TETRA TECH EM INC. February 13, 2008

Transcription

1 TETRA TECH EM INC. February 13, 2008 Greg Haet EH&S Associate Director, Environmental Protection Office of Environment, Health & Safety University of California, Berkeley University Hall, 3rd Floor #1150 Berkeley, CA Subject: Sampling Results for Western Stege Marsh Near-Surface Sediment Samples, University of California, Berkeley, Richmond Field Station, Richmond, California Dear Mr. Haet: Tetra Tech EM Inc. (Tetra Tech) was contracted by the University of California (UC) Berkeley to conduct sampling activities at Richmond Field Station (RFS), in Richmond, California. The objective of the sampling effort was to characterize near-surface sediment in remediated portions of the Western Stege Marsh, as well as evaluate incidental sediment contact by marsh restoration workers. This letter provides the rationale for the selected sampling locations, a summary of field sampling protocols, and sample results. A figure presenting the sampling locations is presented at the end of this letter. Complete analytical results are presented in Attachment 1. Sample Locations Multi-increment sampling was selected for this project to provide a comprehensive and thorough evaluation of chemical concentrations in a specific area of potential exposure, or decision unit. The multi-increment sampling strategy for this project was based on selecting a decision unit to best represent potential exposure by workers performing restoration activities within remediated marsh areas. UC Berkeley provided Tetra Tech with site-specific boundaries of the areas where marsh restoration activities may be performed. Based on this information, it was determined that one decision unit, identified as Western Stege Marsh Decision Unit 1, was sufficient to evaluate possible exposure areas within remediated portions of the marsh under this sampling activity. The location and extent of the Western Stege Marsh Decision Unit 1 is presented on the figure at the end of this letter. Because this was planned as a characterization of near-surface soils, surface sample depths of 0 to 2 inches below ground surface (bgs) were conducted. The rational for this sampling interval is that the sediment to which workers may be exposed during planting or weeding on the marsh plane or that may be migrating in slough channels and being deposited on top of clean bay mud used as backfill in Main Street, Suite 1800, San Francisco, CA Tel Fax

2 Mr. Greg Haet February 13, 2008 Page 2 of 5 Field Sampling Protocols Near-surface sediment samples were collected on January 17, The decision unit was identified in the field based on the decisions discussed above. One multi-increment surface soil sample was collected from the decision unit. The multi-increment soil sample consisted of 50 subsamples, or increment locations, collected from 0 to 3 inches bgs. The multi-increment sampling technique was used to obtain sufficient near-surface soft sediments from the decision unit to account for both compositional and distributional heterogeneity of any possible contamination. The sampling protocol followed these steps: 1. The field sampler began at a corner of the decision unit and sampled in an orthogonal pattern, moving from north to south to collect subsamples from 50 locations with the decision unit. The location of these subsamples was not critical as long as they were distributed throughout the decision unit. The subsamples were collected using one disposable trowel for the decision unit. 2. The 50 subsamples were placed into a clean, stainless steel bowl as they were collected, and mixed to form one composited multi-increment sample. 3. The sediment from the bowl was then redistributed into a 1-inch thick uniform layer (approximately 16 by 24 inches) directly on the surface within the decision unit incremental subsamples of the soil were randomly collected from across the uniform layer described in Step 3 using a disposable spoon and placed in the sample containers provided by the laboratory to form the final sample that was submitted to the analytical laboratory for the analyses listed below. Following collection, the sample jar was labeled, wrapped with protective bubble wrap material, placed into a sealable plastic bag, and packed into an insulated cooler containing frozen Blue Ice to maintain the temperature at or below 4 Celsius. A copy of the chain-of-custody form is presented in Attachment 1. The sample cooler was delivered to Curtis and Tompkins, Ltd. in Berkeley, California on January 17, Sample Results Soil samples were analyzed for metals; total petroleum hydrocarbons (TPH) as gas, motor oil, and diesel; pesticides; polychlorinated biphenyls (PCB); and semi-volatile organic compounds (SVOC) using the methods listed below. Preparation of Sample: EPA 3520C Metals by EPA 6010B; Mercury by EPA 7471A TPH by EPA 8015Modified 5 0

3 Mr. Greg Haet February 13, 2008 Page 3 of 5 PCB analysis by EPA 8081A SVOC analysis by EPA 8270 Sample results are presented below along with California Human Health Screening Levels (CHHSL) [ Use of California Human Health Screening Levels (CHHSLs) in Evaluation of Contaminated Properties California Environmental Protection Agency, January 2005]. Where CHHSLs are not available, other screening levels are presented, such as the Federal Region 9 EPA Preliminary Remediation Goals and the California Regional Water Quality Control Board s Environmental Screening Levels. All of the analytes evaluated were reported at concentrations less than the laboratory reporting limits or less than their respective screening levels in all of the samples collected. If you have any questions or comments regarding this submittal, please call me at (415) Sincerely, Jason Brodersen, P.G. Project Manager Enclosure: Figures 1 Attachment 1: Analytical Results 135 Main Street, Suite 1800, San Francisco, CA Tel Fax

4 TETRA TECH EM INC. TPH, SVOC, PESTICIDE, AND PCB RESULTS REPORTED IN MILLIGRAMS PER KILOGRAM (mg/kg) TPH SVOCs Pesticides PCBs (3) Sample Location Gasoline Diesel CHHSL Residential CHHSL Commercial CRWQCB Residential Non Drinking Water CRWQCB Commercial Non Drinking Water EPA Region 9 Residential PRG EPA Region 9 Commercial PRG Motor Oil (1) (2) , Aroclor Aroclor Aroclor Western Stege Marsh DU 1 ND 130 Y 560 ND ND J Notes: ND Not detected Y Sample exhibits chromatographic pattern which does not resemble standard J Estimated Value 1. No SVOCs were detected 2. No pesticides were detected 3. All other PCBs not detected 135 Main Street, Suite 1800, San Francisco, CA Tel Fax

