SAFETY DATA SHEET (Collect Calls Accepted) Skin corrosion/irritation Serious eye damage/eye irritation

Transcription

1 SAFETY DATA SHEET 1. Identification Product identifier Other means of identification Product code Recommended use Recommended restrictions Part A; GB 5, 7, 10 mils Thermally conductive epoxy material used together with Part B. ne known. Manufacturer/Importer/Supplier/Distributor information Manufacturer/Supplier Address: The Bergquist Company West 78th Street Chanhassen, MN n-emergency calls: Contact person: 1.4. Emergency telephone number Chemical Emergency Call CHEMTREC Day or Night Within USA and Canada: Outside USA and Canada: (Collect Calls Accepted) 2. Hazard(s) identification Physical hazards Health hazards Environmental hazards OSHA defined hazards Label elements Skin corrosion/irritation Serious eye damage/eye irritation Sensitization, skin Hazardous to the aquatic environment, acute hazard Hazardous to the aquatic environment, long-term hazard Category 2 Category 2A Category 1 Category 2 Category 2 Signal word Hazard statement Precautionary statement Prevention Response Storage Disposal Warning Causes skin irritation. Causes serious eye irritation. May cause an allergic skin reaction. Toxic to aquatic life with long lasting effects. Avoid breathing mist or vapor. Wash thoroughly after handling. Wear protective gloves/protective clothing/eye protection/face protection. Contaminated work clothing should not be allowed out of the workplace. Avoid release to the environment. If skin irritation or rash occurs: Get medical advice/attention. If on skin: Wash with plenty of water. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. Take off contaminated clothing and wash before reuse. Collect spillage. Store away from incompatible materials. Dispose of contents/container in accordance with local/regional/national/international regulations Version #: 08 Revision date: 12-October-2015 Issue date: 06-February / 7

2 Hazard(s) not otherwise classified (HNOC) Supplemental information ne known. This product is hazardous according to OSHA 29 CFR requirements, therefore a hazard label does apply. 3. Composition/information on ingredients Mixtures Chemical name Phenol, polymer with formaldehyde, glycidyl ether Reaction product: bisphenol-a-(epichlorohydrin) Silane, dichlorodimethyl-, reaction products with silica CAS number % First-aid measures Inhalation Skin contact Eye contact Ingestion Most important symptoms/effects, acute and delayed Indication of immediate medical attention and special treatment needed General information 5. Fire-fighting measures Suitable extinguishing media Unsuitable extinguishing media Specific hazards arising from the chemical Special protective equipment and precautions for firefighters Fire fighting equipment/instructions General fire hazards Move to fresh air. Get medical attention if symptoms occur. Wash the skin immediately with soap and water. If skin irritation or rash occurs: Get medical advice/attention. Immediately flush eyes with plenty of water for 15 minutes. Get medical attention if irritation persists. Rinse mouth thoroughly. Get medical attention if any discomfort occurs. Irritation of eyes and mucous membranes. Irritation of nose and throat. Skin irritation. Sensitization. Treat symptomatically. Take off contaminated clothing and shoes immediately. Wash contaminated clothing before re-use. Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. Use fire-extinguishing media appropriate for surrounding materials. ne known. ne. Self-contained breathing apparatus and full protective clothing must be worn in case of fire. Selection of respiratory protection for firefighting: follow the general fire precautions indicated in the workplace. Move containers from fire area if you can do so without risk. This product is not flammable. 6. Accidental release measures Personal precautions, protective equipment and emergency procedures Methods and materials for containment and cleaning up Environmental precautions Avoid contact with skin and eyes. For personal protection, see Section 8 of the SDS. Sweep up or gather material and place in appropriate container for disposal. For waste disposal, see section 13 of the SDS. Environmental Manager must be informed of all major spillages. 7. Handling and storage Precautions for safe handling Provide adequate ventilation. Avoid contact with skin and eyes. Observe good industrial hygiene practices. Wear appropriate personal protective equipment (See Section 8). Persons with epoxy allergy should not work with this product Version #: 08 Revision date: 12-October-2015 Issue date: 06-February / 7

