COPPER SULPHATE PENTAHYDRATE

Transcription

1 SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 COPPER SULPHATE PENTAHYDRATE Version 5.0 Print Date 2018/07/03 Revision date / valid from 2018/07/03 MSDS code: MYYY814 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Trade name : COPPER SULPHATE PENTAHYDRATE Substance name : copper sulphate pentahydrate Index-No. : CAS-No. : EC-No. : EU REACH-Reg. No. : xxxx 1.2. Relevant identified uses of the substance or mixture and uses advised against Use of the Substance/Mixture : Identified use: See table in front of appendix for a complete overview of identified uses. Uses advised against : At this moment we have not identified any uses advised against Remarks : Before referring to any Exposure Scenario attached to this Safety Data Sheet please check the grade of the product: the Exposure Scenarios presented are not related to the product grade 1.3. Details of the supplier of the safety data sheet Company : Brenntag UK Limited Alpha House, Lawnswood Business Park GB LS16 6QY Leeds Telephone : +44 (0) Telefax : +44 (0) address : msds@brenntag.co.uk 1.4. Emergency telephone number Emergency telephone number : Emergency only telephone number (open 24 hours): +44 (0) (N.C.E.C. Culham) SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification according to Regulation (EC) No 1272/2008 R /32 EN

2 REGULATION (EC) No 1272/2008 Hazard class Hazard category Target Organs Hazard statements Acute toxicity (Oral) Category H302 Serious eye damage/eye irritation Category H319 Skin corrosion/irritation Category H315 Acute aquatic toxicity Category H400 Chronic aquatic toxicity Category H410 For the full text of the H-Statements mentioned in this Section, see Section 16. Most important adverse effects Human Health : See section 11 for toxicological information. Physical and chemical hazards Potential environmental effects : See section 9/10 for physicochemical information. : See section 12 for environmental information Label elements Labelling according to Regulation (EC) No 1272/2008 Hazard symbols : Signal word : Warning Hazard statements : H302 Harmful if swallowed. H319 Causes serious eye irritation. H315 Causes skin irritation. H410 Very toxic to aquatic life with long lasting effects. Precautionary statements Prevention : P273 Avoid release to the environment. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. Response : P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. R50163 / Version 5.0 2/32 EN

3 P337 + P313 P301 + P312 P302 + P352 If eye irritation persists: Get medical advice/ attention. IF SWALLOWED: Call a POISON CENTER/doctor if you feel unwell. IF ON SKIN: Wash with plenty of water. Hazardous components which must be listed on the label: copper sulphate pentahydrate 2.3. Other hazards For Results of PBT and vpvb assessment see section SECTION 3: Composition/information on ingredients 3.1. Substances Classification (REGULATION (EC) No 1272/2008) Hazardous components Amount [%] copper sulphate pentahydrate Hazard class / Hazard category Hazard statements Index-No. : CAS-No. : EC-No. : EU REACH- : xxxx Reg. No. <= 100 Acute Tox.4 Eye Dam.1 Skin Irrit.2 Aquatic Acute1 Aquatic Chronic1 H302 H318 H315 H400 H410 For the full text of the H-Statements mentioned in this Section, see Section 16. SECTION 4: First aid measures 4.1. Description of first aid measures General advice If inhaled In case of skin contact In case of eye contact : Take off all contaminated clothing immediately. Wash contaminated clothing before re-use. : Remove to fresh air. If breathing is irregular or stopped, administer artificial respiration. If symptoms call a physician. : After contact with skin, wash immediately with plenty of water. If skin irritation persists, call a physician. : Rinse immediately with plenty of water, also under the eyelids, for at least 10 minutes. Consult an eye specialist immediately. Go to an ophthalmic hospital if possible. R50163 / Version 5.0 3/32 EN

4 If swallowed : Rinse mouth. Never give anything by mouth to an unconscious person. Do NOT induce vomiting. Call a physician immediately Most important symptoms and effects, both acute and delayed Symptoms Effects : See Section 11 for more detailed information on health effects and symptoms. : See Section 11 for more detailed information on health effects and symptoms Indication of any immediate medical attention and special treatment needed Treatment : Treat symptomatically. SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media Unsuitable extinguishing media : The product itself does not burn. Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. : High volume water jet 5.2. Special hazards arising from the substance or mixture Specific hazards during firefighting : Fire may cause evolution of: Sulphur oxides 5.3. Advice for firefighters Special protective equipment for firefighters : In the event of fire, wear self-contained breathing apparatus.wear appropriate body protection (full protective suit) Further advice : Collect contaminated fire extinguishing water separately. This must not be discharged into drains.fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Personal precautions : Use personal protective equipment. Provide adequate ventilation. Avoid dust formation. Avoid contact with skin, eyes and clothing. Do not breathe dust Environmental precautions Environmental precautions : Do not flush into surface water or sanitary sewer system. Avoid subsoil penetration. If the product contaminates rivers R50163 / Version 5.0 4/32 EN

5 6.3. Methods and materials for containment and cleaning up and lakes or drains inform respective authorities. If material reaches soil inform authorities responsible for such cases. Methods and materials for containment and cleaning up Further information : Use mechanical handling equipment. Keep in suitable, closed containers for disposal. : Treat recovered material as described in the section "Disposal considerations" Reference to other sections See Section 1 for emergency contact information. See Section 8 for information on personal protective equipment. See Section 13 for waste treatment information. SECTION 7: Handling and storage 7.1. Precautions for safe handling Advice on safe handling Hygiene measures : Keep container tightly closed. Provide for appropriate exhaust ventilation and dust collection at machinery. Avoid contact with skin, eyes and clothing. Avoid dust formation. Emergency eye wash fountains and emergency showers should be available in the immediate vicinity. : Keep away from food, drink and animal feedingstuffs. Smoking, eating and drinking should be prohibited in the application area. Wash hands before breaks and at the end of workday. Take off all contaminated clothing immediately. Do not breathe dust Conditions for safe storage, including any incompatibilities Requirements for storage areas and containers Advice on protection against fire and explosion Fire-fighting class Further information on storage conditions Advice on common storage : Store in original container. : The product is not flammable. Normal measures for preventive fire protection. : non-combustible : Keep container tightly closed. Keep in a dry place. Product is hygroscopic. : Keep away from food, drink and animal feedingstuffs. Incompatible with strong bases and oxidizing agents Specific end use(s) Specific use(s) : No information available. R50163 / Version 5.0 5/32 EN