5 . METALS RESULTS REPORTED IN MILLIGRAMS PER KILOGRAM (mg/kg) Metals Antimony Arsenic (1) Barium Beryllium Cadmium Chromium Cobalt Copper Lead Mercury Molybdenum Nickel Silver Vanadium Zinc Sample Location CHHSL Residential CHHSL Commercial Background ,200 63, , , , ,200 3,000 38, , ,800 1,600 16, , ,700 23, ,000 Western Stege Marsh DU J ND 69 ND Notes: ND Not detected 1. Arsenic screening value based on DTSC-approved ambient concentration developed for the adjacent Campus Bay site. J Estimated Value 135 Main Street, Suite 1800, San Francisco, CA Tel Fax

6 Decision Unit Boundaries (approximate) Multi-Increment Sampling Locations (approximate) Note: Image date March 2005, courtesy of BBL Inc E B R P D B A Y T R A I L Feet RFS CONNECTOR TRAIL Richmond Field Station University of California, Berkeley WESTERN STEGE MARSH NEAR SURFACE SAMPLING AREA V:\Misc_GIS\Richmond_Field_Station\Projects\Coastal_Prairie_Sampling\WSM.mxd TtEMI-SF Aleksandr Zhuk

7 COMPLETE SAMPLING RESULTS

8 Total Volatile Hydrocarbons Client: Tetra Tech EMI Prep: EPA 5030B Project#: 103DS Analysis: EPA 8015B Field ID: RFS-WSM-DU1-001 Diln Fac: Lab ID: Batch#: Matrix: Soil Sampled: 01/17/08 Units: mg/kg Received: 01/17/08 Basis: dry Analyzed: 01/19/08 Moisture: 50% Analyte Result RL Gasoline C7-C12 ND 2.0 Surrogate %REC Limits Trifluorotoluene (FID) Bromofluorobenzene (FID) ND= Not Detected RL= Reporting Limit Page 1 of 1 6.1

9 Total Extractable Hydrocarbons Client: Tetra Tech EMI Prep: SHAKER TABLE Project#: 103DS Analysis: EPA 8015B Matrix: Soil Sampled: 01/17/08 Units: mg/kg Received: 01/17/08 Batch#: Prepared: 01/20/08 Field ID: RFS-WSM-DU1-001 Moisture: 50% Type: SAMPLE Diln Fac: Lab ID: Analyzed: 01/22/08 Basis: dry Cleanup Method: EPA 3630C Analyte Result RL Diesel C10-C Y 10 Motor Oil C24-C Surrogate %REC Limits Hexacosane Type: BLANK Diln Fac: Lab ID: QC Analyzed: 01/21/08 Basis: as received Cleanup Method: EPA 3630C Analyte Result RL Diesel C10-C24 ND 1.0 Motor Oil C24-C36 ND 5.0 Surrogate %REC Limits Hexacosane Y= Sample exhibits chromatographic pattern which does not resemble standard ND= Not Detected RL= Reporting Limit Page 2 of

10 Total Extractable Hydrocarbons Client: Tetra Tech EMI Prep: SHAKER TABLE Project#: 103DS Analysis: EPA 8015B Type: LCS Diln Fac: Lab ID: QC Batch#: Matrix: Soil Prepared: 01/20/08 Units: mg/kg Analyzed: 01/21/08 Basis: as received Cleanup Method: EPA 3630C Analyte Spiked Result %REC Limits Diesel C10-C Surrogate %REC Limits Hexacosane Page 1 of

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19 Semivolatile Organics by GC/MS Client: Tetra Tech EMI Prep: EPA 3550B Project#: 103DS Analysis: EPA 8270C Field ID: RFS-WSM-DU1-001 Batch#: Lab ID: Sampled: 01/17/08 Matrix: Soil Received: 01/17/08 Units: ug/kg Prepared: 01/23/08 Basis: dry Analyzed: 01/25/08 Diln Fac: Moisture: 50% Analyte Result RL N-Nitrosodimethylamine ND 17,000 Phenol ND 17,000 bis(2-chloroethyl)ether ND 17,000 2-Chlorophenol ND 17,000 1,3-Dichlorobenzene ND 17,000 1,4-Dichlorobenzene ND 17,000 Benzyl alcohol ND 17,000 1,2-Dichlorobenzene ND 17,000 2-Methylphenol ND 17,000 bis(2-chloroisopropyl) ether ND 17,000 4-Methylphenol ND 17,000 N-Nitroso-di-n-propylamine ND 17,000 Hexachloroethane ND 17,000 Nitrobenzene ND 17,000 Isophorone ND 17,000 2-Nitrophenol ND 33,000 2,4-Dimethylphenol ND 17,000 Benzoic acid ND 84,000 bis(2-chloroethoxy)methane ND 17,000 2,4-Dichlorophenol ND 17,000 1,2,4-Trichlorobenzene ND 17,000 Naphthalene ND 3,300 4-Chloroaniline ND 17,000 Hexachlorobutadiene ND 17,000 4-Chloro-3-methylphenol ND 17,000 2-Methylnaphthalene ND 3,300 Hexachlorocyclopentadiene ND 33,000 2,4,6-Trichlorophenol ND 17,000 2,4,5-Trichlorophenol ND 17,000 2-Chloronaphthalene ND 17,000 2-Nitroaniline ND 33,000 Dimethylphthalate ND 17,000 Acenaphthylene ND 3,300 2,6-Dinitrotoluene ND 17,000 3-Nitroaniline ND 33,000 Acenaphthene ND 3,300 2,4-Dinitrophenol ND 33,000 4-Nitrophenol ND 33,000 Dibenzofuran ND 17,000 2,4-Dinitrotoluene ND 17,000 Diethylphthalate ND 17,000 Fluorene ND 3,300 4-Chlorophenyl-phenylether ND 17,000 4-Nitroaniline ND 33,000 4,6-Dinitro-2-methylphenol ND 33,000 N-Nitrosodiphenylamine ND 17,000 Azobenzene ND 17,000 4-Bromophenyl-phenylether ND 17,000 Hexachlorobenzene ND 17,000 J= Estimated value DO= Diluted Out ND= Not Detected RL= Reporting Limit Page 1 of

