SAFETY DATA SHEET. 1. Identification. 2. Hazard(s) identification

Transcription

1 SAFETY DATA SHEET 1. Identification Product identifier Other means of identification SDS number Part. Tariff code Recommended use Recommended restrictions Liquid Wrench Disc & Drum Brake Wheel Bearing Grease GR012 GR Wheel Bearing Grease ne known. Manufacturer/Importer/Supplier/Distributor information Manufacturer Company name RSC Chemical Solutions Address 600 Radiator Road Indian Trail, NC Telephone United States Customer Service: (704) Technical: (704) Website Emergency phone number Emergency Telephone: (303) Emergency Contact: RMPDC (877) Hazard(s) identification Physical hazards Health hazards Environmental hazards OSHA defined hazards Label elements t classified. Germ cell mutagenicity Hazardous to the aquatic environment, acute hazard Hazardous to the aquatic environment, long-term hazard t classified. Category 1B Category 2 Category 2 Signal word Hazard statement Precautionary statement Prevention Response Storage Disposal Hazard(s) not otherwise classified (HNOC) Danger May cause genetic defects. Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Wear protective gloves/protective clothing/eye protection/face protection. If exposed or concerned: Get medical advice/attention. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations. ne known. 1 / 8

2 Supplemental information 87.55% of the mixture consists of component(s) of unknown acute oral toxicity % of the mixture consists of component(s) of unknown acute dermal toxicity. 3. Composition/information on ingredients Mixtures Chemical name Distillates (petroleum), Hydrotreated Heavy Naphthenic Other components below reportable levels NOTE: This product is a consumer product and is labeled in accordance with the US Consumer Product Safety Commission regulations which take precedence over OSHA Hazard Communication labeling. The container label may not include the OSHA label elements listed in this document. Always carefully review the entire SDS and the product label prior to use in the workplace. Common name and synonyms CAS number % *Designates that a specific chemical identity and/or percentage of composition has been withheld as a trade secret. 4. First-aid measures Inhalation Skin contact Eye contact Ingestion Most important symptoms/effects, acute and delayed Indication of immediate medical attention and special treatment needed General information 5. Fire-fighting measures Suitable extinguishing media Unsuitable extinguishing media Specific hazards arising from the chemical Special protective equipment and precautions for firefighters Fire fighting equipment/instructions Specific methods General fire hazards 6. Accidental release measures Personal precautions, protective equipment and emergency procedures Methods and materials for containment and cleaning up Move to fresh air. Call a physician if symptoms develop or persist. Wash off with soap and water. Get medical attention if irritation develops and persists. Rinse with water. Get medical attention if irritation develops and persists. Rinse mouth. Get medical attention if symptoms occur. Direct contact with eyes may cause temporary irritation < < 20 Provide general supportive measures and treat symptomatically. Keep victim under observation. Symptoms may be delayed. IF exposed or concerned: Get medical advice/attention. If you feel unwell, seek medical advice (show the label where possible). Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. Show this safety data sheet to the doctor in attendance. Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2). Do not use water jet as an extinguisher, as this will spread the fire. During fire, gases hazardous to health may be formed. Self-contained breathing apparatus and full protective clothing must be worn in case of fire. Move containers from fire area if you can do so without risk. Use standard firefighting procedures and consider the hazards of other involved materials. unusual fire or explosion hazards noted. Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Wear appropriate protective equipment and clothing during clean-up. Ensure adequate ventilation. Local authorities should be advised if significant spillages cannot be contained. For personal protection, see section 8 of the SDS. Prevent entry into waterways, sewer, basements or confined areas. Stop the flow of material, if this is without risk. Following product recovery, flush area with water. Environmental precautions Never return spills to original containers for re-use. Put material in suitable, covered, labeled containers. For waste disposal, see section 13 of the SDS. Avoid discharge into drains, water courses or onto the ground. 2 / 8

