SAFETY DATA SHEET STARCH M-PA EXP. SECTION 1: Identification of the substance/mixture and of the company/undertaking

Transcription

1 SAFETY DATA SHEET STARCH M-PA EXP SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1 Product identifier: Product name: STARCH M-PA EXP 1.2 Relevant identified uses of the substance or mixture and uses advised against: Identified uses: Glue Uses advised against: 1.3 Details of the supplier of the safety data sheet: Supplier: ROQUETTE FRERES 1 Rue de la Haute Loge LESTREM - France Telephone: Fax: sds@roquette.com 1.4 Emergency telephone number: INRS Paris : / CAPTV Nancy : (24/24) SECTION 2: Hazards identification 2.1 Classification of the substance or mixture: Classification according to Regulation (EC) No 1272/2008 as amended.: Self-Classification : 2.2 Label elements: Eye Irrit. Category 2 Causes serious eye irritation. Signal words: Hazard Statement(s): Warning H319 / Causes serious eye irritation. Precautionary statement Prevention: P264 ; P280 Response: P305+P351+P338 ; P337+P313 Supplemental label information EUH208 Contains: 1,2-benzisothiazol-3(2H)-one (BIT) May produce an allergic reaction. 2.3 Other hazards: Dust may form an explosive mixture in the atmosphere. Not fulfilling PBT (persistent/bioaccumulative/toxic) criteria Not fulfilling vpvb (very persistent/very bioaccummulative) criteria EU SDS_FR / EN - Conforms to regulation (EU) 2015/830 Page: 1/7

2 SECTION 3: Composition/information on ingredients 3.1 Mixture: Starch based mixture. Chemical name Concentra tion CAS-No. EC No. Classification according to Specific concentration limit: REACH Registration No. Regulation (EC) No 1272/2008 (CLP) Starch >86% NC Exempted (Annex IV). Calcium dihydroxide >1 - <5% Eye Dam. 1 H318 Skin Irrit. 2 H315 STOT SE 3 H XXXX sodium carbonate >1 - <5% Eye Irrit. 2 H xxxx 1,2-benzisothiazol-3(2H)-one (BIT) >0,005 - <0,05% Acute Tox. 4 H302 Skin Irrit. 2 H315 Eye Dam. 1 H318 Skin Sens. 1 H317 Aquatic Acute 1 H400 Skin Sens. 1 H317 : >= 0,05 % Exempted 2-Methyl-2H-isothiazol-3-one (MIT) <0,05% Acute Tox. 4 H302+H332 Skin Corr. 1B H314 Aquatic Acute 1 H400 Exempted SECTION 4: First aid measures 4.1 Description of first aid measures: Inhalation: Move the exposed person to fresh air at once. Get medical attention if any discomfort continues. Eye contact: Skin contact: Ingestion: 4.2 Most important symptoms and effects, both acute and delayed: Flush thoroughly with water for at least 15 minutes. Get medical assistance. Brush off loose particles from skin. Remove contaminated clothing. Rinse the skin immediately with lots of water. Get medical attention if symptoms occur. Do not induce vomiting. Rinse mouth. Get medical attention immediately. Dust may irritate the eyes and the respiratory system. May cause eye irritation. May produce corrosive solutions on contact with water. 4.3 Indication of any immediate medical attention and special treatment needed: Treatment: Treat symptomatically. EU SDS_FR / EN - Conforms to regulation (EU) 2015/830 Page: 2/7

3 SECTION 5: Firefighting measures 5.1 Extinguishing media: Suitable extinguishing media: Unsuitable extinguishing media: 5.2 Special hazards arising from the substance or mixture: Water spray. Dry chemicals or foams. Fire or excessive heat may produce hazardous decomposition products. Dust may form an explosive mixture in the atmosphere. See Section Advice for firefighters: Special Fire Fighting Procedures: Special protective equipment for fire-fighters: Prevent dust cloud. Firefighters must use standard protective equipment including flame retardant coat, helmet with face shield, gloves, rubber boots, and in enclosed spaces, SCBA. SECTION 6: Accidental release measures 6.1 Personal precautions, protective equipment and emergency procedures: 6.2 Environmental precautions: 6.3 Methods and material for containment and cleaning up: 6.4 Reference to other sections: See Section 8 of the SDS for Personal Protective Equipment. Avoid discharge into drains, water courses or onto the ground. Remove material, as much as possible, using mechanical equipment. Prevent dust cloud. Collect and dispose of spillage as indicated in section 13 of the SDS. For waste disposal, see section 13 of the SDS. SECTION 7: Handling and storage 7.1 Precautions for safe handling: 7.2 Conditions for safe storage, including any incompatibilities: Avoid generation and spreading of dust. See Section 8 of the SDS for Personal Protective Equipment. Store in original container. Store at room temperature. Store in a dry place. Keep away from water. 7.3 Specific end use(s): Glue, SECTION 8: Exposure controls/personal protection 8.1 Control parameters: Occupational exposure limits: EU SDS_FR / EN - Conforms to regulation (EU) 2015/830 Page: 3/7