20 Semivolatile Organics by GC/MS Client: Tetra Tech EMI Prep: EPA 3550B Project#: 103DS Analysis: EPA 8270C Field ID: RFS-WSM-DU1-001 Batch#: Lab ID: Sampled: 01/17/08 Matrix: Soil Received: 01/17/08 Units: ug/kg Prepared: 01/23/08 Basis: dry Analyzed: 01/25/08 Diln Fac: Analyte Result RL Pentachlorophenol ND 33,000 Phenanthrene ND 3,300 Anthracene ND 3,300 Di-n-butylphthalate ND 17,000 Fluoranthene ND 3,300 Pyrene ND 3,300 Butylbenzylphthalate ND 17,000 3,3'-Dichlorobenzidine ND 33,000 Benzo(a)anthracene ND 3,300 Chrysene ND 3,300 bis(2-ethylhexyl)phthalate ND 17,000 Di-n-octylphthalate ND 17,000 Benzo(b)fluoranthene ND 3,300 Benzo(k)fluoranthene ND 3,300 Benzo(a)pyrene ND 3,300 Indeno(1,2,3-cd)pyrene ND 3,300 Dibenz(a,h)anthracene ND 3,300 Benzo(g,h,i)perylene ND 3,300 Tentatively Identified Compounds Result.gamma.-Sitosterol 6900 J 2-Pentanone, 4-hydroxy-4-methyl J Cholesterol 9700 J Cyclohexane,1,1,3-trimethyl-2-(3-methylpentyl) J Surrogate %REC Limits 2-Fluorophenol DO Phenol-d5 DO ,4,6-Tribromophenol DO Nitrobenzene-d5 DO Fluorobiphenyl DO Terphenyl-d14 DO J= Estimated value DO= Diluted Out ND= Not Detected RL= Reporting Limit Page 2 of

21 Semivolatile Organics by GC/MS Client: Tetra Tech EMI Prep: EPA 3550B Project#: 103DS Analysis: EPA 8270C Type: BLANK Diln Fac: Lab ID: QC Batch#: Matrix: Soil Prepared: 01/18/08 Basis: as received Analyzed: 01/18/08 Analyte Result RL Units N-Nitrosodimethylamine ND 330 ug/kg Phenol ND 330 ug/kg bis(2-chloroethyl)ether ND 330 ug/kg 2-Chlorophenol ND 330 ug/kg 1,3-Dichlorobenzene ND 330 ug/kg 1,4-Dichlorobenzene ND 330 ug/kg Benzyl alcohol ND 330 ug/kg 1,2-Dichlorobenzene ND 330 ug/kg 2-Methylphenol ND 330 ug/kg bis(2-chloroisopropyl) ether ND 330 ug/kg 4-Methylphenol ND 330 ug/kg N-Nitroso-di-n-propylamine ND 330 ug/kg Hexachloroethane ND 330 ug/kg Nitrobenzene ND 330 ug/kg Isophorone ND 330 ug/kg 2-Nitrophenol ND 670 ug/kg 2,4-Dimethylphenol ND 330 ug/kg Benzoic acid ND 1,700 ug/kg bis(2-chloroethoxy)methane ND 330 ug/kg 2,4-Dichlorophenol ND 330 ug/kg 1,2,4-Trichlorobenzene ND 330 ug/kg Naphthalene ND 67 ug/kg 4-Chloroaniline ND 330 ug/kg Hexachlorobutadiene ND 330 ug/kg 4-Chloro-3-methylphenol ND 330 ug/kg 2-Methylnaphthalene ND 67 ug/kg Hexachlorocyclopentadiene ND 670 ug/kg 2,4,6-Trichlorophenol ND 330 ug/kg 2,4,5-Trichlorophenol ND 330 ug/kg 2-Chloronaphthalene ND 330 ug/kg 2-Nitroaniline ND 670 ug/kg Dimethylphthalate ND 330 ug/kg Acenaphthylene ND 67 ug/kg 2,6-Dinitrotoluene ND 330 ug/kg 3-Nitroaniline ND 670 ug/kg Acenaphthene ND 67 ug/kg 2,4-Dinitrophenol ND 670 ug/kg 4-Nitrophenol ND 670 ug/kg Dibenzofuran ND 330 ug/kg 2,4-Dinitrotoluene ND 330 ug/kg Diethylphthalate ND 330 ug/kg Fluorene ND 67 ug/kg 4-Chlorophenyl-phenylether ND 330 ug/kg 4-Nitroaniline ND 670 ug/kg 4,6-Dinitro-2-methylphenol ND 670 ug/kg N-Nitrosodiphenylamine ND 330 ug/kg Azobenzene ND 330 ug/kg 4-Bromophenyl-phenylether ND 330 ug/kg Hexachlorobenzene ND 330 ug/kg Pentachlorophenol ND 670 ug/kg Phenanthrene ND 67 ug/kg Anthracene ND 67 ug/kg Di-n-butylphthalate ND 330 ug/kg J= Estimated value ND= Not Detected RL= Reporting Limit Page 1 of

