: Traction Plus GB-100

Transcription

1 SECTION 1: Identification 1.1. Identification Product form Product name Product code Revision date: 04/15/2016 : Mixture : : 2212-GB Relevant identified uses of the substance or mixture and uses advised against Use of the substance/mixture 1.3. Details of the supplier of the safety data sheet Traction Auditing, LLC Greenbriar Southlake, TX T (817) Emergency telephone number : Degreasing agent Emergency number : (800) SECTION 2: Hazard(s) identification 2.1. Classification of the substance or mixture GHS-US classification Skin corrosion/irritation Category 2 Serious eye damage/eye irritation Category 2A Full text of H statements : see section Label elements GHS-US labeling Hazard pictograms (GHS-US) : H315 H319 Signal word (GHS-US) Hazard statements (GHS-US) Precautionary statements (GHS-US) GHS07 : Warning : H315 - Causes skin irritation H319 - Causes serious eye irritation : P264 - Wash hands and forearms thoroughly after handling P280 - Wear protective gloves/eye protection/face protection P302+P352 - If on skin: Wash with plenty of soap and water P305+P351+P338 - If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P321 - Specific treatment (see First aid measures on this label) P332+P313 - If skin irritation occurs: Get medical advice/attention P337+P313 - If eye irritation persists: Get medical advice/attention P362+P364 - Take off contaminated clothing and wash it before reuse 2.3. Other hazards 2.4. Unknown acute toxicity (GHS US) SECTION 3: Composition/Information on ingredients 3.1. Substance 3.2. Mixture 05/26/2016 EN (English US) Page 1

2 Name Product identifier % GHS-US classification Ammonium hydrogen difluoride (CAS No) Acute Tox. 3 (Oral), H301 Skin Corr. 1B, H314 Citric acid (CAS No) Eye Irrit. 2A, H319 Dipropylene Glycol Monomethyl Ether substance with OEL values Full text of hazard classes and H-statements : see section 16 (CAS No) < 1 Flam. Liq. 4, H227 SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures general First-aid measures after inhalation First-aid measures after skin contact First-aid measures after eye contact First-aid measures after ingestion : Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible). : Allow victim to breathe fresh air. Allow the victim to rest. : Wash with plenty of soap and water. Wash contaminated clothing before reuse. If skin irritation occurs: Get medical advice/attention. Specific treatment (see First aid measures on this label). : Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. : Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention Most important symptoms and effects, both acute and delayed Symptoms/injuries after skin contact : Causes skin irritation. Symptoms/injuries after eye contact : Causes serious eye irritation Indication of any immediate medical attention and special treatment needed SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media Unsuitable extinguishing media : Foam. Dry powder. Carbon dioxide. Water spray. Sand. : Do not use a heavy water stream Special hazards arising from the substance or mixture 5.3. Advice for firefighters Firefighting instructions Protection during firefighting : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Prevent fire-fighting water from entering environment. : Do not enter fire area without proper protective equipment, including respiratory protection. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures For non-emergency personnel Emergency procedures For emergency responders Protective equipment Emergency procedures : Evacuate unnecessary personnel. : Equip cleanup crew with proper protection. : Ventilate area Environmental precautions Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters Methods and material for containment and cleaning up Methods for cleaning up 6.4. Reference to other sections See Heading 8. Exposure controls and personal protection. SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling : Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Collect spillage. Store away from other materials. : Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Provide good ventilation in process area to prevent formation of vapor. 05/26/2016 EN (English US) 2/7

3 Hygiene measures : Wash hands and forearms thoroughly after handling Conditions for safe storage, including any incompatibilities Storage conditions Incompatible products Incompatible materials : Keep only in the original container in a cool, well ventilated place away from heat, hot surfaces, sparks, open flame and other ignition sources. No smoking. Keep container closed when not in use. : Strong bases. Strong acids. SECTION 8: Exposure controls/personal protection 8.1. Control parameters : Sources of ignition. Direct sunlight. ACGIH ACGIH TWA (ppm) 100 ppm (2-Methoxymethylethoxy)propanol(DPGME); USA; Time-weighted average exposure limit 8 h; TLV - Adopted Value ACGIH ACGIH STEL (ppm) 150 ppm (2-Methoxymethylethoxy)propanol(DPGME); USA; Short time value; TLV - Adopted Value 8.2. Exposure controls Personal protective equipment : Avoid all unnecessary exposure. Hand protection Eye protection Skin and body protection Respiratory protection Other information : Wear protective gloves/eye protection/face protection protective gloves. : Chemical goggles or safety glasses. : Wear suitable protective clothing. : Wear appropriate mask. : Do not eat, drink or smoke during use. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Liquid Color : orange Odor : mild Odor threshold ph : 4-5 Melting point Freezing point Boiling point : F Flash point : > 200 F Relative evaporation rate (butyl acetate=1) Flammability (solid, gas) : Non flammable. Vapor pressure Relative vapor density at 20 C Relative density : 1.02 Solubility : Soluble in water. Log Pow Auto-ignition temperature Decomposition temperature Viscosity, kinematic Viscosity, dynamic 05/26/2016 EN (English US) 3/7