3 Conditions for safe storage, including any incompatibilities Store in closed original container in a dry place. Store away from incompatible materials. 8. Exposure controls/personal protection Occupational exposure limits US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR ) Components Aluminum oxide (CAS ) US. ACGIH Threshold Limit Values Type Value Form PEL 5 mg/m3 Respirable fraction. 15 mg/m3 Total dust. Components Aluminum oxide (CAS ) Biological limit values Exposure guidelines Appropriate engineering controls Type Value Form TWA 1 mg/m3 Respirable fraction. biological exposure limits noted for the ingredient(s). Follow standard monitoring procedures. Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels below recommended exposure limits. Individual protection measures, such as personal protective equipment Wear approved safety goggles. Eye/face protection Skin protection Hand protection Other Respiratory protection Thermal hazards General hygiene considerations 9. Physical and chemical properties Appearance Odor Physical state Form Color Odor threshold ph Melting point/freezing point Initial boiling point and boiling range Flash point Evaporation rate Flammability (solid, gas) Use suitable protective gloves if risk of skin contact. Suitable gloves can be recommended by the glove supplier. Wear chemical-resistant gloves, footwear and protective clothing appropriate for risk of exposure. Contact chemical protective clothing manufacturer for specific information. In case of inadequate ventilation, use respiratory protection. Wear appropriate thermal protective clothing, when necessary. Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Discard contaminated clothing and footwear that cannot be cleaned. Liquid. Liquid. Liquid. Gray. Slight. Upper/lower flammability or explosive limits Flammability limit - lower t available. (%) Flammability limit - upper (%) Explosive limit - lower (%) Explosive limit - upper (%) Vapor pressure t available. t available. t available Version #: 08 Revision date: 12-October-2015 Issue date: 06-February / 7

4 Vapor density Solubility(ies) Solubility (water) Partition coefficient (n-octanol/water) Auto-ignition temperature Decomposition temperature Viscosity Other information Bulk density Density Explosive properties Oxidizing properties VOC (Weight %) 10. Stability and reactivity Reactivity Chemical stability Possibility of hazardous reactions Conditions to avoid Incompatible materials Hazardous decomposition products Insoluble t available (25 C) t explosive. t oxidizing. t available. The product is stable and non-reactive under normal conditions of use, storage and transport. Material is stable under normal conditions. Hazardous polymerization does not occur. Contact with incompatible materials. Strong oxidizing agents. ne. 11. Toxicological information Information on likely routes of exposure Inhalation Vapors may irritate throat and respiratory system and cause coughing. Skin contact Eye contact Ingestion Symptoms related to the physical, chemical and toxicological characteristics Information on toxicological effects Acute toxicity Components Causes skin irritation. May cause an allergic skin reaction. Causes serious eye irritation. Ingestion may cause irritation and malaise. Irritation of eyes and mucous membranes. Irritation of nose and throat. Skin irritation. Sensitization. t expected to be acutely toxic. Species Reaction product: bisphenol-a-(epichlorohydrin) (CAS ) Acute Dermal LD50 Oral LD50 Skin corrosion/irritation Serious eye damage/eye irritation Respiratory or skin sensitization Respiratory sensitization Skin sensitization Germ cell mutagenicity Carcinogenicity Rat Rat Causes skin irritation. Causes serious eye irritation. May cause an allergic skin reaction. Test Results > 2000 mg/kg > 5000 mg/kg This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA Version #: 08 Revision date: 12-October-2015 Issue date: 06-February / 7