22 Semivolatile Organics by GC/MS Client: Tetra Tech EMI Prep: EPA 3550B Project#: 103DS Analysis: EPA 8270C Type: BLANK Diln Fac: Lab ID: QC Batch#: Matrix: Soil Prepared: 01/18/08 Basis: as received Analyzed: 01/18/08 Analyte Result RL Units Fluoranthene ND 67 ug/kg Pyrene ND 67 ug/kg Butylbenzylphthalate ND 330 ug/kg 3,3'-Dichlorobenzidine ND 670 ug/kg Benzo(a)anthracene ND 67 ug/kg Chrysene ND 67 ug/kg bis(2-ethylhexyl)phthalate ND 330 ug/kg Di-n-octylphthalate ND 330 ug/kg Benzo(b)fluoranthene ND 67 ug/kg Benzo(k)fluoranthene ND 67 ug/kg Benzo(a)pyrene ND 67 ug/kg Indeno(1,2,3-cd)pyrene ND 67 ug/kg Dibenz(a,h)anthracene ND 67 ug/kg Benzo(g,h,i)perylene ND 67 ug/kg Tentatively Identified Compounds Result Units 2-Pentanone, 4-hydroxy-4-methyl- 6.0 J mg/kg Toluene 0.19 J mg/kg Surrogate %REC Limits 2-Fluorophenol Phenol-d ,4,6-Tribromophenol Nitrobenzene-d Fluorobiphenyl Terphenyl-d J= Estimated value ND= Not Detected RL= Reporting Limit Page 2 of

23 Semivolatile Organics by GC/MS Client: Tetra Tech EMI Prep: EPA 3550B Project#: 103DS Analysis: EPA 8270C Type: LCS Diln Fac: Lab ID: QC Batch#: Matrix: Soil Prepared: 01/18/08 Units: ug/kg Analyzed: 01/18/08 Basis: as received Analyte Spiked Result %REC Limits Phenol 2,657 1, Chlorophenol 2,657 1, ,4-Dichlorobenzene 1,328 1, N-Nitroso-di-n-propylamine 1, ,2,4-Trichlorobenzene 1,328 1, Chloro-3-methylphenol 2,657 1, Acenaphthene 1,328 1, Nitrophenol 2,657 2, ,4-Dinitrotoluene 1,328 1, Pentachlorophenol 2,657 2, Pyrene 1, Surrogate %REC Limits 2-Fluorophenol Phenol-d ,4,6-Tribromophenol Nitrobenzene-d Fluorobiphenyl Terphenyl-d Page 1 of

24 Semivolatile Organics by GC/MS Client: Tetra Tech EMI Prep: EPA 3550B Project#: 103DS Analysis: EPA 8270C Type: BLANK Diln Fac: Lab ID: QC Batch#: Matrix: Soil Prepared: 01/23/08 Units: ug/kg Analyzed: 01/25/08 Basis: as received Analyte Result RL N-Nitrosodimethylamine ND 330 Phenol ND 330 bis(2-chloroethyl)ether ND Chlorophenol ND 330 1,3-Dichlorobenzene ND 330 1,4-Dichlorobenzene ND 330 Benzyl alcohol ND 330 1,2-Dichlorobenzene ND Methylphenol ND 330 bis(2-chloroisopropyl) ether ND Methylphenol ND 330 N-Nitroso-di-n-propylamine ND 330 Hexachloroethane ND 330 Nitrobenzene ND 330 Isophorone ND Nitrophenol ND 660 2,4-Dimethylphenol ND 330 Benzoic acid ND 1,700 bis(2-chloroethoxy)methane ND 330 2,4-Dichlorophenol ND 330 1,2,4-Trichlorobenzene ND 330 Naphthalene ND 66 4-Chloroaniline ND 330 Hexachlorobutadiene ND Chloro-3-methylphenol ND Methylnaphthalene ND 66 Hexachlorocyclopentadiene ND 660 2,4,6-Trichlorophenol ND 330 2,4,5-Trichlorophenol ND Chloronaphthalene ND Nitroaniline ND 660 Dimethylphthalate ND 330 Acenaphthylene ND 66 2,6-Dinitrotoluene ND Nitroaniline ND 660 Acenaphthene ND 66 2,4-Dinitrophenol ND Nitrophenol ND 660 Dibenzofuran ND 330 2,4-Dinitrotoluene ND 330 Diethylphthalate ND 330 Fluorene ND 66 4-Chlorophenyl-phenylether ND Nitroaniline ND 660 4,6-Dinitro-2-methylphenol ND 660 N-Nitrosodiphenylamine ND 330 Azobenzene ND Bromophenyl-phenylether ND 330 Hexachlorobenzene ND 330 Pentachlorophenol ND 660 Phenanthrene ND 66 Anthracene ND 66 J= Estimated value ND= Not Detected RL= Reporting Limit Page 1 of

