous substance Section 311 hazardous chemical Yes Clean Air Act (CAA) Clean Water Act (CWA) WHMIS status WHMIS classification WHMIS labeling Controlled Class D - Division 2A, 2B, Class E - Corrosive Material State regulations This product does not contain a chemical known to the State of California to cause cancer, birth defects or other reproductive harm US - California - 8 CCR Section Director's List of Hazardous Substances US - Massachusetts - Right To Know List US - Minnesota - Hazardous Substance List US - New Jersey - Right to Know Hazardous Substance List sn 1445 US - Pennsylvania - RTK (Right to Know) List US - Rhode Island - Hazardous Substance List Toxic; Flammable Inventory name Country(s) or region Inventory name On inventory (yes/no)* Canada Domestic Substances List (DSL) Yes Canada Non-Domestic Substances List (NDSL) No United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory Yes A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s) Disclaimer Effective date Expiry date 16 Other Information Information contained herein was obtained from sources considered technically accurate and reliable While every effort has been made to ensure full disclosure of product hazards, in some cases data is not available and is so stated Since conditions of actual product use are beyond control of the supplier, it is assumed that users of this material have been fully trained according to the requirements of all applicable legislation and regulatory instruments No warranty, expressed or implied, is made and supplier will not be liable for any losses, injuries or consequential damages which may result from the use of or reliance on any information contained in this document 1-Aug-28 1-Aug-211 Prepared by Dell Tech Laboratories Ltd (519) #2362 Page 6 of 6