: Hardcore Blue Mixing Solution, 24 fl.oz.

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1 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form Product name. Product code : Mixture : Hardcore Blue Mixing Solution, 24 fl.oz. : HCB Relevant identified uses of the substance or mixture and uses advised against Use of the substance/preparation 1.3. Details of the supplier of the safety data sheet : Casting material SIRCHIE Finger Print Laboratories 100 Hunter Place Youngsville, NC - USA T ; F ; Emergency telephone number Emergency number : SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification (GHS-US) Not classified Revision date: 01/05/2015 Supersedes:01/27/2011 Version: 2.2. Label elements GHS-US labeling No labeling applicable 2.3. Other hazards Other hazards not contributing to the classification 2.4. Unknown acute toxicity (GHS US) No data available : None under normal conditions. SECTION 3: Composition/information on ingredients 3.1. Substances 3.2. Mixtures Name Product identifier % Classification (GHS-US) AQUA (CAS No.) <= 99 Not classified methylene blue (CAS No.) < 1 Acute Tox. 4 (Oral), H302 SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures general First-aid measures after inhalation First-aid measures after skin contact First-aid measures after eye contact First-aid measures after ingestion : Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible). : Assure fresh air breathing. Allow the victim to rest Most important symptoms and effects, both acute and delayed Symptoms/injuries : Remove affected clothing and wash all exposed skin area with mild soap and water, followed by warm water rinse. : Rinse immediately with plenty of water. Obtain medical attention if pain, blinking or redness persist. : Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention Indication of any immediate medical attention and special treatment needed : Not expected to present a significant hazard under anticipated conditions of normal use. 12/02/2013 EN (English US) 1/5

2 SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media Unsuitable extinguishing media : Foam. Dry powder. Carbon dioxide. Water spray. Sand. : Do not use a heavy water stream Special hazards arising from the substance or mixture Reactivity : None Advice for firefighters Firefighting instructions Protection during firefighting : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Avoid (reject) fire-fighting water to enter environment. : Do not enter fire area without proper protective equipment, including respiratory protection. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures For non-emergency personnel Emergency procedures For emergency responders Protective equipment Emergency procedures : Evacuate unnecessary personnel. : Equip cleanup crew with proper protection. : Ventilate area Environmental precautions Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters Methods and material for containment and cleaning up Methods for cleaning up 6.4. Reference to other sections See Heading 8. Exposure controls and personal protection. SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling 7.2. Conditions for safe storage, including any incompatibilities Storage conditions Incompatible products Incompatible materials 7.3. Specific end use(s) : Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Collect spillage. Store away from other materials. : Wash hands and other exposed areas with mild soap and water before eat, drink or smoke and when leaving work. Provide good ventilation in process area to prevent formation of vapor. : Keep only in the original container in a cool, well ventilated place away from : Keep container closed when not in use. : Strong bases. strong acids. SECTION 8: Exposure controls/personal protection 8.1. Control parameters : Sources of ignition. Direct sunlight Exposure controls Personal protective equipment Hand protection Eye protection Respiratory protection : Avoid all unnecessary exposure. : Wear protective gloves. : Chemical goggles or safety glasses. : Wear approved mask. : When using, do not eat, drink or smoke. 12/02/2013 EN (English US) 2/5

3 SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state Appearance Color Odor Odor threshold ph Relative evaporation rate (butyl acetate=1) Melting point Freezing point Boiling point Flash point Self ignition temperature Decomposition temperature Flammability (solid, gas) Vapor pressure Relative vapor density at 20 C Relative density Solubility Log Pow Log Kow Viscosity, kinematic Viscosity, dynamic Explosive properties Oxidizing properties Explosive limits 9.2. SECTION 10: Stability and reactivity Reactivity None Chemical stability Stable under normal conditions Possibility of hazardous reactions Conditions to avoid Direct sunlight. Extremely high or low temperatures Incompatible materials strong acids. Strong bases Hazardous decomposition products None. SECTION 11: Toxicological information Information on toxicological effects : Liquid : Liquid. : Bluish liquid. : odorless. : Soluble in water. Acute toxicity LD50 oral rat Skin corrosion/irritation Serious eye damage/irritation Respiratory or skin sensitization Germ cell mutagenicity Carcinogenicity 1180 mg/kg (Rat) Based on available data, the classification criteria are not met 12/02/2013 EN (English US) 3/5

4 Reproductive toxicity Specific target organ toxicity (single exposure) Specific target organ toxicity (repeated exposure) Aspiration hazard Potential Adverse human health effects and symptoms Based on available data, the classification criteria are not met Based on available data, the classification criteria are not met Based on available data, the classification criteria are not met : Based on available data, the classification criteria are not met. SECTION 12: Ecological information Toxicity LC50 fish 1 EC50 Daphnia 1 LC50 fish 2 EC50 Daphnia 2 TLM fish 1 13 mg/l (48 h; Oryzias latipes) 2.26 mg/l (48 h; Daphnia magna) 18 mg/l (96 h; Mystus vittatus) 4.93 mg/l (24 h; Daphnia magna) ,48 h; Poecilia reticulata Persistence and degradability Hardcore Blue Mixing Solution, 24 fl.oz. Persistence and degradability Persistence and degradability Biodegradability in water: no data available. Photodegradation in the air Bioaccumulative potential Hardcore Blue Mixing Solution, 24 fl.oz. Bioaccumulative potential Log Pow Bioaccumulative potential 5.85 (Estimated value) Not bioaccumulative Mobility in soil Other adverse effects : Avoid release to the environment. SECTION 13: Disposal considerations Waste treatment methods Waste disposal recommendations : Dispose in a safe manner in accordance with local/national regulations. Ecology - waste materials : Avoid release to the environment. SECTION 14: Transport information In accordance with ADR / RID / ADNR / IMDG / ICAO / IATA UN number UN proper shipping name Additional information : No supplementary information available. Overland transport Transport by sea Air transport 12/02/2013 EN (English US) 4/5

5 SECTION 15: Regulatory information US Federal regulations International regulations CANADA EU-Regulations Classification according to Regulation (EC) No. 1272/2008 [CLP] Classification according to Directive 67/548/EEC or 1999/45/EC Not classified National regulations US State regulations SECTION 16: Indication of changes : Revision - See : *. Data sources Training advice : REGULATION (EC) No 1272/2008 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL of 16 December 2008 on classification, labeling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006. : Normal use of this product shall imply use in accordance with the instructions on the packaging. Keep in tightly closed container. Keep cool and dry. Avoid all ignition sources - heat, open flame, sparks. Avoid incompatible materials. Avoid dust creation and accumulation. Avoid inhalation and ingestion. Avoid contact with eyes. Wash thoroughly after handling. : This has been established in accordance with the applicable European Union legislation. Full text of H-phrases: see section 16: Acute Tox. 4 (Oral) Acute toxicity (oral) Category H302 Harmful if swallowed NFPA health hazard NFPA fire hazard NFPA reactivity : 0 - Exposure under fire conditions would offer no hazard beyond that of ordinary combustible materials. : 0 - Materials that will not burn. : 0 - Normally stable, even under fire exposure conditions, and are not reactive with water. HMIS III Rating Health Flammability Physical Personal Protection : 0 Minimal Hazard - No significant risk to health : 0 Minimal Hazard : 0 Minimal Hazard : B SDS US (GHS HazCom 2012) The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, expressed or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigation to determine the suitability of the information for their particular purposes. 12/02/2013 EN (English US) 5/5