5 IARC Monographs. Overall Evaluation of Carcinogenicity t listed. NTP Report on Carcinogens t listed. OSHA Specifically Regulated Substances (29 CFR ) t regulated. Reproductive toxicity Specific target organ toxicity - single exposure Specific target organ toxicity - repeated exposure Aspiration hazard Chronic effects Further information ne known. ne known. 12. Ecological information Ecotoxicity Components Toxic to aquatic life with long lasting effects. Species Reaction product: bisphenol-a-(epichlorohydrin) (CAS ) Fish LC50 Salmo gairdneri Aquatic Crustacea EC50 Daphnia magna Persistence and degradability data available. Bioaccumulative potential data available. Mobility in soil The product is insoluble in water. Other adverse effects ne known. Test Results 1.5 mg/l, 96 hours 2.7 mg/l, 48 hours 13. Disposal considerations Disposal instructions Local disposal regulations Hazardous waste code Waste from residues / unused products Contaminated packaging 14. Transport information DOT UN number UN proper shipping name Transport hazard class(es) Class Subsidiary risk Label(s) Packing group Environmental hazards Marine pollutant Special precautions for user Special provisions Packaging exceptions Packaging non bulk Packaging bulk IATA UN number Dispose of contents/container in accordance with local/regional/national/international regulations. Dispose of in accordance with local regulations. The waste code should be assigned in discussion between the user, the producer and the waste disposal company. Disposal recommendations are based on material as supplied. Disposal must be in accordance with current applicable laws and regulations, and material characteristics at time of disposal. Since emptied containers may retain product residue, follow label warnings even after container is emptied. UN3082 Environmentally hazardous substances, liquid, n.o.s. (Phenol, polymer with formaldehyde, glycidyl ether, Reaction product: bisphenol-a-(epichlorohydrin)) 9-9 III Read safety instructions, SDS and emergency procedures before handling. 8, 146, 335, IB3, T4, TP1, TP UN Version #: 08 Revision date: 12-October-2015 Issue date: 06-February / 7

6 UN proper shipping name Transport hazard class(es) Class Subsidiary risk Label(s) Packing group Environmental hazards ERG Code Special precautions for user IMDG UN number UN proper shipping name Transport hazard class(es) Class Subsidiary risk Label(s) Packing group Environmental hazards Marine pollutant EmS Special precautions for user Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code 15. Regulatory information US federal regulations Environmentally hazardous substance, liquid, n.o.s. (Phenol, polymer with formaldehyde, glycidyl ether, Reaction product: bisphenol-a-(epichlorohydrin)) 9-9 III 9L Read safety instructions, SDS and emergency procedures before handling. UN3082 Environmentally hazardous substance, liquid, n.o.s. (Phenol, polymer with formaldehyde, glycidyl ether, Reaction product: bisphenol-a-(epichlorohydrin)) 9-9 III F-A, S-F Read safety instructions, SDS and emergency procedures before handling. t applicable. This product is hazardous according to OSHA 29 CFR All components are on the U.S. EPA TSCA Inventory List. TSCA Section 12(b) Export tification (40 CFR 707, Subpt. D) t regulated. OSHA Specifically Regulated Substances (29 CFR ) t regulated. CERCLA Hazardous Substance List (40 CFR 302.4) t listed. Superfund Amendments and Reauthorization Act of 1986 (SARA) Hazard categories Immediate Hazard - Delayed Hazard - Fire Hazard - Pressure Hazard - Reactivity Hazard - SARA 302 Extremely hazardous substance t listed. SARA 311/312 Hazardous chemical SARA 313 (TRI reporting) Chemical name CAS number % by wt. Aluminum oxide Other federal regulations Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List t regulated. Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR ) t regulated. Safe Drinking Water Act (SDWA) t regulated Version #: 08 Revision date: 12-October-2015 Issue date: 06-February / 7

