Identification of the substance/preparation and of the company/undertaking

Transcription

1 Conforms to 91/155/EEC 2001/58/EC United Kingdom (UK) SAFETY DATA SHEET FOOD GRADE NONBUTYL CLEANER/DEGREASER #31 1. Identification of the substance/preparation and of the company/undertaking Identification of the substance or preparation Product name Product No. Use of the substance/preparation Company/undertaking identification Manufacturer Supplier Emergency telephone number 2. FOOD GRADE NONBUTYL CLEANER/DEGREASER # SC Concentrated cleaner and degreaser Essential Industries, Inc. P.O. Box Essential Rd. Merton, WI USA Essential Industries, Inc. P.O. Box Essential Rd. Merton, WI USA Composition/information on ingredients Substance/Preparation Preparation CAS number % EC Number Classification poly(oxy1,2ethanediyl), Xn; R22.alpha.(nonylphenyl).omega.hydroxy 2Aminoethanol Xn; R20 Xi; R36/37/38 See Section 16 for the full text of the R Phrases declared above * Occupational Exposure Limit(s), if available, are listed in section 8 3. Hazards identification The preparation is classified as dangerous according to Directive 1999/45/EC and its amendments. Classification Xi; R36/38 Human health hazards Irritating to eyes and skin. See Section 11 for more detailed information on health effects and symptoms. 4. First aid measures Inhalation Ingestion First aid measures Skin contact Eye contact Specific treatments If inhaled, remove to fresh air. If breathing is difficult, give oxygen. If not breathing, give artificial respiration. Get medical attention. Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. If large quantities of this material are swallowed, call a physician immediately. In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Thoroughly clean shoes before reuse. Get medical attention immediately. In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Get medical attention immediately. See Section 11 for more detailed information on health effects and symptoms. Date of issue 5/11/2005. Page 1/5

2 FOOD GRADE NONBUTYL CLEANER/DEGREASER #31 5. Firefighting measures Extinguishing media Special exposure hazards Hazardous thermal decomposition products Special protective equipment for firefighters Remark Personal precautions Environmental Precautions and Cleanup Methods In case of fire, use water spray (fog), foam, dry chemical, or CO2. No specific hazard. These products are carbon oxides (CO, CO2), nitrogen oxides (NO, NO2...). Firefighters should wear positive pressure selfcontained breathing apparatus (SCBA) and full turnout gear. No additional remark. 6. Accidental release measures Immediately contact emergency personnel. Keep unnecessary personnel away. Use suitable protective equipment (Section 8). Follow all fire fighting procedures (Section 5). Minimize contact of spilled material with soils to prevent runoff to surface waterways. See Section 13 for Waste Disposal Information. If emergency personnel are unavailable, contain spilled material. For small spills add absorbent (soil may be used in the absence of other suitable materials) scoop up material and place in a sealed, liquidproof container for disposal. For large spills dike spilled material or otherwise contain material to ensure runoff does not reach a waterway. Place spilled material in an appropriate container for disposal. Note See section 8 for personal protective equipment and section 13 for waste disposal. 7. Handling Storage Handling and storage Packaging materials Recommended Specific uses Avoid contact with eyes, skin and clothing. Wash thoroughly after handling. Keep container tightly closed. Keep container in a cool, wellventilated area. Use original container. Industrial applications 8. Exposure controls/personal protection Occupational Exposure Limits 2Aminoethanol EH40OES (United Kingdom (UK), 2002). STEL 15 mg/m 3 15 minute(s). STEL 6 ppm 15 minute(s). TWA 7.6 mg/m 3 8 hour(s). TWA 3 ppm 8 hour(s). Recommended monitoring procedures Exposure controls Occupational exposure controls Respiratory protection Hand protection Eye protection Skin protection Good general ventilation should be sufficient to control airborne levels. Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapors below their respective occupational exposure limits. Ensure that eyewash stations and safety showers are proximal to the workstation location. A respirator is not needed under normal and intended conditions of product use. Use latex gloves. Double latex gloves should be considered. Safety glasses. Goggles, face shield, or other fullface protection if potential exists for direct exposure to aerosols or splashes. Additional body garments should be used based upon the task being performed (e.g., sleevelets, apron, gauntlets, disposable suits) to avoid exposed skin surfaces. Appropriate techniques should be used to remove potentially contaminated clothing. Date of issue 5/11/2005. Page 2/5

