VF2000 Epoxy Casting Resin

Transcription

1 Page 1 of 8 VF2000 Epoxy Casting Resin 1. IDENTIFICATION OF THE SUBSTANCE / PREPARATION AND THE COMPANY / UNDERTAKING 1.1. PRODUCTS IDENTIFICATION: VF2000 Epoxy Casting Resin 1.2. USE OF SUBSTANCE: Information not supplied 1.3. COMPANY: Ebalta (UK) Ltd B2 Langham Park Trent Lane Castle Donington Derbyshire DE74 2UT Telephone Number: Fax Number: EMERGENCY TELEPHONE: HAZARDS IDENTIFICATION Hazard Description: Xi Irritant Information Concerning Particular Hazards for Human and Environment: This product has to be labelled due to the calculation procedure of the General Classification guideline for preparations of the EU in the latest valid version R36/38 Irritating to eyes and skin R43 May cause sensitization by skin contact R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment Contains epoxy constituents. See information supplied by the manufacturer Classification System: The classification is according to the latest editions of the EU-lists, and extended by company and literature data.

2 Page 2 of 8 VF2000 Epoxy Casting Resin 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical characterization Description: Modified epoxy resin Dangerous Components Components CAS No NLP/EINECS No % R Phrases Reaction product: bisphenol-a-(epichlorhydrin) epoxy resin (number average molecular weight = 700) NLP % Xi; N; R 36/ /53 Bisphenol-F-epichlorhydrineresin MG NLP % Xi; N; R 36/ /53 1,6-Hexandioldiglycidylether EINECS Additional Information: For the wording of the listed risk phrases refer to section FIRST-AID MEASURES General Information: Immediately remove any clothing soiled by the product After Inhalation: Supply fresh air and be sure to call for a doctor In case of unconsciousness place patient stably in side position for transportation After Skin Contact: If skin irritation continues, consult a doctor Immediately wash with water and soap and rinse thoroughly After Eye Contact: Rinse opened eye for several minutes under running water. Then consult a doctor. After Swallowing: Seek medical treatment Rinse out mouth and then drink plenty of water 5. FIRE-FIGHTING MEASURES Suitable Extinguishing Agents: CO 2, Powder or water spray. Fight larger fires with water spray or alcohol resistant foam. Do not use: Water with full jet Special hazards caused by the substance, its products of combustion or resulting gases: In case of fire, the following can be released: Carbon monoxide (CO)

3 Page 3 of 8 VF2000 Epoxy Casting Resin Under certain fire conditions, traces of other toxic gases cannot be excluded, e.g. Hydrogen chloride (HCI) Burning produces harmful smoke Carbon oxides Protective equipment: Wear fully protective suit Wear self contained respiratory protective device Additional Information: Collect contaminated fire fighting water separately. It must not enter the sewage system Dispose of fire debris and contaminated fire fighting water in accordance with official regulations 6. ACCIDENTAL RELEASE MEASURES Person-related Safety Precautions: Wear protective clothing Measures for Environmental Protection: Do not allow to enter sewers/surface or ground water Do not allow product to reach sewerage system or water course Inform respective authorities in case of seepage into water course or sewage system Measures for Cleaning/Collecting: Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust) 7. HANDLING AND STORAGE Handling: Open and handle receptacle with care Ensure good ventilation/exhaust at the workplace Information about Fire and Explosion Protection: No special measures required Storage: Requirements to be met by Storerooms and Receptacles: No special requirements Information about Storage in One Common Storage Facility: Store away from foodstuffs Further Information about Storage Conditions: Please stir or shake thoroughly before use! Keep container tightly closed Protect against frost and heat

