SAFETY DATA SHEET THERMAL BONDING SYSTEM

Transcription

1 Report Date : 20/06/2011 SAFETY DATA SHEET 1 IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING PRODUCT NAME PRODUCT NO. APPLICATION SUPPLIER EMERGENCY TELEPHONE TBS-B ETBS20S ETBS01K ZE Adhesive ELECTROLUBE. A division of HK WENTWORTH LTD ASHBY PARK, COALFIELD WAY, ASHBY DE LA ZOUCH, LEICESTERSHIRE LE65 1JF UNITED KINGDOM +44 (0) (0) info@hkw.co.uk +44 (0) between 8.30am pm Mon Fri 2 HAZARDS IDENTIFICATION Causes severe burns. Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. CLASSIFICATION (1999/45) C;R35. R43. N;R50/53. ENVIRONMENT Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Do not empty into drains, dispose of this material and its container at hazardous or special waste collection point. Use appropriate containment to avoid environmental contamination. Avoid release to the environment. Refer to special instructions/safety data sheets. Dispose of waste and residues in accordance with local authority requirements. 3 COMPOSITION/INFORMATION ON INGREDIENTS Name EC No. CAS-No. Content % Classification (67/548/EEC) ZINC OXIDE % N;R50/53 Methylene Di(cyclohexylamine) % Xn;R22. C;R35. Xi;R37. R43. TRIETHYLENETETRAMINE % C;R34 Xn;R21 R43 R52/53 The Full Text for all R-Phrases is Displayed in Section 16 COMPOSITION COMMENTS Ingredients not listed are classified as non-hazardous or at a concentration below reportable levels 4 FIRST-AID MEASURES NOTES TO THE PHYSICIAN Treat symptomatically INHALATION Move the exposed person to fresh air at once. Get medical attention. Provide rest, warmth and fresh air. When breathing is difficult, properly trained personnel may assist affected person by administering oxygen. 1 / 5

2 Report Date : 20/06/2011 INGESTION DO NOT INDUCE VOMITING! NEVER MAKE AN UNCONSCIOUS PERSON VOMIT OR DRINK FLUIDS! Rinse mouth thoroughly. Drink plenty of water. Get medical attention immediately! Provide rest, warmth and fresh air. SKIN CONTACT Remove affected person from source of contamination. Remove contaminated clothing. Wash the skin immediately with soap and water. Get medical attention promptly if symptoms occur after washing. EYE CONTACT Make sure to remove any contact lenses from the eyes before rinsing. Promptly wash eyes with plenty of water while lifting the eye lids. Get medical attention immediately. Continue to rinse. 5 FIRE-FIGHTING MEASURES EXTINGUISHING MEDIA Use fire-extinguishing media appropriate for surrounding materials. SPECIFIC HAZARDS Fire creates: Toxic gases/vapours/fumes of: Carbon monoxide (CO). Carbon dioxide (CO2). 6 ACCIDENTAL RELEASE MEASURES ENVIRONMENTAL PRECAUTIONS Do not allow ANY environmental contamination. Do not discharge onto the ground or into water courses. SPILL CLEAN UP METHODS DO NOT touch spilled material. Absorb in vermiculite, dry sand or earth and place into containers. Flush with plenty of water to clean spillage area. Do not contaminate water sources or sewer. 7 HANDLING AND STORAGE USAGE PRECAUTIONS Avoid spilling, skin and eye contact. STORAGE PRECAUTIONS Store in tightly closed original container in a dry, cool and well-ventilated place. Keep in original container. STORAGE CLASS Corrosive storage. 8 EXPOSURE CONTROLS/PERSONAL PROTECTION Name STD TWA - 8 Hrs STEL - 15 Min Notes ZINC OXIDE WEL 5 mg/m3 10 mg/m3 WEL = Workplace Exposure Limit. PROTECTIVE EQUIPMENT ENGINEERING MEASURES Must not be handled in confined space without sufficient ventilation. RESPIRATORY EQUIPMENT No specific recommendation made, but respiratory protection must be used if the general level exceeds the recommended occupational exposure limit. HAND PROTECTION Protective gloves should be used if there is a risk of direct contact or splash. The most suitable glove must be chosen in consultation with the gloves supplier, who can inform about the breakthrough time of the glove material. EYE PROTECTION Wear approved chemical safety goggles where eye exposure is reasonably probable. OTHER PROTECTION Wear appropriate clothing to prevent any possibility of liquid contact and repeated or prolonged vapour contact. 2 / 5

