Version 7 Revision Date 04/30/2015 Print Date 05/08/2015

Transcription

1 SECTION 1. IDENTIFICATION Product name : Manufacturer or supplier's details Company : BYK USA Inc. 524 South Cherry Street Wallingford CT Telephone : (203) Visit our web site : address : ehs.byk.usa@altana.com Emergency telephone number : ; CHEMTREC / Recommended use of the chemical and restrictions on use Recommended use : Surface Additive Restrictions on use : Refer to Section 15 for any restrictions that may apply SECTION 2. HAZARDS IDENTIFICATION GHS Classification Flammable liquids : Category 4 Skin sensitisation : Category 1 GHS Label element Hazard pictograms : Signal word Hazard statements Precautionary statements : Warning : H227 Combustible liquid. H317 May cause an allergic skin reaction. : Prevention: P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking. P261 Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray. P272 Contaminated work clothing should not be allowed out of the workplace. P280 Wear protective gloves/ eye protection/ face protection. Response: P302 + P352 IF ON SKIN: Wash with plenty of soap and water. P333 + P313 If skin irritation or rash occurs: Get medical advice/ attention. 1 / 12

2 Other hazards None known. SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS P363 Wash contaminated clothing before reuse. P370 + P378 In case of fire: Use dry sand, dry chemical or alcohol-resistant foam for extinction. Storage: P403 + P235 Store in a well-ventilated place. Keep cool. Disposal: P501 Dispose of contents/ container to an approved waste disposal plant. Chemical nature : Solution of an acrylfunctional polyester modified polydimethylsiloxane Hazardous components Component CAS-No. Concentration (%) Propoxylated Neopentyl Glycol Diacrylate >= 29 - < 30 Glycerol, propoxylated, esters with acrylic acid >= 0 - < 1 SECTION 4. FIRST AID MEASURES If inhaled In case of skin contact In case of eye contact : Remove to fresh air. Administer artificial respiration if necessary. Get medical aid as soon as possible. : Remove contaminated clothing. Wash thoroughly with soap and water. : Immediately flush with plenty of water for at least 20 minutes. Get medical aid. If swallowed : Do not induce vomiting; aspiration hazard. Dilute with 1-2 glasses of water. Get medical aid. If vomiting occurs spontaneously, keep head below hips to prevent aspiration of liquid into lungs. Most important symptoms and effects, both acute and delayed : No information available. SECTION 5. FIREFIGHTING MEASURES 2 / 12

3 Suitable extinguishing media Unsuitable extinguishing media Specific hazards during firefighting Hazardous combustion products Further information Special protective equipment for firefighters : Foam Carbon dioxide (CO2) Dry chemical : No information available. : Cool closed containers exposed to fire with water spray. Will not explode on mechanical impact. : Carbon oxides Nitrogen oxides (NOx) silicone compounds formaldehyde : Keep away from heat and sources of ignition. Keep away from oxidizing agents. : In the event of fire, wear self-contained breathing apparatus. SECTION 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Environmental precautions Methods and materials for containment and cleaning up : Eliminate all sources of ignition. Wear protective equipment: safety glasses, gloves and an appropriate respirator. : Prevent spilled material from entering the ground, water and/or air by using appropriate containment methods. : Stop leak. Dike and contain spill. Pump into salvage tanks and/or absorb with suitable material. Use sparkless shovels to remove material. SECTION 7. HANDLING AND STORAGE Advice on safe handling Conditions for safe storage : Harmful in contact with skin. Avoid contact with skin and eyes. Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray. Ensure all equipment is electrically grounded before beginning transfer operations. Containers should be grounded when being emptied. Vapours may travel to areas away from work site before igniting/flashing back to Vapour source. Keep container tightly closed. Handle as an industrial chemical. : Avoid prolonged exposure to heat, light and temperatures >30 C/86 F. 3 / 12

