Iron Oxide Yellow 920, medium

Transcription

1 Revised edition: Version: 3 Identification of the Substance/Mixture and of the Company/Undertaking Product Identifier Page 1 Product Name: Iron Oxide Yellow 920, medium Article No.: Relevant identified Uses of the Substance or Mixture and Uses advised against Identified uses: Coloring agent (pigment and dyes), inorganic Uses advised against: Details of the Supplier of the Safety Data Sheet (Producer/Importer) Company: Address: Kremer Pigmente GmbH & Co. KG Hauptstr , Aichstetten, Germany Tel./Fax.: Tel , Fax Internet: info@kremer-pigmente.de Importer: -- Emergency No. Emergency No.: (Mon-Fri 8:00-17:00) Hazards Identification Classification of the Substance or Mixture Classification according to EC Regulation 1272/2008 Classification according to EC Regulation No. 67/548 or No. 1999/45 This product does not require classification and labelling as hazardous according to CLP/GHS. The material is not subject to classification according to EC lists. Safety Phrases: Possible Environmental Effects: Label Elements Classification according to EC Regulation 1272/2008 Hazard designation: This product does not require classification and labelling as hazardous according to CLP/GHS. Not applicable. Signal word: Hazard designation: Safety designation: Hazardous components for labelling: Other Hazards 2

2 Composition/Information on Ingredients Substance Mixture Page 2 Chemical Characterization: Pigment Yellow , FeO(OH) (CAS No , EINECS ); REACH Reg. No Hazardous Ingredients: Additional information: First Aid Measures Description of the First Aid Measures General information: After inhalation: After skin contact: After eye contact: No special measures required. Supply fresh air. If required give artificial respiration. In case of complaints or unconsiousness consult a physician. In case of unconsciousness place patient stable in side position for transportation. In case of unconsciousness place patient stable in side position for transportation. Keep the airways open. Unfasten tight garments (collar, tie, belt). No special measures required. Remove contact lens. Rinse open eyes with plenty of water (10-15 min). Should irritation continue, seek medical advice After ingestion: Most important Symptoms and Effects, both Acute and Delayed No special measures required. Symptoms: No further information available Effects: No further information available. Indication of any Immediate Medical Attention and special Treatment needed Treatment: Fire-Fighting Measures Extinguishing Media Suitable extinguishing media: No further information available. Foam, carbon dioxide (CO2), extinguishing powder, water spray. Unsuitable extinguishing media: None known. 3

3 5. 2. Special Hazards arising from the Substance or Mixture Page Special hazards: Advice for Firefighters Protective equipment: No special hazards. Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode Further information: Accidential Release Measures Personal Precautions, Protective Equipment and Emergency Procedures Personal precautions: Environmental Precautions Wear appropriate protective equipment. Keep spectators away. Ensure adequate ventilation. Floor may be slippery; use care to avoid falling Environmental precautions: Methods and Material for Containment and Cleaning Up Prevent contamination of soil, drains and surface waters. Contact local authorities if product pollutes soil or vegetation Methods and material: Reference to other Sections Handling and Storage Precautions for Safe Handling Instructions on safe handling: Clean up mechanically. Transfer liquids and solid diking material to separate suitable containers for recovery or disposal. In case of emergency, see Section 1. Protective clothing, see Section 8. See Section 13 for information on disposal. No special measures necessary if properly handled Hygienic measures: Conditions for Safe Storage, including any Incompatibilities No special measures required. Storage conditions: Requirements for storage areas and containers: Store dry and in the original tightly sealed containers. No special measures necessary. Information on fire and explosion protection: No special measures necessary. 4

4 Storage class (VCI): 13; Non combustible solids Page Further Information: Specific End Use(s) Further information: Exposure Controls/Personal Protection Parameters to be Controlled Parameters to be controlled (DE): TRGS 900 (D 1/06): FeO(OH) TLV: 10 mg/m3 inhalable fraction (general dust limit) TLV: 3 mg/m3 air-borne fraction (general dust limit) Parameters to be controlled (EC): Derived No-Effect Level (DNEL): DNEL/DMEL: 10 mg/m3 (worker, inhalation, long-term exposition - systemic effects) 3 mg/m3 (worker, inhalation, long-term exposition) Predicted No-Effect Concentration (PNEC): Additional Information: Exposure Controls Technical protective measures: Personal Protection General protective measures: Respiratory protection: Hand protection: Protective glove material: Eye protection: Workplace Exposure Limit (WEL): The user must take precautions to ensure that the environmental controls employed are adequate to maintain the exposure level below the WEL. Ensure adequate ventilation, especially in confined areas. Keep away from foodstuffs and drinks. Do not eat, drink or smoke during work. Wash hands before breaks and at the end of work. Wash contaminated clothes before reuse. Dust mask. Protective gloves (EN 374) Safety glasses with protective shields (EN 166). Body protection: Protective clothing. 5