25 Semivolatile Organics by GC/MS Client: Tetra Tech EMI Prep: EPA 3550B Project#: 103DS Analysis: EPA 8270C Type: BLANK Diln Fac: Lab ID: QC Batch#: Matrix: Soil Prepared: 01/23/08 Units: ug/kg Analyzed: 01/25/08 Basis: as received Analyte Result RL Di-n-butylphthalate ND 330 Fluoranthene ND 66 Pyrene ND 66 Butylbenzylphthalate ND 330 3,3'-Dichlorobenzidine ND 660 Benzo(a)anthracene ND 66 Chrysene ND 66 bis(2-ethylhexyl)phthalate ND 330 Di-n-octylphthalate ND 330 Benzo(b)fluoranthene ND 66 Benzo(k)fluoranthene ND 66 Benzo(a)pyrene ND 66 Indeno(1,2,3-cd)pyrene ND 66 Dibenz(a,h)anthracene ND 66 Benzo(g,h,i)perylene ND 66 Tentatively Identified Compounds Result 2-Pentanone, 4-hydroxy-4-methyl J Surrogate %REC Limits 2-Fluorophenol Phenol-d ,4,6-Tribromophenol Nitrobenzene-d Fluorobiphenyl Terphenyl-d J= Estimated value ND= Not Detected RL= Reporting Limit Page 2 of

26 Semivolatile Organics by GC/MS Client: Tetra Tech EMI Prep: EPA 3550B Project#: 103DS Analysis: EPA 8270C Type: LCS Diln Fac: Lab ID: QC Batch#: Matrix: Soil Prepared: 01/23/08 Units: ug/kg Analyzed: 01/25/08 Basis: as received Analyte Spiked Result %REC Limits Phenol 2,670 1, Chlorophenol 2,670 1, ,4-Dichlorobenzene 1, N-Nitroso-di-n-propylamine 1, ,2,4-Trichlorobenzene 1, Chloro-3-methylphenol 2,670 2, Acenaphthene 1, Nitrophenol 2,670 1, ,4-Dinitrotoluene 1,335 1, Pentachlorophenol 2,670 1, Pyrene 1, Surrogate %REC Limits 2-Fluorophenol Phenol-d ,4,6-Tribromophenol Nitrobenzene-d Fluorobiphenyl Terphenyl-d Page 1 of

27 Semivolatile Organics by GC/MS Client: Tetra Tech EMI Prep: EPA 3550B Project#: 103DS Analysis: EPA 8270C Field ID: ZZZZZZZZZZ Batch#: MSS Lab ID: Sampled: 01/22/08 Matrix: Soil Received: 01/23/08 Units: ug/kg Prepared: 01/23/08 Basis: as received Analyzed: 01/25/08 Diln Fac: Type: MS Lab ID: QC Analyte MSS Result Spiked Result %REC Limits Phenol < ,668 1, Chlorophenol < ,668 2, ,4-Dichlorobenzene < ,334 1, N-Nitroso-di-n-propylamine < , ,2,4-Trichlorobenzene < ,334 1, Chloro-3-methylphenol < ,668 2, Acenaphthene < ,334 1, Nitrophenol < ,668 2, ,4-Dinitrotoluene < ,334 1, Pentachlorophenol < ,668 1, Pyrene ,334 1, Surrogate %REC Limits 2-Fluorophenol Phenol-d ,4,6-Tribromophenol Nitrobenzene-d Fluorobiphenyl Terphenyl-d Type: MSD Lab ID: QC Analyte Spiked Result %REC Limits RPD Lim Phenol 2,672 1, Chlorophenol 2,672 1, ,4-Dichlorobenzene 1, N-Nitroso-di-n-propylamine 1, ,2,4-Trichlorobenzene 1, Chloro-3-methylphenol 2,672 2, Acenaphthene 1,336 1, Nitrophenol 2,672 2, ,4-Dinitrotoluene 1, Pentachlorophenol 2,672 1, Pyrene 1,336 1, Surrogate %REC Limits 2-Fluorophenol Phenol-d ,4,6-Tribromophenol Nitrobenzene-d Fluorobiphenyl Terphenyl-d RPD= Relative Percent Difference Page 1 of

28 Organochlorine Pesticides Client: Tetra Tech EMI Prep: EPA 3550B Project#: 103DS Analysis: EPA 8081A Field ID: RFS-WSM-DU1-001 Batch#: Lab ID: Sampled: 01/17/08 Matrix: Soil Received: 01/17/08 Units: ug/kg Prepared: 01/19/08 Basis: dry Analyzed: 01/31/08 Diln Fac: Moisture: 50% Cleanup Method: EPA 3620B Analyte Result RL alpha-bhc ND 17 beta-bhc ND 17 gamma-bhc ND 17 delta-bhc ND 17 Heptachlor ND 17 Aldrin ND 17 Heptachlor epoxide ND 17 Endosulfan I ND 17 Dieldrin ND 33 4,4'-DDE ND 33 Endrin ND 33 Endosulfan II ND 33 Endosulfan sulfate ND 33 4,4'-DDD ND 33 Endrin aldehyde ND 33 4,4'-DDT ND 33 alpha-chlordane ND 17 gamma-chlordane ND 17 Methoxychlor ND 170 Toxaphene ND 600 Surrogate %REC Limits TCMX Decachlorobiphenyl ND= Not Detected RL= Reporting Limit Page 1 of

29 Organochlorine Pesticides Client: Tetra Tech EMI Prep: EPA 3550B Project#: 103DS Analysis: EPA 8081A Type: BLANK Diln Fac: Lab ID: QC Batch#: Matrix: Soil Prepared: 01/18/08 Units: ug/kg Analyzed: 01/18/08 Basis: as received Cleanup Method: EPA 3620B Analyte Result RL alpha-bhc ND 1.7 beta-bhc ND 1.7 gamma-bhc ND 1.7 delta-bhc ND 1.7 Heptachlor ND 1.7 Aldrin ND 1.7 Heptachlor epoxide ND 1.7 Endosulfan I ND 1.7 Dieldrin ND 3.3 4,4'-DDE ND 3.3 Endrin ND 3.3 Endosulfan II ND 3.3 Endosulfan sulfate ND 3.3 4,4'-DDD ND 3.3 Endrin aldehyde ND 3.3 4,4'-DDT ND 3.3 alpha-chlordane ND 1.7 gamma-chlordane ND 1.7 Methoxychlor ND 17 Toxaphene ND 60 Surrogate %REC Limits TCMX Decachlorobiphenyl ND= Not Detected RL= Reporting Limit Page 1 of