3 7. Handling and storage Precautions for safe handling Conditions for safe storage, including any incompatibilities 8. Exposure controls/personal protection Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Avoid prolonged exposure. Should be handled in closed systems, if possible. Provide adequate ventilation. Wear appropriate personal protective equipment. Observe good industrial hygiene practices. Store locked up. Store in original tightly closed container. Store away from incompatible materials (see Section 10 of the SDS). Occupational exposure limits The following constituents are the only constituents of the product which have a PEL, TLV or other recommended exposure limit. At this time, the other constituents have no known exposure limits. US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR ) Components Type Value Form Distillates (petroleum), Hydrotreated Heavy Naphthenic (CAS ) US. ACGIH Threshold Limit Values Components PEL 5 mg/m3 Mist. Type 2000 mg/m3 500 ppm Value Form Distillates (petroleum), Hydrotreated Heavy Naphthenic (CAS ) US. NIOSH: Pocket Guide to Chemical Hazards Components Type Distillates (petroleum), Hydrotreated Heavy Naphthenic (CAS ) Biological limit values Appropriate engineering controls TWA 5 mg/m3 Inhalable fraction. Ceiling Value 1800 mg/m3 Form STEL 10 mg/m3 Mist. biological exposure limits noted for the ingredient(s). Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. Individual protection measures, such as personal protective equipment Wear safety glasses with side shields (or goggles). Eye/face protection Skin protection Hand protection Other Respiratory protection Thermal hazards General hygiene considerations 9. Physical and chemical properties Appearance Odor Physical state Form Color Wear appropriate chemical resistant gloves. Use of an impervious apron is recommended. In case of insufficient ventilation, wear suitable respiratory equipment. Chemical respirator with organic vapor cartridge and full facepiece if threshold limits are exceeded. Wear appropriate thermal protective clothing, when necessary. Observe any medical surveillance requirements. Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. semi-solid Liquid. Blue green Slight. hydrocarbon 3 / 8

4 Odor threshold ph Melting point/freezing point Initial boiling point and boiling range Flash point Evaporation rate Flammability (solid, gas) -20 F ( C) estimated 500 F (260 C) estimated F (204.4 C) Cleveland Open Cup Upper/lower flammability or explosive limits Flammability limit - lower (%) Flammability limit - upper (%) Explosive limit - lower (%) Explosive limit - upper (%) Vapor pressure Vapor density < 1 Relative density Solubility(ies) Solubility (water) Partition coefficient (n-octanol/water) Auto-ignition temperature Decomposition temperature Viscosity Other information Density Explosive properties Flammability class Oxidizing properties Specific gravity 0.87 VOC 10. Stability and reactivity Reactivity Chemical stability Possibility of hazardous reactions Conditions to avoid Incompatible materials Hazardous decomposition products 11. Toxicological information < 0.13 kpa 600 F ( C) estimated 7.51 lbs/gal t explosive. Combustible IIIB estimated t oxidizing. 1 % w/w The product is stable and non-reactive under normal conditions of use, storage and transport. Material is stable under normal conditions. dangerous reaction known under conditions of normal use. Contact with incompatible materials. Strong oxidizing agents. hazardous decomposition products are known. Information on likely routes of exposure Inhalation Prolonged inhalation may be harmful. Skin contact Eye contact Ingestion Symptoms related to the physical, chemical and toxicological characteristics Information on toxicological effects adverse effects due to skin contact are expected. Direct contact with eyes may cause temporary irritation. Expected to be a low ingestion hazard. Direct contact with eyes may cause temporary irritation. 4 / 8

5 Acute toxicity Skin corrosion/irritation Serious eye damage/eye irritation Respiratory or skin sensitization Respiratory sensitization Skin sensitization Germ cell mutagenicity Carcinogenicity t known. Prolonged skin contact may cause temporary irritation. Direct contact with eyes may cause temporary irritation. t a respiratory sensitizer. This product is not expected to cause skin sensitization. May cause genetic defects. t classifiable as to carcinogenicity to humans. IARC Monographs. Overall Evaluation of Carcinogenicity t listed. OSHA Specifically Regulated Substances (29 CFR ) t regulated. US. National Toxicology Program (NTP) Report on Carcinogens t listed. Reproductive toxicity Specific target organ toxicity - single exposure Specific target organ toxicity - repeated exposure Aspiration hazard Chronic effects 12. Ecological information Ecotoxicity Persistence and degradability Bioaccumulative potential Mobility in soil Other adverse effects 13. Disposal considerations Disposal instructions Local disposal regulations Hazardous waste code Waste from residues / unused products Contaminated packaging 14. Transport information This product is not expected to cause reproductive or developmental effects. t classified. t classified. t likely, due to the form of the product. Prolonged inhalation may be harmful. The product is not classified as environmentally hazardous. However, this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment. data available. data available. other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component. Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Dispose of contents/container in accordance with local/regional/national/international regulations. Dispose in accordance with all applicable regulations. The waste code should be assigned in discussion between the user, the producer and the waste disposal company. Dispose of in accordance with local regulations. Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe manner (see: Disposal instructions). Since emptied containers may retain product residue, follow label warnings even after container is emptied. Empty containers should be taken to an approved waste handling site for recycling or disposal. DOT UN number UN proper shipping name Consumer Commodity Transport hazard class(es) Class ORM-D Subsidiary risk - Packing group Special precautions for user Read safety instructions, SDS and emergency procedures before handling. Special provisions 8, 146, 335, IB3, T4, TP1, TP29 Packaging exceptions 155 Packaging non bulk / 8

