COSMETIC PRODUCT MATERIAL SAFETY DATA SHEET (MSDS)

Transcription

1 1. PRODUCT AND COMPANY IDENTIFICATION: PRODUCT NAME: KERATIN SHOT SERUM 3 BRAND NAME: PRODUCT TYPE: COMPANY: SALERM COSMETICS TREATMENT Salerm Cosmetica Profesional, S.A. Plz. Victor Martinez s/n P.I.Els Cantallops Lliça de Vall Barcelona Tel: Fax: COMPOSITION/INGREDIENT INFORMATION: CAS Nº % WEIGHT COMPONENT NAME SYMBOL R/S PHRASES MAX 95% Hexametildisloxano HMDS F R10 S2 S16 S24 The above mentioned components are hazardous due to their flammability in accordance with the definition in 29 CFR HAZARDS IDENTIFICATION: Potentially acute health effects: Eyes: Direct contact may cause mild eye irritation. Skin: Should not cause significant irritation after one short exposure. Inhalation: Mild irritation of respiratory tract. Overexposure to vapour may cause drowsiness. Ingestion: Ingestion of large quantities may cause drowsiness. Effects of repeated or prolonged exposure: Skin: Repeated or prolonged exposure may cause loss of oils and lead to dry skin, which may result in irritation or dermatitis. Inhalation: Information not available. Ingestion: Repeated ingestion or ingestion of large quantities can cause internal damage. Exposure signs and symptoms: No information available Page 1 of 6

2 Aggravation of pre-existing conditions: No information available. 4. FIRST AID MEASURES: Eye contact: Skin contact: Inhalation: Ingestion: Wash eyes immediately with plenty of water for 15 minutes. Remove from skin and wash with soap and water or clean water. Obtain medical attention if irritation continues, or if other conditions arise. Move into the open air. If symptoms persist seek medical attention. Get medical attention immediately. Notes for medical staff: Treat according to specific exposure conditions. 5. FIRE FIGHTING MEASURES: FLASH POINT: 26.1 ºF / -3.3 º C (Closed cup Pensky-Martens) AUTO IGNITION TEMPERATURE: ºF / 352º C FLAMMABLE LIMITS IN AIR: Lower limit: 1.50 % Upper limit: % SUITABLE EXTINGUISHING MEDIA: In the event of large fires, use AFFF foam compatible with alcohol or atomized water (mist). To combat small fires use AFFF foam compatible with alcohol, CO₂ or atomized water (mist). Water can be used to cool containers exposed to fire. PROTECTON OF FIREFIGHTERS: Self-contained breathing apparatus and protective clothing must be used when dealing with fires involving chemical products. Determine the need to evacuate or isolate the area in accordance with local emergency criteria. SPECIFIC RISKS: Vapours are heavier than air and may move toward an ignition source and become ignited. Static electricity can build up and ignite the vapours. Prevent a possible fire risk by grounding or purging with inert gas. The fire is more intense than expected. 6. ACCIDENTAL RELEASE MEASURES: CLEAN UP METHODS: Remove any possible ignition sources. Determine, according to emergency planning in your area, if the area should be evacuated or isolated. Follow all the instructions in sections 5 and 8 regarding personal protection equipment. In the case of large spills, use dikes or other contention methods to avoid further spreading Page 2 of 6

3 of the material. If it s possible to pump the material accumulated in the dike, store the recovered material in an appropriate container. Clean residual spill materials with an appropriate absorbent substance. Clean the area appropriately, as some silicone based materials, even if in small quantities, may present a slip risk. Final cleaning may require the use of steam, solvents or detergents. Dispose of the saturated absorbent material, or cleaning materials appropriately, as they may heat up spontaneously. Local, regional and state and laws and regulations should be checked before the disposal of the material. The same applies to materials and equipment used in the clean up and destruction process. It s necessary to determine which laws and regulations must be applied to the above mentioned materials. Sections 13 and 15 of the MDMS contain information with regards to regional and state requirements. Note: See Section 8 for Personal Protection in the case of spills. After cleaning eliminate traces with water. 7. HANDLING AND STORAGE: Use with adequate ventilation. Avoid contact with eyes. Avoid contact with skin. Avoid breathing vapours. Keep containers tightly closed. Do not ingest. Static electricity can build up and ignite the vapours. Prevent a possible fire risk by grounding or purging with inert gas. Keep containers away from heat, sparks and flame. 8. EXPOSURE CONTROLS AND PERSONAL PROTECTION Exposure limit control: CAS Nº COMPONENT NAME Exposure limit Hexametildisloxano HMDS CPT 200 ppm Safety and hygiene protective measures: When using do not smoke, eat or drink. Wash hands before breaks and immediately after finishing work. Exposure levels are not exceeded in normal working conditions. 9. PHYSICAL AND CHEMICAL PROPERTIES: Appearance: Colour: Smell: ph: Density: Viscosity (50/1) Punto de inflamación Clear liquid Yellow Characteristic NA 0.77+/-0.01gr/ml 15+/-5CPS -3,3 C (Pensky-Martens Closed Cup) Page 3 of 6