30 Organochlorine Pesticides Client: Tetra Tech EMI Prep: EPA 3550B Project#: 103DS Analysis: EPA 8081A Type: LCS Diln Fac: Lab ID: QC Batch#: Matrix: Soil Prepared: 01/18/08 Units: ug/kg Analyzed: 01/18/08 Basis: as received Cleanup Method: EPA 3620B Analyte Spiked Result %REC Limits gamma-bhc Heptachlor Aldrin Dieldrin Endrin ,4'-DDT Surrogate %REC Limits TCMX Decachlorobiphenyl Page 1 of

31 Organochlorine Pesticides Client: Tetra Tech EMI Prep: EPA 3550B Project#: 103DS Analysis: EPA 8081A Type: BLANK Diln Fac: Lab ID: QC Batch#: Matrix: Soil Prepared: 01/19/08 Units: ug/kg Analyzed: 01/21/08 Basis: as received Cleanup Method: EPA 3620B Analyte Result RL alpha-bhc ND 1.7 beta-bhc ND 1.7 gamma-bhc ND 1.7 delta-bhc ND 1.7 Heptachlor ND 1.7 Aldrin ND 1.7 Heptachlor epoxide ND 1.7 Endosulfan I ND 1.7 Dieldrin ND 3.3 4,4'-DDE ND 3.3 Endrin ND 3.3 Endosulfan II ND 3.3 Endosulfan sulfate ND 3.3 4,4'-DDD ND 3.3 Endrin aldehyde ND 3.3 4,4'-DDT ND 3.3 alpha-chlordane ND 1.7 gamma-chlordane ND 1.7 Methoxychlor ND # 17 Toxaphene ND 59 Surrogate %REC Limits TCMX Decachlorobiphenyl #= CCV drift outside limits; average CCV drift within limits per method requirements ND= Not Detected RL= Reporting Limit Page 1 of

32 Organochlorine Pesticides Client: Tetra Tech EMI Prep: EPA 3550B Project#: 103DS Analysis: EPA 8081A Type: LCS Diln Fac: Lab ID: QC Batch#: Matrix: Soil Prepared: 01/19/08 Units: ug/kg Analyzed: 01/21/08 Basis: as received Cleanup Method: EPA 3620B Analyte Spiked Result %REC Limits gamma-bhc Heptachlor Aldrin Dieldrin Endrin ,4'-DDT Surrogate %REC Limits TCMX Decachlorobiphenyl Page 1 of

33 Polychlorinated Biphenyls (PCBs) Client: Tetra Tech EMI Prep: EPA 3550B Project#: 103DS Analysis: EPA 8082 Field ID: RFS-WSM-DU1-001 Batch#: Lab ID: Sampled: 01/17/08 Matrix: Soil Received: 01/17/08 Units: ug/kg Prepared: 01/20/08 Basis: dry Analyzed: 01/21/08 Diln Fac: Moisture: 50% Cleanup Method: EPA 3665A Analyte Result RL Aroclor-1016 ND 24 Aroclor-1221 ND 48 Aroclor-1232 ND 24 Aroclor-1242 ND 24 Aroclor Aroclor Aroclor J 24 Surrogate %REC Limits TCMX Decachlorobiphenyl J= Estimated value ND= Not Detected RL= Reporting Limit Page 1 of

34 Polychlorinated Biphenyls (PCBs) Client: Tetra Tech EMI Prep: EPA 3550B Project#: 103DS Analysis: EPA 8082 Type: BLANK Diln Fac: Lab ID: QC Batch#: Matrix: Soil Prepared: 01/18/08 Units: ug/kg Analyzed: 01/18/08 Basis: as received Cleanup Method: EPA 3620B Analyte Result RL Aroclor-1016 ND 12 Aroclor-1221 ND 24 Aroclor-1232 ND 12 Aroclor-1242 ND 12 Aroclor-1248 ND 12 Aroclor-1254 ND 12 Aroclor-1260 ND 12 Surrogate %REC Limits TCMX Decachlorobiphenyl ND= Not Detected RL= Reporting Limit Page 1 of

35 Polychlorinated Biphenyls (PCBs) Client: Tetra Tech EMI Prep: EPA 3550B Project#: 103DS Analysis: EPA 8082 Type: LCS Diln Fac: Lab ID: QC Batch#: Matrix: Soil Prepared: 01/18/08 Units: ug/kg Analyzed: 01/18/08 Basis: as received Cleanup Method: EPA 3620B Analyte Spiked Result %REC Limits Aroclor Surrogate %REC Limits TCMX Decachlorobiphenyl Page 1 of

36 Polychlorinated Biphenyls (PCBs) Client: Tetra Tech EMI Prep: EPA 3550B Project#: 103DS Analysis: EPA 8082 Field ID: ZZZZZZZZZZ Batch#: MSS Lab ID: Sampled: 01/16/08 Matrix: Soil Received: 01/17/08 Units: ug/kg Prepared: 01/18/08 Basis: as received Analyzed: 01/18/08 Diln Fac: Type: MS Cleanup Method: EPA 3620B Lab ID: QC Analyte MSS Result Spiked Result %REC Limits Aroclor-1221 < Surrogate %REC Limits TCMX Decachlorobiphenyl Type: MSD Cleanup Method: EPA 3620B Lab ID: QC Analyte Spiked Result %REC Limits RPD Lim Aroclor Surrogate %REC Limits TCMX Decachlorobiphenyl RPD= Relative Percent Difference Page 1 of