3 FOOD GRADE NONBUTYL CLEANER/DEGREASER #31 9. Physical and chemical properties General information Physical state Boiling Point Melting Point Relative density Solubility Octanol/water partition coefficient Viscosity Vapor Density Liquid. Odor Fresh. Important health, safety and environmental information ph Color Flash point Flammability (solid, gas) Explosive properties Evaporation rate (butyl acetate = 1) Other information 10. Appearance Oxidizing Properties Stability Conditions to avoid Purple Stability and reactivity Materials to avoid Hazardous decomposition products 11. Acute toxicity The lowest known value is 100 C (212 F) (water). Weighted average C (233.9 F) May start to solidify at C (51.1 F) based on data for 2Aminoethanol. Weighted average 1.83 C (35.3 F) Closed cup >93.3 C (199.9 F). Not applicable. Risks of explosion of the product in presence of mechanical impact Risks of explosion of the product in presence of static discharge Weighted average 0.11 g/cm 3 Easily soluble in cold water, hot water, methanol, acetone. Not determined. Not determined. The highest known value is 2.11 (Air = 1) (2Aminoethanol). The highest known value is 0.36 (water) Weighted average 0.3compared to Butyl acetate. The product is stable. Toxicological information Potential Acute Health Effects Inhalation Ingestion Skin contact Eye contact These products are carbon oxides (CO, CO2), nitrogen oxides (NO, NO2...). Test Result Route Species poly(oxy1,2ethanediyl), 1310 mg/kg Rat.alpha.(nonylphenyl).omega.hydrox 2Aminoethanol LDLo 1720 mg/kg 620 mg/kg 700 mg/kg 1400 mg/kg Rat Guinea pig Mouse Mammal Carcinogenicity No carcinogenic effect known. Mutagenicity No mutagenic effect. Reproductive toxicity No teratogenic effect. Overexposure signs/symptoms Target Organs No known acute effects of this product resulting from inhalation. May irritate digestive tract. Irritating to skin. Irritating to eyes. Date of issue 5/11/2005. Page 3/5

4 FOOD GRADE NONBUTYL CLEANER/DEGREASER #31 Other adverse effects 12. Contains material which causes damage to the following organs upper respiratory tract, skin, central nervous system (CNS), eye, lens or cornea. Ecological information Ecotoxicity Data Species Period Result poly(oxy1,2ethanediyl),.alpha.(nonylphenyl).omega.hydroxy 2Aminoethanol Mobility Other adverse effects 13. Disposal considerations Methods of disposal Waste Classification European Waste Catalogue (EWC) Hazardous Waste 14. International transport regulations Regulatory information ADR/RID Class 1.3 mg/l 4.7 mg/l 7.6 mg/l 7.9 mg/l >10 mg/l >1000 mg/l 150 mg/l 150 mg/l >200 mg/l 300 mg/l >300 mg/l mg/l Avoid contact of spilled material and runoff with soil and surface waterways. Dispose of according to all federal, state and local applicable regulations. Not applicable. Transport information The classification of the product may meet the criteria for a hazardous waste UN number Proper shipping name Class Packing Group Label Additional information Not ADN Class Not IMDG Class Not IATADGR Class Not 15. Regulatory information EU Regulations Hazard symbol(s) Risk phrases Irritant R36/38 Irritating to eyes and skin. Date of issue 5/11/2005. Page 4/5

5 FOOD GRADE NONBUTYL CLEANER/DEGREASER #31 Safety phrases Product Use EC Statistical Classification (Tariff Code) National regulations S24/25 Avoid contact with skin and eyes. S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S37/39 Wear suitable gloves and eye/face protection. S46 If swallowed, seek medical advice immediately and show this container or label. Classification and labeling have been performed according to EU directives 67/548/EEC, 1999/45/EC including amendments and the intended use. Industrial applications Other information Full text of R phrases referred to in Sections 2 and 3 United Kingdom (UK) R20 Harmful by inhalation. R22 Harmful if swallowed. R36/37/38 Irritating to eyes, respiratory system and skin. R36/38 Irritating to eyes and skin. Full text of classifications referred to in Sections 2 and 3 United Kingdom (UK) HISTORY Date of printing Date of issue Date of Previous Issue Version Prepared by Notice to Reader Xn Harmful Xi Irritant 5/11/ /11/2005. No Previous Validation. 1 Regulatory Affairs. To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor any of its subsidiaries assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist. Version 1 Page 5/5