ES3: Use at industrial site: Coatings, paints, thinners, paint removers*

Transcription

1 ES3: Use at industrial site: Coatings, paints, thinners, paint removers* 1. Title Section Coatings and paints, thinners, paint removers (PC 9a) Environment CS 1: Industrial application of coatings and inks; Water-based scrubbing process Workers CS 2: : Industrial application of coatings and inks; Closed systems; With occasional controlled exposure CS 3: Raw material transfer and/or dispensing with dedicated equipment ERC 5 PROC 2 PROC 8b CS 4: Mixing operations (open systems) PROC 5 CS 5: Loading of application equipment; Manual PROC 8a CS 6: Spraying PROC 7 CS 7: Roller, spreader, flow coating or printing PROC 10 CS 8: Dipping, immersion and pouring PROC 13 CS 9: Force drying (50 100oC) PROC 2 CS 10: Equipment cleaning and maintenance; Manual PROC 8a 2. Conditions of use affecting exposure CS1: Control of environmental exposure: Industrial application of coatings and inks; Water-based scrubbing process (ERC 5) Amount used, frequency and duration of use (or from service life) Daily amount per site <= 0.02 tonnes/day Annual amount per site <= 4.0 tonnes/year Remove sludge regularly from process/cleaning water in reservoir. Equalising tank required; Continuous releases. Conditions and measures related to sewage treatment plant Estimated substance removal from wastewater via municipal sewage treatment 22% Assumed municipal sewage treatment plant flow >= 2000 m3/d Conditions and measures related to treatment of waste (including article waste) Dispose of waste or used sacks/containers according to local regulations. Other conditions affecting environmental exposure Receiving surface water flow >= m3/d CS2: Control of worker exposure: Industrial application of coatings and inks; Closed systems; With occasional controlled exposure (PROC 2) Amount used (or contained in articles) frequency and duration of use/exposure Covers daily exposure up to 8 hours *From ECHA s illustrative example of exposure scenario to be annexed to the safety data sheet

2 Use in closed, continuous process with occasional controlled exposure CS3: Control of worker exposure: Raw material transfer and/or dispensing with dedicated equipment (PROC 8b) Avoid carrying out activities involving exposure for more than 1 hour. CS 4 : Control of worker exposure: Mixing operations (open systems) (PROC 5) Avoid carrying out activities involving exposure for more than 1 hour. Provide a basic standard of general ventilation (1 to 3 air changes per hour). CS 5 : Control of worker exposure: Loading of application equipment; Manual (PROC 8a) Avoid carrying out activities involving exposure for more than 1 hour. CS 6: Control of worker exposure: Spraying (PROC 7)

3 Local exhaust ventilation - efficiency of at least 95.0 % Conditions and measures related to personal protection, hygiene and health evaluation Wear suitable chemical resistant sleeves and gloves. For further specification, refer to section 8 of the SDS. Additional good practice advice. Obligations according to Article 37(4) of REACH do not apply Use suitable eye protection. Wear suitable coveralls to prevent exposure to the skin; Wear protective shoes. Wear respiratory protection. CS 7: Control of worker exposure: Roller, spreader, flow coating or printing (PROC 10) Local exhaust ventilation - efficiency of at least 90.0 % Additional good practice advice. Obligations according to Article 37(4) of REACH do not apply Use suitable eye protection. Wear suitable gloves tested to EN374. CS 8: Control of worker exposure: Dipping, immersion and pouring (PROC 13) Provide a basic standard of general ventilation (1 to 3 air changes per hour). Local exhaust ventilation - efficiency of at least 90.0 %

4 Additional good practice advice. Obligations according to Article 37(4) of REACH do not apply Use suitable eye protection. Wear suitable gloves tested to EN374. CS 9: Control of worker exposure: Force drying (50 100oC) (PROC 2) Provide a basic standard of general ventilation (1 to 3 air changes per hour). Use in closed, continuous process with occasional controlled exposure Assumes process temperature up to 70.0 C CS 10: Control of worker exposure: Equipment cleaning and maintenance; Manual (PROC 8a) Avoid carrying out activities involving exposure for more than 4 hours. Conditions and measures related to personal protection, hygiene and health evaluation Wear suitable gloves tested to EN374; For further specification, refer to section 8 of the SDS.

5 3. Exposure estimation and reference to its source CS1: Environmental release and exposure: Industrial application of coatings and inks; Water-based process (ERC 5) Release route Release rate Release estimation method Water 0.1 kg/day SpERC based xxxx a.v1 Industrial use of coatings and inks (low volatiles) - Process with water involved (low volatiles, medium water solubility) Air 0.2 kg/day SpERC based same as above Soil 0 kg/day SpERC based same as above Protection target Exposure estimate (based on: EUSES 2.1.2) Freshwater mg/l Sediment (freshwater) mg/kg dw Marine water 3.891E-4 mg/l Sediment (marine water) mg/kg dw Sewage treatment plant mg/l Agricultural soil mg/kg dw Man via Environment Inhalation 3.109E-5 mg/m³ < 0.01 Man via Environment Oral mg/kg bw/day < 0.01 CS2: Worker exposure: Industrial application of coatings and inks; Closed systems; With occasional controlled exposure (PROC 2) Dermal, systemic, long-term mg/kg bw/day (TRA Worker v3) Combined routes, systemic, long-term 0.14 CS3: Worker exposure Raw material transfer and/or dispensing with dedicated equipment (PROC 8b) Combined routes, systemic, long-term CS4: Worker exposure: Mixing operations (open systems) (PROC 5) Combined routes, systemic, long-term 0.493

6 CS5: Worker exposure: Loading of application equipment; Manual (PROC 8a) Inhalation, systemic, long-term 5 mg/m³ (TRA Worker v3) Combined routes, systemic, long-term CS6: Worker exposure: Spraying (PROC 7) Inhalation, systemic, long-term 12.5 mg/m³ (TRA Worker v3) Dermal, systemic, long-term mg/kg bw/day (TRA Worker v3) Combined routes, systemic, long-term CS7: Worker exposure Roller, spreader, flow coating or printing (PROC 10) Dermal, systemic, long-term mg/kg bw/day (TRA Worker v3) Combined routes, systemic, long-term CS8: Worker exposure Dipping, immersion and pouring (PROC 13) Combined routes, systemic, long-term CS9: Worker exposure Force drying (50 100oC) (PROC 2) Dermal, systemic, long-term mg/kg bw/day (TRA Worker v3) Combined routes, systemic, long-term 0.14 CS10: Worker exposure Raw material transfer and/or dispensing with dedicated equipment (PROC 8a) Inhalation, systemic, long-term 15 mg/m³ (TRA Worker v3) Dermal, systemic, long-term mg/kg bw/day (TRA Worker v3) Combined routes, systemic, long-term 0.686

7 4. Guidance to DU to evaluate whether he works inside the boundaries set by the ES Scaling method - Workers Exposure estimation tool used: ECETOC TRA v3. Scalable Parameters Workers Exposure duration Maximum concentration Non scalable parameters Other parameters (different from those indicated under scalable parameters) have to be taken (with no change) from the exposure scenario provided. Boundaries of Scaling not to be exceeded are described in Section 3 above. Scaling instructions For scaling instructions please go to the following website: