Pan Pucks Pee-Wee Safety Data Sheet

Transcription

1 Pan Pucks Pee-Wee SECTION 1: Product and company identification Product name : Pan Pucks Pee-Wee Use of the substance/mixture : Cleaner Product code : Company : Share Corporation P.O. Box Milwaukee, WI USA T (414) Emergency number : Chemtrec: (800) SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification (GHS-US) Acute Tox. 4 (Oral) H302 Skin Irrit. 2 H315 Eye Dam. 1 H318 Full text of H-phrases: see section Label elements GHS-US labeling Hazard pictograms (GHS-US) : Signal word (GHS-US) Hazard statements (GHS-US) Precautionary statements (GHS-US) 2.3. Other hazards 2.4. Unknown acute toxicity (GHS US) Not applicable : Danger GHS05 SECTION 3: Composition/information on ingredients 3.1. Substance Not applicable Full text of H-phrases: see section Mixture GHS07 : Harmful if swallowed Causes skin irritation Causes serious eye damage : Wash thoroughly after handling Do not eat, drink or smoke when using this product Wear protective gloves, eye protection, face protection If swallowed: Call a doctor, a POISON CENTER if you feel unwell If on skin: Wash with plenty of water If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing Immediately call a doctor, a POISON CENTER Specific treatment (see First aid measures on this label) Rinse mouth If skin irritation occurs: Get medical advice/attention Take off contaminated clothing and wash before reuse Dispose of contents/container to comply with local/regional/national/international regulations Name Product identifier % Classification (GHS-US) urea (CAS No) Skin Irrit. 2, H315 Eye Irrit. 2A, H319 STOT SE 3, H335 BENZALKONIUM CHLORIDE (CAS No) Acute Tox. 3 (Oral), H301 Acute Tox. 4 (Dermal), H312 Skin Corr. 1B, H314 Eye Dam. 1, H318 Aquatic Acute 1, H400 Aquatic Chronic 1, H410 Date of issue: 10/30/2015 Revision date: 05/07/2015 Version: 1.0 P GHS SDS Page 1 of 5

2 Pan Pucks Pee-Wee SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures general : If you feel unwell, seek medical advice (show the label where possible). Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. First-aid measures after inhalation : Remove person to fresh air and keep comfortable for breathing. Call a physician immediately. First-aid measures after skin contact : Take off immediately all contaminated clothing and wash it before reuse. Wash immediately with lots of water. If skin irritation or rash occurs: Get medical advice/attention. First-aid measures after eye contact : Rinse immediately with plenty of water. Call a physician immediately. First-aid measures after ingestion : Do NOT induce vomiting. Rinse mouth with water. Drink plenty of water. Get immediate medical advice/attention Most important symptoms and effects, both acute and delayed Symptoms/injuries : Harmful if swallowed. Causes serious eye damage. Causes skin irritation. Symptoms/injuries after skin contact : Causes skin irritation. Symptoms/injuries after eye contact : Causes serious eye damage Symptoms/injuries after ingestion : Harmful if swallowed Indication of any immediate medical attention and special treatment needed Treat symptomatically. SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media : All extinguishing media allowed Special hazards arising from the substance or mixture Reactivity : On burning: release of toxic and corrosive gases/vapours (hydrogen chloride, phosgene, chlorine, carbon monoxide - carbon dioxide) Advice for firefighters Firefighting instructions : Exercise caution when fighting any chemical fire. Use water spray or fog for cooling exposed containers. Take account of environmentally hazardous firefighting water. Protection during firefighting : Do not enter fire area without proper protective equipment, including respiratory protection. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures General measures : Isolate from fire, if possible, without unnecessary risk For non-emergency personnel Protective equipment : Protective goggles. Gloves. Protective clothing. Emergency procedures : Evacuate unnecessary personnel. Avoid contact with skin, eyes and clothing. Ventilate spillage area For emergency responders Protective equipment : Equip cleanup crew with proper protection. Emergency procedures : Stop leak if safe to do so. Stop release. Ventilate area Environmental precautions Avoid release to the environment. Prevent entry to sewers and public waters Methods and material for containment and cleaning up For containment : Contain released substance, pump into suitable containers. Methods for cleaning up : This material and its container must be disposed of in a safe way, and as per local legislation Reference to other sections SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling : Comply with the legal requirements. Do not handle until all safety precautions have been read and understood. Use personal protective equipment as required. Do not eat, drink or smoke when using this product. Do not get in eyes, on skin, or on clothing. Hygiene measures : Wash thoroughly after handling. Wash contaminated clothing before reuse Conditions for safe storage, including any incompatibilities Technical measures : Comply with applicable regulations. Storage conditions : Keep container closed when not in use. Storage area : Meet the legal requirements. Store in a cool area. Store in a well-ventilated place. Special rules on packaging : meet the legal requirements. Date of issue: 10/30/2015 Revision date: 05/07/2015 Version: 1.0 P GHS SDS Page 2 of 5