7 US state regulations US. Massachusetts RTK - Substance List WARNING: This product contains a chemical known to the State of California to cause cancer and birth defects or other reproductive harm. US. New Jersey Worker and Community Right-to-Know Act US. Pennsylvania Worker and Community Right-to-Know Law US. Rhode Island RTK US. California Proposition 65 US - California Proposition 65 - Carcinogens & Reproductive Toxicity (CRT): Listed substance Carbon black (CAS ) Reaction product: bisphenol-a-(epichlorohydrin) (CAS ) International Inventories Country(s) or region Inventory name On inventory (yes/no)* Australia Australian Inventory of Chemical Substances (AICS) Canada Canada China Europe Europe Japan Korea New Zealand Philippines United States & Puerto Rico Domestic Substances List (DSL) n-domestic Substances List (NDSL) Inventory of Existing Chemical Substances in China (IECSC) European Inventory of Existing Commercial Chemical Substances (EINECS) European List of tified Chemical Substances (ELINCS) Inventory of Existing and New Chemical Substances (ENCS) Existing Chemicals List (ECL) New Zealand Inventory Philippine Inventory of Chemicals and Chemical Substances (PICCS) Toxic Substances Control Act (TSCA) Inventory *A "" indicates this product complies with the inventory requirements administered by the governing country(s). A "" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing country(s). 16. Other information, including date of preparation or last revision Issue date Revision date Version # 08 NFPA ratings 06-February October References Disclaimer Registry of Toxic Effects of Chemical Substances (RTECS) HSDB - Hazardous Substances Data Bank The data contained herein are furnished for information only and are believed to be reliable. However, Henkel Corporation and its affiliates ( Henkel ) does not assume responsibility for any results obtained by persons over whose methods mentioned herein for a particular purpose, and to adopt such precautions as may be advisable for the protection of property and persons against any hazards that may be involved in the handling and use of any Henkel s products. In light of the foregoing, Henkel specifically disclaims all warranties, express or implied, including warranties of merchantability and fitness for a particular purpose, arising from sale or use of Henkel products. Henkel further disclaims any liability for consequential or incidental damages of any kind, including lost profits Version #: 08 Revision date: 12-October-2015 Issue date: 06-February / 7

8 SAFETY DATA SHEET 1. Identification Product identifier Other means of identification Product code Recommended use Recommended restrictions Part B; GB 5, 7, 10 mils Thermally conductive epoxy material used together with Part A. ne known. Manufacturer/Importer/Supplier/Distributor information Manufacturer/Supplier Address: The Bergquist Company West 78th Street Chanhassen, MN n-emergency calls: Contact person: 1.4. Emergency telephone number Chemical Emergency Call CHEMTREC Day or Night Within USA and Canada: Outside USA and Canada: (Collect Calls Accepted) 2. Hazard(s) identification Physical hazards Health hazards OSHA defined hazards Label elements Hazard symbol Signal word Hazard statement Precautionary statement Prevention Response Storage Disposal Hazard(s) not otherwise classified (HNOC) Supplemental information ne. t applicable. t applicable. Observe good industrial hygiene practices. Wash thoroughly after handling. Store away from incompatible materials. Dispose of waste and residues in accordance with local authority requirements. ne known. This product is not hazardous according to OSHA 29 CFR requirements, therefore a hazard label does not apply. 3. Composition/information on ingredients Mixtures The manufacturer lists no ingredients as hazardous according to OSHA 29 CFR First-aid measures Inhalation Skin contact Eye contact Ingestion Move to fresh air. Get medical attention if symptoms occur. Wash skin with soap and water. Get medical attention if irritation persists after washing. Flush thoroughly with water. If irritation occurs, get medical assistance. Rinse mouth thoroughly. Get medical attention if any discomfort occurs Version #: 07 Revision date: 12-October-2015 Issue date: 06-February / 6

