SAFETY DATA SHEET V.K.2 FOGGING SOLUTION

Transcription

1 Section: 1. PRODUCT AND COMPANY IDENTIFICATION Product name : Other means of identification : Not applicable. Recommended use : Cleaning product Restrictions on use : Reserved for industrial and professional use. Product dilution information : Product is sold ready to use. Company : Ecolab New Zealand 2 Daniel Place Te Rapa, Hamilton New Zealand Emergency telephone number : (0800 CHEMCALL) Issuing date : Section: 2. HAZARDS IDENTIFICATION HSNO Hazard classification Skin irritation Aquatic toxicity (Acute or Chronic) : 6.3 A : 9.1 D GHS Label element Hazard pictograms : Signal Word Hazard Statements Precautionary Statements Other hazards : Warning : Causes skin irritation. Harmful to aquatic life with long lasting effects. : Prevention: Wash skin thoroughly after handling. Avoid release to the environment. Wear eye protection/face protection. Response: IF ON SKIN: Wash with plenty of soap and water. Specific treatment: consult MSDS Section 4. If skin irritation occurs: Get medical advice/attention. Take off contaminated clothing. Disposal: Dispose of contents/ container to an approved waste disposal plant. Section: 3. COMPOSITION/INFORMATION ON INGREDIENTS Pure substance/mixture : Mixture Chemical Name CAS-No. Concentration: (%) / 7

2 Propylene glycol alcohols, c12-15, ethoxylated Section: 4. FIRST AID MEASURES In case of eye contact In case of skin contact If swallowed If inhaled Protection of first-aiders Notes to physician Most important symptoms and effects, both acute and delayed : Rinse with plenty of water. : Wash off immediately with plenty of water for at least 15 minutes. Use a mild soap if available. Get medical attention if irritation develops and persists. : Rinse mouth. Get medical attention if symptoms occur. : Get medical attention if symptoms occur. : If potential for exposure exists refer to Section 8 for specific personal protective equipment. : Treat symptomatically. : See Section 11 for more detailed information on health effects and symptoms. Section: 5. FIREFIGHTING MEASURES Suitable extinguishing media Unsuitable extinguishing media Specific hazards during firefighting Hazardous combustion products Special protective equipment for firefighters Specific extinguishing methods : Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. : Not flammable or combustible. : Decomposition products may include the following materials: Carbon oxides : Use personal protective equipment. : Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations. In the event of fire and/or explosion do not breathe fumes. Section: 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Environmental precautions Methods and materials for containment and cleaning up : Ensure clean-up is conducted by trained personnel only. Refer to protective measures listed in sections 7 and 8. : Do not allow contact with soil, surface or ground water. : Stop leak if safe to do so. Contain spillage, and then collect with noncombustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local / national regulations (see section 13). Flush away traces with water. For large spills, dike spilled material or otherwise contain / 7

3 Emergency Management Trigger Levels The following triger level applies: material to ensure runoff does not reach a waterway. Emergency Plan Signage : 10,000 L : 10,000 L Section: 7. HANDLING AND STORAGE Advice on safe handling Conditions for safe storage : Avoid contact with skin and eyes. Wash hands thoroughly after handling. : Keep out of reach of children. Keep container tightly closed. Store in suitable labeled containers. Storage temperature : 0 C to 30 C Section: 8. EXPOSURE CONTROLS/PERSONAL PROTECTION with workplace control parameters CAS-No. Form of exposure Propylene glycol WES-TWA (Particulate.) WES-TWA (Vapour and particles) Permissible concentration Basis 10 mg/m3 NZ OEL 150 ppm 474 mg/m3 NZ OEL Engineering measures : Good general ventilation should be sufficient to control worker exposure to airborne contaminants. Personal protective equipment Eye protection Hand protection Skin protection Respiratory protection Hygiene measures : In case of contact through splashing: Wear eye protection/face protection. : Wear the following personal protective equipment: Standard glove type. Gloves should be discarded and replaced if there is any indication of degradation or chemical breakthrough. : No special protective equipment required. : No personal respiratory protective equipment normally required. : Handle in accordance with good industrial hygiene and safety practice. Wash face, hands and any exposed skin thoroughly after handling. Section: 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance : liquid / 7