3 Pan Pucks Pee-Wee SECTION 8: Exposure controls/personal protection 8.1. Control parameters 8.2. Exposure controls Personal protective equipment : Use appropriate personal protective equipment when risk assessment indicates this is necessary. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Solid Appearance Odor Odor threshold ph Melting point Freezing point Boiling point Flash point Relative evaporation rate (butyl acetate=1) Flammability (solid, gas) Explosion limits Explosive properties Oxidizing properties Vapor pressure Relative density Relative vapor density at 20 C Solubility Log Pow Log Kow Auto-ignition temperature Decomposition temperature Viscosity Viscosity, kinematic Viscosity, dynamic SECTION 10: Stability and reactivity : Solid. : Fresh : 8.3 (10% solution) Reactivity On burning: release of toxic and corrosive gases/vapours (hydrogen chloride, phosgene, chlorine, carbon monoxide - carbon dioxide) Chemical stability Possibility of hazardous reactions Refer to section 10.1 on Reactivity Conditions to avoid Incompatible materials Hazardous decomposition products On burning: release of toxic and corrosive gases/vapors phosgene hydrogen chloride chlorine carbon monoxide - carbon dioxide. SECTION 11: Toxicological information Information on toxicological effects Acute toxicity : Oral: Harmful if swallowed. Date of issue: 10/30/2015 Revision date: 05/07/2015 Version: 1.0 P GHS SDS Page 3 of 5

4 Pan Pucks Pee-Wee LD50 oral rat LD50 dermal rat LD50 dermal rabbit ATE CLP (oral) 8471 mg/kg (Rat; OECD 401: Acute Oral Toxicity; Literature study; mg/kg bodyweight; Rat; Experimental value) > 3200 mg/kg (Rat; Literature study) > mg/kg (Rabbit; Literature study) mg/kg body weight Skin corrosion/irritation : Causes skin irritation. Not classified. ph: 8.3 (10% solution) Serious eye damage/irritation : Causes serious eye damage. ph: 8.3 (10% solution) Respiratory or skin sensitization : Not classified Germ cell mutagenicity : Not classified Carcinogenicity : Not classified Reproductive toxicity : Not classified Specific target organ toxicity (single exposure) : Not classified. Specific target organ toxicity (repeated exposure) Aspiration hazard Symptoms/injuries after skin contact Symptoms/injuries after eye contact Symptoms/injuries after ingestion : Not classified : Not classified : Causes skin irritation. : Causes serious eye damage. : Harmful if swallowed. SECTION 12: Ecological information Toxicity LC50 fish 1 EC50 Daphnia 1 LC50 fish 2 EC50 Daphnia 2 TLM fish 1 Threshold limit other aquatic organisms 1 Threshold limit other aquatic organisms 2 Threshold limit algae 1 Threshold limit algae 2 > 6810 mg/l (96 h; Leuciscus idus; Nominal concentration) > mg/l (48 h; Daphnia magna; Nominal concentration) mg/l (96 h; Poecilia reticulata) > mg/l (24 h; Daphnia magna) ppm (96 h; Poecilia reticulata) mg/l (16 h; Bacteria; Toxicity test) > mg/l (Pseudomonas putida) > mg/l (168 h; Scenedesmus quadricauda; Growth rate) 47 mg/l (192 h; Microcystis aeruginosa; Growth rate) Persistence and degradability Persistence and degradability ThOD Inherently biodegradable. Hydrolysis in water. Highly mobile in soil g O /g substance Bioaccumulative potential BCF fish 1 BCF other aquatic organisms 1 Log Pow Bioaccumulative potential 1 (72 h; Brachydanio rerio; Fresh water) (Chlorella sp.) < (Experimental value; EU Method A.8: Partition Coefficient) Bioaccumulation: not applicable. SECTION 13: Disposal considerations Waste treatment methods Waste treatment methods : Dispose of contents/container to comply with local/regional/national/international regulations. Waste disposal recommendations : Dispose of contents/container to local/regional/national regulations. SECTION 14: Transport information Department of Transportation (DOT) Date of issue: 10/30/2015 Revision date: 05/07/2015 Version: 1.0 P GHS SDS Page 4 of 5

