Material Safety Data Sheet acc. to ISO/DIS 11014

Transcription

1 Page 1/6 1 Identification of the substance/mixture and of the company/undertaking Product identifier Application of the substance / the preparation Plastic additive Details of the supplier of the safety data sheet Manufacturer/Supplier: DAIKIN CHEMICAL EUROPE GmbH Immermannstraße 65 d, Düsseldorf, GERMANY Phone: (+49) Information department: sales@daikinchem.de Emergency telephone number: During normal opening times: Composition/information on ingredients Chemical characterization: Mixtures Description: Mixture of the substances listed below with nonhazardous additions. Dangerous components: Polyethylene glycol 25-50% Talc (Mg3H2(SiO3)4) % 3 Hazards identification Classification of the substance or mixture The product is not classified according to the Globally Harmonized System (GHS). Classification according to Directive 67/548/EEC or Directive 1999/45/EC Not applicable. Information concerning particular hazards for human and environment: The product does not have to be labelled due to the calculation procedure of international guidelines. Classification system: The classification was made according to the latest editions of international substances lists, and expanded upon from company and literature data. Label elements Labelling according to EU guidelines: Observe the general safety regulations when handling chemicals. The substance is not subject to classification according to the sources of literature known to us. The product has been classified and marked in accordance with directives on hazardous materials. Safety phrases: Keep away from heat. When using do not smoke. Avoid contact with skin. Classification system: NFPA ratings (scale 0-4) Health = 0 Fire = 0 Reactivity = 0 (Contd. on page 2)

2 Page 2/6 HMIS-ratings (scale 0-4) (Contd. of page 1) HEALTH FIRE REACTIVITY Health = 0 Fire = 0 Reactivity = 0 4 First aid measures General information: Seek medical treatment. After inhalation: Supply fresh air; consult doctor in case of complaints. After skin contact: Immediately wash with water and soap and rinse thoroughly. After contact with the molten product, cool rapidly with cold water. After eye contact: Rinse opened eye for several minutes under running water. After swallowing: If symptoms persist consult doctor. 5 Firefighting measures Suitable extinguishing agents: CO2, extinguishing powder or water spray. Fight larger fires with water spray or alcohol resistant foam. For safety reasons unsuitable extinguishing agents: None Special hazards arising from the substance or mixture Formation of toxic gases is possible during heating or in case of fire. Protective equipment: Wear fully protective suit. 6 Accidental release measures Personal precautions, protective equipment and emergency procedures Wear protective clothing. Environmental precautions: Do not allow to enter sewers/ surface or ground water. Methods and material for containment and cleaning up: Pick up mechanically. Reference to other sections No dangerous substances are released. 7 Handling and storage Handling: Precautions for safe handling Extractors are required on all machines used for thermal processing or splinter removal processes. Information about protection against explosions and fires: No special measures required. Storage: Requirements to be met by storerooms and receptacles: No special requirements. Information about storage in one common storage facility: Not required. Further information about storage conditions: Store in a cool place. 8 Exposure controls/personal protection Additional information about design of technical systems: No further data; see item 7. (Contd. on page 3)

3 Page 3/6 (Contd. of page 2) Components with limit values that require monitoring at the workplace: Polyethylene glycol WEEL 10 mg/m³ Talc (Mg3H2(SiO3)4) PEL 20 mppcf ppm (containing <1% Quartz) REL 2* mg/m³ *respirable dust TLV 2* mg/m³ *as respirable fraction; Withdrawn from NIC; E Additional information: The lists that were valid during the creation were used as basis. Personal protective equipment: General protective and hygienic measures: Wash hands before breaks and at the end of work. Avoid contact with the eyes and skin. Keep away from tobacco products. Breathing equipment: For conditions where exist a potential for significant exposure to fumes and/or toxic vapours use a full-face-mask with the acid and organic vapor cartidges. Protection of hands: Protective gloves Material of gloves Synthetic gloves Penetration time of glove material The exact break through time has to be found out by the manufacturer of the protective gloves and has to be observed. Eye protection: Tightly sealed goggles Body protection: Protective work clothing 9 Physical and chemical properties General Information Appearance: Form: Powder Color: White Odor: Odorless Change in condition Melting point/melting range: Undetermined. Boiling point/boiling range: Undetermined. Flash point: Not applicable. Flammability (solid, gaseous): Product is not flammable. (Contd. on page 4)