4 Colour Odour : clear, light pink : odourless ph : , 100 % Flash point Odour Threshold Melting point/freezing point Initial boiling point and boiling range Evaporation rate Flammability (solid, gas) Upper explosion limit Lower explosion limit Vapour pressure Relative vapour density : Not applicable. Relative density : Water solubility Solubility in other solvents Partition coefficient: n- octanol/water Auto-ignition temperature Thermal decomposition Viscosity, kinematic Explosive properties Oxidizing properties Molecular weight VOC : soluble Section: 10. STABILITY AND REACTIVITY Chemical stability Possibility of hazardous reactions Conditions to avoid Incompatible materials Hazardous decomposition products : Stable under normal conditions. : No dangerous reaction known under conditions of normal use. : Decomposition products may include the following materials: Carbon oxides Section: 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure : Inhalation, Eye contact, Skin contact Potential Health Effects / 7

5 Eyes Skin Ingestion Inhalation Chronic Exposure : Causes skin irritation. Experience with human exposure Eye contact Skin contact Ingestion Inhalation : No symptoms known or expected. : Redness, Irritation : No symptoms known or expected. : No symptoms known or expected. Toxicity Product Acute oral toxicity Acute inhalation toxicity Acute dermal toxicity Skin corrosion/irritation Serious eye damage/eye irritation Respiratory or skin sensitization Carcinogenicity Reproductive effects Germ cell mutagenicity Teratogenicity STOT - single exposure STOT - repeated exposure Aspiration toxicity Acute inhalation toxicity : Acute toxicity estimate : > 5,000 mg/kg : Acute toxicity estimate : > 5,000 mg/kg 4 h LC50 rat: > mg/l Section: 12. ECOLOGICAL INFORMATION Ecotoxicity Environmental Effects : Harmful to aquatic life with long lasting effects. Product / 7

6 Toxicity to fish Toxicity to daphnia and other aquatic invertebrates Toxicity to algae Toxicity to fish 96 h LC50: > 10,000 mg/l alcohols, c12-15, ethoxylated 96 h LC50 Pimephales promelas (fathead minnow): 1.4 mg/l Toxicity to daphnia and other aquatic invertebrates Toxicity to algae 48 h EC50: 18,340 mg/l 96 h EC50: 19,000 mg/l Persistence and degradability Readily biodegradable. Bioaccumulative potential no data available Mobility in soil no data available Other adverse effects no data available Section: 13. DISPOSAL CONSIDERATIONS Disposal methods : Where possible recycling is preferred to disposal or incineration. If recycling is not practicable, dispose of in compliance with local regulations. Dispose of wastes in an approved waste disposal facility. The product should not be allowed to enter drains, water courses or the soil. Disposal considerations : Dispose of as unused product. Empty containers should be taken to an approved waste handling site for recycling or disposal. Do not reuse empty containers. Dispose of in accordance with local, state, and federal regulations. Section: 14. TRANSPORT INFORMATION The shipper/consignor/sender is responsible to ensure that the packaging, labeling, and markings are in compliance with the selected mode of transport. Land transport (NZ_DG) Not dangerous goods Sea transport (IMDG/IMO) / 7

7 Not dangerous goods Special precautions for user : None Section: 15. REGULATORY INFORMATION HSNO Approval Number : HSR HSNO Group Standard : Cleaning Products (Subsidiary Hazard) Group Standard The components of this product are reported in the following inventories: United States TSCA Inventory : On TSCA Inventory Canadian Domestic Substances List (DSL) : All components of this product are on the Canadian DSL. Australia. Industrial Chemical (Notification and Assessment) Act : New Zealand. Inventory of Chemicals (NZIoC), as published by ERMA New Zealand : Japan. ENCS - Existing and New Chemical Substances Inventory : Japan. ISHL - Inventory of Chemical Substances (METI) : Korea. Korean Existing Chemicals Inventory (KECI) : Philippines Inventory of Chemicals and Chemical Substances (PICCS) : China Inventory of Existing Chemical Substances : Section: 16. OTHER INFORMATION Issuing date : version : 1.0 Prepared by : Regulatory Affairs REVISED INFORMATION: Significant changes to regulatory or health information for this revision is indicated by a bar in the left-hand margin of the SDS. The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text / 7