6 SECTION 8: Exposure controls/personal protection 8.1. Control parameters (Additional) Information Other Occupational Exposure Limit Values : Contains no substances with occupational exposure limit values. Contains no substances with occupational exposure limit values. Component: copper sulphate pentahydrate CAS-No Derived No Effect Level (DNEL)/Derived Minimal Effect Level (DMEL) No DNEL value was derived. : Predicted No Effect Concentration (PNEC) Fresh water copper sulphate Marine water copper sulphate Sewage treatment plant (STP) copper sulphate Fresh water sediment copper sulphate Marine sediment copper sulphate Soil copper sulphate : 7.8 µg/l : 5.2 µg/l : 230 µg/l : 87 mg/kg d.w. : 676 mg/kg d.w. : 65 mg/kg d.w Exposure controls Personal protective equipment Respiratory protection Advice : Required if dust is released Recommended Filter type: Particle filter:p2 Particle filter:p3 If ventilation is insufficient, suitable respiratory protection must be provided Hand protection Advice : Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation. R50163 / Version 5.0 6/32 EN

7 Material : Natural Rubber Break through time : >= 8 min Glove thickness : 0.5 mm Take note of the information given by the producer concerning permeability and break through times, and of special workplace conditions (mechanical strain, duration of contact). Protective gloves should be replaced at first signs of wear. The following information applies to aqueous, saturated solutions. Material : Nitrile rubber Break through time : >= 8 min Glove thickness : 0.35 mm Material : polychloroprene Break through time : >= 8 min Glove thickness : 0.5 mm Material : Fluorinated rubber Break through time : >= 8 min Glove thickness : 0.4 mm Material : butyl-rubber Break through time : >= 8 min Glove thickness : 0.5 mm Material : Polyvinylchloride Break through time : >= 8 min Glove thickness : 0.5 mm Eye protection Advice : Safety goggles Ensure that eyewash stations and safety showers are close to the workstation location. Skin and body protection Advice : Choose body protection in relation to its type, to the concentration and amount of dangerous substances, and to the specific workplace. Wear appropriate chemical resistant clothing and boots. Dust impervious protective suit Environmental exposure controls General advice : Do not flush into surface water or sanitary sewer system. Avoid subsoil penetration. If the product contaminates rivers and lakes or drains inform R50163 / Version 5.0 7/32 EN

8 respective authorities. If material reaches soil inform authorities responsible for such cases. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Form : solid Colour : blue Odour : odourless Odour Threshold : no data available ph : (50 g/l ; 20 C) Melting point/range : Not applicablethermal decomposition Boiling point/boiling range : no data available Flash point : Not applicable Evaporation rate : no data available Flammability (solid, gas) : The product is not flammable. Upper explosion limit : Not applicable Lower explosion limit : Not applicable Vapour pressure : no data available Relative vapour density : no data available Density : 2.29 g/cm3 (20 C) Water solubility : 317 g/l (20 C) Partition coefficient: n-octanol/water : no data available Auto-ignition temperature : Not applicable Thermal decomposition : > 560 C Viscosity, dynamic : Not applicable Explosive properties : EU legislation: Not explosive Explosivity : Product is not explosive. R50163 / Version 5.0 8/32 EN

9 Oxidizing properties : not oxidising 9.2. Other information Bulk density : ca kg/m3 SECTION 10: Stability and reactivity Reactivity Advice : No decomposition if used as directed Chemical stability Advice : Stable under recommended storage conditions Possibility of hazardous reactions Hazardous reactions : No dangerous reaction known under conditions of normal use Conditions to avoid Conditions to avoid : humid air and waterproduct is hygroscopic. Thermal decomposition : > 560 C Incompatible materials Materials to avoid : Hydroxylamine, Strong oxidizing agents, Magnesium powder, Hydrazine, Bases Hazardous decomposition products Hazardous decomposition products : Sulphur oxides, toxic metal oxide fume SECTION 11: Toxicological information Information on toxicological effects Component: copper sulphate pentahydrate CAS-No Acute toxicity Oral LD50 : 482 mg/kg body weight(rat, male and female) (OECD Test Guideline 401) no data available Inhalation R50163 / Version 5.0 9/32 EN

10 Dermal LD50 : > 2000 mg/kg body weight(rat, male and female) (OECD Test Guideline 402) Result : Irritating to skin. Irritation Skin Eyes Result : Severe eye irritation (Rabbit) (OECD - Guideline 405) Sensitisation Result : not sensitizing (Dermal; Guinea pig) (OECD Test Guideline 406) CMR effects CMR Properties Carcinogenicity : It is not considered carcinogenic. Mutagenicity : In vitro tests did not show mutagenic effects In vivo tests showed mutagenic effects Teratogenicity : Animal testing did not show any effects on foetal development. Reproductive toxicity : Animal testing did not show any effects on fertility. Genotoxicity in vitro Result : negative (Ames test; Salmonella typhimurium) Genotoxicity in vivo Result : negative (In vivo micronucleus test) Specific Target Organ Toxicity Single exposure Remarks : The substance or mixture is not classified as specific target organ toxicant, single exposure. Repeated exposure R50163 / Version /32 EN

