Sulfamic Acid Reagent

Transcription

1 Safety Data Sheet Sulfamic Acid Reagent 1. PRODUCT AND COMPANY IDENTIFICATION Product Name: Sulfamic Acid Reagent Synonyms/Generic Names: None Product Number: 5600 Product Use: Industrial, Manufacturing or Laboratory use Manufacturer: Columbus Chemical Industries, Inc. N4335 Temkin Rd. Columbus, WI For More Information Call: (Monday-Friday 8:00-4:30) In Case of Emergency Call: CHEMTREC or (24 Hours/Day, 7 Days/Week) 2. HAZARDS IDENTIFICATION OSHA Hazards: Corrosive Target Organs: None Signal Words: Danger Pictograms: GHS Classification: irritation Category 2 Serious eye damage Category 1 Acute aquatic toxicity Category 3 Chronic aquatic toxicity Category 3 GHS Label Elements, including precautionary statements: Hazards Statements: H315 Causes skin irritation. H318 Causes serious eye damage. H412 Harmful to aquatic life with long lasting effects Precautionary Statements: P264 Wash hands thoroughly after handling. P273 Avoid release to the environment. P280 Wear protective gloves/eye protection/face protection. P302+P352 IF ON SKIN: Wash with plenty of water. Revised on 07/21/2016 Page 1 of 5

2 P305+P351+P338 P310 P332+P313 P362+P364 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor/physician. If skin irritation occurs: Get medical advice/attention. Take off contaminated clothing and wash it before reuse. Potential Health Effects Causes eye burns. Inhalation May be harmful if inhaled. Inhalation of dust can cause corrosive action on mucous membranes. May be harmful if absorbed through skin. Causes skin burns. Ingestion May be harmful if swallowed. NFPA Ratings Health 3 Flammability 0 Reactivity 0 Specific hazard N/A HMIS Ratings Health 3 Fire 0 Reactivity 0 Personal. 3. COMPOSITION/INFORMATION ON INGREDIENTS Component Weight % CAS # EINECS# / ELINCS# Formula Molecular Weight Sulfamic Acid > H 3 NO 3 S g/mol 4. FIRST-AID MEASURES Inhalation Ingestion Rinse with plenty of water for at least 15 minutes and seek medical attention immediately. Move casualty to fresh air and keep at rest. If breathing is difficult, give oxygen. If not breathing, give artificial respiration. Get medical attention. Flush with plenty of water for at least 15 minutes while removing contaminated clothing and wash using soap. Get medical attention immediately. Do Not Induce Vomiting! Never give anything by mouth to an unconscious person. If conscious, wash out mouth with water. Get medical attention immediately. 5. FIREFIGHTING MEASURES Suitable (and unsuitable) extinguishing media Special protective equipment and precautions for firefighters Specific hazards arising from the chemical Product is not flammable. Use appropriate media for adjacent fire. Cool containers with water. Wear self-contained, approved breathing apparatus and full protective clothing, including eye protection and boots. Emits toxic fumes (sulfur oxides, nitrogen oxides) under fire conditions. See also Stability and Reactivity section. 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Environmental precautions See section 8 for recommendations on the use of personal protective equipment. Do not let product enter drains. Any release to the environment may be Revised on 07/21/2016 Page 2 of 5

3 Methods and materials for containment and cleaning up subject to federal/national or local reporting requirements. Pick up and arrange disposal without creating dust. Sweep up and place in suitable, closed containers for disposal. Clean surfaces thoroughly with water to remove residual contamination. Dispose of all waste and cleanup materials in accordance with regulations. 7. HANDLING AND STORAGE Precautions for safe handling See section 8 for recommendations on the use of personal protective equipment. Use with adequate ventilation. Wash thoroughly after using. Keep container closed when not in use. Conditions for safe storage, including any incompatibilities Store in a cool, dry, well ventilated area. Keep away from incompatible materials (see section 10 for incompatibilities). 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Occupational exposure controls: Contains no substances with occupational exposure limit values. Personal Protection Wear chemical safety glasses with a face shield for splash protection. Inhalation Provide local exhaust, preferably mechanical. If exposure levels are excessive, use an approved respirator. Wear neoprene or rubber gloves, apron and other protective clothing appropriate to the risk of exposure. Other Other Recommendations Provide eyewash stations, quick-drench showers and washing facilities accessible to areas of use and handling. Have supplies and equipment for neutralization and running water available. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance (physical state, color, etc.) Odor Odor threshold ph Melting point/freezing point Initial boiling point and boiling range Flash point Evaporation rate Flammability (solid, gas) Upper/lower flammability or explosive limit Vapor pressure Vapor density Relative density Solubility (ies) Partition coefficient: n-octanol/water Auto-ignition temperature Decomposition temperature Fine, white crystals Acidic 1.5 at 10g/L C ( F) Completely soluble in water Revised on 07/21/2016 Page 3 of 5