4 Page 4 of 8 VF2000 Epoxy Casting Resin 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Additional Information about Design of Technical Facilities: No further data; see item 7 Ingredients with Limit values that require Monitoring at the Workplace: The product does not contain any relevant quantities of materials with critical values that have to be monitored at the workplace Additional Information: The lists valid during the making were used as basis Personal protective Equipment: General Protective and Hygienic Measures: Keep away from foodstuffs, beverages and feed Immediately remove all soiled and contaminated clothing Wash hands before breaks and at the end of work Avoid contact with eyes and skin Respiratory Protection: In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use self-contained respiratory protective device Eye protection: Tightly sealed goggles Hand Protection: Protective gloves For the permanent contact gloves made of Nitrilkautschuk with a layer thickness of at least 0.2mm are suitable. The penetration time of this glove material is 480 minutes The glove material has to be according the specifications of EU-guideline 89/686/EWG and the resulting norm EN 374, for example KCL Dermatril P,0743. The above mentioned penetration times are based on laboratory measurements of KCL according to EN 374. This recommendation is only valid for the product, which is delivered from us and only for the intended mentions application. Regarding dissolution or mixing with other substances please contact suppliers of CE-approved gloves. (For example KCL GmbH, D Eichenzell, internet: Material of Gloves: Nitrile rubber, NBR The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. As the product is a preparation of several

5 Page 5 of 8 VF2000 Epoxy Casting Resin substances, the resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the application. Body Protection: Protective work clothing 9. PHYSICAL AND CHEMICAL PROPERTIES Physical state: Liquid Colour: Grey Odour: Characteristic Melting Point/Melting Range: Undetermined Boiling Point/Boiling Range: > 200 C (DIN 53171) Flash point: > 100 C (c.c.) Self-igniting: Product is not self-igniting Danger of Explosion: Product does not present an explosion hazard Density at 20 o C: 1.9 g/cm 3 (ISO 2811) Solubility in/miscibility with Water: Not miscible or difficult to mix Viscosity: Dynamic at 25 C: mpas (ISO 9371) 10. STABILITY AND REACTIVITY Thermal decomposition/conditions to be avoided: No decomposition if used and stored according to specifications Dangerous Reactions: Exothermic polymerization May produce violent reactions with bases and numerous organic substances including alcohols and amines Dangerous decomposition Products: Irritant gases/vapours Incase of incomplete burning poisonous gases are developing, which contain mainly carbon monoxide and carbon dioxide 11. TOXICOLOGICAL INFORMATION Acute toxicity: LD/LC50 values relevant for classification: Oral LD mg/kg (rat) reaction product: bisphenol-a-(epichlorhydrin) epoxy resin (number average molecular weight = 700 Oral LD mg/kg (rat) Dermal LD50 >2000 mg/kg (rabbit)

6 Page 6 of 8 VF2000 Epoxy Casting Resin bisphenol-f-epichlorhydrinresin MG 700 Oral LD mg/kg (rat) Dermal LD50 >2000 mg/kg (rabbit) Primary Irritant Effect: Eye: Irritating effect Skin: Irritant to skin and mucous membranes Sensitisation: Sensitising possible through skin contact Additional Toxicological Information: The product shows the following dangers according to the calculation method of the General EU Classification Guidelines for Preparations as issued in the latest version: Irritant Sensitising Sensitisation: May cause sensitisation by skin contact 12. ECOLOGICAL INFORMATION Ecotoxical Effects: Aquatic Toxicity: EC 05 (24 h) <1 mg/l (Acute fish toxicity) reaction product: bisphenol-a-(epichlorhydrin) epoxy resin (number average molecular weight = 700) EC 50 (24 h) mg/l (daphnia magna) LC 50 (96 h) 220 mg/l (Al) mg/l (rainbow trout) bisphenol-f-epichlorhudrinresin MG 700 EC 50 (24 h) > 100 mg/l (daphnia magna) Remark: Harmful to fish General Notes: Water hazard class 2 (German Regulation) (Self-assessment): slightly hazardous for water Do not allow product to reach ground water, water courses or sewage system Danger to drinking water if even small quantities leak into the ground Harmful to aquatic organisms 13. DISPOSAL CONSIDERATIONS Product Recommendation: Must not be disposed of together with household garbage. Do not allow product to reach sewage system.