5 Pan Pucks Pee-Wee In accordance with DOT : Additional information Other information ADR Transport by sea Air transport Not regulated for transport SECTION 15: Regulatory information : No supplementary information available. All components of this product are listed, or excluded from listing, on the United States Environmental Protection Agency Toxic Substances Control Act (TSCA) inventory This product or mixture does not contain a toxic chemical or chemicals in excess of the applicable de minimis concentration as specified in 40 CFR (a) subject to the reporting requirements of section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372. California Proposition 65 - This product does not contain a substance(s) known to the state of California to cause cancer and/or reproductive toxicity SECTION 16: Other information Training advice : Normal use of this product shall imply use in accordance with the instructions on the packaging. Full text of H-phrases: Acute Tox. 3 (Oral) Acute toxicity (oral) Category Acute Tox. 4 (Dermal) Acute toxicity (dermal) Category Acute Tox. 4 (Oral) Acute toxicity (oral) Category Aquatic Acute 1 Hazardous to the aquatic environment - Acute Hazard Category Aquatic Chronic 1 Hazardous to the aquatic environment - Chronic Hazard Category Eye Dam. 1 Serious eye damage/eye irritation Category Eye Irrit. 2A Serious eye damage/eye irritation Category 2A Skin Corr. 1B Skin corrosion/irritation Category 1B Skin Irrit. 2 Skin corrosion/irritation Category STOT SE 3 Specific target organ toxicity (single exposure) Category H301 Toxic if swallowed H302 Harmful if swallowed H312 Harmful in contact with skin H314 Causes severe skin burns and eye damage H315 Causes skin irritation H318 Causes serious eye damage H319 Causes serious eye irritation H335 May cause respiratory irritation H400 Very toxic to aquatic life H410 Very toxic to aquatic life with long lasting effects NFPA health hazard : 2 - Intense or continued exposure could cause temporary incapacitation or possible residual injury unless prompt medical attention is given. NFPA fire hazard : 0 - Materials that will not burn. NFPA reactivity : 0 - Normally stable, even under fire exposure conditions, and are not reactive with water. Prepared by: Technical Department This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product. No warranty is expressed or implied regarding the accuracy of this data or the results obtained from the use thereof. Our company assumes no responsibility for personal injury or property damage to the vendee, users or third parties caused by the material. Such vendees or users assume all risks associated with the use of this material. Date of issue: 10/30/2015 Revision date: 05/07/2015 Version: 1.0 P GHS SDS Page 5 of 5

6 Pan Pucks Junior SECTION 1: Product and company identification Product name : Pan Pucks Junior Use of the substance/mixture : Cleaner Product code : Company : Share Corporation P.O. Box Milwaukee, WI USA T (414) Emergency number : Chemtrec: (800) SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification (GHS-US) Acute Tox. 4 (Oral) H302 Skin Irrit. 2 H315 Eye Dam. 1 H318 Full text of H-phrases: see section Label elements GHS-US labeling Hazard pictograms (GHS-US) : Signal word (GHS-US) Hazard statements (GHS-US) Precautionary statements (GHS-US) 2.3. Other hazards 2.4. Unknown acute toxicity (GHS US) Not applicable : Danger GHS05 SECTION 3: Composition/information on ingredients 3.1. Substance Not applicable Full text of H-phrases: see section Mixture GHS07 : Harmful if swallowed Causes skin irritation Causes serious eye damage : Wash thoroughly after handling Do not eat, drink or smoke when using this product Wear protective gloves, eye protection, face protection If swallowed: Call a doctor, a POISON CENTER if you feel unwell If on skin: Wash with plenty of water If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing Immediately call a doctor, a POISON CENTER Specific treatment (see First aid measures on this label) Rinse mouth If skin irritation occurs: Get medical advice/attention Take off contaminated clothing and wash before reuse Dispose of contents/container to comply with local/regional/national/international regulations Name Product identifier % Classification (GHS-US) urea (CAS No) Skin Irrit. 2, H315 Eye Irrit. 2A, H319 STOT SE 3, H335 BENZALKONIUM CHLORIDE (CAS No) Acute Tox. 3 (Oral), H301 Acute Tox. 4 (Dermal), H312 Skin Corr. 1B, H314 Eye Dam. 1, H318 Aquatic Acute 1, H400 Aquatic Chronic 1, H410 Date of issue: 10/30/2015 Revision date: 05/07/2015 Version: 1.0 P GHS SDS Page 1 of 5