9 Most important symptoms/effects, acute and delayed Indication of immediate medical attention and special treatment needed General information 5. Fire-fighting measures Suitable extinguishing media Unsuitable extinguishing media Specific hazards arising from the chemical Special protective equipment and precautions for firefighters Fire fighting equipment/instructions General fire hazards Under normal conditions of intended use, this material does not pose a risk to health. Treat symptomatically. Get medical attention if any discomfort develops. Use fire-extinguishing media appropriate for surrounding materials. ne known. ne. Self-contained breathing apparatus and full protective clothing must be worn in case of fire. Selection of respiratory protection for firefighting: follow the general fire precautions indicated in the workplace. Move containers from fire area if you can do so without risk. This product is not flammable. 6. Accidental release measures Personal precautions, protective equipment and emergency procedures Methods and materials for containment and cleaning up Environmental precautions Avoid contact with skin and eyes. For personal protection, see Section 8 of the SDS. Sweep up or gather material and place in appropriate container for disposal. For waste disposal, see Section 13 of the SDS. Environmental manager must be informed of all major spillages. 7. Handling and storage Precautions for safe handling Conditions for safe storage, including any incompatibilities Provide adequate ventilation. Avoid contact with skin and eyes. Observe good industrial hygiene practices. Wear appropriate personal protective equipment (See Section 8). Store in closed original container in a dry place. Store away from incompatible materials. 8. Exposure controls/personal protection Occupational exposure limits US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR ) Components Aluminum oxide (CAS ) US. ACGIH Threshold Limit Values Type Value Form PEL 5 mg/m3 Respirable fraction. 15 mg/m3 Total dust. Components Aluminum oxide (CAS ) Biological limit values Exposure guidelines Appropriate engineering controls Type Value Form TWA 1 mg/m3 Respirable fraction. biological exposure limits noted for the ingredient(s). Follow standard monitoring procedures. Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels below recommended exposure limits. Individual protection measures, such as personal protective equipment Risk of contact: Wear approved safety goggles. Eye/face protection Skin protection Hand protection Other Respiratory protection Use suitable protective gloves if risk of skin contact. Suitable gloves can be recommended by the glove supplier. If prolonged or repeated contact is likely, chemical resistant clothing is recommended. In case of inadequate ventilation, use respiratory protection Version #: 07 Revision date: 12-October-2015 Issue date: 06-February / 6

10 Thermal hazards General hygiene considerations Wear appropriate thermal protective clothing, when necessary. Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Discard contaminated clothing and footwear that cannot be cleaned. 9. Physical and chemical properties Appearance Odor Physical state Form Color Odor threshold ph Melting point/freezing point Initial boiling point and boiling range Flash point Evaporation rate Flammability (solid, gas) Liquid. Liquid. Liquid. Gray. Slight. Upper/lower flammability or explosive limits Flammability limit - lower t available. (%) Flammability limit - upper (%) Explosive limit - lower (%) Explosive limit - upper (%) Vapor pressure Vapor density Solubility(ies) Solubility (water) Partition coefficient (n-octanol/water) Auto-ignition temperature Decomposition temperature Viscosity Other information Bulk density Density Explosive properties Oxidizing properties VOC (Weight %) t available. t available. t available. t available. Insoluble t available (25 C) t explosive. t oxidizing. t available. 10. Stability and reactivity Reactivity Chemical stability Possibility of hazardous reactions Conditions to avoid Incompatible materials Hazardous decomposition products The product is stable and non-reactive under normal conditions of use, storage and transport. Material is stable under normal conditions. Hazardous polymerization does not occur. Contact with incompatible materials. Strong oxidizing agents. ne Version #: 07 Revision date: 12-October-2015 Issue date: 06-February / 6

11 11. Toxicological information Information on likely routes of exposure Inhalation Vapors may irritate throat and respiratory system and cause coughing. Skin contact Eye contact Ingestion Symptoms related to the physical, chemical and toxicological characteristics Information on toxicological effects Acute toxicity Skin corrosion/irritation Serious eye damage/eye irritation Respiratory or skin sensitization Respiratory sensitization Skin sensitization Germ cell mutagenicity Carcinogenicity Prolonged skin contact may cause temporary irritation. May cause eye irritation on direct contact. Ingestion may cause irritation and malaise. Under normal conditions of intended use, this material does not pose a risk to health. Under normal conditions of intended use, this material does not pose a risk to health. IARC Monographs. Overall Evaluation of Carcinogenicity t listed. NTP Report on Carcinogens t listed. OSHA Specifically Regulated Substances (29 CFR ) t regulated. Reproductive toxicity Specific target organ toxicity - single exposure Specific target organ toxicity - repeated exposure Aspiration hazard Chronic effects Further information ne known. ne known. 12. Ecological information Ecotoxicity Persistence and degradability Bioaccumulative potential Mobility in soil Other adverse effects The product is not classified as environmentally hazardous. data available. data available. The product is insoluble in water. ne known. 13. Disposal considerations Disposal instructions Local disposal regulations Hazardous waste code Waste from residues / unused products Contaminated packaging Dispose of contents/container in accordance with local/regional/national/international regulations. Dispose of in accordance with local regulations. The waste code should be assigned in discussion between the user, the producer and the waste disposal company. Disposal recommendations are based on material as supplied. Disposal must be in accordance with current applicable laws and regulations, and material characteristics at time of disposal. Since emptied containers retain product residue, follow label warnings even after container is emptied Version #: 07 Revision date: 12-October-2015 Issue date: 06-February / 6

