: Iodine, 0.01N (0.005M)

Transcription

1 Date of issue: 12/13/2013 Revision date: 11/01/2017 Supersedes: 12/13/2013 Version: 1.1 SECTION 1: Identification 1.1. Identification Product form Product name Product code : Mixtures : Iodine, 0.01N (0.005M) : LC Recommended use and restrictions on use Use of the substance/mixture Recommended use Restrictions on use 1.3. Supplier : For laboratory and manufacturing use only. : Laboratory chemicals : Not for food, drug or household use LabChem Inc Jackson's Pointe Commerce Park Building 1000, 1010 Jackson's Pointe Court Zelienople, PA USA T F info@labchem.com Emergency telephone number Emergency number : CHEMTREC: or SECTION 2: Hazard(s) identification 2.1. Classification of the substance or mixture GHS-US classification Not classified 2.2. GHS Label elements, including precautionary statements Not classified as a hazardous chemical. Other hazards not contributing to the classification 2.4. Unknown acute toxicity (GHS US) : None. SECTION 3: Composition/Information on ingredients 3.1. Substances 3.2. Mixtures Name Product identifier % GHS-US classification Water (CAS-No.) Not classified Potassium Iodide (CAS-No.) Aquatic Acute 2, H401 Iodine (CAS-No.) Acute Tox. 3 (Dermal), H311 Acute Tox. 4 (Inhalation), H332 Skin Corr. 1C, H314 Eye Dam. 1, H318 Skin Sens. 1B, H317 Aquatic Acute 1, H400 Hydrochloric Acid, 37% w/w (CAS-No.) Acute Tox. 4 (Oral), H302 Skin Corr. 1B, H314 Eye Dam. 1, H318 STOT SE 3, H335 Aquatic Acute 3, H402 Full text of hazard classes and H-statements : see section 16 SECTION 4: First-aid measures 4.1. Description of first aid measures First-aid measures general First-aid measures after inhalation : Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible). : Allow victim to breathe fresh air. Allow the victim to rest. 11/01/2017 EN (English US) Page 1

2 First-aid measures after skin contact First-aid measures after eye contact First-aid measures after ingestion : Remove affected clothing and wash all exposed skin area with mild soap and water, followed by warm water rinse. : Rinse immediately with plenty of water. Obtain medical attention if pain, blinking or redness persists. : Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention Most important symptoms and effects (acute and delayed) Symptoms/effects 4.3. Immediate medical attention and special treatment, if necessary Obtain medical assistance. SECTION 5: Fire-fighting measures 5.1. Suitable (and unsuitable) extinguishing media Suitable extinguishing media Unsuitable extinguishing media 5.2. Specific hazards arising from the chemical Fire hazard Explosion hazard : Not expected to present a significant hazard under anticipated conditions of normal use. : Foam. Dry powder. Carbon dioxide. Water spray. Sand. : Do not use a heavy water stream. : Not flammable. : Special protective equipment and precautions for fire-fighters Firefighting instructions Protection during firefighting SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Prevent fire-fighting water from entering environment. : Do not enter fire area without proper protective equipment, including respiratory protection For non-emergency personnel Protective equipment Emergency procedures For emergency responders Protective equipment Emergency procedures : Safety glasses. Gloves. : Evacuate unnecessary personnel. : Equip cleanup crew with proper protection. : Ventilate area Environmental precautions Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters. Avoid release to the environment Methods and material for containment and cleaning up Methods for cleaning up 6.4. Reference to other sections See Heading 8. Exposure controls and personal protection. SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling Hygiene measures 7.2. Conditions for safe storage, including any incompatibilities Storage conditions Incompatible products Incompatible materials : Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Collect spillage. Store away from other materials. : Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Provide good ventilation in process area to prevent formation of vapor. : Do not eat, drink or smoke when using this product. Wash contaminated clothing before reuse. : Keep only in the original container in a cool, well ventilated place away from : Direct sunlight, incompatible materials. Keep container closed when not in use. : Strong reducing agents. Ammonia. Acetaldehyde. metals. : Sources of ignition. Direct sunlight. SECTION 8: Exposure controls/personal protection 8.1. Control parameters 11/01/2017 EN (English US) 2/8