5 Environmental precautions: Physical and Chemical Properties Information on Basic Physical and Chemical Properties Page 5 Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels. Form: Color: Odor: Odor threshold: ph-value: Melting temperature: Boiling temperature: Flash point: Evaporation rate: Flammability (solid, gas): Upper explosion limit: Lower explosion limit: Vapor pressure: Vapor density: Density: Solubility in water: Coefficient of variation (n- Octanol/Water): Auto-ignition temperature: powder yellow odorless (50 g/l H2O) > 1000 C (>1832 F) not available not available not available not determined not determined 4.26 g/cm3 (20 C) insoluble no information available Decomposition temperature: 180 C Viscosity, dynamic: 6

6 Page Explosive properties: Oxidizing properties: Bulk density: Further Information Solubility in solvents: Viscosity, kinematic Burning class: Solvent content: Solid content: Particle size: Other information: Stability and Reactivity Reactivity Chemical Stability Possibility of Hazardous Reactions Conditions to Avoid Conditions to avoid: Thermal decomposition: Imcompatible Materials Hazardous Decomposition Products Further Information Toxicological Information Information on Toxicological Effects Acute Toxicity LD50, oral: LD50, dermal: kg/m3 No further information. The product is stable. This material is considered to be stable. > 180 C. Conversion to Fe2O3. None if stored and handled according to specifications. > mg/kg (rat) LC50, inhalation: > 195 g/m3 (6h, 14d; rat) 7

7 Primary effects Page Irritant effect on skin: Irritant effect on eyes: Inhalation: Ingestion: Sensitization: Mutagenicity: Reproductive toxicity: Cancerogenity: Teratogenicity: Specific target organ toxicity (STOT): Additional toxicological information: Ecological Information Aquatic Toxicity Fish toxicity: Daphnia toxicity: Bacteria toxicity: Non irritating Non-irritating to eyes Chronic toxicity, NOAEC: > 195 mg/m3 (rat, male, 14d, 6h/day, 5 days per week). No information available No sensitizing effect (guinea pig). Not mutagenic (Ames Test) In vitro Mammalian Cell Gene Mutation Test (OECD 476): negative In vitro Mammalian Chromosomal Aberration Test (OECD 473): negative No data available. Negative, intraperitoneal (600 mg/kg, rat, 914 days; 3 injections / 200 mg/kg in 8 weaks) No data available. Chronic effects: Inhalation: Repeated or prolonged inhalation of dust can cause a chronic irritation of the respiratory tract. FeO(OH) LC0: > mg/l (96h, Brachydanio rerio; OECD 203) EC50: > 100 mg/l (48h, Daphnia magna; OECD 202) EC50: > mg/l (3h, active sludge) Algae toxicity: 8

8 Persistency and Degradability Bioaccumulation Mobility Results of PBT- und vpvp Assessment Other Adverse Effects Page 8 Methods for the evaluation of the biological degradability are not applicable for inorganic substances. Not applicable. Water hazard class: Not hazardous. Behaviour in sewage systems: Further ecological effects: No special effects or hazards known AOX Value: Disposal Considerations Waste Treatment Methods Product: If possible reuse product. Dispose of according to official national and local regulations. European Waste Code (EWC): Uncleaned packaging: Uncontaminated packaging may be recycled. Completely empty packaging can be disposed of with the regular waste Waste Code No.: Transport Information UN Number ADR, IMDG, IATA UN Proper Shipping Name ADR/RID: IMDG/IATA: Transport Hazard Classes ADR Class: Hazard no.: Classification code: No hazardous goods according to ADR (land transportation). No hazardous goods according to IMDG. Tunnel no.: 9

9 IMDG Class (sea): Page 9 Hazard no.: EmS No.: IATA Class: Hazard no.: Packaging Group ADR/RID: IMDG: IATA: Environmental Hazards Special Precautions for User None Transportation in Bulk according to Annex II of MARPOL 73/78 and IBC-Code Further Information Regulatory Information Not classified as a dangerous good under transport regulations. Not classified as a dangerous good under transport regulations. Do not store together with foodstuffs. Safety, Health and Environmental Regulations/Legislation specific for the Substance or Mixture Water hazard class: 0, not hazardous Local regulations on chemical accidents: Employment restrictions: Restriction and prohibition of application: Not applicable. EC. REACH, Section XVII, Restrictions on the Manufacture, Placing on the Market and Use of Certain Dangerous Substances, Preparations and Articles: Technical instructions on air quality: Chemical Safety Assessment Further Information Other Information A Chemical Safety Assessment is not necessary for this product. Seveso II Directive: this product is not regulated under this directive. This product should be stored, handled and used in accordance with good hygiene practices and in conformity with any legal regulations. This information contained herein is based on the present state of knowledge and is intended to describe our product from the point of view of safety requirements. It should be 10

10 Page 10 therefore not be construed as guaranteeing specific properties.