7 Pan Pucks Junior SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures general : If you feel unwell, seek medical advice (show the label where possible). Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. First-aid measures after inhalation : Remove person to fresh air and keep comfortable for breathing. Call a physician immediately. First-aid measures after skin contact : Take off immediately all contaminated clothing and wash it before reuse. Wash immediately with lots of water. If skin irritation or rash occurs: Get medical advice/attention. First-aid measures after eye contact : Rinse immediately with plenty of water. Call a physician immediately. First-aid measures after ingestion : Do NOT induce vomiting. Rinse mouth with water. Drink plenty of water. Get immediate medical advice/attention Most important symptoms and effects, both acute and delayed Symptoms/injuries : Harmful if swallowed. Causes serious eye damage. Causes skin irritation. Symptoms/injuries after skin contact : Causes skin irritation. Symptoms/injuries after eye contact : Causes serious eye damage Symptoms/injuries after ingestion : Harmful if swallowed Indication of any immediate medical attention and special treatment needed Treat symptomatically. SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media : All extinguishing media allowed Special hazards arising from the substance or mixture Reactivity : On burning: release of toxic and corrosive gases/vapours (hydrogen chloride, phosgene, chlorine, carbon monoxide - carbon dioxide) Advice for firefighters Firefighting instructions : Exercise caution when fighting any chemical fire. Use water spray or fog for cooling exposed containers. Take account of environmentally hazardous firefighting water. Protection during firefighting : Do not enter fire area without proper protective equipment, including respiratory protection. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures General measures : Isolate from fire, if possible, without unnecessary risk For non-emergency personnel Protective equipment : Protective goggles. Gloves. Protective clothing. Emergency procedures : Evacuate unnecessary personnel. Avoid contact with skin, eyes and clothing. Ventilate spillage area For emergency responders Protective equipment : Equip cleanup crew with proper protection. Emergency procedures : Stop leak if safe to do so. Stop release. Ventilate area Environmental precautions Avoid release to the environment. Prevent entry to sewers and public waters Methods and material for containment and cleaning up For containment : Contain released substance, pump into suitable containers. Methods for cleaning up : This material and its container must be disposed of in a safe way, and as per local legislation Reference to other sections SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling : Comply with the legal requirements. Do not handle until all safety precautions have been read and understood. Use personal protective equipment as required. Do not eat, drink or smoke when using this product. Do not get in eyes, on skin, or on clothing. Hygiene measures : Wash thoroughly after handling. Wash contaminated clothing before reuse Conditions for safe storage, including any incompatibilities Technical measures : Comply with applicable regulations. Storage conditions : Keep container closed when not in use. Storage area : Meet the legal requirements. Store in a cool area. Store in a well-ventilated place. Special rules on packaging : meet the legal requirements. Date of issue: 10/30/2015 Revision date: 05/07/2015 Version: 1.0 P GHS SDS Page 2 of 5

8 Pan Pucks Junior SECTION 8: Exposure controls/personal protection 8.1. Control parameters 8.2. Exposure controls Personal protective equipment : Use appropriate personal protective equipment when risk assessment indicates this is necessary. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Solid Appearance Odor Odor threshold ph Melting point Freezing point Boiling point Flash point Relative evaporation rate (butyl acetate=1) Flammability (solid, gas) Explosion limits Explosive properties Oxidizing properties Vapor pressure Relative density Relative vapor density at 20 C Solubility Log Pow Log Kow Auto-ignition temperature Decomposition temperature Viscosity Viscosity, kinematic Viscosity, dynamic SECTION 10: Stability and reactivity : Solid. : Fresh : 8.3 (10% solution) Reactivity On burning: release of toxic and corrosive gases/vapours (hydrogen chloride, phosgene, chlorine, carbon monoxide - carbon dioxide) Chemical stability Possibility of hazardous reactions Refer to section 10.1 on Reactivity Conditions to avoid Incompatible materials Hazardous decomposition products On burning: release of toxic and corrosive gases/vapors phosgene hydrogen chloride chlorine carbon monoxide - carbon dioxide. SECTION 11: Toxicological information Information on toxicological effects Acute toxicity : Oral: Harmful if swallowed. Date of issue: 10/30/2015 Revision date: 05/07/2015 Version: 1.0 P GHS SDS Page 3 of 5