12 14. Transport information DOT t regulated as dangerous goods. IATA t regulated as dangerous goods. IMDG t regulated as dangerous goods. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code 15. Regulatory information US federal regulations t applicable. TSCA Section 12(b) Export tification (40 CFR 707, Subpt. D) t regulated. OSHA Specifically Regulated Substances (29 CFR ) t regulated. CERCLA Hazardous Substance List (40 CFR 302.4) t listed. Superfund Amendments and Reauthorization Act of 1986 (SARA) Hazard categories Immediate Hazard - Delayed Hazard - Fire Hazard - Pressure Hazard - Reactivity Hazard - SARA 302 Extremely hazardous substance t listed. SARA 311/312 Hazardous chemical SARA 313 (TRI reporting) Chemical name CAS number % by wt. Aluminum oxide Other federal regulations Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List t regulated. Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR ) t regulated. Safe Drinking Water Act (SDWA) US state regulations t regulated. US. Massachusetts RTK - Substance List This product does not contain a chemical known to the State of California to cause cancer, birth defects or other reproductive harm. US. New Jersey Worker and Community Right-to-Know Act US. Pennsylvania Worker and Community Right-to-Know Law US. Rhode Island RTK US. California Proposition 65 t Listed. International Inventories Country(s) or region Inventory name On inventory (yes/no)* Australia Australian Inventory of Chemical Substances (AICS) Canada Domestic Substances List (DSL) Version #: 07 Revision date: 12-October-2015 Issue date: 06-February / 6

13 Country(s) or region Inventory name On inventory (yes/no)* Canada n-domestic Substances List (NDSL) China Europe Europe Japan Korea New Zealand Philippines United States & Puerto Rico Inventory of Existing Chemical Substances in China (IECSC) European Inventory of Existing Commercial Chemical Substances (EINECS) European List of tified Chemical Substances (ELINCS) Inventory of Existing and New Chemical Substances (ENCS) Existing Chemicals List (ECL) New Zealand Inventory Philippine Inventory of Chemicals and Chemical Substances (PICCS) Toxic Substances Control Act (TSCA) Inventory *A "" indicates this product complies with the inventory requirements administered by the governing country(s). A "" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing country(s). 16. Other information, including date of preparation or last revision Issue date Revision date Version # 07 NFPA ratings 06-February October References Disclaimer ESIS (European chemical Substances Information System) Registry of Toxic Effects of Chemical Substances (RTECS) HSDB - Hazardous Substances Data Bank The data contained herein are furnished for information only and are believed to be reliable. However, Henkel Corporation and its affiliates ( Henkel ) does not assume responsibility for any results obtained by persons over whose methods mentioned herein for a particular purpose, and to adopt such precautions as may be advisable for the protection of property and persons against any hazards that may be involved in the handling and use of any Henkel s products. In light of the foregoing, Henkel specifically disclaims all warranties, express or implied, including warranties of merchantability and fitness for a particular purpose, arising from sale or use of Henkel products. Henkel further disclaims any liability for consequential or incidental damages of any kind, including lost profits Version #: 07 Revision date: 12-October-2015 Issue date: 06-February / 6