7 Page 7 of 8 VF2000 Epoxy Casting Resin Waste Disposal Key: The Waste-Key-Numbers have to be given from the waste-producer depending on the respective trade. Therefore no information can be stated from the manufacturer Uncleaned Packaging Recommendation: Empty contaminated packaging thoroughly. They may be recycled after thorough and proper cleaning. Packaging s that may not be cleansed are to be disposed of in the same manner as the product. 14. TRANSPORT INFORMATION Land Transport ADR/RID (cross-border) ADR/RID Class: 9 Miscellaneous dangerous substances and articles Danger Code (Kemler): 90 UN Number: 3082 Packaging Group: III Hazard Label: 9 Description of goods: 3082 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (epoxy resin) Limited Quantities (LQ): LQ7 Transport Category: 3 Tunnel Restriction Code: E Maritime Transport IMDG: IMDG Class: 9 UN Number: 3082 Label: 9 Packaging Group: III EMS Number: F-A, S-F Marine Pollutant: Proper Shipping Name: Air Transport ICAO-TI and IATA-DGR: ICAO/IATA Class: 9 UN/ID Number: 3082 Label: 9 Packaging Group: Proper Shipping Name: No ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (epoxy (epoxy resin) III ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (epoxy (epoxy resin) 15. REGULATORY INFORMATION Labelling According to EU Guidelines: The product has been classified and marked in accordance with EU directives/ordinance on Hazardous Materials

8 Page 8 of 8 VF2000 Epoxy Casting Resin Code Letter and Hazard Designation of Product: Xi Irritant Hazard-determining Components of labeling: Reaction product: bisphenol-a-(epichlorhydrin) epoxy resin (number average molecular weight = 700) Bisphenol-F-epichlorhydrinresin MG 700 1,6-Hexandioldiglycidylether Risk Phrases: 36/38 Irritating to eyes and skin 43 May cause sensitization by skin contact 52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment Safety Phrases: 23 Do not breathe fumes/aerosols 24 Avoid contact with skin 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 37 Wear suitable gloves 61 Avoid release to the environment. Refer to special instructions/safety data sheets Special Labelling of Certain preparations: Contains epoxy constituents. See information supplied by the manufacturer National Regulations: Technical Instructions (air): Class Chare in % III 25.5 Water Hazard Class: Water hazard class 2 (self-assessment): slightly hazardous for water 16. OTHER INFORNATION This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. Relevant R-phrases 36/38 Irritating to eyes and skin 43 May cause sensitisation by skin contact 51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment 52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment

9 Page 1 of 8 VF2000 Epoxy Casting Resin Accelerator 1. IDENTIFICATION OF THE SUBSTANCE / PREPARATION AND THE COMPANY / UNDERTAKING 1.1. PRODUCTS IDENTIFICATION: VF2000 Epoxy Casting Resin Accelerator 1.2. USE OF SUBSTANCE: Information not supplied 1.3. COMPANY: Ebalta (UK) Ltd B2 Langham Park Trent Lane Castle Donington Derbyshire DE74 2UT Telephone Number: Fax Number: EMERGENCY TELEPHONE: HAZARDS IDENTIFICATION Hazard Description: Corrosive Information Concerning Particular Hazards for Human and Environment: This product has to be labelled due to the calculation procedure of the General Classification guideline for preparations of the EU in the latest valid version R21/22 Harmful in contact with skin and if swallowed R34 Caused burns R43 May cause sensitization by skin contact R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment Classification System: The classification is according to the latest editions of the EU-lists, and extended by company and literature data. 3. COMPOSITION/INFORMATION ON INGREDIENTS

