SAFETY DATA SHEET. Revision Date 10-Feb-2015 Revision Number Identification AC ; AC ; AC ; AC ; AC

Transcription

1 SAFETY DATA SHEET Revision Number 1 Product Name Cat No. : 1. Identification 2-Nitroaniline AC ; AC ; AC ; AC ; AC Synonyms 1-amino-2-nitrobenzene; CI 37025; Azoic Diazo Component 6 Recommended Use Laboratory chemicals. Uses advised against No Information available Details of the supplier of the safety data sheet Company Fisher Scientific One Reagent Lane Fair Lawn, NJ Tel: (201) Entity / Business Name Acros Organics One Reagent Lane Fair Lawn, NJ Emergency Telephone Number For information US call: ACROS-01 / Europe call: Emergency Number US: / Europe: CHEMTREC Tel. No.US: / Europe: Hazard(s) identification Classification This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR ) Acute oral toxicity Category 3 Acute dermal toxicity Category 3 Specific target organ toxicity - (repeated exposure) Category 2 Label Elements Signal Word Danger Hazard Statements Toxic if swallowed Toxic in contact with skin May cause damage to organs through prolonged or repeated exposure Precautionary Statements Page 1 / 7

2 Prevention Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product Wear protective gloves/protective clothing/eye protection/face protection Do not breathe dust/fume/gas/mist/vapors/spray Response Get medical attention/advice if you feel unwell Skin IF ON SKIN: Wash with plenty of soap and water Call a POISON CENTER or doctor/physician if you feel unwell Remove/Take off immediately all contaminated clothing Wash contaminated clothing before reuse Ingestion IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician Rinse mouth Storage Store locked up Disposal Dispose of contents/container to an approved waste disposal plant Hazards not otherwise classified (HNOC) Harmful to aquatic life with long lasting effects 3. Composition / information on ingredients Component CAS-No Weight % o-nitroaniline First-aid measures Eye Contact Skin Contact Inhalation Ingestion Most important symptoms/effects Notes to Physician Suitable Extinguishing Media Unsuitable Extinguishing Media Immediate medical attention is required. Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Wash off immediately with soap and plenty of water while removing all contaminated clothes and shoes. Immediate medical attention is required. Remove from exposure, lie down. Move to fresh air. If breathing is difficult, give oxygen. If not breathing, give artificial respiration. Immediate medical attention is required. Clean mouth with water. Get medical attention.. Treat symptomatically 5. Fire-fighting measures Water spray. Carbon dioxide (CO 2). Dry chemical. chemical foam. Flash Point 168 C / F Method - Autoignition Temperature 521 C / F Explosion Limits Upper Lower Sensitivity to Mechanical Impact Sensitivity to Static Discharge Page 2 / 7

3 Specific Hazards Arising from the Chemical Keep product and empty container away from heat and sources of ignition. Hazardous Combustion Products Nitrogen oxides (NOx) Carbon monoxide (CO) Carbon dioxide (CO2) Protective Equipment and Precautions for Firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. NFPA Health 3 Flammability 0 Instability 0 Physical hazards N/A Personal Precautions Environmental Precautions 6. Accidental release measures Ensure adequate ventilation. Use personal protective equipment. See Section 12 for additional ecological information. Avoid release to the environment. Collect spillage. Do not flush into surface water or sanitary sewer system. Methods for Containment and Clean Sweep up or vacuum up spillage and collect in suitable container for disposal. Up Handling Storage Exposure Guidelines 7. Handling and storage Do not breathe dust. Do not get in eyes, on skin, or on clothing. Use only in area provided with appropriate exhaust ventilation. Use explosion-proof equipment. Use only non-sparking tools. Keep in a dry, cool and well-ventilated place. Keep container tightly closed. 8. Exposure controls / personal protection This product does not contain any hazardous materials with occupational exposure limits established by the region specific regulatory bodies. Component Quebec Mexico OEL (TWA) Ontario TWAEV o-nitroaniline TWA: 2 ppm TWA: 10 mg/m 3 STEL: 5 ppm STEL: 20 mg/m 3 Engineering Measures Ensure adequate ventilation, especially in confined areas. Ensure that eyewash stations and safety showers are close to the workstation location. Personal Protective Equipment Eye/face Protection Skin and body protection Respiratory Protection Hygiene Measures Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR or European Standard EN166. Wear appropriate protective gloves and clothing to prevent skin exposure. Follow the OSHA respirator regulations found in 29 CFR or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Handle in accordance with good industrial hygiene and safety practice. 9. Physical and chemical properties Page 3 / 7

