Version: 1. Hauptstr , Aichstetten, Germany. Tel./Fax.: Tel , Fax

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1 Revised edition: Version: 1 Identification of the Substance/Mixture and of the Company/Undertaking Product Identifier Page 1 Product Name: ORASOL Yellow 4GN Article No.: Relevant identified Uses of the Substance or Mixture and Uses advised against Identified uses: Coloring agent for dye and varnish industry. Coloring agent for industrial purposes Uses advised against: Details of the Supplier of the Safety Data Sheet Company: Address: Kremer Pigmente GmbH & Co. KG Hauptstr , Aichstetten, Germany Tel./Fax.: Tel , Fax Internet: Emergency No. info@kremer-pigmente.de Emergency No.: (Mon-Fri 8:00-17:00) Hazards Identification Classification of the Substance or Mixture Classification according to EC Regulation 1272/2008 H317 Cat.: 1 H319 Cat.: 2 H411 Cat.: 2 Classification according to EC Regulation No. 67/548 or No. 1999/45 Irritating (Xi) R36 Irritating (Xi) R43 Hazardous to the R51 environment (N) R53 Skin sensitization, hazard category 1 Serious eye damage, hazard category 2 Hazardous to the aquatic environment, hazard category 2 May cause an allergic skin reaction. Causes serious eye irritation. Toxic to aquatic life with long lasting effects. Irritating to eyes. May cause sensitization by skin contact. Toxic to aquatic organisms. May cause long-term adverse effects in the aquatic environment. Safety Phrases: Possible Environmental Effects: Label Elements Classification according to EC Regulation 1272/2008 2

2 Hazard designation: Page 2 GHS07 GHS09-1 Signal word: Hazard designation: Safety designation: H317 H319 H411 P260 P272 P273 P280 P302+P352 P337+P313 P501 Warning May cause an allergic skin reaction. Causes serious eye irritation. Toxic to aquatic life with long lasting effects. Do not breathe dust/fume/gas/mist/vapours/spray. Contaminated work clothing should not be allowed out of the workplace. Avoid release to the environment. Wear protective gloves/ clothing/ eye/ face protection. If on skin: Wash with soap and water. If eye irritation persists: Get medical advice/ attention. Dispose of contents/ container according to regional, national and international regulations Hazardous components for labelling: Other Hazards Composition/Information on Ingredients Substance Mixture This product is capable of dust explosion under certain circumstances. Chemical Characterization: Dye, woodstain. C.I. Solvent Yellow 146 Hazardous Ingredients: Amines, C12-14-branched Alkyl-, 4[(5-Cyano-1- ethyl-5,6-dihydro-2-hydroxy-4-methyl-6-oxo-3- pyridinyl)azo]-1,3]benzol disulfonate CAS-Nr: EINECS-Nr: EC-Nr: Additional information: First Aid Measures Description of the First Aid Measures General information: After inhalation: Remove contaminated clothes. Supply fresh air. 3

3 In case of complaints consult a physician. Page 3 After skin contact: After eye contact: Wash with soap and rinse with plenty of water. Remove contaminated clothing. Rinse open eyes with plenty of water for at least 15 minutes After ingestion: Most important Symptoms and Effects, both Acute and Delayed Rinse mouth with water and drink plenty of water. Symptoms: No further information available Effects: No further information available. Indication of any Immediate Medical Attention and special Treatment needed Treatment: Fire-Fighting Measures Extinguishing Media Suitable extinguishing media: Treat symptomatically. Extingishing powder, foam Unsuitable extinguishing media: Special Hazards arising from the Substance or Mixture Carbon dioxide (CO2) Special hazards: Advice for Firefighters Protective equipment: In case of fire: hazardous vapors may be released. Development of fumes/aerosol. Wear self-contained respiratory protective device Further information: Accidential Release Measures Personal Precautions, Protective Equipment and Emergency Procedures Avoid formation of dust: risk of dust explosion. Dispose of fire debris and contaminated extinguishing water in accordance with local regulations Personal precautions: Environmental Precautions Environmental precautions: Avoid formation of dust, wear protective clothing. Keep spills and cleaning runoff out of municipal sewers and open bodies of water. 4

4 6. 3. Methods and Material for Containment and Cleaning Up Page Methods and material: Reference to other Sections Handling and Storage Precautions for Safe Handling Instructions on safe handling: Small spills: Clean up with suitable appliance and dispose adequately. Large spills: Clean up mechanically. Avoid dust formation. Protective clothing, see Section 8. Dispose of contaminated material according to Section 13. Respiratory protection when handling without exhaust system. Avoid contact with eyes, skin and clothing. Avoid formation of dust. Do not inhale dust Hygienic measures: Conditions for Safe Storage, including any Incompatibilities Do not eat or drink during work. Do not smoke. Storage conditions: Requirements for storage areas and containers: Information on fire and explosion protection: Storage class (VCI): Store in tightly sealed containers in a dry and cool room. No special measures necessary. Avoid dust formation. Protect against electrostatic charging. Do not store together with ignitable sources, heat and fire. Dust explosion class 2 (Kst-value bar m/s). 11; Combustible solids Further Information: Specific End Use(s) Further information: Exposure Controls/Personal Protection Parameters to be Controlled Parameters to be controlled (DE): No exposure limits for this product. Parameters to be controlled (EC): Derived No-Effect Level (DNEL): Predicted No-Effect Concentration 5