10 Page 2 of 8 VF2000 Epoxy Casting Resin Accelerator Chemical characterization Description: Mixture of substances listed below with non-hazardous additions Dangerous Components: Product: Cas No. EINECS No. % R-Phrases 3-aminomehtyl-3,5,5-trimethylcyclohexylamine % C, Xn; R21/ /53 Additional Information: For the wording of the listed risk phrases refer to section FIRST-AID MEASURES General Information: Immediately remove any clothing soiled by the product After Inhalation: Supply fresh air and be sure to call for a doctor In case of unconsciousness place patient stably in side position for transportation After Skin Contact: Immediately wash with water and soap and rinse thoroughly Cover wound with sterile dressing After Eye Contact: Rinse opened eye for several minutes under running water. Then consult a doctor. After Swallowing: Rinse out mouth and then drink plenty of water Consult immediately a doctor 5. FIRE-FIGHTING MEASURES Suitable Extinguishing Agents: CO 2, Powder or water spray. Fight larger fires with water spray or alcohol resistant foam. Do not use: Water with full jet Special hazards caused by the substance, its products of combustion or resulting gases: In case of fire, the following can be released: Nitrogen Oxides (NOx) Carbon monoxide (CO) Ammonia Protective equipment:

11 Page 3 of 8 VF2000 Epoxy Casting Resin Accelerator Wear fully protective suit Wear self contained respiratory protective device Additional Information: Collect contaminated fire fighting water separately. It must not enter the sewage system Dispose of fire debris and contaminated fire fighting water in accordance with official regulations 6. ACCIDENTAL RELEASE MEASURES Person-related Safety Precautions: Wear protective equipment. Keep unprotected persons away Wear protective clothing Measures for Environmental Protection: Do not allow product to reach sewerage system or water course Inform respective authorities in case of seepage into water course or sewage system Do not allow to enter sewers/surface or ground water Measures for Cleaning/Collecting: Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust) Use neutralizing agent Dispose contaminated material as waste according to item 13 Ensure adequate ventilation 7. HANDLING AND STORAGE Handling: Open and handle receptacle with care Ensure good ventilation/exhaust at the workplace Prevent formation of aerosols The air limiting values mentioned in chapter 8 have to be controlled. At places of work, where aerosols and/or fumes can occur in higher concentrations, exceeding of limiting hygienic values has to be prevented by specific air exhaust. The air motions have to be carried out from the persons away. Storage: Requirements to be met by Storerooms and Receptacles: Sufficient ventilation for storage and working rooms Prevent any seepage into the ground Information about Storage in One Common Storage Facility: Store away from foodstuffs Further Information about Storage Conditions: Store in dry conditions Store in a cool place Keep container tightly closed 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

12 Page 4 of 8 VF2000 Epoxy Casting Resin Accelerator Additional Information about Design of Technical Facilities: No further data; see item 7 Ingredients with Limit values that require Monitoring at the Workplace: The product does not contain any relevant quantities of materials with critical values that have to be monitored at the workplace Additional Information: The lists valid during the making were used as basis Personal protective Equipment: General Protective and Hygienic Measures: Keep away from foodstuffs, beverages and feed Immediately remove all soiled and contaminated clothing Wash hands before breaks and at the end of work Do not inhale gases/fumes/aerosols Respiratory Protection: Not necessary if room is well-ventilated In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use self-contained respiratory protective device Eye protection: Tightly sealed goggles Hand Protection: Protective gloves For the permanent contact gloves made of Nitrilkautschuk with a layer thickness of at least 0.33mm are suitable. The penetration time of this glove material is 480 minutes The glove material has to be according the specifications of EU-guideline 89/686/EWG and the resulting norm EN 374, for example KCL Camatril,0731. The above mentioned penetration times are based on laboratory measurements of KCL according to EN 374. This recommendation is only valid for the product, which is delivered from us and only for the intended mentions application. Regarding dissolution or mixing with other substances please contact suppliers of CE-approved gloves. (For example KCL GmbH, D Eichenzell, internet: Material of Gloves: The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. As the product is a preparation of several