11 Remarks : The substance or mixture is not classified as specific target organ toxicant, repeated exposure. Other toxic properties Aspiration hazard No aspiration toxicity classification, SECTION 12: Ecological information Toxicity Component: copper sulphate pentahydrate CAS-No Acute toxicity Fish LC50 : mg/l (Oncorhynchus mykiss; 96 h; Test substance: copper sulphate) Toxicity to daphnia and other aquatic invertebrates EC50 : mg/l (Daphnia magna (Water flea); 48 h; Test substance: copper sulphate) algae EC50 : 0.1 mg/l (scenedesmus quadricauda; 4 h; Test substance: copper sulphate) Bacteria LC50 : 0.08 mg/l (Escherichia coli) M-Factor M-Factor (Acute Aquat. Tox.) : Persistence and degradability R50163 / Version /32 EN

12 Component: copper sulphate pentahydrate CAS-No Persistence and degradability Persistence Result : (Related to: Water) study scientifically unjustified Biodegradability Result : The methods for determining the biological degradability are not applicable to inorganic substances Bioaccumulative potential Component: copper sulphate pentahydrate CAS-No Bioaccumulation Result : Bioaccumulation is potentially possible Mobility in soil Component: copper sulphate pentahydrate CAS-No Mobility Water : The product is water soluble. Soil : Has low mobility Results of PBT and vpvb assessment Component: copper sulphate pentahydrate CAS-No Results of PBT and vpvb assessment Result : The PBT or vpvb criteria of Annex XIII to the REACH Regulation does not apply to inorganic substances Other adverse effects Component: copper sulphate pentahydrate CAS-No Additional ecological information Result : Do not flush into surface water or sanitary sewer system. Avoid subsoil penetration. SECTION 13: Disposal considerations R50163 / Version /32 EN

13 13.1. Waste treatment methods Product : Disposal together with normal waste is not allowed. Special disposal required according to local regulations. Do not let product enter drains. Contact waste disposal services. Contaminated packaging : Dispose of contaminated packaging in the same way as the product. In accordance with local and national regulations. European Waste Catalogue Number : No waste code according to the European Waste Catalogue can be assigned for this product, as the intended use dictates the assignment. The waste code is established in consultation with the regional waste disposer. SECTION 14: Transport information UN number UN proper shipping name ADR RID IMDG : ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (Copper sulfate pentahydrate) : ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (Copper sulfate pentahydrate) : ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (Copper sulfate pentahydrate) Transport hazard class(es) ADR-Class (Labels; Classification Code; Hazard identification No; Tunnel restriction code) RID-Class (Labels; Classification Code; Hazard identification No) IMDG-Class (Labels; EmS) : 9 9; M7; 90; (-) : 9 9; M7; 90 : 9 9; F-A, S-F Packaging group ADR RID IMDG : III : III : III Environmental hazards Environmentally hazardous according to ADR Environmentally hazardous according to RID Marine Pollutant according to IMDG-Code : yes : yes : yes R50163 / Version /32 EN

14 14.6. Special precautions for user Not applicable Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code IMDG : Not applicable. SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture Component: copper sulphate pentahydrate CAS-No EU. Regulation No 1451/2007 [Biocides], Annex I, OJ (L 325) : EC Number:, ; Listed EU. Directive 2012/18/EU (SEVESO III) Annex I : Lower-tier requirements: 100 tonnes; Part 1: Categories of dangerous substances; E1: Hazardous to the Aquatic Environment in Category Acute 1 or Chronic 1 Upper-tier requirements: 200 tonnes; Part 1: Categories of dangerous substances; E1: Hazardous to the Aquatic Environment in Category Acute 1 or Chronic 1 UK. Releases to air and water (UK ISR) : Annual reporting level threshold: 10 kg UK. Releases to air and water (UK ISR) : Annual reporting level threshold: 20.0 kg UK. Releases to air and water (UK ISR) : Annual reporting level threshold: 20.0 kg WGK (DE) : WGK 3: highly water endangering: 141 Notification status copper sulphate pentahydrate: R50163 / Version /32 EN

15 Regulatory List Notification Notification number AICS YES INV (CN) YES ENCS (JP) YES (1)-300 ISHL (JP) YES (1)-300 IECSC YES Chemical safety assessment no data available SECTION 16: Other information Full text of H-Statements referred to under sections 2 and 3. H302 H315 H318 H319 H400 H410 Harmful if swallowed. Causes skin irritation. Causes serious eye damage. Causes serious eye irritation. Very toxic to aquatic life. Very toxic to aquatic life with long lasting effects. Abbreviations and Acronyms BCF BOD CAS CLP CMR COD DNEL EINECS ELINCS GHS LC50 LOAEC LOAEL LOEL NLP NOAEC NOAEL NOEC NOEL OECD bioconcentration factor biochemical oxygen demand Chemical Abstracts Service Classification, Labelling and Packaging carcinogenic, mutagenic or toxic to reproduction chemical oxygen demand derived no-effect level European Inventory of Existing Commercial Chemical Substances European List of Notified Chemical Substances Globally Harmonized System of Classification and Labelling of Chemicals median lethal concentration lowest observed adverse effect concentration lowest observed adverse effect level lowest observed effect level no-longer polymer no observed adverse effect concentration no observed adverse effect level no observed effect concentration no observed effect level Organisation for Economic Cooperation and Development R50163 / Version /32 EN

16 OEL PBT PNEC STOT SVHC UVCB vpvb Further information occupational exposure limit persistent, bioaccumulative and toxic predicted no-effect concentration specific target organ toxicity substance of very high concern substance of unknown or variable composition, complex reaction products or biological materials very persistent and very bioaccumulative Key literature references and sources for data Methods used for product classification : Supplier information and data from the "Database of registered substances" of the European Chemicals Agency (ECHA) were used to create this safety data sheet. : The classification for human health, physical and chemical hazards and environmental hazards were derived from a combination of calculation methods and if available test data. Hints for trainings : The workers have to be trained regularly on the safe handling of the products based on the information provided in the Safety Data Sheet and the local conditions of the workplace. National regulations for the training of workers in the handling of hazardous materials must be adhered to. Other information : The information provided in this Safety Data Sheet is correct to our knowledge at the date of its revision. The information given only describes the products with regard to safety arrangements and is not to be considered as a warranty or quality specification and does not constitute a legal relationship. Indicates updated section. The information contained in this Safety Data Sheet relates only to the specific material designated and may not be valid for such material used in combination with any other material or in any process, unless specified in the text. R50163 / Version /32 EN

17 No. 1 Short title Industrial use for Downstream user Main User Group (SU) Sector of Use (SU) Product Category (PC) 3 NA NA 2 Professional use 22 NA NA 3 Consumer use 21 NA 1, 9a, 9b, 12, 24, 30, 31, 35 Process Category (PROC) 1, 2, 3, 4, 5, 7, 8a, 8b, 9, 10, 13, 14, 15, 17, 22, 23, 24, 25 1, 2, 3, 4, 5, 8a, 8b, 9, 10, 11, 13, 14, 15, 17, 19, 20, 21, 22, 25, 26 NA Environm ental Release Category (ERC) 2, 3, 4, 5, 6a, 6b, 6d, 7 2, 3, 4, 5, 6a, 6b, 6d, 8a, 8b, 8c, 8d, 8f, 9a, 9b, 10a, 11a 8a, 8b, 8c, 8d, 8f, 9a, 9b, 10a, 10b, 11a Article Category (AC) NA NA NA Specified ES10308 ES10695 ES10699 R50163 / Version /32 EN

18 1. Short title of Exposure Scenario 1: Industrial use for Downstream user Main User Groups Process categories Environmental Release Categories SU 3: Industrial uses: Uses of substances as such or in preparations at industrial sites PROC1: Chemical production or refinery in closed process without likelihood of exposure or processes with equivalent containment conditions PROC2: Use in closed, continuous process with occasional controlled exposure PROC3: Manufacture or formulation in the chemical industry in closed batch processes with occasional controlled exposure or processes with equivalent containment condition PROC4: Use in batch and other process (synthesis) where opportunity for exposure arises PROC5: Mixing or blending in batch processes for formulation of preparations and articles (multistage and/ or significant contact) PROC7: Industrial spraying PROC8a: Transfer of substance or preparation (charging/ discharging) from/ to vessels/ large containers at non-dedicated facilities PROC8b: Transfer of substance or preparation (charging/ discharging) from/ to vessels/ large containers at dedicated facilities PROC9: Transfer of substance or preparation into small containers (dedicated filling line, including weighing) PROC10: Roller application or brushing PROC13: Treatment of articles by dipping and pouring PROC14: Production of preparations or articles by tabletting, compression, extrusion, pelletisation PROC15: Use as laboratory reagent PROC17: Lubrication at high energy conditions and in partly open process PROC22: Manufacturing and processing of minerals and/or metals at substantially elevated temperature PROC23: Open processing and transfer operations with minerals/ metals at elevated temperature PROC24: High (mechanical) energy work-up of substances bound in materials and/ or articles PROC25: Other hot work operation with metals ERC2: Formulation of preparations ERC3: Formulation in materials ERC4: Industrial use of processing aids in processes and products, not becoming part of articles ERC5: Industrial use resulting in inclusion into or onto a matrix ERC6a: Industrial use resulting in manufacture of another substance (use of intermediates) ERC6b: Industrial use of reactive processing aids ERC6d: Industrial use of process regulators for polymerisation processes in production of resins, rubbers, polymers ERC7: Industrial use of substances in closed systems 2.1 Contributing scenario controlling environmental exposure for: ERC2, ERC3, ERC4, ERC5, ERC6a, ERC6b, ERC6d, ERC7 Amount used Annual amount per site Annual amount per site Annual amount per site Annual amount per site Annual amount per site Annual amount per site Annual amount per site Annual amount per site Annual amount per site 10 ton(s)/year (Dilution of 10 ERC2, ERC6a) 100 ton(s)/year (Dilution of 10 ERC3) 0.2 ton(s)/year (Dilution of 10 ERC4) 0.4 ton(s)/year (Dilution of 10 ERC5) 4 ton(s)/year (Dilution of 10 ERC6b, ERC7) 4100 ton(s)/year (Dilution of 10 ERC6d) 17 ton(s)/year (Dilution of 100 ERC2, ERC6a) 170 ton(s)/year (Dilution of 100 ERC3) 0.3 ton(s)/year (Dilution of 100 ERC4) R50163 / Version /32 EN

19 Annual amount per site Annual amount per site Annual amount per site Frequency and duration of use Continuous exposure 220 days/year Environment factors not influenced by risk management Other given operational conditions affecting environmental exposure Technical conditions and measures at process level to prevent release Technical onsite conditions and measures to reduce or limit discharges, air emissions and releases to soil Organizational measures to prevent/limit release from the site Conditions and measures related to sewage treatment plant Conditions and measures related to external treatment of waste for disposal Flow rate of receiving surface water Other data. Other information Other data. Other information Other data. Other information Factor: Air Factor: Soil 0.65 ton(s)/year (Dilution of 100 ERC5) 6.5 ton(s)/year (Dilution of 100 ERC6b, ERC7) 5000 ton(s)/year (Dilution of 100 ERC6d) 18,000 m3/d Local freshwater dilution factor: 10 Local freshwater dilution factor: 100 Local marine water dilution factor: % 0 % Indoor use Either wet or dry process 2 % (only ERC2) 0.2 % (only ERC3) 100 % (only ERC4) 50 % (only ERC5) 2 % (only ERC6a) 5 % (only ERC6b) % (only ERC6d) 5 % (only ERC7) Air Bag filters (Efficiency: 99 %) Water Chemical precipitation, Sedimentation, Filtration (Degradation effectiveness: %) Air Wet scrubbers (Efficiency: %) Air Type of Sewage Treatment Plant Flow rate of sewage treatment plant effluent Degradation efficiency 92 % Waste treatment This may create a general negative pressure in the building, Treatment and monitoring of releases to outside air, and exhaust gas streams, according to national regulation. Municipal sewage treatment plant 2,000 m3/d Users of the substance and the substance compounds have to minimize substance containing waste, promote recycling routes and, for the remaining, dispose the waste stream according the Waste regulation, All residues containing the substance are recycled R50163 / Version /32 EN

