Version: 5. Hauptstr , Aichstetten, Germany. Tel./Fax.: Tel , Fax

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1 Revised edition: Version: 5 Identification of the Substance/Mixture and of the Company/Undertaking Product Identifier Page 1 Product Name: Iron(II) Sulphate Article No.: Relevant identified Uses of the Substance or Mixture and Uses advised against Identified uses: Precipitating agent and fluocculent Waste water treatment Water treatment. Chromate reduction in cement For the purpose of land rehabilitation Combat of chlorosis Production of pigments Electroplating additive Uses advised against: Details of the Supplier of the Safety Data Sheet (Producer/Importer) Company: Address: Kremer Pigmente GmbH & Co. KG Hauptstr , Aichstetten, Germany Tel./Fax.: Tel , Fax Internet: info@kremer-pigmente.de Importer: -- Emergency No. Emergency No.: (Mon-Fri 8:00-17:00) Hazards Identification Classification of the Substance or Mixture Classification according to Regulation (EC) No. 1272/2008 (CLP/GHS) H302 Cat.: 4 H315 Cat.: 2 H319 Cat.: 2 Classification according to Directive No. 67/548/EC or No. 1999/45/EC Harmful (Xn) R22 Irritating (Xi) R36 Irritating (Xi) R38 Acute toxicity (oral), hazard category 4 Skin irritation, hazard category 2 Eye irritation, hazard category 2 Harmful if swallowed. Causes skin irritation. Causes serious eye irritation. Harmful if swallowed. Irritating to eyes. Irritating to skin. Safety Phrases: Possible Environmental Effects: 2

2 2. 2. Label Elements Page 2 Classification according to Regulation (EC) No. 1272/2008 (CLP/GHS) Hazard designation: GHS07-1 Signal word: Hazard designation: Safety designation: H302 H315 H319 P280 P301+P312 P302+P352 P305+P351+P338 P332+P313 P337+P313 Warning Harmful if swallowed. Causes skin irritation. Causes serious eye irritation. Wear protective gloves/ clothing/ eye/ face protection. If swallowed: Call a poison center or physician if you feel unwell. If on skin: Wash with soap and water. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses and continue rinsing. If skin irritation occurs: Get medical attention. If eye irritation persists: Get medical advice/ attention Hazardous components for labelling: Iron(II)-sulfate heptahydrate Other Hazards Composition/Information on Ingredients Substance Mixture Chemical Characterization: Information on Components / Hazardous Ingredients: Iron(II) sulfate heptahydrate (Xn,Xi; R22-36/38; H ); REACH Reg. No xxxx CAS-Nr: EINECS-Nr: EC-Nr: Additional information: First Aid Measures Description of the First Aid Measures General information: After inhalation: Seek medical attention in case of complaints. Supply fresh air. After skin contact: 3

3 Page 3 Remove contaminated clothing immediately. Wash off immediately with plenty of water and soap. After eye contact: Rinse open eye for several minutes under running water. Should irritation continue, seek medical advice After ingestion: Most important Symptoms and Effects, both Acute and Delayed Immediately get medical help. Rinse mouth with water and drink plenty of water. Symptoms: No further information available Effects: Indication of any Immediate Medical Attention and special Treatment needed Treatment: Fire-Fighting Measures Extinguishing Media Suitable extinguishing media: No further information available. Product itself does not burn. Use extinguishing media for surrounding fire Unsuitable extinguishing media: Special Hazards arising from the Substance or Mixture Special hazards: Advice for Firefighters Protective equipment: In case of fire: formation of sulfur dioxide. Wear self-contained respiratory protective device and full protective gear Further information: Accidential Release Measures Personal Precautions, Protective Equipment and Emergency Procedures Contaminated extinguishing water and debris should be disposed of according to local regulations Personal precautions: Environmental Precautions Wear appropriate protective equipment. Keep spectators away. Avoid contact with eyes and skin. Avoid formation of dust. Environmental precautions: Prevent contamination of soils, drains and surface water. Contact local authorities if product pollutes soil or vegetation. 4

4 Page Methods and Material for Containment and Cleaning Up Methods and material: Reference to other Sections Handling and Storage Precautions for Safe Handling Instructions on safe handling: Hygienic measures: Clean up mechanically. Transfer liquids and solid diking material to separate suitable containers for recovery or disposal. Dispopse of contaminated material as waste according to section 13. Protective clothing, see Section 8. Dispose of contaminated material according to Section 13. No special measures necessary if properly handled. No further measures, see Section Conditions for Safe Storage, including any Incompatibilities Storage conditions: Requirements for storage areas and containers: Information on fire and explosion protection: Storage class (VCI): Store in tightly sealed containers in a cool and well ventilated location. Protect against heat and direct sunlight. Do not store above 30 C. Suitable container material: steel, plastic. Product is not combustible. 13; Non combustible solids Further Information: Specific End Use(s) Further information: See Section 1.2.; no other uses provided Exposure Controls/Personal Protection Parameters to be Controlled Parameters to be controlled (DE): none known Parameters to be controlled: Derived No-Effect Level (DNEL): 99.6 mg/kg bw/d (consumer, swallowing, short-term exposition - systemic effects) 1.4 mg/kg bw/d (consumer, swallowing, long-term exposition - 5