4 Keep in a dry, cool and well-ventilated place. Keep product and empty container away from heat and sources of ignition. Take measures to prevent the build up of electrostatic charge. Materials to avoid : Keep away from strong bases. Keep away from oxidizing agents. SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Components with workplace control parameters Contains no substances with occupational exposure limit values. Engineering measures : Use with local exhaust ventilation. Personal protective equipment Respiratory protection : Not necessary. Hand protection Material Eye protection Skin and body protection Hygiene measures : Impervious gloves : Safety Glasses Goggles : Choose body protection according to the amount and concentration of the dangerous substance at the work place. : Clean long legged, long sleeved work clothes. Handle in accordance with good industrial hygiene and safety practice. SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance Colour Odour Odour Threshold ph Melting point/freezing point Initial boiling point and boiling range : liquid : yellow : acrylic-like : > F (> C) 4 / 12

5 Flash point Evaporation rate Upper explosion limit Lower explosion limit Vapour pressure Relative vapour density Relative Density/Specific Gravity Density : 180 F (82 C) Method: 49 (Pensky-Martens) : < hpa (68.00 F (20.00 C)) Method: calculated : g/cm3 (68.00 F (20.00 C)) Method: 4 (20 C oscillating U-tube) Bulk density Solubility(ies) Water solubility : Not applicable : immiscible Solubility in other solvents Partition coefficient: n- octanol/water Auto-ignition temperature : > 392 F (> 200 C) Method: DIN Thermal decomposition Viscosity Viscosity, dynamic Viscosity, kinematic SECTION 10. STABILITY AND REACTIVITY Reactivity Chemical stability Possibility of hazardous : Not classified as a reactivity hazard. : Stable at room temperatures; polymerization may occur 5 / 12

6 reactions Conditions to avoid Incompatible materials Hazardous decomposition products : Temp.>30 C, heat/light sources : alkalis Strong oxidizing agents : None known. SECTION 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure Skin contact Skin absorption Inhalation Eyes Ingestion Acute toxicity Acute oral toxicity Acute dermal toxicity : Acute toxicity estimate : > 5,000 mg/kg Method: Calculation method : Acute toxicity estimate : > 5,000 mg/kg Method: Calculation method Components: Propoxylated Neopentyl Glycol Diacrylate: Acute oral toxicity : LD50 (Rat): > 5,000 mg/kg Glycerol, propoxylated, esters with acrylic acid: Acute oral toxicity : LD50 (Rat): 10,000 mg/kg Acute dermal toxicity : LD50 (Rabbit): 5,000 mg/kg Skin corrosion/irritation Remarks Components: Propoxylated Neopentyl Glycol Diacrylate: Species: Rabbit Method: OECD Test Guideline 404 Result: No skin irritation GLP: yes 6 / 12

7 Glycerol, propoxylated, esters with acrylic acid: Species: Rabbit Result: No skin irritation Serious eye damage/eye irritation Remarks Components: Propoxylated Neopentyl Glycol Diacrylate: Species: Rabbit Result: No eye irritation Method: OECD Test Guideline 405 GLP: yes Glycerol, propoxylated, esters with acrylic acid: Species: Rabbit Result: Eye irritation Respiratory or skin sensitisation Remarks Components: Propoxylated Neopentyl Glycol Diacrylate: Test Type: Mouse Local Lymph Node assay (LLNA) Exposure routes: Dermal Species: Mouse Method: OECD Test Guideline 429 Result: Causes sensitisation. GLP: yes Carcinogenicity IARC ACGIH OSHA No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC. No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by ACGIH. No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by OSHA. 7 / 12

8 NTP No component of this product present at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen by NTP. Repeated dose toxicity Remarks: No known chronic health effects. Experience with human exposure Inhalation: Symptoms: None expected. Skin contact: Symptoms: Contact may cause irritation. Eye contact: Symptoms: Contact may cause irritation. Ingestion: Symptoms: Ingestion may irritate the digestive tract. SECTION 12. ECOLOGICAL INFORMATION Ecotoxicity Toxicity to fish : Remarks Persistence and degradability Biodegradability : Remarks Bioaccumulative potential Bioaccumulation : Remarks Mobility in soil No data available 8 / 12