9 Pan Pucks Junior LD50 oral rat LD50 dermal rat LD50 dermal rabbit ATE CLP (oral) 8471 mg/kg (Rat; OECD 401: Acute Oral Toxicity; Literature study; mg/kg bodyweight; Rat; Experimental value) > 3200 mg/kg (Rat; Literature study) > mg/kg (Rabbit; Literature study) mg/kg body weight Skin corrosion/irritation : Causes skin irritation. Not classified. ph: 8.3 (10% solution) Serious eye damage/irritation : Causes serious eye damage. ph: 8.3 (10% solution) Respiratory or skin sensitization : Not classified Germ cell mutagenicity : Not classified Carcinogenicity : Not classified Reproductive toxicity : Not classified Specific target organ toxicity (single exposure) : Not classified. Specific target organ toxicity (repeated exposure) Aspiration hazard Symptoms/injuries after skin contact Symptoms/injuries after eye contact Symptoms/injuries after ingestion : Not classified : Not classified : Causes skin irritation. : Causes serious eye damage. : Harmful if swallowed. SECTION 12: Ecological information Toxicity LC50 fish 1 EC50 Daphnia 1 LC50 fish 2 EC50 Daphnia 2 TLM fish 1 Threshold limit other aquatic organisms 1 Threshold limit other aquatic organisms 2 Threshold limit algae 1 Threshold limit algae 2 > 6810 mg/l (96 h; Leuciscus idus; Nominal concentration) > mg/l (48 h; Daphnia magna; Nominal concentration) mg/l (96 h; Poecilia reticulata) > mg/l (24 h; Daphnia magna) ppm (96 h; Poecilia reticulata) mg/l (16 h; Bacteria; Toxicity test) > mg/l (Pseudomonas putida) > mg/l (168 h; Scenedesmus quadricauda; Growth rate) 47 mg/l (192 h; Microcystis aeruginosa; Growth rate) Persistence and degradability Persistence and degradability ThOD Inherently biodegradable. Hydrolysis in water. Highly mobile in soil g O /g substance Bioaccumulative potential BCF fish 1 BCF other aquatic organisms 1 Log Pow Bioaccumulative potential 1 (72 h; Brachydanio rerio; Fresh water) (Chlorella sp.) < (Experimental value; EU Method A.8: Partition Coefficient) Bioaccumulation: not applicable. SECTION 13: Disposal considerations Waste treatment methods Waste treatment methods : Dispose of contents/container to comply with local/regional/national/international regulations. Waste disposal recommendations : Dispose of contents/container to local/regional/national regulations. SECTION 14: Transport information Department of Transportation (DOT) Date of issue: 10/30/2015 Revision date: 05/07/2015 Version: 1.0 P GHS SDS Page 4 of 5