13 Page 5 of 8 VF2000 Epoxy Casting Resin Accelerator substances, the resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the application. Body Protection: Protective work clothing 9. PHYSICAL AND CHEMICAL PROPERTIES Physical state: Fluid Colour: Yellow-brown Odour: Amine-like Melting Point/Melting Range: Undetermined Boiling Point/Boiling Range: > 200 C (DIN 53171) Flash point: 115 C (ISO 2719) Ignition Temperature: 380 C (DIN 51794) Self-igniting: Product is not self-igniting Density at 20 o C: 0.98 g/cm 3 (ISO 2811) Solubility in/miscibility with Water: Not miscible or difficult to mix ph-value (20 g/l) at 20 C: ca. 11 (ISO 9371) Viscosity: Dynamic at 25 C: mpas (ISO 9371) 10. STABILITY AND REACTIVITY Thermal decomposition/conditions to be avoided: No decomposition if used and stored according to specifications Dangerous Reactions: Strong exothermic reaction with acids Dangerous decomposition Products: Corrosive gases/vapours Ammonia 11. TOXICOLOGICAL INFORMATION Acute toxicity: LD/LC50 values relevant for classification: Oral LD mg/kg (rat) Dermal LD mg/kg (rabbit) Primary Irritant Effect: Eye: Strong caustic effect Skin: Caustic effect on skin and mucous membranes Sensitisation: Sensitising possible through skin contact

14 Page 6 of 8 VF2000 Epoxy Casting Resin Accelerator Additional Toxicological Information: The product shows the following dangers according to the calculation method of the General EU Classification Guidelines for Preparations as issued in the latest version: Harmful Corrosive Irritant Swallowing will lead to a strong caustic effect on mouth and throat and to the danger of perforation of oesophagus and stomach. Sensitisation: May cause sensitisation by skin contact 12. ECOLOGICAL INFORMATION Ecotoxical Effects: Harmful to fish General Notes: Water hazard class 1 (German Regulation) (Self-assessment): slightly hazardous for water Do not allow undiluted product or large quantities of it to reach ground water, water courses or sewage system Must not reach sewage water or drainage ditch undiluted or unneutralised Harmful to aquatic organisms 13. DISPOSAL CONSIDERATIONS Product Recommendation: Must not be disposed of together with household garbage. Do not allow product to reach sewage system. Waste Disposal Key: The Waste-Key-Numbers have to be given from the waste-producer depending on the respective trade. Therefore no information can be stated from the manufacturer Uncleaned Packaging Recommendation: Disposal must be made according to official regulations. 14. TRANSPORT INFORMATION Land Transport ADR/RID (cross-border) ADR/RID Class: 8 Corrosive substances Danger Code (Kemler): 80 UN Number: 2289 Packaging Group: III Hazard Label: 8 Description of goods: 2289 ISOPHORONWSIAMINE

15 Page 7 of 8 VF2000 Epoxy Casting Resin Accelerator Limited Quantities (LQ): LQ7 Transport Category: 3 Tunnel Restriction Code: E Maritime Transport IMDG: IMDG Class: 8 UN Number: 2289 Label: 8 Packaging Group: III EMS Number: F-A, S-B Marine Pollutant: No Proper Shipping Name: ISOPHORONEDIAMINE Air Transport ICAO-TI and IATA-DGR: ICAO/IATA Class: 8 UN/ID Number: 2289 Label: 8 Packaging Group: III Proper Shipping Name: ISOPHORONEDIAMINE 15. REGULATORY INFORMATION Labelling According to EU Guidelines: The product has been classified and marked in accordance with EU directives/ordinance on Hazardous Materials Code Letter and Hazard Designation of Product: C Corrosive Hazard-determining Components of labeling: 3-aminomethyl-3,5,5-trimethylcyclohexylamine Risk Phrases: 21/22 Harmful in contact with skin and if swallowed 34 Causes burns 43 May cause sensitisation by skin contact 52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment Safety Phrases: 20 After contact with skin, wash immediately with plenty of soap and water. 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 36/37/39 Wear suitable protective clothing, gloves and eye/face protection 45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible) 61 Avoid release to the environment. Refer to special instructions/safety data sheets National Regulations:

16 Page 8 of 8 VF2000 Epoxy Casting Resin Accelerator Water Hazard Class: Water hazard class 1 (self-assessment): slightly hazardous for water 16. OTHER INFORNATION This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. Relevant R-phrases 21/22 Harmful in contact with skin and if swallowed 34 Causes burns 43 May cause sensitisation by skin contact 52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment