Safety Data Sheet BIOWOOD Safety Data Sheet dated 29/4/2010, version 4

Transcription

1 1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING Trade name: Colour: all the colours Trade code: Product type and use: Wood preservative Company: BOERO BARTOLOMEO S.p.A. - Via Macaggi Genova - Tel Fax CF/P. IVA/REG. IMPRESE DI GENOVA Emergency telephone number of the company and/or of an authorised advisory centre: BOERO BARTOLOMEO S.p.A. - Tel Centro Antiveleni - Ospedale San Martino - Genova - Tel.: Competent person responsible for the safety data sheet: sicurezzaprodotti@boero.it 2. HAZARDS IDENTIFICATION Properties / Symbols: Xn Harmful R Phrases: R10 Flammable. R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic R65 Harmful: may cause lung damage if swallowed. R66 Repeated exposure may cause skin dryness or cracking. 3. COMPOSITION/INFORMATION ON INGREDIENTS Hazardous components within the meaning of EEC directive 67/548 and corresponding classification: 60% - 70% dearomatized white spirit N.67/548/CEE: CAS: EC: Xn; R % - 5% solvent naphtha N.67/548/CEE: CAS: EC: Xn,N; R % - 5% white spirit N.67/548/CEE: CAS: EC: Xn,N; R % - 3% 1,2,4-trimethylbenzene N.67/548/CEE: CAS: EC: Xn,Xi,N; R /37/ % - 1% 1,3,5-trimethylbenzene N.67/548/CEE: CAS: EC: Xi,N; R % - 1% xylene [4] N.67/548/CEE: CAS: EC: Xn,Xi; R10-20/21-38 Page 1 of 8

2 0.25% - 0.5% octane [and isomers] N.67/548/CEE: CAS: EC: F,Xn,Xi,N; R % - 0.5% cumene [1] N.67/548/CEE: X CAS: EC: Xn,Xi,N; R % % 2-butanone oxime N.67/548/CEE: CAS: EC: Carc. Cat. 3,Xn,Xi; R % % ethylbenzene N.67/548/CEE: CAS: EC: F,Xn; R mg/kg heptane [and isomers] N.67/548/CEE: CAS: EC: F,Xn,Xi,N; R mg/kg isopropanol N.67/548/CEE: CAS: EC: F,Xi; R mg/kg 2-methylpropan-1-ol N.67/548/CEE: CAS: EC: Xi; R10-37/ FIRST AID MEASURES Contact with skin: Immediately take off all contaminated clothing. Areas of the body that have - or are only even suspected of having - come into contact with the product must be rinsed immediately with plenty of running water and possibly with soap. Contact with eyes: Wash immediately with water for at least 10 minutes. Swallowing: DO NOT INDUCE VOMITING: risk of chemical pneumonitis caused by possible aspiration of liquid hydrocarbons. SEEK A MEDICAL EXAMINATION IMMEDIATELY and present the safety-data sheet. A suspension of activated charcoal in water, or liquid paraffin may be administered. Inhalation: Ventilate the premises. The patient is to be removed immediately from the contaminated premises and made to rest in a well ventilated area. Should the patient feel unwell, OBTAIN MEDICAL ATTENTION. 5. FIRE-FIGHTING MEASURES Recommended extinguishers: In case of fire use CO2 or chemical powder. Never use water. Extinguishers not to be used: in particular. Risks arising from combustion: Avoid inhaling the fumes. Page 2 of 8