5 Page 5 systemic effects) mg7kg bw/d (worker, skin contact, long-term exposition - systemic effects) 6.97 mg7kg bw/d (consumer, skin contact, long-term exposition - systemic effects) Predicted No-Effect Concentration (PNEC): Water: iron is an essential trace element for fish, aquatic invertebrates and plants. No toxicity Additional Information: Exposure Controls Technical protective measures: No further measures, see Section 7. Personal Protection General protective measures: Respiratory protection: Hand protection: Protective glove material: Eye protection: Body protection: The usual precautionary measures are to be adhered to when handling chemicals. Keep away from foodstuffs and drinks. Do not eat, drink or smoke during work. Wash hands before breaks and at the end of work. Wear protective mask, particle filter P2 or FFP2 or NIOSH N95 (for solid and liquid particles, EN 143, 149) if dust occurs. Protective gloves (EN 374) Protective gloves should be changed regularly, especially after intensive contact with the product. Recommended: Protective index 6, > 480 min. of permeation time accord. EN 374. Chloroprene rubber (CR). Tightly fitting safety goggles (EN 166). Protective clothing Environmental precautions: Physical and Chemical Properties Information on Basic Physical and Chemical Properties Form: crystalline Color: bright green Odor: odorless Odor threshold: ph-value: 2.5 (400 g/l, 20 C) 6

6 Melting temperature: ca. 64 C Page Boiling temperature: Flash point: Evaporation rate: Flammability (solid, gas): Upper explosion limit: Lower explosion limit: Vapor pressure: Vapor density: Density: Solubility in water: Coefficient of variation (n- Octanol/Water): Auto-ignition temperature: Decomposition temperature: Viscosity, dynamic: Explosive properties: Oxidizing properties: Bulk density: Further Information Solubility in solvents: Viscosity, kinematic Burning class: Solvent content: Solid content: not determined not flammable no information available no information available 1.89 g/cm3 (20 C) 400 g/l Product is not auto-ignitable. No data available. 3 mpa.s (20 C) Product does not present an explosion hazard. no information available t/m3 Particle size: 7

7 Other information: Stability and Reactivity Reactivity Chemical Stability Possibility of Hazardous Reactions Conditions to Avoid No further information. Loss of water of crystallization when heated. Stable if used according to specifications. Page Conditions to avoid: Thermal decomposition: Imcompatible Materials Hazardous Decomposition Products Further Information Toxicological Information Information on Toxicological Effects Acute Toxicity Avoid direct sunlight and heat. Avoid heat. None known. LD50, oral: 1096 mg/kg (rat; OECD 423) NOAEL: 274 mg/kg/d (rat; OECD 422) LD50, dermal: > 2000 mg/kg (rat; OECD 202) LC50, inhalation: Primary effects Irritant effect on skin: Irritant effect on eyes: Inhalation: Ingestion: Sensitization: Causes skin irritation (OECD 404) Causes serious eye irritation (OECD 405) No information available Not sensitizing (OECD 429, Mouse Local Lymph Node Assay (LLNA)) Mutagenicity: No relevant data found. 8

8 Reproductive toxicity: No relevant data found. Page Carcinogenicity: Teratogenicity: Specific target organ toxicity (STOT): Additional toxicological information: Ecological Information Aquatic Toxicity Fish toxicity: Daphnia toxicity: Bacteria toxicity: Algae toxicity: Persistency and Degradability Bioaccumulation Mobility Results of PBT- und vpvp Assessment Other Adverse Effects Water hazard class: Behaviour in sewage systems: Further ecological effects: No relevant data found. No specific target organic toxicity available according to EC Regulation 1272/2008. Aspiration hazard: Data are not experimentally disclosed. The Fe2+ ion is not stabil under standard test conditions, it oxidizes to the Fe3+ ion. Unsoluble Iron(III)-hydroxid Fe(OH)3 are formed at a high rate from the Fe3+ salts, thus withdrawing the Fe2+ from the testing system. Iron is an important substance in biological processes, the iron homeostasis is strictly controlled. This shows that iron is not toxic for the aquatic environment. Method is for inorganic substances. No bioaccumulation expected. The product is not mobile in the soil. Inorganic substance: does not comply with the criteria for the classification as PBT or vpvb. 1 (German Regulation) (Assessment by list): slightly hazardous. Iron sulfate hydrolyses forming iron hydrate and diluted sulfuric acid. Both are ecologically harmless. AOX Value: < 2 mg/kg 9

9 13. Disposal Considerations Waste Treatment Methods Page 9 Product: European Waste Code (EWC): Uncleaned packaging: Dispose of according to official national and local regulations. The waste code is determined according to the kind of waste and industry stated in the European Waste Catalogue. Dispose of according to official local regulations Waste Code No.: Transport Information UN Number ADR, IMDG, IATA UN Proper Shipping Name ADR/RID: IMDG/IATA: Transport Hazard Classes ADR Class: Hazard no.: Classification code: Tunnel restriction code: IMDG Class (sea): Hazard no.: EmS No.: IATA Class: Hazard no.: Packaging Group ADR/RID: IMDG: IATA: Environmental Hazards Special Precautions for User No hazardous goods according to ADR (land transportation). No hazardous goods according to IMDG. None Not classified as a dangerous good under transport regulations. 10

10 Page Transportation in Bulk according to Annex II of MARPOL 73/78 and IBC-Code Further Information Regulatory Information Safety, Health and Environmental Regulations/Legislation specific for the Substance or Mixture Water hazard class: Local regulations on chemical accidents: 1, slightly hazardous for water (German Regulation) Not listed Employment restrictions: Restriction and prohibition of application: Technical instructions on air quality: Chemical Safety Assessment Further Information Other Information A Chemical Safety Assessment has been carried out for this product. EC SVHC-List: This product does not contain a substance in the candidate list for substances of very high concern (REACH Regulation (EC) 1907/2006, Article 57) This product should be stored, handled and used in accordance with good hygiene practices and in conformity with any legal regulations. This information contained herein is based on the present state of knowledge and is intended to describe our product from the point of view of safety requirements. It should be therefore not be construed as guaranteeing specific properties.