4 10. CHEMICAL STABILITY AND REACTIVITY INFORMATION: Stability: Stable. Hazardous Polymerization: Hazardous polymerization will not occur under normal conditions. Conditions to avoid: None. Incompatibility with other materials: Strong oxidizing agents. 11. TOXICOLOGICAL INFORMATION: TOXICITY CAS Nº COMPONENT NAME Exposure limit Hexametildisiloxano HMDS CL50/oral/rat => 87mg / l (calculated) Toxicological component data (information provided by product supplier) The lack of relevant findings from studies conducted on human subjects permits the use of HMDS for approved uses. Special component risk information None available. 12. ECOLOGICAL INFORMATION: ENVIRONMENTAL FATE Air: Volatile siloxanes with low molecular weight in air decompose by reaction with hydroxyl radicals, which is the principal decomposition process for the majority of chemical compounds present in the atmosphere. Water: Volatile siloxanes with low molecular weight have very low hydrosolubility and evaporate into the air. Earth: Volatile siloxanes with low molecular weight in the ground are eliminated through various simultaneously occurring processes including volatilization, hydrolysis and catalysing decomposition with clay. ENVIRONMENTAL TOXICITY Aquatic toxicity: This product is volatile and has a short half-life in water; it therefore presents no danger to aquatic life. Terrestrial toxicity: As a result of its volatility, it s unlikely to be found in earth. Bioaccumulation: Volatile siloxanes with low molecular weight become bioconcentrated in fish exposed Page 4 of 6

5 to the material under controlled laboratory conditions, which do not represent natural atmospheric conditions. FATE AND EFFECTS IN RESIDUAL WATER TREATMENT PLANTS Volatile siloxanes with low molecular weight are effectively eliminated (>90%) during residual water treatment with quantities approximately equivalent transferred into the atmosphere and mud. Volatile siloxanes with low molecular weight in treated residual water will be limited to particulate matter, due to its very low hydrosolubility. ECOTOXICITY CLASSIFICATION CRITERIA Hazard parameters (CL50 oe CE50) High Medium Low Acute aquatic toxicity (mg/l) <=1 >1 and <=100 >100 Acute terrestrial toxicity <=100 >100 and <=2000 >2000 This table is adapted from the Environmental Toxicology and Risk Assessment, ASTM STP 1179, p34, This table can be used to classify ecotoxicity of the product when detailed in the above ecological information section. Please read carefully all the information contained in the section on environmental hazards. 13. DISPOSAL CONSIDERATIONS: Dispose of in accordance with Local Authority requirements. Do not release into water or drainage systems or store in direct contact with the environment. 14. TRANSPORT INFORMATION: GENERAL: The derogation of LIMITED QUANTITIES is applied to volumes of less than 1Lt. TRANSPORT LABEL: Terrestrial transport (ADR/RID): Basic transport requirements: DOT shipping name: Flammable. class: 3 No. ONU: UN 1993 Additional information: Packaging group: II ( inf. 1L) Page 5 of 6

6 Labelling: 3 Maritime transport (IMDG) No. ONU : UN 1993 Proper Shipping Name : FLAMMABLE LIQUID, N.O.S.(Hexamethyldisiloxane) Class : 3 Packaging group : II EmS : F-E S-E Marine pollutant : Hexamethyldisiloxane Labelling : flammable liquid Air transport (IATA) No. ONU : UN 1993 Proper Shipping Name : Flammable liquid, n.o.s.(hexamethyldisiloxane) Class : 3 Packaging group : II Labeling : Flammable Liquid 15. REGULATORY INFORMATION: In accordance with cosmetic product regulation RD1599/1997 of the 17 th of October, this product is exempt from compliance with regulation 88/379/CEE which has been transposed by Spanish legislation RD1078/ OTHER INFORMATION: This security information sheet is for information only. No legal obligation to deliver a copy of this document to the customer exists. Page 6 of 6