10 Pan Pucks Junior In accordance with DOT : Additional information Other information ADR Transport by sea Air transport Not regulated for transport SECTION 15: Regulatory information : No supplementary information available. All components of this product are listed, or excluded from listing, on the United States Environmental Protection Agency Toxic Substances Control Act (TSCA) inventory This product or mixture does not contain a toxic chemical or chemicals in excess of the applicable de minimis concentration as specified in 40 CFR (a) subject to the reporting requirements of section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372. California Proposition 65 - This product does not contain a substance(s) known to the state of California to cause cancer and/or reproductive toxicity SECTION 16: Other information Training advice : Normal use of this product shall imply use in accordance with the instructions on the packaging. Full text of H-phrases: Acute Tox. 3 (Oral) Acute toxicity (oral) Category Acute Tox. 4 (Dermal) Acute toxicity (dermal) Category Acute Tox. 4 (Oral) Acute toxicity (oral) Category Aquatic Acute 1 Hazardous to the aquatic environment - Acute Hazard Category Aquatic Chronic 1 Hazardous to the aquatic environment - Chronic Hazard Category Eye Dam. 1 Serious eye damage/eye irritation Category Eye Irrit. 2A Serious eye damage/eye irritation Category 2A Skin Corr. 1B Skin corrosion/irritation Category 1B Skin Irrit. 2 Skin corrosion/irritation Category STOT SE 3 Specific target organ toxicity (single exposure) Category H301 Toxic if swallowed H302 Harmful if swallowed H312 Harmful in contact with skin H314 Causes severe skin burns and eye damage H315 Causes skin irritation H318 Causes serious eye damage H319 Causes serious eye irritation H335 May cause respiratory irritation H400 Very toxic to aquatic life H410 Very toxic to aquatic life with long lasting effects NFPA health hazard : 2 - Intense or continued exposure could cause temporary incapacitation or possible residual injury unless prompt medical attention is given. NFPA fire hazard : 0 - Materials that will not burn. NFPA reactivity : 0 - Normally stable, even under fire exposure conditions, and are not reactive with water. Prepared by: Technical Department This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product. No warranty is expressed or implied regarding the accuracy of this data or the results obtained from the use thereof. Our company assumes no responsibility for personal injury or property damage to the vendee, users or third parties caused by the material. Such vendees or users assume all risks associated with the use of this material. Date of issue: 10/30/2015 Revision date: 05/07/2015 Version: 1.0 P GHS SDS Page 5 of 5

11 Pan Pucks Pro SECTION 1: Product and company identification Product name : Pan Pucks Pro Use of the substance/mixture : Cleaner Product code : Company : Share Corporation P.O. Box Milwaukee, WI USA T (414) Emergency number : Chemtrec: (800) SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification (GHS-US) Acute Tox. 4 (Oral) H302 Skin Irrit. 2 H315 Eye Dam. 1 H318 Full text of H-phrases: see section Label elements GHS-US labeling Hazard pictograms (GHS-US) : Signal word (GHS-US) Hazard statements (GHS-US) Precautionary statements (GHS-US) 2.3. Other hazards 2.4. Unknown acute toxicity (GHS US) Not applicable : Danger GHS05 SECTION 3: Composition/information on ingredients 3.1. Substance Not applicable Full text of H-phrases: see section Mixture GHS07 : Harmful if swallowed Causes skin irritation Causes serious eye damage : Wash thoroughly after handling Do not eat, drink or smoke when using this product Wear protective gloves, eye protection, face protection If swallowed: Call a doctor, a POISON CENTER if you feel unwell If on skin: Wash with plenty of water If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing Immediately call a doctor, a POISON CENTER Specific treatment (see First aid measures on this label) Rinse mouth If skin irritation occurs: Get medical advice/attention Take off contaminated clothing and wash before reuse Dispose of contents/container to comply with local/regional/national/international regulations Name Product identifier % Classification (GHS-US) urea (CAS No) Skin Irrit. 2, H315 Eye Irrit. 2A, H319 STOT SE 3, H335 BENZALKONIUM CHLORIDE (CAS No) Acute Tox. 3 (Oral), H301 Acute Tox. 4 (Dermal), H312 Skin Corr. 1B, H314 Eye Dam. 1, H318 Aquatic Acute 1, H400 Aquatic Chronic 1, H410 Date of issue: 10/30/2015 Revision date: 05/07/2015 Version: 1.0 P GHS SDS Page 1 of 5