3 ACGIH ACGIH TWA (mg/m³) 0.1 mg/m³ Inhalable fraction ACGIH ACGIH TWA (ppm) 0.01 ppm Inhalable fraction ACGIH ACGIH STEL (mg/m³) 1 mg/m³ ACGIH ACGIH STEL (ppm) 0.1 ppm OSHA OSHA PEL (Ceiling) (mg/m³) 1 mg/m³ OSHA OSHA PEL (Ceiling) (ppm) 0.1 ppm IDLH US IDLH (ppm) 2 ppm NIOSH NIOSH REL (ceiling) (mg/m³) 1 mg/m³ NIOSH NIOSH REL (ceiling) (ppm) 0.1 ppm ACGIH ACGIH TWA (ppm) 0.01 ppm Inhalable fraction Water ( ) ACGIH ACGIH Ceiling (mg/m³) 2.98 mg/m³ ACGIH ACGIH Ceiling (ppm) 2 ppm OSHA OSHA PEL (Ceiling) (mg/m³) 7 mg/m³ OSHA OSHA PEL (Ceiling) (ppm) 5 ppm IDLH US IDLH (ppm) 50 ppm NIOSH NIOSH REL (ceiling) (mg/m³) 7 mg/m³ NIOSH NIOSH REL (ceiling) (ppm) 5 ppm 8.2. Appropriate engineering controls Appropriate engineering controls : Emergency eye wash fountains should be available in the immediate vicinity of any potential exposure. Provide adequate general and local exhaust ventilation Individual protection measures/personal protective equipment Personal protective equipment: Safety glasses. Hand protection: Wear protective gloves Eye protection: Chemical goggles or safety glasses Respiratory protection: Respiratory protection not required in normal conditions Other information: Do not eat, drink or smoke during use. 11/01/2017 EN (English US) 3/8

4 SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state Color Odor Odor threshold ph Melting point Freezing point Boiling point Flash point Relative evaporation rate (butyl acetate=1) Flammability (solid, gas) Vapor pressure Relative vapor density at 20 C Relative density Solubility Log Pow Auto-ignition temperature Decomposition temperature Viscosity, kinematic Viscosity, dynamic Explosion limits Explosive properties Oxidizing properties 9.2. Other information No additional information available SECTION 10: Stability and reactivity Reactivity No additional information available Chemical stability Stable under normal conditions Possibility of hazardous reactions Conditions to avoid Direct sunlight. Extremely high or low temperatures Incompatible materials metals. Strong reducing agents. Ammonia Hazardous decomposition products Iodine vapor. Potassium oxide. SECTION 11: Toxicological information Information on toxicological effects : Liquid : amber : characteristic : Non flammable. : Miscible with water. :.. Likely routes of exposure Acute toxicity LD50 oral rat ATE US (oral) ATE US (dermal) : Inhalation; Skin and eye contact mg/kg mg/kg body weight 220 mg/kg body weight 11/01/2017 EN (English US) 4/8

5 ATE US (dust, mist) Water ( ) LD50 oral rat ATE US (oral) LD50 oral rat LD50 dermal rabbit ATE US (oral) ATE US (dermal) Skin corrosion/irritation Serious eye damage/irritation Respiratory or skin sensitization Germ cell mutagenicity Carcinogenicity 1.5 mg/l/4h mg/kg mg/kg body weight 700 mg/kg 5010 mg/kg 700 mg/kg body weight 5010 mg/kg body weight Based on available data, the classification criteria are not met IARC group Reproductive toxicity Specific target organ toxicity single exposure 3 - Not classifiable Based on available data, the classification criteria are not met Specific target organ toxicity repeated exposure Aspiration hazard Potential Adverse human health effects and symptoms SECTION 12: Ecological information Toxicity Ecology - water Iodine, 0.01N (0.005M) EC50 Daphnia 1 LC50 fish 1 EC50 Daphnia 1 LC50 fish 1 EC50 Daphnia 1 : Based on available data, the classification criteria are not met. : Harmful to aquatic life mg/l 1.7 mg/l 0.2 mg/l 3200 mg/l 120 h 2.7 mg/l 24 h LC50 fish mg/l (LC50; 96 h) EC50 Daphnia 1 < 56 mg/l (EC50; 72 h) Iodine, 0.01N (0.005M) 11/01/2017 EN (English US) 5/8