37 Polychlorinated Biphenyls (PCBs) Client: Tetra Tech EMI Prep: EPA 3550B Project#: 103DS Analysis: EPA 8082 Type: BLANK Diln Fac: Lab ID: QC Batch#: Matrix: Soil Prepared: 01/20/08 Units: ug/kg Analyzed: 01/21/08 Basis: as received Cleanup Method: EPA 3665A Analyte Result RL Aroclor-1016 ND 12 Aroclor-1221 ND 24 Aroclor-1232 ND 12 Aroclor-1242 ND 12 Aroclor-1248 ND 12 Aroclor-1254 ND 12 Aroclor-1260 ND 12 Surrogate %REC Limits TCMX Decachlorobiphenyl ND= Not Detected RL= Reporting Limit Page 1 of

38 Polychlorinated Biphenyls (PCBs) Client: Tetra Tech EMI Prep: EPA 3550B Project#: 103DS Analysis: EPA 8082 Type: LCS Diln Fac: Lab ID: QC Batch#: Matrix: Soil Prepared: 01/20/08 Units: ug/kg Analyzed: 01/21/08 Basis: as received Cleanup Method: EPA 3665A Analyte Spiked Result %REC Limits Aroclor Surrogate %REC Limits TCMX Decachlorobiphenyl Page 1 of

39 Polychlorinated Biphenyls (PCBs) Client: Tetra Tech EMI Prep: EPA 3550B Project#: 103DS Analysis: EPA 8082 Field ID: ZZZZZZZZZZ Batch#: MSS Lab ID: Sampled: 01/18/08 Matrix: Soil Received: 01/18/08 Units: ug/kg Prepared: 01/20/08 Basis: dry Analyzed: 01/21/08 Diln Fac: Type: MS Moisture: 15% Lab ID: QC Cleanup Method: EPA 3665A Analyte MSS Result Spiked Result %REC Limits Aroclor-1221 < Surrogate %REC Limits TCMX Decachlorobiphenyl Type: MSD Moisture: 15% Lab ID: QC Cleanup Method: EPA 3665A Analyte Spiked Result %REC Limits RPD Lim Aroclor Surrogate %REC Limits TCMX Decachlorobiphenyl RPD= Relative Percent Difference Page 1 of

40 Target Analyte List Metals Lab #: Project#: 103DS Client: Tetra Tech EMI Location: Multi-Inc. Samp Field ID: RFS-WSM-DU1-001 Basis: dry Lab ID: Sampled: 01/17/08 Matrix: Soil Received: 01/17/08 Units: mg/kg Moisture: 50% Analyte Result RL Diln Fac Batch# Prepared Analyzed Prep Analysis Aluminum 28, /21/08 01/22/08 EPA 3050B EPA 6010B Antimony /21/08 01/22/08 EPA 3050B EPA 6010B Arsenic /21/08 01/22/08 EPA 3050B EPA 6010B Barium /21/08 01/22/08 EPA 3050B EPA 6010B Beryllium /21/08 01/22/08 EPA 3050B EPA 6010B Cadmium 0.38 J /21/08 01/22/08 EPA 3050B EPA 6010B Calcium 2, /21/08 01/22/08 EPA 3050B EPA 6010B Chromium /21/08 01/22/08 EPA 3050B EPA 6010B Cobalt /21/08 01/22/08 EPA 3050B EPA 6010B Copper /21/08 01/22/08 EPA 3050B EPA 6010B Iron 46, /21/08 01/22/08 EPA 3050B EPA 6010B Lead /21/08 01/22/08 EPA 3050B EPA 6010B Magnesium 15, /21/08 01/22/08 EPA 3050B EPA 6010B Manganese /21/08 01/22/08 EPA 3050B EPA 6010B Mercury /18/08 01/18/08 METHOD EPA 7471A Molybdenum ND /21/08 01/22/08 EPA 3050B EPA 6010B Nickel /21/08 01/22/08 EPA 3050B EPA 6010B Potassium 3, /21/08 01/22/08 EPA 3050B EPA 6010B Selenium ND /21/08 01/22/08 EPA 3050B EPA 6010B Silver ND /21/08 01/22/08 EPA 3050B EPA 6010B Sodium 8, /21/08 01/22/08 EPA 3050B EPA 6010B Thallium ND /21/08 01/22/08 EPA 3050B EPA 6010B Vanadium /21/08 01/22/08 EPA 3050B EPA 6010B Zinc /21/08 01/22/08 EPA 3050B EPA 6010B J= Estimated value ND= Not Detected RL= Reporting Limit Page 1 of

41 Target Analyte List Metals Client: Tetra Tech EMI Prep: METHOD Project#: 103DS Analysis: EPA 7471A Analyte: Mercury Basis: as received Type: BLANK Diln Fac: Lab ID: QC Batch#: Matrix: Soil Prepared: 01/18/08 Units: mg/kg Analyzed: 01/18/08 Result RL ND ND= Not Detected RL= Reporting Limit Page 1 of

42 Target Analyte List Metals Client: Tetra Tech EMI Prep: METHOD Project#: 103DS Analysis: EPA 7471A Analyte: Mercury Diln Fac: Matrix: Soil Batch#: Units: mg/kg Prepared: 01/18/08 Basis: as received Analyzed: 01/18/08 Type Lab ID Spiked Result %REC Limits RPD Lim BS QC BSD QC RPD= Relative Percent Difference Page 1 of