12 Pan Pucks Pro SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures general : If you feel unwell, seek medical advice (show the label where possible). Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. First-aid measures after inhalation : Remove person to fresh air and keep comfortable for breathing. Call a physician immediately. First-aid measures after skin contact : Take off immediately all contaminated clothing and wash it before reuse. Wash immediately with lots of water. If skin irritation or rash occurs: Get medical advice/attention. First-aid measures after eye contact : Rinse immediately with plenty of water. Call a physician immediately. First-aid measures after ingestion : Do NOT induce vomiting. Rinse mouth with water. Drink plenty of water. Get immediate medical advice/attention Most important symptoms and effects, both acute and delayed Symptoms/injuries : Harmful if swallowed. Causes serious eye damage. Causes skin irritation. Symptoms/injuries after skin contact : Causes skin irritation. Symptoms/injuries after eye contact : Causes serious eye damage Symptoms/injuries after ingestion : Harmful if swallowed Indication of any immediate medical attention and special treatment needed Treat symptomatically. SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media : All extinguishing media allowed Special hazards arising from the substance or mixture Reactivity : On burning: release of toxic and corrosive gases/vapours (hydrogen chloride, phosgene, chlorine, carbon monoxide - carbon dioxide) Advice for firefighters Firefighting instructions : Exercise caution when fighting any chemical fire. Use water spray or fog for cooling exposed containers. Take account of environmentally hazardous firefighting water. Protection during firefighting : Do not enter fire area without proper protective equipment, including respiratory protection. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures General measures : Isolate from fire, if possible, without unnecessary risk For non-emergency personnel Protective equipment : Protective goggles. Gloves. Protective clothing. Emergency procedures : Evacuate unnecessary personnel. Avoid contact with skin, eyes and clothing. Ventilate spillage area For emergency responders Protective equipment : Equip cleanup crew with proper protection. Emergency procedures : Stop leak if safe to do so. Stop release. Ventilate area Environmental precautions Avoid release to the environment. Prevent entry to sewers and public waters Methods and material for containment and cleaning up For containment : Contain released substance, pump into suitable containers. Methods for cleaning up : This material and its container must be disposed of in a safe way, and as per local legislation Reference to other sections SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling : Comply with the legal requirements. Do not handle until all safety precautions have been read and understood. Use personal protective equipment as required. Do not eat, drink or smoke when using this product. Do not get in eyes, on skin, or on clothing. Hygiene measures : Wash thoroughly after handling. Wash contaminated clothing before reuse Conditions for safe storage, including any incompatibilities Technical measures : Comply with applicable regulations. Storage conditions : Keep container closed when not in use. Storage area : Meet the legal requirements. Store in a cool area. Store in a well-ventilated place. Special rules on packaging : meet the legal requirements. Date of issue: 10/30/2015 Revision date: 05/07/2015 Version: 1.0 P GHS SDS Page 2 of 5

13 Pan Pucks Pro SECTION 8: Exposure controls/personal protection 8.1. Control parameters 8.2. Exposure controls Personal protective equipment : Use appropriate personal protective equipment when risk assessment indicates this is necessary. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Solid Appearance Odor Odor threshold ph Melting point Freezing point Boiling point Flash point Relative evaporation rate (butyl acetate=1) Flammability (solid, gas) Explosion limits Explosive properties Oxidizing properties Vapor pressure Relative density Relative vapor density at 20 C Solubility Log Pow Log Kow Auto-ignition temperature Decomposition temperature Viscosity Viscosity, kinematic Viscosity, dynamic SECTION 10: Stability and reactivity : Solid. : Fresh : 8.3 (10% solution) Reactivity On burning: release of toxic and corrosive gases/vapours (hydrogen chloride, phosgene, chlorine, carbon monoxide - carbon dioxide) Chemical stability Possibility of hazardous reactions Refer to section 10.1 on Reactivity Conditions to avoid Incompatible materials Hazardous decomposition products On burning: release of toxic and corrosive gases/vapors phosgene hydrogen chloride chlorine carbon monoxide - carbon dioxide. SECTION 11: Toxicological information Information on toxicological effects Acute toxicity : Oral: Harmful if swallowed. Date of issue: 10/30/2015 Revision date: 05/07/2015 Version: 1.0 P GHS SDS Page 3 of 5