4 Chemical name Type Exposure Limit Values Source Calcium dihydroxide TWA 5 mg/m3 EU. Indicative Exposure Limit Values in Directives 91/322/EEC, 2000/39/EC, 2006/15/EC, 2009/161/EU Calcium dihydroxide ( ) VME 5 mg/m3 France. Threshold Limit Values (VLEP) for Occupational Exposure to Chemicals in France, INRS ED 984 ( ) 8.2 Exposure controls: Appropriate engineering controls: Ventilate as needed to control airborne dust. Use explosion-proof ventilation equipment if airborne dust levels are high. Individual protection measures, such as personal protective equipment: Eye/face protection: Wear dust-resistant safety goggles where there is danger of eye contact. (EN 166) Skin protection: Hand Protection: Chemical resistant gloves. (EN 374) Other: Respiratory Protection: Hygiene measures: Environmental exposure controls: Wear appropriate clothing to prevent any possibility of skin contact. In case of inadequate ventilation or risk of inhalation of dust, use suitable respiratory equipment with particle filter (type P1). (EN 143) Handle the product in accordance with the good hygiene practices and safety instructions. Avoid discharge to the aquatic environment. SECTION 9: Physical and chemical properties 9.1 Information on basic physical and chemical properties: Physical State: solid Form: Powder Water, moisture: ~ 10 % Color: Light brown Odor: ph: ~ 12,1 at 20 % Melting Point: Boiling Point: Flash Point: Vapor pressure: Vapor density (air=1): Relative density: Not determined. Solubility in Water: The product is partly soluble in water. ~ 6,2 %(w/w) 9.2 Other information: EU SDS_FR / EN - Conforms to regulation (EU) 2015/830 Page: 4/7

5 SECTION 10: Stability and reactivity 10.1 Reactivity: Oxidizing agents. Acids. Material reacts with water Chemical stability: Material is stable under normal conditions Possibility of hazardous reactions: No hazardous reactions under ordinary conditions of use and storage. May produce corrosive solutions on contact with water Conditions to avoid: Prevent dust cloud. Dust clouds may be explosive under certain conditions. Avoid dust close to ignition sources Incompatible materials: Strong oxidizing substances. Strong Acids 10.6 Hazardous decomposition products: Carbon Dioxide. Carbon Monoxide. SECTION 11: Toxicological information 11.1 Information on toxicological effects: Acute toxicity: Skin irritation. : Test / Substance Species Result Exposure Remarks OECD 431 Mixture In vitro Not classified. - Internal data - Serious eye irritation : Sensitization : Repeated dose toxicity : Mutagenesis: Carcinogenicity: Reproductive toxicity: Remarks: Irritation of eyes and mucous membranes. May produce corrosive solutions on contact with water. SECTION 12: Ecological information No information is available on the mixture itself Toxicity: 12.2 Persistence and degradability: 12.3 Bioaccumulative potential: 12.4 Mobility in soil: 12.5 Results of PBT and vpvb assessment: This mixture does not contain any substances that are assessed to be a PBT or a vpvb Other adverse effects: None known. EU SDS_FR / EN - Conforms to regulation (EU) 2015/830 Page: 5/7

6 SECTION 13: Disposal considerations 13.1 Waste treatment methods: Product: Packaging material: Dispose of waste in an appropriate authorised treatment facility in accordance with regulations in force and product characteristics at time of disposal. Single use packaging. Dispose of in the same way as the product SECTION 14: Transport information 14.1 UN number: 14.2 UN proper shipping name: 14.3 Transport hazard class(es): 14.4 Packing group: Other information: ADR/RID IATA IMDG ADN NC NC NC NC 14.5 Environmental hazards: Not classified 14.6 Special precautions for user: Not relevant Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code: Not applicable. SECTION 15: Regulatory information 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture: This Safety Data Sheet conforms to regulation (EU) No 453/2010 amending annex II of regulation (EC) No 1907/2006 (REACH) Chemical safety assessment: Not Available SECTION 16: Other information Revision Information: Key literature references and sources for data: Not relevant. Suppliers's SDS. - Internal data - H319 : Causes serious eye irritation. Eye Irrit.: Serious eye irritation P305+P351+P338 ; P337+P313: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to remove. Continue rinsing. ; If eye irritation persists: Get medical advice/attention. P264 ; P280: Wash hands thoroughly after handling. ; Wear eye protection. Abbreviations and acronyms used in the SDS.: CAS: Chemical Abstracts Service (division of the American Chemical Society) NC: Not Classified CLP : Classification, Labelling and Packaging. PBT: Persistent, Bioaccumulative and Toxic REACH : Registration, Evaluation, Authorisation and Restriction of Chemicals. vpvb: very persistent and very bioaccumulative substance. EU SDS_FR / EN - Conforms to regulation (EU) 2015/830 Page: 6/7

7 Disclaimer: The information provided in this Safety Data Sheet (SDS) relates only to the specific product designated and may not be applicable when such product is used in combination with other materials or in any process. It is the responsibility of the user to be aware of and to follow the regulations applying to our product for its possession, handling and use. The information given is designed only as a guidance and is not to be considered a warranty or quality specification. All information and instructions provided in this SDS are based on the current state of our knowledge at the latest revision date indicated. EU SDS_FR / EN - Conforms to regulation (EU) 2015/830 Page: 7/7