3 Protective equipment: Use protection for the respiratory tract. Cool the containers exposed to the fire with water. 6. ACCIDENTAL RELEASE MEASURES Measures for personal safety: Use gloves and protective clothing. Environmental measures: Limit leakages with earth or sand. Eliminate all unguarded flames and possible sources of ignition. Do not smoke. If the product has escaped into a water course, into the drainage system, or has contaminated the ground or vegetation, notify the competent authorities. Cleaning methods: If the product is in a liquid form, stop it from entering the drainage system. Recover the product for re-use if possible, or for elimination. The product might, where appropriate, be absorbed by inert material. After the product has been recovered, rinse the area and materials involved with water. 7. HANDLING AND STORAGE Handling precautions: Avoid contact and inhalation of the vapours. See, too, paragraph 8 below. Do not eat or drink while working. Do not smoke while working. Storage conditions: Always keep the containers tightly closed. Keep away from unguarded flame, sparks, and heat sources. Avoid direct exposure to sunlight. Instructions as regards storage premises: Cool and adequately ventilated. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Precautionary measures: Give adequate ventilation to the premises where the product is stored and/or handled. Respiratory protection: Use adequate protective respiratory equipment: a carbon filter mask with filters certified UNI EN 149 or dust masks certified UNI EN 140. Filters of types A and P1 or similar types may be considered. Protection for hands: Use protective gloves: waterproof rubber gloves certified UNI EN 374. Nitrile gloves provide good protection. Use care in selecting a penetration time of the gloves longer than the foreseen usage time. Eye protection: Use goggles/facemask certified UNI EN 166. Protection for skin: Suitable protective clothing is required for complete skin protection: for example Page 3 of 8

4 coveralls with long sleeves and trousers, rubber boots and apron, etc. Exposure limit(s) (ACGIH): 1,2,4-trimethylbenzene VLE 8h: ppm 20 mg/m ,3,5-trimethylbenzene VLE 8h: ppm 20 mg/m3 100 xylene [4] VLE 8h: ppm 50 - mg/m3 221,Skin VLE short: ppm mg/m3 442,Skin TLV TWA: ppm 100,A4 TLV STEL: ppm 150,A4 octane [and isomers] TLV TWA: ppm 300 TLV STEL: 375 ppm mg/m3 cumene [1] VLE 8h: ppm 20 mg/m3 100,Skin VLE short: ppm 50 mg/m3 25,Skin TLV TWA: ppm 50 ethylbenzene VLE 8h: ppm 100 mg/m3 442,Skin VLE short: ppm 200 mg/m3 884,Skin TLV TWA: ppm 100 A3 TLV STEL: ppm 125 A3 heptane [and isomers] VLE 8h: ppm 500 mg/m TLV TWA: ppm 400 TLV STEL: ppm 500 isopropanol TLV TWA: ppm 200 A4 TLV STEL: ppm 400 A4 2-methylpropan-1-ol TLV TWA: ppm PHYSICAL AND CHEMICAL PROPERTIES Appearance and colour: liquid Odour: ph: Melting point: Boiling point: Flash point: 35 C Solid/gas flammability: Explosive properties: Oxidizing properties: Vapour pressure: Specific gravity (Kg/L) 20 C : Solubility in water: Lipid solubility: Partition c. (n-octanol/h2o): Vapour density: 10. STABILITY AND REACTIVITY Conditions to avoid: Stable under normal conditions. Substances to avoid: Avoid contact with combustible materials. The product could catch fire. Hazardous decomposition products: 11. TOXICOLOGICAL INFORMATION Page 4 of 8

5 There is no toxicological data available on the mixture. Consider the individual concentration of each component to assess toxicological effects resulting from exposure to the mixture. Set out below is the toxicological information relating to the main substances in the preparation. There are no data about toxicological effects of components. See paragraph 3. Acute toxicity: Harmful: may cause lung damage if swallowed. Irritant effects: Eyes: Skin: Inhalation: Corrosive effects: Sensitising effects: Long-term effects: Carcinogenic effects, mutagenic effects, toxic effects for reproduction: 12. ECOLOGICAL INFORMATION List of substances dangerous for the environment and corresponding classification: 3% - 5% solvent naphtha N.67/548/CEE: CAS: EC: % - 5% white spirit N.67/548/CEE: CAS: EC: % - 3% 1,2,4-trimethylbenzene N.67/548/CEE: CAS: EC: % - 1% 1,3,5-trimethylbenzene N.67/548/CEE: CAS: EC: % - 0.5% octane [and isomers] N.67/548/CEE: CAS: EC: R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic 0.25% - 0.5% cumene [1] N.67/548/CEE: X CAS: EC: Adopt good working practices, so that the product is not released into the Waste and disposal have to be controlled and evaluated according to their possible polluting power and to the local law. Page 5 of 8