20 Conditions and measures related to external recovery of waste Disposal methods Recovery Methods Dispose of as hazardous waste in compliance with local and national regulations. Users of the substance and the substance compounds have to favour the recycling channels of the end-of-life products 2.2 Contributing scenario controlling environmental exposure for: ERC4, ERC5, ERC6a, ERC6b, ERC6c, ERC6d, ERC7 spercs for metal and metal compounds for formulation have been used to evaluate the exposure for the environment, The ERC are provided only for reference. Amount used Annual amount per site Annual amount per site 41 ton(s)/year 67 ton(s)/year Frequency and duration of use Continuous exposure 220 days/year Environment factors not influenced by risk management Other given operational conditions affecting environmental exposure Technical conditions and measures at process level to prevent release Technical onsite conditions and measures to reduce or limit discharges, air emissions and releases to soil Organizational measures to prevent/limit release from the site Conditions and measures related to sewage treatment plant Conditions and measures related to external treatment of waste for disposal Flow rate of receiving surface water Other data. Other information Other data. Other information Other data. Other information Factor: Air 18,000 m3/d Local freshwater dilution factor: 10 Local freshwater dilution factor: 100 Local marine water dilution factor: % 0.5 % Maximum of the 90th percentiles of reported site-specific release factors,. Factor: Soil Water Type of Sewage Treatment Plant 0 % Degradation efficiency 92 % Waste treatment Required removal efficiency for wastewater can be achieved using onsite/offsite technologies, either alone or in combination. (Degradation effectiveness: 92 %) Municipal sewage treatment plant To be incinerated or recycled 2.3 Contributing scenario controlling environmental exposure for: ERC4, ERC5, ERC6a, ERC6b, ERC6c, ERC6d, ERC7 spercs for metal and metal compounds have been used to evaluate the exposure for the environment, The ERC are provided only for reference. Annual amount per site 35 ton(s)/year (Dilution of 10 n/a) Amount used Annual amount per site 190 ton(s)/year (Dilution of 100 n/a) Frequency and duration of use Continuous exposure 220 days/year R50163 / Version /32 EN

21 Environment factors not influenced by risk management Other given operational conditions affecting environmental exposure Technical conditions and measures at process level to prevent release Technical onsite conditions and measures to reduce or limit discharges, air emissions and releases to soil Organizational measures to prevent/limit release from the site Conditions and measures related to sewage treatment plant Flow rate of receiving surface water Other data. Other information Other data. Other information Other data. Other information Factor: Air 18,000 m3/d Local freshwater dilution factor: 10 Local freshwater dilution factor: 100 Local marine water dilution factor: 100 R50163 / Version /32 EN 0.1 % 0.6 % Maximum of the 90th percentiles of reported site-specific release factors,. Water Type of Sewage Treatment Plant Degradation efficiency 92 % Required removal efficiency for wastewater can be achieved using onsite/offsite technologies, either alone or in combination. (Degradation effectiveness: 92 %) Municipal sewage treatment plant Conditions and measures related to external treatment of waste for disposal Waste treatment To be incinerated or recycled 2.4 Contributing scenario controlling worker exposure for: PROC1, PROC2, PROC3, PROC4, PROC5, PROC7, PROC8a, PROC8b, PROC9, PROC10, PROC13, PROC14, PROC15, PROC17, PROC22, PROC23, PROC24, PROC25 Product characteristics Frequency and duration of use Human factors not influenced by risk management Technical conditions and measures to control dispersion from source towards the worker Organisational measures to prevent /limit releases, dispersion and exposure Physical Form (at time of use) solid, or, liquid Covers daily exposures up to 8 hours Exposed skin area Respiration volume under conditions of use Exposed skin surface 240 cm² 10 m3/day Body weight 70 kg Local exhaust ventilation on furnaces and other work areas with potential dust generation, dust capturing and removal techniques Containment of liquid volumes in sumps to collect/prevent accidental spillage Closed process and closed circuits where relevant and possible Provide local exhaust ventilation (LEV).(Solid, high dustiness PROC2, PROC3, PROC4, PROC5, PROC8a, PROC8b, PROC9, PROC14, PROC15, PROC22, PROC23, PROC24, PROC25) Provide local exhaust ventilation (LEV).(Solid, medium dustiness PROC3, PROC4, PROC5, PROC8a, PROC8b, PROC9, PROC14, PROC22, PROC23, PROC24, PROC25) Provide local exhaust ventilation (LEV).(Liquid preparations PROC7) Provide local exhaust ventilation (LEV).(Solid, low dustiness PROC22, PROC23, PROC24, PROC25) General occupational hygiene measures are required to ensure a safe handling of the substance Regular cleaning of equipment and work area Worker training in process operations