6 Packaging bulk 241 IATA UN number UN3082 UN proper shipping name Environmentally hazardous substance, liquid, n.o.s. (Distillates (petroleum), Hydrotreated Heavy Naphthenic) Transport hazard class(es) Class 9 Subsidiary risk - Packing group III Environmental hazards Yes ERG Code 9L Special precautions for user Read safety instructions, SDS and emergency procedures before handling. Other information Passenger and cargo Allowed with restrictions. aircraft Cargo aircraft only Allowed with restrictions. IMDG UN number UN3082 UN proper shipping name ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Distillates (petroleum), Hydrotreated Heavy Naphthenic), MARINE POLLUTANT Transport hazard class(es) Class 9 Subsidiary risk - Packing group III Environmental hazards Marine pollutant Yes EmS F-A, S-F Special precautions for user Read safety instructions, SDS and emergency procedures before handling. Transport in bulk according to t established. t applicable. Annex II of MARPOL 73/78 and the IBC Code IATA; IMDG Marine pollutant General information 15. Regulatory information US federal regulations IMDG Regulated Marine Pollutant. This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR / 8

7 TSCA Section 12(b) Export tification (40 CFR 707, Subpt. D) t regulated. CERCLA Hazardous Substance List (40 CFR 302.4) t listed. SARA 304 Emergency release notification t regulated. OSHA Specifically Regulated Substances (29 CFR ) t regulated. Superfund Amendments and Reauthorization Act of 1986 (SARA) Hazard categories Immediate Hazard - Delayed Hazard - Yes Fire Hazard - Pressure Hazard - Reactivity Hazard - SARA 302 Extremely hazardous substance t listed. SARA 311/312 Hazardous chemical SARA 313 (TRI reporting) t regulated. Other federal regulations Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List t regulated. Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR ) t regulated. Safe Drinking Water Act (SDWA) US state regulations t regulated. California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): This material is not known to contain any chemicals currently listed as carcinogens or reproductive toxins. US. California. Candidate Chemicals List. Safer Consumer Products Regulations (Cal. Code Regs, tit. 22, , subd. (a)) International Inventories Distillates (petroleum), Hydrotreated Heavy Naphthenic (CAS ) Country(s) or region Inventory name On inventory (yes/no)* Australia Australian Inventory of Chemical Substances (AICS) Canada Canada China Europe Europe Japan Korea New Zealand Philippines United States & Puerto Rico Domestic Substances List (DSL) n-domestic Substances List (NDSL) Inventory of Existing Chemical Substances in China (IECSC) European Inventory of Existing Commercial Chemical Substances (EINECS) European List of tified Chemical Substances (ELINCS) Inventory of Existing and New Chemical Substances (ENCS) Existing Chemicals List (ECL) New Zealand Inventory Philippine Inventory of Chemicals and Chemical Substances (PICCS) Toxic Substances Control Act (TSCA) Inventory *A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s) A "" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing country(s). 16. Other information, including date of preparation or last revision Issue date Revision date Version # Yes 7 / 8

8 HMIS ratings NFPA ratings NFPA ratings Health: 0* Flammability: 0 Physical hazard: 0 Health: 0 Flammability: 0 Instability: Disclaimer Revision information The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. This document has undergone significant changes and should be reviewed in its entirety. 8 / 8