9 Other adverse effects Results of PBT and vpvb assessment Regulation Remarks Additional ecological information : This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vpvb) at levels of 0.1% or higher. 40 CFR Protection of Environment; Part 82 Protection of Stratospheric Ozone - CAA Section 602 Class I Substances This product neither contains, nor was manufactured with a Class I or Class II ODS as defined by the U.S. Clean Air Act Section 602 (40 CFR 82, Subpt. A, App.A + B). : There is no data available for this product. SECTION 13. DISPOSAL CONSIDERATIONS Disposal methods EPA Hazardous Waste Code(s) Waste from residues : Not applicable. : Dispose of in accordance with applicable local/municipal, state/provincial and federal regulations. SECTION 14. TRANSPORT INFORMATION International Regulation IATA-DGR UN/ID No. : UN 3082 Proper shipping name : Environmentally hazardous substance, liquid, n.o.s. (Propoxylated Neopentyl Glycol Diacrylate) Class : 9 Packing group : III Labels : Miscellaneous substances and articles Packing instruction (cargo : 964 aircraft) Packing instruction : 964 (passenger aircraft) IMDG-Code UN number : UN 3082 Proper shipping name : ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Propoxylated Neopentyl Glycol Diacrylate) 9 / 12

10 Class : 9 Packing group : III Labels : 9 EmS Code : F-A, S-F Marine pollutant : no Remarks : IMDG Code segregation group - none Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable for product as supplied. National Regulations 49 CFR UN/ID/NA number : UN 3082 Proper shipping name : Environmentally hazardous substance, liquid, n.o.s. (Propoxylated Neopentyl Glycol Diacrylate) Class : 9 Packing group : III Labels : Miscellaneous substances and articles ERG Code : 171 Marine pollutant : no Container sizes: 55 gallon drums, 5 or 6-gallon pails, 2oz/16oz samples SECTION 15. REGULATORY INFORMATION EPCRA - Emergency Planning and Community Right-to-Know Act CERCLA Reportable Quantity This material does not contain any components with a CERCLA RQ. SARA 304 Extremely Hazardous Substances Reportable Quantity This material does not contain any components with a section 304 EHS RQ. SARA 302 Extremely Hazardous SubstancesReportable Quantity This material does not contain any components with a SARA 302 RQ. SARA 311/312 Hazards SARA 302 SARA 313 : Fire Hazard : No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302. : This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313. Clean Air Act This product does not contain any hazardous air pollutants (HAP), as defined by the U.S. Clean Air Act Section 12 (40 CFR 61). 10 / 12

11 This product does not contain any chemicals listed under the U.S. Clean Air Act Section 112(r) for Accidental Release Prevention (40 CFR , Subpart F). Massachusetts Right To Know No components are subject to the Massachusetts Right to Know Act. Pennsylvania Right To Know Polyester modified polydimethylsiloxanes - Propoxylated Neopentyl Glycol Diacrylate New Jersey Right To Know Polyester modified polydimethylsiloxanes - Propoxylated Neopentyl Glycol Diacrylate New Jersey Trade Secret : Registry Number for the product (NJ TSRN) California Prop 65 This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm. CONEG Heavy Metal: We confirm that we use packaging and/or packaging components in which the sum of the incidental concentration levels of lead, mercury, cadmium and hexavalent chromium do not exceed 100 parts per million by weight. The components of this product are reported in the following inventories: TSCA : We certify that all of the components of this product are either listed on the TSCA Inventory or are not subject to the notification requirements per 40 CFR (h). Section 4 / 12(b) DSL : Not applicable : The following component(s) is/are not listed on the DSL: CEPA Category : Polymer Weight percent : 68 % NSN Filed : Schedule 9 Max. NSN Required : Schedule 10 SECTION 16. OTHER INFORMATION Revision Date : 04/30/2015 The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a 11 / 12

12 guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. 12 / 12