22 Conditions and measures related to personal protection, hygiene and health evaluation 3. Exposure estimation and reference to its source Wear respiratory protection. Wear air purifying mask APF4(Solid, high dustiness PROC4, PROC5, PROC8b, PROC9, PROC14, PROC24, PROC25) Wear respiratory protection. Wear air purifying mask APF4(Liquid preparations PROC7) Wear respiratory protection. Wear air purifying half mask APF10(Solid, high dustiness PROC8a) Environment ERC2, ERC3, ERC4, ERC6a: EUSES Contributing Scenario ERC2, ERC3, ERC4, ERC6a ERC2, ERC3, ERC4, ERC6a ERC2, ERC3, ERC6a ERC2, ERC3, ERC6a ERC2, ERC3, ERC6a ERC2, ERC3, ERC6a ERC2, ERC3, ERC6a ERC2, ERC3, ERC6a Specific conditions Compartment Value Level of Exposure Dilution of 10 Fresh water PEC 5.4µg/L 0.69 Dilution of 100 Fresh water PEC 3.3µg/L 0.43 Dilution of 100 Marine water PEC 1.5µg/L 0.27 Dilution of 10 Dilution of 100 Fresh water sediment Fresh water sediment R50163 / Version /32 EN PEC PEC Dilution of 100 Marine sediment PEC Dilution of 10 Soil PEC Dilution of 100 Soil PEC 74.77mg/kg dry weight (d.w.) 12.71mg/kg dry weight (d.w.) 28.81mg/kg dry weight (d.w.) 44.07mg/kg dry weight (d.w.) 57.85mg/kg dry weight (d.w.) Relevant for section 2.2: spercs for metal and metal compounds for formulation have been used to evaluate the exposure for the environment. Relevant for section 2.3: spercs for metal and metal compounds have been used to evaluate the exposure for the environment. Workers PROC1, PROC2, PROC3: MEASE Contributing Scenario PROC Specific conditions Exposure routes Level of Exposure RCR Solid, medium dustiness, Solid, low dustiness PROC1 liquid PROC2 Solid, high dustiness PROC2 Solid, medium dustiness PROC2 Solid, low dustiness PROC2 liquid PROC3 Solid, medium dustiness, Solid, low dustiness RCR

23 PROC3 liquid PROC4 Solid, high dustiness PROC4 Solid, medium dustiness, Solid, low dustiness PROC4 liquid PROC5 Solid, high dustiness PROC5 Solid, medium dustiness, Solid, low dustiness PROC5 liquid PROC7 liquid PROC8a Solid, low dustiness PROC8a Solid, medium dustiness PROC8a liquid PROC8b Solid, high dustiness PROC8b Solid, medium dustiness PROC8b Solid, low dustiness PROC8b liquid PROC9 Solid, medium dustiness PROC9 Solid, low dustiness PROC9 liquid PROC10 liquid PROC13 liquid PROC14 Solid, high dustiness PROC14 Solid, medium dustiness, Solid, low dustiness PROC14 liquid PROC15 Solid, medium dustiness PROC15 Solid, low dustiness PROC15 liquid PROC17 liquid PROC22 PROC23 Solid, medium dustiness, Solid, low dustiness Solid, medium dustiness, Solid, low dustiness PROC24 Solid, high dustiness PROC24 Solid, medium dustiness PROC24 Solid, low dustiness PROC25 Solid, medium dustiness, Solid, low dustiness, no respiratory protection (RPE) Guidance to Downstream User to evaluate whether he works inside the boundaries set by the Exposure Scenario R50163 / Version /32 EN

24 Guidance is based on assumed operating conditions which may not be applicable to all sites; thus, scaling may be necessary to define appropriate site-specific risk management measures. Where other risk management measures/operational conditions are adopted, then users should ensure that risks are managed to at least equivalent levels. Environment For scaling see: tool R50163 / Version /32 EN

25 1. Short title of Exposure Scenario 2: Professional use Main User Groups Process categories Environmental Release Categories SU 22: Professional uses: Public domain (administration, education, entertainment, services, craftsmen) PROC1: Chemical production or refinery in closed process without likelihood of exposure or processes with equivalent containment conditions PROC2: Use in closed, continuous process with occasional controlled exposure PROC3: Manufacture or formulation in the chemical industry in closed batch processes with occasional controlled exposure or processes with equivalent containment condition PROC4: Use in batch and other process (synthesis) where opportunity for exposure arises PROC5: Mixing or blending in batch processes for formulation of preparations and articles (multistage and/ or significant contact) PROC8a: Transfer of substance or preparation (charging/ discharging) from/ to vessels/ large containers at non-dedicated facilities PROC8b: Transfer of substance or preparation (charging/ discharging) from/ to vessels/ large containers at dedicated facilities PROC9: Transfer of substance or preparation into small containers (dedicated filling line, including weighing) PROC10: Roller application or brushing PROC11: Non industrial spraying PROC13: Treatment of articles by dipping and pouring PROC14: Production of preparations or articles by tabletting, compression, extrusion, pelletisation PROC15: Use as laboratory reagent PROC17: Lubrication at high energy conditions and in partly open process PROC19: Hand-mixing with intimate contact and only PPE available PROC20: Heat and pressure transfer fluids in dispersive, professional use but closed systems PROC21: Low energy manipulation of substances bound in materials and/ or articles PROC22: Manufacturing and processing of minerals and/or metals at substantially elevated temperature PROC25: Other hot work operation with metals PROC26: Handling of solid inorganic substances at ambient temperature ERC2: Formulation of preparations ERC3: Formulation in materials ERC4: Industrial use of processing aids in processes and products, not becoming part of articles ERC5: Industrial use resulting in inclusion into or onto a matrix ERC6a: Industrial use resulting in manufacture of another substance (use of intermediates) ERC6b: Industrial use of reactive processing aids ERC6d: Industrial use of process regulators for polymerisation processes in production of resins, rubbers, polymers ERC8a: Wide dispersive indoor use of processing aids in open systems ERC8b: Wide dispersive indoor use of reactive substances in open systems ERC8c: Wide dispersive indoor use resulting in inclusion into or onto a matrix ERC8d: Wide dispersive outdoor use of processing aids in open systems ERC8f: Wide dispersive outdoor use resulting in inclusion into or onto a matrix ERC9a: Wide dispersive indoor use of substances in closed systems ERC9b: Wide dispersive outdoor use of substances in closed systems ERC10a: Wide dispersive outdoor use of long-life articles and materials with low release ERC11a: Wide dispersive indoor use of long-life articles and materials with low release 2.1 Contributing scenario controlling environmental exposure for: ERC2, ERC3, ERC4, ERC5, ERC6a, ERC6b, ERC6d, ERC8a, ERC8b, ERC8c, ERC8d, ERC8f, ERC9a, ERC9b, ERC10a, R50163 / Version /32 EN