4 10. STABILITY AND REACTIVITY Chemical Stability Possibility of Hazardous Reactions Conditions to Avoid Incompatible Materials Hazardous Decomposition Products Stable Will not occur. Uncontrolled addition of water. Strong oxidizers and strong bases. Nitrogen oxides, sulfur oxides. 11. TOXICOLOGICAL INFORMATION Acute Toxicity Respiratory Ingestion Carcinogenicity IARC ACGIH NTP OSHA LD50 Oral - rat - 3,160 mg/kg LD50 Oral - mouse - 1,312 mg/kg LD50 Oral - guinea pig - 1,050 mg/kg as probable, possible or confirmed human carcinogen by IARC. as a carcinogen or potential carcinogen by ACGIH. as a known or anticipated carcinogen by NTP. as a carcinogen or potential carcinogen by OSHA. Signs & Symptoms of Exposure Burning, itching, redness, inflammation and/or swelling of exposed tissues. Harmful if absorbed through skin. Eye burns, watering eyes. Respiratory Burning, choking, coughing, wheezing, laryngitis, shortness of breath, headache or nausea. Ingestion Burning, choking, nausea, vomiting and severe pain. Chronic Toxicity Teratogenicity Mutagenicity Embryotoxicity Specific Target Organ Toxicity Reproductive Toxicity Respiratory/ Sensitization 12. ECOLOGICAL INFORMATION Ecotoxicity Aquatic Vertebrate Aquatic Invertebrate Terrestrial LC50 - Pimephales promelas (fathead minnow) mg/l - 96 h Revised on 07/21/2016 Page 4 of 5

5 Persistence and Degradability Bioaccumulative Potential Mobility in Soil PBT and vpvb Assessment Other Adverse Effects 13. DISPOSAL CONSIDERATIONS Waste Product or Residues Product Containers Users should review their operations in terms of the applicable federal/national or local regulations and consult with appropriate regulatory agencies if necessary before disposing of waste product or residue. Users should review their operations in terms of the applicable federal/national or local regulations and consult with appropriate regulatory agencies if necessary before disposing of waste product container. The information offered in section 13 is for the product as shipped. Use and/or alterations to the product may significantly change the characteristics of the material and alter the waste classification and proper disposal methods. 14. TRANSPORT INFORMATION US DOT TDG IMDG Marine Pollutant IATA/ICAO UN2967, Sulfamic acid, 8, pg III UN2967, SULFMAIC ACID, 8, pg III UN2967, SULFMAIC ACID, 8, pg III No UN2967, Sulfamic acid, 8, pg III 15. REGULATORY INFORMATION TSCA Inventory Status DSCL (EEC) California Proposition 65 SARA 302 SARA 304 SARA 311 SARA 312 SARA 313 WHMIS Canada All ingredients are listed on the TSCA inventory. All ingredients are listed n the DSCL inventory. Acute Health Hazard Acute Health Hazard Class E: Corrosive material. Revised on 07/21/2016 Page 5 of 5

6 16. OTHER INFORMATION Revision Date Revision Revision Revision 3 07/21/2016 Disclaimer: Columbus Chemical Industries, Inc. ( Columbus ) believes that the information herein is factual but is not intended to be all inclusive. The information relates only to the specific material designated and does not relate to its use in combination with other materials or its use as to any particular process. Because safety standards and regulations are subject to change and because Columbus has no continuing control over the material, those handling, storing or using the material should satisfy themselves that they have current information regarding the particular way the material is handled, stored or used and that the same is done in accordance with federal, state and local law. COLUMBUS MAKES NO WARRANTY, EXPRESS OR IMPLIED, INCLUDING (WITHOUT LIMITATION) WARRANTIES WITH RESPECT TO THE COMPLETENESS OR CONTINUING ACCURACY OF THE INFORMATION CONTAINED HEREIN OR WITH RESPECT TO FITNESS FOR ANY PARTICULAR USE. Revised on 07/21/2016 Page 6 of 5