4 Page 4/6 Decomposition temperature: > 230 C (> 446 F) (1%TG) Danger of explosion: Product does not present an explosion hazard. (Contd. of page 3) Density at 20 C (68 F): g/cm³ ( lbs/gal) Solubility in / Miscibility with Water: Solvent content: Organic solvents: 0.0 % Partly soluble. Solids content: % 10 Stability and reactivity Thermal decomposition / conditions to be avoided: To avoid thermal decomposition do not overheat. Even at the temperatures reached during the normal hot processing of fluoropolymers fume will be generated, that will present a potential health hazard. Hazardous decomposition products: Danger of toxic fluorine based pyrolysis products. 11 Toxicological information Acute toxicity: Primary irritant effect: on the skin: No irritant effect known on the eye: No irritant effect known Sensitization: No sensitizing effects known. Additional toxicological information: When used and handled according to specifications, the product does not have any harmful effects according to our experience and the information provided to us. The substance is not subject to classification. 12 Ecological information Acquatic toxicity: No further relevant information available. Additional ecological information: General notes: Water hazard class 1 (Self-assessment): slightly hazardous for water Do not allow undiluted product or large quantities of it to reach ground water, water course or sewage system. 13 Disposal considerations Waste treatment methods Recommendation: Incineration in an adequate incinerator is recommended. (Contd. on page 5)

5 Page 5/6 Uncleaned packagings: Recommendation: Disposal must be made according to EU, national and local regulations. (Contd. of page 4) 14 Transport information DOT regulations: Hazard class: - Land transport ADR/RID (cross-border): ADR/RID class: - Maritime transport IMDG: IMDG Class: - Marine pollutant: No Air transport ICAO-TI and IATA-DGR: ICAO/IATA Class: - UN "Model Regulation": - 15 Regulatory information Sara Section 355 (extremely hazardous substances): Section 313 (Specific toxic chemical listings): TSCA (Toxic Substances Control Act): All ingredients are listed. Proposition 65 Chemicals known to cause cancer: Chemicals known to cause reproductive toxicity for females: Chemicals known to cause reproductive toxicity for males: Chemicals known to cause developmental toxicity: Carcinogenic categories EPA (Environmental Protection Agency) IARC (International Agency for Research on Cancer) Talc (Mg3H2(SiO3)4) silicon dioxide, chemically prepared 3 (Contd. on page 6)

6 Page 6/6 NTP (National Toxicology Program) (Contd. of page 5) TLV (Threshold Limit Value established by ACGIH) Talc (Mg3H2(SiO3)4) A4 NIOSH-Ca (National Institute for Occupational Safety and Health) OSHA-Ca (Occupational Safety & Health Administration) Product related hazard informations: Observe the general safety regulations when handling chemicals. The substance is not subject to classification according to the sources of literature known to us. The product has been classified and marked in accordance with directives on hazardous materials. Safety phrases: Keep away from heat. When using do not smoke. Avoid contact with skin. 16 Other information This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. Department issuing MSDS: product safety department Contact: sales@daikinchem.de Abbreviations and acronyms: ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International Carriage of Dangerous Goods by Road) RID: Règlement international concernant le transport des marchandises dangereuses par chemin de fer (Regulations Concerning the International Transport of Dangerous Goods by Rail) IMDG: International Maritime Code for Dangerous Goods DOT: US Department of Transportation IATA: International Air Transport Association IATA-DGR: Dangerous Goods Regulations by the "International Air Transport Association" (IATA) ICAO: International Civil Aviation Organization ICAO-TI: Technical Instructions by the "International Civil Aviation Organization" (ICAO) ACGIH: American Conference of Governmental Industrial Hygienists NFPA: National Fire Protection Association () HMIS: Hazardous Materials Identification System ()