43 Target Analyte List Metals Client: Tetra Tech EMI Prep: METHOD Project#: 103DS Analysis: EPA 7471A Analyte: Mercury Basis: as received Field ID: ZZZZZZZZZZ Diln Fac: Type: Serial Dilution Batch#: MSS Lab ID: Sampled: 01/16/08 Lab ID: QC Received: 01/17/08 Matrix: Soil Analyzed: 01/18/08 Units: mg/kg MSS Result MSS RL Result RL % Diff Lim * 10 *= Value outside of QC limits; see narrative RL= Reporting Limit Page 1 of

44 Target Analyte List Metals Client: Tetra Tech EMI Prep: METHOD Project#: 103DS Analysis: EPA 7471A Analyte: Mercury Diln Fac: Field ID: ZZZZZZZZZZ Batch#: MSS Lab ID: Sampled: 01/16/08 Matrix: Soil Received: 01/17/08 Units: mg/kg Prepared: 01/18/08 Basis: as received Analyzed: 01/18/08 Type Lab ID MSS Result Spiked Result %REC Limits RPD Lim MS QC * MSD QC *= Value outside of QC limits; see narrative RPD= Relative Percent Difference Page 1 of

45 Target Analyte List Metals Client: Tetra Tech EMI Prep: METHOD Project#: 103DS Analysis: EPA 7471A Analyte: Mercury Basis: as received Type: BLANK Diln Fac: Lab ID: QC Batch#: Matrix: Soil Prepared: 01/21/08 Units: mg/kg Analyzed: 01/21/08 Result RL ND ND= Not Detected RL= Reporting Limit Page 1 of

46 Target Analyte List Metals Client: Tetra Tech EMI Prep: METHOD Project#: 103DS Analysis: EPA 7471A Analyte: Mercury Diln Fac: Matrix: Soil Batch#: Units: mg/kg Prepared: 01/21/08 Basis: as received Analyzed: 01/21/08 Type Lab ID Spiked Result %REC Limits RPD Lim BS QC BSD QC RPD= Relative Percent Difference Page 1 of

47 Target Analyte List Metals Client: Tetra Tech EMI Prep: METHOD Project#: 103DS Analysis: EPA 7471A Analyte: Mercury Basis: as received Field ID: ZZZZZZZZZZ Diln Fac: Type: Serial Dilution Batch#: MSS Lab ID: Sampled: 01/18/08 Lab ID: QC Received: 01/18/08 Matrix: Soil Analyzed: 01/21/08 Units: mg/kg MSS Result MSS RL Result RL % Diff Lim J NC 10 J= Estimated value NC= Not Calculated RL= Reporting Limit Page 1 of

48 Target Analyte List Metals Client: Tetra Tech EMI Prep: METHOD Project#: 103DS Analysis: EPA 7471A Analyte: Mercury Diln Fac: Field ID: ZZZZZZZZZZ Batch#: MSS Lab ID: Sampled: 01/18/08 Matrix: Soil Received: 01/18/08 Units: mg/kg Prepared: 01/21/08 Basis: as received Analyzed: 01/21/08 Type Lab ID MSS Result Spiked Result %REC Limits RPD Lim MS QC MSD QC RPD= Relative Percent Difference Page 1 of

49 Target Analyte List Metals Client: Tetra Tech EMI Prep: EPA 3050B Project#: 103DS Analysis: EPA 6010B Type: BLANK Diln Fac: Lab ID: QC Batch#: Matrix: Soil Prepared: 01/21/08 Units: mg/kg Analyzed: 01/22/08 Basis: as received Analyte Result RL Aluminum 7.9 b 5.0 Antimony ND 0.50 Arsenic ND 0.29 Barium ND 0.25 Beryllium ND 0.10 Cadmium ND 0.25 Calcium ND 25 Chromium ND 0.25 Cobalt ND 0.25 Copper ND 0.29 Iron 19 b 5.0 Lead ND 0.25 Magnesium ND 25 Manganese 0.15 J 0.25 Molybdenum ND 0.25 Nickel ND 0.25 Potassium ND 25 Selenium ND 0.50 Silver ND 0.25 Sodium ND 25 Thallium ND 0.50 Vanadium ND 0.25 Zinc ND 1.0 J= Estimated value b= See narrative ND= Not Detected RL= Reporting Limit Page 1 of

50 Target Analyte List Metals Client: Tetra Tech EMI Prep: EPA 3050B Project#: 103DS Analysis: EPA 6010B Matrix: Soil Batch#: Units: mg/kg Prepared: 01/21/08 Basis: as received Analyzed: 01/22/08 Diln Fac: Type: BS Lab ID: QC Analyte Spiked Result %REC Limits Aluminum 1, Antimony Arsenic Barium Beryllium Cadmium Calcium 1, Chromium Cobalt Copper Iron 1, Lead Magnesium 1, Manganese Molybdenum Nickel Potassium Selenium Silver Sodium 1, Thallium Vanadium Zinc RPD= Relative Percent Difference Page 1 of

51 Target Analyte List Metals Client: Tetra Tech EMI Prep: EPA 3050B Project#: 103DS Analysis: EPA 6010B Matrix: Soil Batch#: Units: mg/kg Prepared: 01/21/08 Basis: as received Analyzed: 01/22/08 Diln Fac: Type: BSD Lab ID: QC Analyte Spiked Result %REC Limits RPD Lim Aluminum 1, Antimony Arsenic Barium Beryllium Cadmium Calcium 1, Chromium Cobalt Copper Iron 1, Lead Magnesium 1, Manganese Molybdenum Nickel Potassium Selenium Silver Sodium 1, Thallium Vanadium Zinc RPD= Relative Percent Difference Page 2 of

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