: KD-81 Pine Deodorant-Cleaner

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1 SECTION 1: Identification 1.1. Identification Product form Product name KD-81 Pine Deodorant-Cleaner Date of issue: 02/09/2018 Revision date: 04/15/2015 : Mixture Product code : Recommended use and restrictions on use Use of the substance/mixture 1.3. Supplier Kandel And Son, Inc. 155 Dupont Street Plainview, NY T (516) Emergency telephone number : KD-81 Pine Deodorant-Cleaner : Deodorant Emergency number : (800) SECTION 2: Hazard(s) identification 2.1. Classification of the substance or mixture GHS-US classification Not classified 2.2. GHS Label elements, including precautionary statements GHS-US labeling No labeling applicable 2.3. Other hazards which do not result in classification 2.4. Unknown acute toxicity (GHS US) Not applicable SECTION 3: Composition/Information on ingredients 3.1. Substances Not applicable 3.2. Mixtures Name Product identifier % GHS-US classification Sodium Xylene Sulfonate (CAS No) Skin Irrit. 2, H315 Eye Irrit. 2A, H319 STOT SE 3, H335 Full text of hazard classes and H-statements : see section 16 SECTION 4: First-aid measures 4.1. Description of first aid measures First-aid measures general First-aid measures after inhalation First-aid measures after skin contact First-aid measures after eye contact First-aid measures after ingestion : Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible). : Allow victim to breathe fresh air. Allow the victim to rest. : Remove affected clothing and wash all exposed skin area with mild soap and water, followed by warm water rinse. : Rinse immediately with plenty of water. Obtain medical attention if pain, blinking or redness persists. : Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention Most important symptoms and effects (acute and delayed) Potential Adverse human health effects and symptoms Symptoms/effects : Based on available data, the classification criteria are not met. : Not expected to present a significant hazard under anticipated conditions of normal use. 02/09/2018 EN (English US) Page 1

2 4.3. Immediate medical attention and special treatment, if necessary SECTION 5: Fire-fighting measures 5.1. Suitable (and unsuitable) extinguishing media Suitable extinguishing media Unsuitable extinguishing media 5.2. Specific hazards arising from the chemical : Foam. Dry powder. Carbon dioxide. Water spray. Sand. : Do not use a heavy water stream Special protective equipment and precautions for fire-fighters Firefighting instructions Protection during firefighting SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Prevent fire-fighting water from entering environment. : Do not enter fire area without proper protective equipment, including respiratory protection For non-emergency personnel Emergency procedures For emergency responders Protective equipment Emergency procedures : Evacuate unnecessary personnel. : Equip cleanup crew with proper protection. : Ventilate area Environmental precautions Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters Methods and material for containment and cleaning up Methods for cleaning up 6.4. Reference to other sections See Heading 8. Exposure controls and personal protection. : Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Collect spillage. Store away from other materials. SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling : Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Provide good ventilation in process area to prevent formation of vapor Conditions for safe storage, including any incompatibilities Storage conditions Incompatible products Incompatible materials : Keep only in the original container in a cool, well ventilated place away from heat, hot surfaces, sparks, open flame and other ignition sources. No smoking. Keep container closed when not in use. : Strong bases. Strong acids. SECTION 8: Exposure controls/personal protection 8.1. Control parameters Not applicable : Sources of ignition. Direct sunlight Appropriate engineering controls 8.3. Individual protection measures/personal protective equipment Personal protective equipment: Avoid all unnecessary exposure. 02/09/2018 EN (English US) 2/6

3 Hand protection: Wear protective gloves/eye protection/face protection protective gloves Eye protection: Chemical goggles or safety glasses Respiratory protection: Wear appropriate mask Other information: Do not eat, drink or smoke during use. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state Color Odor Odor threshold : Liquid : Green : Pine ph : 9-10 Melting point Freezing point Boiling point : F Flash point : 200 F Relative evaporation rate (butyl acetate=1) Flammability (solid, gas) Vapor pressure Relative vapor density at 20 C Relative density : 1 Solubility Log Pow Auto-ignition temperature Decomposition temperature Viscosity, kinematic Viscosity, dynamic Explosion limits Explosive properties Oxidizing properties 9.2. Other information SECTION 10: Stability and reactivity Reactivity Chemical stability Stable under normal conditions. Not established Possibility of hazardous reactions Not established Conditions to avoid Direct sunlight. Extremely high or low temperatures Incompatible materials Strong acids. Strong bases. : Non flammable. : Same as water : Soluble in water. 02/09/2018 EN (English US) 3/6

4 10.6. Hazardous decomposition products Fume. Carbon monoxide. Carbon dioxide. SECTION 11: Toxicological information Information on toxicological effects Acute toxicity LD50 oral rat LD50 dermal rabbit Skin corrosion/irritation Serious eye damage/irritation Respiratory or skin sensitization Germ cell mutagenicity Carcinogenicity Reproductive toxicity Specific target organ toxicity single exposure Specific target organ toxicity repeated exposure Aspiration hazard Potential Adverse human health effects and symptoms Symptoms/effects > 7000 mg/kg body weight (OECD 401: Acute Oral Toxicity, Rat, Male/female, Read-across) > 2000 mg/kg body weight (Equivalent or similar to OECD 402, Rabbit, Read-across) ph: 9-10 ph: 9-10 : Based on available data, the classification criteria are not met. : Not expected to present a significant hazard under anticipated conditions of normal use. SECTION 12: Ecological information Toxicity LC50 fish 1 EC50 Daphnia 1 > 1000 mg/l (EPA OTS , 96 h, Oncorhynchus mykiss, Static system, Fresh water, Experimental value) > 1000 mg/l (EPA OTS , 48 h, Daphnia magna, Static system, Fresh water, Experimental value) Persistence and degradability KD-81 Pine Deodorant-Cleaner Persistence and degradability Persistence and degradability Not established. Readily biodegradable in water Bioaccumulative potential KD-81 Pine Deodorant-Cleaner Bioaccumulative potential Log Pow Bioaccumulative potential Not established (Experimental value, EU Method A.8: Partition Coefficient, 20 C) Not bioaccumulative Mobility in soil Surface tension 71 mn/m (20 C, 90 %) Ecology - soil No (test)data on mobility of the substance available Other adverse effects 02/09/2018 EN (English US) 4/6

5 Other information : Avoid release to the environment. SECTION 13: Disposal considerations Disposal methods Product/Packaging disposal recommendations : Dispose in a safe manner in accordance with local/national regulations. Ecology - waste materials : Avoid release to the environment. SECTION 14: Transport information Department of Transportation (DOT) In accordance with DOT Other information : No supplementary information available. TDG Transport by sea Air transport SECTION 15: Regulatory information US Federal regulations Listed on the United States TSCA (Toxic Substances Control Act) inventory International regulations CANADA EU-Regulations National regulations US State regulations SECTION 16: Other information Revision date : 04/15/2015 Other information : None. Full text of H-phrases: H315 H319 H335 HMIS III Rating Health Flammability Physical Personal protection Causes skin irritation Causes serious eye irritation May cause respiratory irritation : 1 Slight Hazard - Irritation or minor reversible injury possible : 0 Minimal Hazard - Materials that will not burn : 0 Minimal Hazard - Materials that are normally stable, even under fire conditions, and will NOT react with water, polymerize, decompose, condense, or self-react. Non-Explosives. : B B - Safety glasses, Gloves SDS US (GHS HazCom 2012) 02/09/2018 EN (English US) 5/6

6 This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product 02/09/2018 EN (English US) 6/6