26 ERC11a Frequency and duration of use Environment factors not influenced by risk management Other given operational conditions affecting environmental exposure Technical conditions and measures at process level to prevent release Technical onsite conditions and measures to reduce or limit discharges, air emissions and releases to soil Organizational measures to prevent/limit release from the site Conditions and measures related to sewage treatment plant Conditions and measures related to external treatment of waste for disposal Conditions and measures related to external recovery of waste Single exposure Continuous exposure Flow rate of receiving surface water Factor: Air Factor: Soil Intermittent release < 12 days/year 18,000 m3/d (Dilution of 10 n/a) 0.4 % 0 % 2 % (only ERC2, ERC6a, ERC8b, ERC8e) 0.2 % (only ERC3) 100 % (only ERC4, ERC8a, ERC8d) 50 % (only ERC5) 5 % (only ERC6b, ERC9b) % (only ERC6d) 1 % (only ERC8c, ERC8f) 0 % (only ERC9a) 0.16 % (only ERC10a) 0.05 % (only ERC11a) Indoor use Either wet or dry process Process may involve high temperature Air Bag filters (Efficiency: 99 %) Water Chemical precipitation, Sedimentation, Filtration (Degradation effectiveness: %) Air Wet scrubbers (Efficiency: %) Air Type of Sewage Treatment Plant Flow rate of sewage treatment plant effluent Waste treatment Disposal methods Recovery Methods This may create a general negative pressure in the building Municipal sewage treatment plant 2,000 m3/d Users of the substance and the substance compounds have to minimize substance containing waste, promote recycling routes and, for the remaining, dispose the waste stream according the Waste regulation, All residues containing the substance are recycled Dispose of as hazardous waste in compliance with local and national regulations. Users of the substance and the substance compounds have to favour the recycling channels of the end-of-life products R50163 / Version /32 EN

27 2.2 Contributing scenario controlling environmental exposure for: ERC8a, ERC8b, ERC8c, ERC8d, ERC8e, ERC8f, ERC9a, ERC9b spercs for metal and metal compounds for formulation have been used to evaluate the exposure for the environment, The ERC are provided only for reference. Environment factors not influenced by risk management Other given operational conditions affecting environmental exposure Flow rate of receiving surface water Factor: Air Factor: Soil 18,000 m3/d (Dilution of 10 n/a) % 2.3 Contributing scenario controlling environmental exposure for: ERC8a, ERC8b, ERC8c, ERC8d, ERC8e, ERC8f, ERC9a, ERC9b R50163 / Version /32 EN 0.5 % spercs for metal and metal compounds have been used to evaluate the exposure for the environment, The ERC are provided only for reference. Environment factors not influenced by risk management Other given operational conditions affecting environmental exposure Flow rate of receiving surface water Factor: Air Factor: Soil 0 % 18,000 m3/d (Dilution of 10 n/a) % 0.1 % 2.4 Contributing scenario controlling worker exposure for: PROC1, PROC2, PROC3, PROC4, PROC5, PROC8a, PROC8b, PROC9, PROC10, PROC11, PROC13, PROC14, PROC15, PROC17, PROC19, PROC20, PROC21, PROC22, PROC25, PROC26 Product characteristics Frequency and duration of use Human factors not influenced by risk management Technical conditions and measures to control dispersion from source towards the worker Organisational measures to prevent /limit releases, dispersion Physical Form (at time of use) 0.6 % Covers daily exposures up to 8 hours Exposed skin area Respiration volume under conditions of use solid, or, liquid, Aqueous solution Exposed skin surface 240 cm² 10 m3/day Body weight 70 kg Local exhaust ventilation on furnaces and other work areas with potential dust generation, dust capturing and removal techniques Containment of liquid volumes in sumps to collect/prevent accidental spillage Closed process and closed circuits where relevant and possible Provide local exhaust ventilation (LEV).(Solid, high dustiness PROC2, PROC3, PROC4, PROC5, PROC8a, PROC8b, PROC9, PROC14, PROC15, PROC22, PROC25, PROC26) Provide local exhaust ventilation (LEV).(Solid, medium dustiness PROC2, PROC3, PROC4, PROC5, PROC8a, PROC8b, PROC9, PROC14, PROC22, PROC25, PROC26) Provide local exhaust ventilation (LEV).(Solid, low dustiness PROC4, PROC5, PROC14, PROC22, PROC25, PROC26) Provide local exhaust ventilation (LEV).(Liquid preparations PROC11) Provide local exhaust ventilation (LEV).(Liquid preparations PROC17) General occupational hygiene measures are required to ensure a safe handling of the substance