5 (PNEC): Page Additional Information: Exposure Controls Technical protective measures: Provide adequate ventilation. Personal Protection General protective measures: Respiratory protection: Hand protection: Protective glove material: Eye protection: The usual precautionary measures are to be adhered to when handling chemicals. Keep away from foodstuffs and drinks. Do not eat, drink or smoke during work. Wash hands before breaks and at the end of work. Suitable respiratory protection for lower concentration or shortterm effect: particle filter with medium efficiency for solid and liquid particles (e.g. EN 143 or 149, type P2 or FFP2). Chemical protective gloves (EN 374 (Europe), F739 (US)). The manufacturer s directions for use should be observed because of the great diversity of types. Recommended: Protective index 6, > 480 min. of permeation time accord. EN 374. Nitrile rubber (0.4 mm), chloroprene rubber (0.5 mm), polyvinyl chloride (0.7 mm). Safety glasses with protective shields (EN 166). Body protection: Environmental precautions: Physical and Chemical Properties Information on Basic Physical and Chemical Properties Avoid contamination of sewage system, open water ways and ground water. Form: Color: Odor: Odor threshold: ph-value: yellow odorless 6.5 (Suspension) Melting temperature: ca. 185 C Boiling temperature: Flash point: 6

6 Page 6 Evaporation rate: Flammability (solid, gas): Upper explosion limit: Lower explosion limit: Vapor pressure: not easily flammable no information available no information available Vapor density: Density: Solubility in water: Coefficient of variation (n- Octanol/Water): insoluble Auto-ignition temperature: 310 C Decomposition temperature: > 350 C Viscosity, dynamic: Explosive properties: Product is not explosive. Oxidizing properties: no information available Bulk density: 1110 kg/m3 (20 C) Further Information Solubility in solvents: Viscosity, kinematic Burning class: Solvent content: Solid content: Particle size: Other information: No further information. 10. Stability and Reactivity Reactivity No decomposition if used according to specifications. 7

7 10.2. Chemical Stability Stable if used according to specifications Possibility of Hazardous Reactions Risk of dust explosion Conditions to Avoid Page Conditions to avoid: Thermal decomposition: Imcompatible Materials Hazardous Decomposition Products Further Information Toxicological Information Information on Toxicological Effects Acute Toxicity LD50, oral: LD50, dermal: LC50, inhalation: Primary effects Irritant effect on skin: Irritant effect on eyes: Inhalation: Ingestion: Sensitization: Mutagenicity: Reproductive toxicity: Avoid formation of dust. Avoid ignition sources. Avoid humidity. see section 9 Strong acids, strong bases and strong oxidizing agents. Carbon oxides, nitrogen oxides, chromoxides, toxic fumes/vapors mg/kg (rat) Non irritating (rabbit) Irritating effect (rabbit). No information available No data available. No data available. Cancerogenity: No data available. 8

8 Teratogenicity: Page Specific target organ toxicity (STOT): Additional toxicological information: Ecological Information Aquatic Toxicity Fish toxicity: Daphnia toxicity: Bacteria toxicity: Algae toxicity: Persistency and Degradability Bioaccumulation Moblity Results of PBT- und vpvp Assessment Other Adverse Effects Water hazard class: Behaviour in sewage systems: Further ecological effects: AOX Value: Disposal Considerations Waste Treatment Methods Product: Single exposure: no information available. Repeated exposure: no information available. LC50: 1.6 mg/l (96h, Brachydanio rerio; OECD 203) no information available Very insoluble product and can thus be removed from water mechanically in suitable effluent treatment plants. Not readily biodegradable. Not applicable. 2 (German Regulation) (Assessment by list): hazardous. Treatment and discharge of waste water into biological treatment plant should be carried out according to official national and local regulations. In accordance with current regulations, product may be taken to a waste disposal site or incineration plant, after consultation with site operator and/or with the responsible authority. 9

9 Page 9 European Waste Code (EWC): Uncleaned packaging: Uncontaminated packaging may be recycled. Packaging that may not are to be disposed of in the same manner as the product. Waste Code No.: Transport Information UN Number ADR, IMDG, IATA UN Proper Shipping Name ADR/RID: IMDG/IATA: UMWELTGEFÄHRDENDER STOFF, FEST, N.A.G. (Aminsalz eines Monoazo-Derivates) ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (Aminosalt Monoazo-Derivates) Transport Hazard Classes ADR Class: 9 Hazard no.: 9 Classification code: Tunnel no.: M7 E IMDG Class (sea): 9 Hazard no.: 9 EmS No.: IATA Class: 9 Hazard no.: Packaging Group ADR/RID: IMDG: IATA: Environmental Hazards Special Precautions for User III III III Labelling according ADR/RID: fish and tree Labelling according IMDG: fish and tree Labelled with "P" according 2.10 IMDG: yes none known Transportation in Bulk according to Annex II of MARPOL 73/78 and IBC-Code not evaluated Further Information Regulatory Information Safety, Health and Environmental Regulations/Legislation specific for the Substance or Mixture 10

10 Water hazard class: 2, hazardous for water Page 10 Local regulations on chemical accidents: Employment restrictions: Restriction and prohibition of application: Technical instructions on air quality: Chemical Safety Assessment Further Information Other Information Not applicable. A Chemical Safety Assessment has not yet been carried out for this product. This product should be stored, handled and used in accordance with good hygiene practices and in conformity with any legal regulations. This information contained herein is based on the present state of knowledge and is intended to describe our product from the point of view of safety requirements. It should be therefore not be construed as guaranteeing specific properties.