4 Explosion limits Explosive properties Oxidizing properties 9.2. Other information SECTION 10: Stability and reactivity Reactivity Chemical stability Possibility of hazardous reactions Conditions to avoid Direct sunlight. Extremely high or low temperatures Incompatible materials Strong acids. Strong bases Hazardous decomposition products Fume. Carbon monoxide. Carbon dioxide. SECTION 11: Toxicological information Information on toxicological effects Acute toxicity LD50 oral rat LD50 dermal rat ATE US (oral) LD50 oral rat ATE US (oral) 3000 mg/kg (Rat; Literature study) > 2000 mg/kg body weight (Rat; Experimental value; OECD 402: Acute Dermal Toxicity) mg/kg body weight 130 mg/kg (Rat; Literature) mg/kg body weight LD50 oral rat LD50 dermal rat LD50 dermal rabbit ATE US (oral) ATE US (dermal) Skin corrosion/irritation Serious eye damage/irritation Respiratory or skin sensitization Germ cell mutagenicity Carcinogenicity 5135 mg/kg (Rat; Equivalent or similar to OECD 401; Literature study; >5000 mg/kg; Rat; Experimental value) 9500 mg/kg (Rat; Literature study; Equivalent or similar to OECD 402; >19020 mg/kg bodyweight; Rat; Experimental value) 9500 mg/kg (Rabbit; Literature study) mg/kg body weight mg/kg body weight : Causes skin irritation. ph: 4-5 : Causes serious eye irritation. ph: 4-5 Reproductive toxicity Specific target organ toxicity (single exposure) Specific target organ toxicity (repeated exposure) 05/26/2016 EN (English US) 4/7

5 Aspiration hazard Potential Adverse human health effects and symptoms Symptoms/injuries after skin contact Symptoms/injuries after eye contact : Based on available data, the classification criteria are not met. : Causes skin irritation. : Causes serious eye irritation. SECTION 12: Ecological information Toxicity EC50 Daphnia mg/l (EC50; 72 h) LC50 fish mg/l (LC50; 96 h) Threshold limit algae mg/l (EC0; 168 h) LC50 fish 1 LC50 fish mg/l (96 h; Brachydanio rerio) 237 mg/l (96 h; Brachydanio rerio) LC50 fish 1 EC50 Daphnia 1 LC50 fish 2 Threshold limit algae 1 Threshold limit algae mg/l (96 h; Pimephales promelas; GLP) 1919 mg/l (LC50; Equivalent or similar to OECD 202; 48 h; Daphnia magna; Static system; Fresh water; Experimental value) 150 mg/l (72 h; Pisces) 969 mg/l (NOEC; OECD 201: Alga, Growth Inhibition Test; 72 h; Selenastrum capricornutum; Static system; Fresh water; Experimental value) > 969 mg/l (EC50; OECD 201: Alga, Growth Inhibition Test; 72 h; Selenastrum capricornutum; Static system; Fresh water; Experimental value) Biochemical oxygen demand (BOD) Chemical oxygen demand (COD) ThOD BOD (% of ThOD) ThOD Readily biodegradable in water. Biodegradable in the soil. No (test)data on mobility of the substance available g O₂/g substance g O₂/g substance g O₂/g substance 0.89 (20 days; Literature study) Biodegradability: not applicable. Biochemical oxygen demand (BOD) ThOD BOD (% of ThOD) Bioaccumulative potential Readily biodegradable in water. No (test)data on mobility of the substance available. Photolysis in the air. 0 g O₂/g substance 2.06 g O₂/g substance Bioaccumulative potential BCF other aquatic organisms (BCF; Other) Log Pow / -1.80,Experimental value; Other Bioaccumulative potential Low potential for bioaccumulation (Log Kow < 4). 05/26/2016 EN (English US) 5/7

6 Bioaccumulative potential Bioaccumulation: not applicable. Log Pow (Experimental value; OECD 102: Melting Point/Melting Range; 25 C) Bioaccumulative potential Low potential for bioaccumulation (Log Kow < 4) Mobility in soil Other adverse effects Effect on the global warming GWPmix comment Other information : No known effects from this product. : No known effects from this product. : Avoid release to the environment. SECTION 13: Disposal considerations Waste treatment methods Waste disposal recommendations : Dispose in a safe manner in accordance with local/national regulations. Ecology - waste materials : Avoid release to the environment. SECTION 14: Transport information Department of Transportation (DOT) In accordance with DOT TDG Transport by sea Air transport SECTION 15: Regulatory information US Federal regulations Not listed on the United States TSCA (Toxic Substances Control Act) inventory Listed on the United States TSCA (Toxic Substances Control Act) inventory Listed on the United States TSCA (Toxic Substances Control Act) inventory Not subject to reporing requirements of the United States SARA Section 313 CERCLA RQ 100 lb Listed on the United States TSCA (Toxic Substances Control Act) inventory International regulations CANADA EU-Regulations 05/26/2016 EN (English US) 6/7

7 National regulations US State regulations SECTION 16: Other information Revision date : 04/15/2016 Other information : None. Full text of H-phrases: H227 Combustible liquid H301 Toxic if swallowed H314 Causes severe skin burns and eye damage H315 Causes skin irritation H319 Causes serious eye irritation HMIS III Rating Health Flammability Physical Personal Protection : 2 Moderate Hazard - Temporary or minor injury may occur : 0 Minimal Hazard - Materials that will not burn : 0 Minimal Hazard - Materials that are normally stable, even under fire conditions, and will NOT react with water, polymerize, decompose, condense, or self-react. Non-Explosives. : B B - Safety glasses, Gloves SDS US (GHS HazCom 2012) This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product 05/26/2016 EN (English US) 7/7