4 Physical State Solid Appearance Amber Odor Odorless Odor Threshold ph g/l aq.sol Melting Point/Range C / F Boiling Point/Range 284 C / F Flash Point 168 C / F Evaporation Rate Flammability (solid,gas) Flammability or explosive limits Upper Lower Vapor Pressure C Vapor Density Relative Density Solubility Partition coefficient; n-octanol/water Autoignition Temperature 521 C / F Decomposition Temperature 288 C Viscosity Molecular Formula C6 H6 N2 O2 Molecular Weight Stability and reactivity Reactive Hazard Stability Conditions to Avoid Incompatible Materials None known, based on information available Stable under normal conditions. Incompatible products. Acids, Strong oxidizing agents, Acid anhydrides, Acid chlorides, Chloroformates Hazardous Decomposition Products Nitrogen oxides (NOx), Carbon monoxide (CO), Carbon dioxide (CO2) Hazardous Polymerization Hazardous Reactions Acute Toxicity. None under normal processing. 11. Toxicological information Product Information Component Information Component LD50 Oral LD50 Dermal LC50 Inhalation o-nitroaniline 535 mg/kg ( Rat ) mg/kg ( Rat ) 2529 mg/m 3 ( Rat ) 4 h Toxicologically Synergistic Products Delayed and immediate effects as well as chronic effects from short and long-term exposure Irritation Sensitization Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen. Component CAS-No IARC NTP ACGIH OSHA Mexico o-nitroaniline Not listed Not listed Not listed Not listed Not listed Page 4 / 7

5 Mutagenic Effects Reproductive Effects Developmental Effects Teratogenicity STOT - single exposure STOT - repeated exposure Aspiration hazard Symptoms / effects,both acute and delayed Endocrine Disruptor Information Other Adverse Effects... None known None known See actual entry in RTECS for complete information. 12. Ecological information Ecotoxicity Contains a substance which is:. Harmful to aquatic organisms. The product contains following substances which are hazardous for the environment. Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Toxic to aquatic organisms. Component Freshwater Algae Freshwater Fish Microtox Water Flea o-nitroaniline Not listed mg/l LC50 96 h Not listed mg/l EC50 48 h mg/l EC50 48 h Persistence and Degradability Soluble in water Persistence is unlikely based on information available. Bioaccumulation/ Accumulation. Mobility. Will likely be mobile in the environment due to its water solubility. Component log Pow o-nitroaniline 1.85 Waste Disposal Methods 13. Disposal considerations Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. Chemical waste generators must also consult local, regional, and national hazardous waste regulations to ensure complete and accurate classification. 14. Transport information DOT UN-No UN1661 TDG UN-No UN1661 IATA UN-No 1661 Proper Shipping Name NITROANILINES IMDG/IMO UN-No 1661 Proper Shipping Name NITROANILINES Page 5 / 7

6 International Inventories 15. Regulatory information Component TSCA DSL NDSL EINECS ELINCS NLP PICCS ENCS AICS IECSC KECL o-nitroaniline X X X X X X X Legend: X - Listed E - Indicates a substance that is the subject of a Section 5(e) Consent order under TSCA. F - Indicates a substance that is the subject of a Section 5(f) Rule under TSCA. N - Indicates a polymeric substance containing no free-radical initiator in its inventory name but is considered to cover the designated polymer made with any free-radical initiator regardless of the amount used. P - Indicates a commenced PMN substance R - Indicates a substance that is the subject of a Section 6 risk management rule under TSCA. S - Indicates a substance that is identified in a proposed or final Significant New Use Rule T - Indicates a substance that is the subject of a Section 4 test rule under TSCA. XU - Indicates a substance exempt from reporting under the Inventory Update Rule, i.e. Partial Updating of the TSCA Inventory Data Base Production and Site Reports (40 CFR 710(B). Y1 - Indicates an exempt polymer that has a number-average molecular weight of 1,000 or greater. Y2 - Indicates an exempt polymer that is a polyester and is made only from reactants included in a specified list of low concern reactants that comprises one of the eligibility criteria for the exemption rule. U.S. Federal Regulations TSCA 12(b) SARA 313 SARA 311/312 Hazardous Categorization Acute Health Hazard Chronic Health Hazard Fire Hazard Sudden Release of Pressure Hazard Reactive Hazard Yes Yes No No No Clean Water Act Clean Air Act OSHA Occupational Safety and Health Administration CERCLA California Proposition 65 State Right-to-Know This product does not contain any Proposition 65 chemicals U.S. Department of Transportation Reportable Quantity (RQ): DOT Marine Pollutant DOT Severe Marine Pollutant N N N U.S. Department of Homeland Security This product does not contain any DHS chemicals. Other International Regulations Mexico - Grade Page 6 / 7

7 Canada This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all the information required by the CPR WHMIS Hazard Class D1A Very toxic materials D2B Toxic materials Prepared By 16. Other information Regulatory Affairs Thermo Fisher Scientific Revision Date Print Date Revision Summary 10-Feb Feb-2015 This document has been updated to comply with the US OSHA HazCom 2012 Standard replacing the current legislation under 29 CFR to align with the Globally Harmonized System of Classification and Labeling of Chemicals (GHS) Disclaimer The information provided on this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guide for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered as a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other material or in any process, unless specified in the text. End of SDS Page 7 / 7