6 Water ( ) Biochemical oxygen demand (BOD) Chemical oxygen demand (COD) ThOD Biodegradability: not applicable. No test data on mobility of the components available Bioaccumulative potential Iodine, 0.01N (0.005M) Bioaccumulative potential Log Pow 2.49 Bioaccumulative potential Bioaccumulative potential Water ( ) Bioaccumulative potential Log Pow 0.25 (QSAR) Bioaccumulative potential Low potential for bioaccumulation (Log Kow < 4) Mobility in soil Ecology - soil May be harmful to plant growth, blooming and fruit formation Other adverse effects Effect on the global warming GWPmix comment Other information : No known effects from this product. : No known effects from this product. : Avoid release to the environment. SECTION 13: Disposal considerations Disposal methods Waste disposal recommendations : Dispose in a safe manner in accordance with local/national regulations. Ecology - waste materials : Avoid release to the environment. SECTION 14: Transport information Department of Transportation (DOT) In accordance with DOT Not regulated SECTION 15: Regulatory information US Federal regulations All components of this product are listed, or excluded from listing, on the United States Environmental Protection Agency Toxic Substances Control Act (TSCA) inventory Chemical(s) subject to the reporting requirements of Section 313 or Title III of the Superfund Amendments and Reauthorization Act (SARA) of 1986 and 40 CFR Part 372. Hydrochloric Acid, 37% w/w CAS-No % 11/01/2017 EN (English US) 6/8

7 SARA Section 311/312 Hazard Classes SARA Section 311/312 Hazard Classes EPA TSCA Regulatory Flag RQ (Reportable quantity, section 304 of EPA's List of Lists) SARA Section 302 Threshold Planning Quantity (TPQ) SARA Section 311/312 Hazard Classes Immediate (acute) health hazard Delayed (chronic) health hazard Immediate (acute) health hazard Delayed (chronic) health hazard T - T - indicates a substance that is the subject of a Section 4 test rule under TSCA lb 500 lb Immediate (acute) health hazard International regulations CANADA Listed on the Canadian DSL (Domestic Substances List) Listed on the Canadian DSL (Domestic Substances List) EU-Regulations No additional information available National regulations Listed on the Canadian IDL (Ingredient Disclosure List) Listed on the Canadian IDL (Ingredient Disclosure List) US State regulations California Proposition 65 - This product does not contain any substances known to the state of California to cause cancer, developmental and/or reproductive harm SECTION 16: Other information Revision date : 11/01/2017 Other information : None. 11/01/2017 EN (English US) 7/8

8 Full text of H-phrases: see section 16: H302 H311 H314 H317 H318 H332 H335 H400 H401 H402 NFPA health hazard NFPA fire hazard NFPA reactivity Harmful if swallowed Toxic in contact with skin Causes severe skin burns and eye damage May cause an allergic skin reaction Causes serious eye damage Harmful if inhaled May cause respiratory irritation Very toxic to aquatic life Toxic to aquatic life Harmful to aquatic life : 1 - Materials that, under emergency conditions, can cause significant irritation. : 0 - Materials that will not burn under typical dire conditions, including intrinsically noncombustible materials such as concrete, stone, and sand. : 0 - Material that in themselves are normally stable, even under fire conditions. Hazard Rating Health Flammability Physical Personal protection : 1 Slight Hazard - Irritation or minor reversible injury possible : 0 Minimal Hazard - Materials that will not burn : 0 Minimal Hazard - Materials that are normally stable, even under fire conditions, and will NOT react with water, polymerize, decompose, condense, or self-react. Non-Explosives. : B B - Safety glasses, Gloves SDS US LabChem Information in this SDS is from available published sources and is believed to be accurate. No warranty, express or implied, is made and LabChem Inc assumes no liability resulting from the use of this SDS. The user must determine suitability of this information for his application. 11/01/2017 EN (English US) 8/8