3 Report Date : 20/06/2011 HYGIENE MEASURES DO NOT SMOKE IN WORK AREA! Wash at the end of each work shift and before eating, smoking and using the toilet. Promptly remove any clothing that becomes contaminated. Wash promptly with soap & water if skin becomes contaminated. Use appropriate skin cream to prevent drying of skin. When using do not eat, drink or smoke. 9 PHYSICAL AND CHEMICAL PROPERTIES APPEARANCE COLOUR ODOUR Liquid Not known. Characteristic RELATIVE DENSITY 20 C (68 F) VISCOSITY 0 20 C (68 F) FLASH POINT ( C) Not noted. 10 STABILITY AND REACTIVITY STABILITY Stable under normal temperature conditions. HAZARDOUS DECOMPOSITION PRODUCTS Fire creates: Toxic gases/vapours/fumes of: Carbon monoxide (CO). Carbon dioxide (CO2). 11 TOXICOLOGICAL INFORMATION TOXICOLOGICAL INFORMATION No information available. INHALATION Harmful by inhalation. Irritating to respiratory system. INGESTION Harmful if swallowed. SKIN CONTACT Causes burns. EYE CONTACT Spray and vapour in the eyes may cause irritation and smarting. HEALTH WARNINGS Prolonged inhalation of high concentrations may damage respiratory system. 12 ECOLOGICAL INFORMATION ECOTOXICITY The product contains a substance which is very toxic to aquatic organisms and which may cause long term adverse effects in the aquatic environment. 13 DISPOSAL CONSIDERATIONS DISPOSAL METHODS Dispose of waste and residues in accordance with local authority requirements. 14 TRANSPORT INFORMATION GENERAL For US Domestic transportation this product is classified as a Consumer Commodity. For International transportation this product is classified as UN1760 CORROSIVE LIQUID PROPER SHIPPING NAME PROPER SHIPPING NAME UN NO. ROAD ADR CLASS NO. CORROSIVE LIQUID, N.O.S. (TRIETHYLENETETRAMINE, ZINC OXIDE) CONSUMER COMMODITY / 5

4 Report Date : 20/06/2011 ADR CLASS ADR PACK GROUP HAZARD No. (ADR) ADR LABEL NO. HAZCHEM CODE UN NO. SEA IMDG CLASS IMDG PACK GR. EMS UN NO. AIR AIR CLASS AIR PACK GR. Class 8: Corrosive substances. II X II F-A, S-B II 15 REGULATORY INFORMATION LABELLING CONTAINS RISK PHRASES SAFETY PHRASES UK REGULATORY REFERENCES Corrosive Dangerous for the environment Methylene Di(cyclohexylamine) TRIETHYLENETETRAMINE R35 R43 Causes severe burns. R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S25 S26 S36/37/39 S45 S57 S60 S61 Chemicals (Hazard Information & Packaging) Regulations. Avoid contact with eyes. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show label where possible). Use appropriate containment to avoid environmental contamination. This material and its container must be disposed of as hazardous waste. Avoid release to the environment. Refer to special instructions/safety data sheets. The Control of Substances Hazardous to Health Regulations 2002 (S.I 2002 No. 2677) with amendments. ENVIRONMENTAL LISTING Control of Pollution Act Control of Pollution (Special Waste Regulations) Act Rivers (Prevention of Pollution) Act EU DIRECTIVES Dangerous Substance Directive 67/548/EEC. Dangerous Preparations Directive 1999/45/EC. System of specific information relating to Dangerous Preparations. 2001/58/EC. Commission Directive 2000/39/EC of 8 June 2000 establishing a first list of indicative occupational exposure limit values in implementation of Council Directive 98/24/EC on the protection of the health and safety of workers from the risks related to chemical agents at work. 4 / 5

5 Report Date : 20/06/2011 Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European Chemicals Agency, amending Directive 1999/45/EC and repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC) No 1488/94 as well as Council Directive 76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and 2000/21/EC, including amendments. Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16 December 2008 on classification, labelling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006 with amendments. APPROVED CODE OF PRACTICE Classification and Labelling of Substances and Preparations Dangerous for Supply. Safety Data Sheets for Substances and Preparations. GUIDANCE NOTES Workplace Exposure Limits EH OTHER INFORMATION REVISION COMMENTS Revised in accordance with CHIP3 and EU Directives 1999/45/EC and 2001/58/EC ISSUED BY Helen O'Reilly REV. NO./REPL. SDS GENERATED SDS NO RISK PHRASES IN FULL R34 R35 R22 R21 R52/53 R37 R43 R50/53 Causes burns. Causes severe burns. Harmful if swallowed. Harmful in contact with skin. Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Irritating to respiratory system. Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. DISCLAIMER This information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process. Such information is, to the best of the company's knowledge and belief, accurate and reliable as of the date indicated. However, no warranty guarantee or representation is made to its accuracy, reliability or completeness. It is the user's responsibility to satisfy himself as to the suitability of such information for his own particular use. 5 / 5

6 Report Date : 16/06/2011 SAFETY DATA SHEET 1 IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING PRODUCT NAME PRODUCT NO. APPLICATION SUPPLIER EMERGENCY TELEPHONE TBS-A ETBS20S ETBS01K ZE Adhesive ELECTROLUBE. A division of HK WENTWORTH LTD ASHBY PARK, COALFIELD WAY, ASHBY DE LA ZOUCH, LEICESTERSHIRE LE65 1JF UNITED KINGDOM +44 (0) (0) info@hkw.co.uk +44 (0) between 8.30am pm Mon Fri 2 HAZARDS IDENTIFICATION Irritating to eyes and skin. Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. CLASSIFICATION (1999/45) Xi;R36/38. R43. N;R50/53. ENVIRONMENT Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Do not empty into drains, dispose of this material and its container at hazardous or special waste collection point. Dispose of waste and residues in accordance with local authority requirements. 3 COMPOSITION/INFORMATION ON INGREDIENTS Name EC No. CAS-No. Content % Classification (67/548/EEC) ZINC OXIDE % N;R50/53 EPOXY RESIN (Number average MW <= 700 ) % R43 Xi;R36/38 N;R51/53 Polypropyleneglycol Diglycidylether % Xi;R36/38. R43. The Full Text for all R-Phrases is Displayed in Section 16 COMPOSITION COMMENTS Ingredients not listed are classified as non-hazardous or at a concentration below reportable levels 4 FIRST-AID MEASURES NOTES TO THE PHYSICIAN Treat symptomatically INHALATION Move the exposed person to fresh air at once. INGESTION DO NOT INDUCE VOMITING! Get medical attention immediately! Rinse nose, mouth and throat with water. 1 / 5

7 Report Date : 16/06/2011 SKIN CONTACT Remove affected person from source of contamination. Rinse the skin immediately with lots of water. Get medical attention promptly if symptoms occur after washing. EYE CONTACT Make sure to remove any contact lenses from the eyes before rinsing. Promptly wash eyes with plenty of water while lifting the eye lids. Continue to rinse for at least 15 minutes and get medical attention. 5 FIRE-FIGHTING MEASURES EXTINGUISHING MEDIA Fire can be extinguished using: Foam. Alcohol resistant foam. Dry chemicals, sand, dolomite etc. DO NOT use water if avoidable. 6 ACCIDENTAL RELEASE MEASURES SPILL CLEAN UP METHODS Keep combustibles away from spilled material. Stop leak if possible without risk. DO NOT touch spilled material! Wear necessary protective equipment. Absorb in vermiculite, dry sand or earth and place into containers. Wash thoroughly after dealing with a spillage. 7 HANDLING AND STORAGE USAGE PRECAUTIONS Avoid spilling, skin and eye contact. Keep away from heat, sparks and open flame. STORAGE PRECAUTIONS Store in tightly closed original container in a dry, cool and well-ventilated place. Keep in original container. 8 EXPOSURE CONTROLS/PERSONAL PROTECTION Name STD TWA - 8 Hrs STEL - 15 Min Notes ZINC OXIDE WEL 5 mg/m3 10 mg/m3 WEL = Workplace Exposure Limit. PROTECTIVE EQUIPMENT ENGINEERING MEASURES No specific ventilation requirements noted, except this product must not be used in a confined space without good ventilation. RESPIRATORY EQUIPMENT No specific recommendation made, but respiratory protection must be used if the general level exceeds the recommended occupational exposure limit. HAND PROTECTION Use suitable protective gloves if risk of skin contact. The most suitable glove must be chosen in consultation with the gloves supplier, who can inform about the breakthrough time of the glove material. EYE PROTECTION Wear approved, tight fitting safety glasses where splashing is probable. OTHER PROTECTION Wear appropriate clothing to prevent any possibility of skin contact. HYGIENE MEASURES DO NOT SMOKE IN WORK AREA! Wash at the end of each work shift and before eating, smoking and using the toilet. Wash promptly if skin becomes wet or contaminated. Promptly remove any clothing that becomes contaminated. When using do not eat, drink or smoke. 9 PHYSICAL AND CHEMICAL PROPERTIES APPEARANCE COLOUR Viscous Liquid Blue 2 / 5

8 Report Date : 16/06/2011 SOLUBILITY Insoluble in water RELATIVE DENSITY c VISCOSITY c 10 STABILITY AND REACTIVITY STABILITY Stable under normal temperature conditions. CONDITIONS TO AVOID Avoid contact with acids and oxidising substances. HAZARDOUS DECOMPOSITION PRODUCTS Fire creates: Vapours/gases/fumes of: Carbon monoxide (CO). Carbon dioxide (CO2). Nitrous gases (NOx). 11 TOXICOLOGICAL INFORMATION INHALATION May cause irritation to the respiratory system. INGESTION May cause discomfort if swallowed. May cause stomach pain or vomiting. SKIN CONTACT Irritating to skin. May cause allergic contact eczema. Prolonged contact may cause dryness of the skin. Acts as a defatting agent on skin. May cause cracking of skin, and eczema. EYE CONTACT Irritating to eyes. May cause chemical eye burns. ROUTE OF ENTRY Inhalation. Ingestion. Skin and/or eye contact. Name EPOXY RESIN (Number average MW <= 700 ) Toxic Dose 1 - LD 50 Toxic Dose 2 - LD ECOLOGICAL INFORMATION >5000 mg/kg (oral rat) >20000 mg/kg (oral rat) ECOTOXICITY Dangerous for the environment if discharged into watercourses. Name EPOXY RESIN (Number average MW <= 700 ) LC 50, 96 Hrs, Fish mg/l 3.1 EC 50, 48 Hrs, Daphnia, mg/l IC 50, 72 Hrs, Algae, mg/l DISPOSAL CONSIDERATIONS DISPOSAL METHODS Dispose of waste and residues in accordance with local authority requirements. 14 TRANSPORT INFORMATION GENERAL For US Domestic transportation this product is classified as a Consumer Commodity. For International transportation this product is classified as UN 3082 ENVIRONMENTALLY HAZARDOUS SUBSTANCE PROPER SHIPPING NAME PROPER SHIPPING NAME UDF Phrase 1 UN NO. ROAD ADR CLASS NO. ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (ZINC OXIDE) CONSUMER COMMODITY Class 9 Environmentally Hazardous substance / 5

9 Report Date : 16/06/2011 ADR CLASS ADR PACK GROUP HAZARD No. (ADR) ADR LABEL NO. HAZCHEM CODE UN NO. SEA IMDG CLASS IMDG PACK GR. EMS UN NO. AIR AIR CLASS AIR PACK GR. Class 9: Miscellaneous dangerous substances and articles. III Z III F-A, S-F III 15 REGULATORY INFORMATION LABELLING Irritant Dangerous for the environment CONTAINS EPOXY RESIN (Number average MW <= 700 ) RISK PHRASES SAFETY PHRASES UK REGULATORY REFERENCES Polypropyleneglycol Diglycidylether R36/38 Irritating to eyes and skin. R43 R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S24/25 Avoid contact with skin and eyes. S26 S37 Chemicals (Hazard Information & Packaging) Regulations. P5 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable gloves. Contains epoxy constituents. See information supplied by the manufacturer. The Control of Substances Hazardous to Health Regulations 2002 (S.I 2002 No. 2677) with amendments. ENVIRONMENTAL LISTING Control of Pollution Act Control of Pollution (Special Waste Regulations) Act Rivers (Prevention of Pollution) Act EU DIRECTIVES Dangerous Substance Directive 67/548/EEC. Dangerous Preparations Directive 1999/45/EC. System of specific information relating to Dangerous Preparations. 2001/58/EC. Commission Directive 2000/39/EC of 8 June 2000 establishing a first list of indicative occupational exposure limit values in implementation of Council Directive 98/24/EC on the protection of the health and safety of workers from the risks related to chemical agents at work. Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European Chemicals Agency, amending Directive 1999/45/EC and repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC) No 1488/94 as well as Council Directive 76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and 2000/21/EC, including amendments. APPROVED CODE OF PRACTICE Classification and Labelling of Substances and Preparations Dangerous for Supply. Safety Data Sheets for Substances and Preparations. 4 / 5

10 Report Date : 16/06/2011 GUIDANCE NOTES Workplace Exposure Limits EH OTHER INFORMATION REVISION COMMENTS Revised in accordance with CHIP3 and EU Directives 1999/45/EC and 2001/58/EC ISSUED BY Helen O'Reilly REV. NO./REPL. SDS GENERATED SDS NO RISK PHRASES IN FULL R36/38 R43 R51/53 R50/53 Irritating to eyes and skin. Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. DISCLAIMER This information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process. Such information is, to the best of the company's knowledge and belief, accurate and reliable as of the date indicated. However, no warranty guarantee or representation is made to its accuracy, reliability or completeness. It is the user's responsibility to satisfy himself as to the suitability of such information for his own particular use. 5 / 5