6 13. DISPOSAL CONSIDERATIONS Recover, if possible. Send to authorised disposal plants or for incineration under controlled conditions. In so doing, comply with the local and national regulations currently in force. Where applicable, refer to the following regulatory provisions : 91/156/EEC, 91/689/EEC, 94/62/EC and subsequent amendments. 14.TRANSPORT INFORMATION Land transport ADR/RID UN no.: UN 1263 Proper shipping name: Paint. Class: 3 ADR Classification code: F1 Packing group: PG III Label: 3 Marittime transport (IMDG) UN no.: UN 1263 Proper shipping name: Paint. IMDG-code: 3 Packing group: PG III Label: 3 Marine Pollutant: - EmS number: F-E/S-E Stowage provisions: A Air transport(iata/icao) UN no.: UN 1263 Proper shipping name: Paint. Class: 3 Packing group: PG III Label: 3 Erg-code: 3L Pkg. inst. passenger and cargo aircraft: 309 Pkg. inst. cargo aircraft only: REGULATORY INFORMATION Council Directive 67/548/EEC (Classification, packaging and labelling of dangerous substances) and subsequent amendments. Commmission Directive 1999/45/EC (Classification, packaging and labelling of dangerous preparation) and subsequent amendments. Commission Directive 98/24/EC (Protection of the health and safety of workers from the risk related to chemical agent). Commission Directive 2000/39/EC and 2006/15/EC (Occupational exposure limit values). Regulation (CE) No. 1907/2006 (REACh). Symbols: Xn Harmful R Phrases: R10 Flammable. Page 6 of 8

7 R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic R65 Harmful: may cause lung damage if swallowed. R66 Repeated exposure may cause skin dryness or cracking. S Phrases: S13 Keep away from food, drink and animal feedingstuffs. S2 Keep out of reach of children. S23 Do not breathe vapour S43 In case of fire use CO2 or chemical powder. Never use water. S46 If swallowed, seek medical advice immediately and show this container or label. S62 If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label. Contents: dearomatized white spirit 2-butanone oxime: May produce an allergic reaction. Notes: PACK1 The packing must be featured by a safety lock for children and have a tactive indications for blind people. Where applicable, refer to the following regulatory provisions : Directive 96/82/EC ( control of major-accident hazards involving dangerous substances) and subsequent amendments. Regulation (EC) nr 648/2004 (detergents). Presidential Decree D.P.R. 303/56 (Health checks). Law by Decree D.L. 81/08 (Health and safety for workers) and subsequent amendments. International Maritime Dangerous Goods Code, IATA Dangerous Goods Regulation, International Carriage of Dangerous Goods by Road (ADR). 16. OTHER INFORMATION Main bibliographic sources: ECDIN - Environmental Chemicals Data and Information Network - Joint Research Centre, Commission of the European Communities SAX's DANGEROUS PROPERTIES OF INDUSTRIAL MATERIALS - Eight Edition - Van Nostrand Reinold ACGIH - Threshold Limit Values edition The information contained herein is based on our state of knowledge at the above-specified date. It refers solely to the product indicated and constitutes no guarantee of particular quality. It is the duty of the user to ensure that this information is appropriate and complete with respect to the specific use intended. This MSDS cancels and replaces any preceding release. Text of R phrases referred to under heading 3: R10 Flammable. R11 Highly flammable. R20 Harmful by inhalation. R20/21 Harmful by inhalation and in contact with skin. R21 Harmful in contact with skin. R36 Irritating to eyes. R36/37/38 Irritating to eyes, respiratory system and skin. R37 Irritating to respiratory system. R37/38 Irritating to respiratory system and skin. R38 Irritating to skin. R40 Limited evidence of a carcinogenic effect. R41 Risk of serious damage to eyes. Page 7 of 8

8 R43 May cause sensitization by skin contact. R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic R65 Harmful: may cause lung damage if swallowed. R66 Repeated exposure may cause skin dryness or cracking. R67 Vapours may cause drowsiness and dizziness. Page 8 of 8