14 Pan Pucks Pro LD50 oral rat LD50 dermal rat LD50 dermal rabbit ATE CLP (oral) 8471 mg/kg (Rat; OECD 401: Acute Oral Toxicity; Literature study; mg/kg bodyweight; Rat; Experimental value) > 3200 mg/kg (Rat; Literature study) > mg/kg (Rabbit; Literature study) mg/kg body weight Skin corrosion/irritation : Causes skin irritation. Not classified. ph: 8.3 (10% solution) Serious eye damage/irritation : Causes serious eye damage. ph: 8.3 (10% solution) Respiratory or skin sensitization : Not classified Germ cell mutagenicity : Not classified Carcinogenicity : Not classified Reproductive toxicity : Not classified Specific target organ toxicity (single exposure) : Not classified. Specific target organ toxicity (repeated exposure) Aspiration hazard Symptoms/injuries after skin contact Symptoms/injuries after eye contact Symptoms/injuries after ingestion : Not classified : Not classified : Causes skin irritation. : Causes serious eye damage. : Harmful if swallowed. SECTION 12: Ecological information Toxicity LC50 fish 1 EC50 Daphnia 1 LC50 fish 2 EC50 Daphnia 2 TLM fish 1 Threshold limit other aquatic organisms 1 Threshold limit other aquatic organisms 2 Threshold limit algae 1 Threshold limit algae 2 > 6810 mg/l (96 h; Leuciscus idus; Nominal concentration) > mg/l (48 h; Daphnia magna; Nominal concentration) mg/l (96 h; Poecilia reticulata) > mg/l (24 h; Daphnia magna) ppm (96 h; Poecilia reticulata) mg/l (16 h; Bacteria; Toxicity test) > mg/l (Pseudomonas putida) > mg/l (168 h; Scenedesmus quadricauda; Growth rate) 47 mg/l (192 h; Microcystis aeruginosa; Growth rate) Persistence and degradability Persistence and degradability ThOD Inherently biodegradable. Hydrolysis in water. Highly mobile in soil g O /g substance Bioaccumulative potential BCF fish 1 BCF other aquatic organisms 1 Log Pow Bioaccumulative potential 1 (72 h; Brachydanio rerio; Fresh water) (Chlorella sp.) < (Experimental value; EU Method A.8: Partition Coefficient) Bioaccumulation: not applicable. SECTION 13: Disposal considerations Waste treatment methods Waste treatment methods : Dispose of contents/container to comply with local/regional/national/international regulations. Waste disposal recommendations : Dispose of contents/container to local/regional/national regulations. SECTION 14: Transport information Department of Transportation (DOT) Date of issue: 10/30/2015 Revision date: 05/07/2015 Version: 1.0 P GHS SDS Page 4 of 5

15 Pan Pucks Pro In accordance with DOT : Additional information Other information ADR Transport by sea Air transport Not regulated for transport SECTION 15: Regulatory information : No supplementary information available. All components of this product are listed, or excluded from listing, on the United States Environmental Protection Agency Toxic Substances Control Act (TSCA) inventory This product or mixture does not contain a toxic chemical or chemicals in excess of the applicable de minimis concentration as specified in 40 CFR (a) subject to the reporting requirements of section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372. California Proposition 65 - This product does not contain a substance(s) known to the state of California to cause cancer and/or reproductive toxicity SECTION 16: Other information Training advice : Normal use of this product shall imply use in accordance with the instructions on the packaging. Full text of H-phrases: Acute Tox. 3 (Oral) Acute toxicity (oral) Category Acute Tox. 4 (Dermal) Acute toxicity (dermal) Category Acute Tox. 4 (Oral) Acute toxicity (oral) Category Aquatic Acute 1 Hazardous to the aquatic environment - Acute Hazard Category Aquatic Chronic 1 Hazardous to the aquatic environment - Chronic Hazard Category Eye Dam. 1 Serious eye damage/eye irritation Category Eye Irrit. 2A Serious eye damage/eye irritation Category 2A Skin Corr. 1B Skin corrosion/irritation Category 1B Skin Irrit. 2 Skin corrosion/irritation Category STOT SE 3 Specific target organ toxicity (single exposure) Category H301 Toxic if swallowed H302 Harmful if swallowed H312 Harmful in contact with skin H314 Causes severe skin burns and eye damage H315 Causes skin irritation H318 Causes serious eye damage H319 Causes serious eye irritation H335 May cause respiratory irritation H400 Very toxic to aquatic life H410 Very toxic to aquatic life with long lasting effects NFPA health hazard : 2 - Intense or continued exposure could cause temporary incapacitation or possible residual injury unless prompt medical attention is given. NFPA fire hazard : 0 - Materials that will not burn. NFPA reactivity : 0 - Normally stable, even under fire exposure conditions, and are not reactive with water. Prepared by: Technical Department This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product. No warranty is expressed or implied regarding the accuracy of this data or the results obtained from the use thereof. Our company assumes no responsibility for personal injury or property damage to the vendee, users or third parties caused by the material. Such vendees or users assume all risks associated with the use of this material. Date of issue: 10/30/2015 Revision date: 05/07/2015 Version: 1.0 P GHS SDS Page 5 of 5