28 and exposure Conditions and measures related to personal protection, hygiene and health evaluation 3. Exposure estimation and reference to its source Regular cleaning of equipment and work area Worker training in process operations Wear respiratory protection. Wear air purifying mask APF4(Solid, high dustiness PROC8b, PROC9, PROC22) Wear respiratory protection. Wear air purifying mask APF10(Liquid preparations PROC11) Wear respiratory protection. Wear air purifying half mask APF10(Solid, high dustiness PROC4, PROC5, PROC8a, PROC14, PROC26) Avoid carrying out operation for more than 4 hours.(solid, high dustiness PROC11, PROC19) Wear respiratory protection. With respiratory mask APF 40(Solid, high dustiness PROC19) Wear respiratory protection. Wear air purifying mask APF10(Solid, medium dustiness PROC19) Wear respiratory protection. Wear air purifying mask APF4(Solid, medium dustiness PROC22, PROC26) Wear respiratory protection. Wear air purifying mask APF4(Solid, low dustiness PROC22) Environment EUSES Contributing Scenario Specific conditions Compartment Value Level of Exposure Fresh water PEC mg/L Fresh water sediment R50163 / Version /32 EN PEC 0mg/kg dry weight (d.w.) Marine water PEC mg/L mg/kg dry Marine sediment PEC weight (d.w.) mg/kg dry Soil PEC weight (d.w.) --- Relevant for section 2.2: spercs for metal and metal compounds for formulation have been used to evaluate the exposure for the environment. Relevant for section 2.3: spercs for metal and metal compounds have been used to evaluate the exposure for the environment. Workers PROC2, PROC3, PROC4, PROC5, PROC8a, PROC8b, PROC9, PROC10, PROC11, PROC13, PROC14, PROC15, PROC17, PROC19, PROC20, PROC21, PROC22, PROC25, PROC26: MEASE Contributing Scenario Specific conditions Exposure routes Level of Exposure RCR PROC2 Solid, high dustiness PROC2 Solid, medium dustiness PROC2 Solid, low dustiness PROC2 liquid PROC3 Solid, high dustiness PROC3 Solid, medium dustiness, Solid, low dustiness PROC3 liquid PROC4 Solid, medium dustiness RCR

29 PROC4 Solid, low dustiness PROC4 liquid PROC5 Solid, medium dustiness PROC5 Solid, low dustiness PROC5 liquid PROC8a Solid, medium dustiness, Solid, low dustiness PROC8a liquid PROC8b Solid, high dustiness PROC8b Solid, medium dustiness PROC8b Solid, low dustiness PROC8b liquid PROC9 Solid, medium dustiness, Solid, low dustiness PROC9 liquid PROC10 liquid PROC11 liquid PROC13 liquid PROC14 Solid, medium dustiness PROC14 Solid, low dustiness PROC14 liquid PROC15 Solid, medium dustiness PROC15 Solid, low dustiness PROC15 liquid PROC17 liquid PROC19 Solid, high dustiness PROC19 Solid, medium dustiness, Solid, low dustiness PROC19 liquid PROC20 liquid PROC21 Solid, low dustiness PROC22 PROC25 PROC26 Solid, medium dustiness, Solid, low dustiness Solid, medium dustiness, Solid, low dustiness Solid, medium dustiness PROC26 Solid, low dustiness Guidance to Downstream User to evaluate whether he works inside the boundaries set by the Exposure Scenario Guidance is based on assumed operating conditions which may not be applicable to all sites; thus, scaling may be necessary to define appropriate site-specific risk management measures. R50163 / Version /32 EN

30 Where other risk management measures/operational conditions are adopted, then users should ensure that risks are managed to at least equivalent levels. Environment For scaling see: tool Health R50163 / Version /32 EN

31 1. Short title of Exposure Scenario 3: Consumer use Main User Groups Chemical product category Environmental Release Categories SU 21: Consumer uses: Private households (= general public = consumers) PC1: Adhesives, sealants PC9a: Coatings and paints, thinners, paint removers PC9b: Fillers, putties, plasters, modelling clay PC12: Fertilizers PC24: Lubricants, greases, release products PC30: Photo-chemicals PC31: Polishes and wax blends PC35: Washing and cleaning products ERC8a: Wide dispersive indoor use of processing aids in open systems ERC8b: Wide dispersive indoor use of reactive substances in open systems ERC8c: Wide dispersive indoor use resulting in inclusion into or onto a matrix ERC8d: Wide dispersive outdoor use of processing aids in open systems ERC8f: Wide dispersive outdoor use resulting in inclusion into or onto a matrix ERC9a: Wide dispersive indoor use of substances in closed systems ERC9b: Wide dispersive outdoor use of substances in closed systems ERC10a: Wide dispersive outdoor use of long-life articles and materials with low release ERC10b: Wide dispersive outdoor use of long-life articles and materials with high or intended release (including abrasive processing) ERC11a: Wide dispersive indoor use of long-life articles and materials with low release 2.1 Contributing scenario controlling environmental exposure for: ERC8a, ERC8b, ERC8c, ERC8d, ERC8f, ERC9a, ERC9b, ERC10a, ERC10b, ERC11a Frequency and duration of use Continuous exposure 365 days/year, Continuous release Environment factors not influenced by risk management Other given operational conditions affecting environmental exposure Conditions and measures related to sewage treatment plant Conditions and measures related to external treatment of waste for disposal Flow rate of receiving surface water Indoor or outdoor use Type of Sewage Treatment Plant Flow rate of sewage treatment plant effluent Waste treatment 18,000 m3/d 100 % (only ERC8a, ERC8d, ERC10b, ERC11b) 2 % (only ERC8b, ERC8e) 1 % (only ERC8c, ERC8f) 5 % (only ERC9b) 0.16 % (only ERC10a) 0.05 % (only ERC11a) Municipal sewage treatment plant 2,000 m3/d External treatment and disposal of waste should comply with applicable local and/or national regulations. 2.2 Contributing scenario controlling consumer exposure for: PC1, PC9a, PC9b, PC12, PC15, PC24, PC30, PC31, PC35 Product characteristics Physical Form (at time of use) liquid, slurry, or, Solid, low dustiness R50163 / Version /32 EN