ANNEXURES. 1 Google image showing proposed project site. 2 Plant Lay-out. 3 Details of Manufacturing process. 4 Details of hazardous waste management

Transcription

1 ANNEXURES Annexure No. Description 1 Google image showing proposed project site 2 Plant Lay-out 3 Details of Manufacturing process 4 Details of hazardous waste management 5 Details of Effluent Treatment Plant 6 Water Balance Diagram 7 Details of flue gas stacks 8 List of Products and Raw Materials Form-1 for Environmental Clearance Page

2 ANNEXURE-1 Google Image showing location of Proposed Project Site GPS Coordinates of all corners of Project Site: Key Map showing Project Site: Project Site Form-1 for Environmental Clearance Page

3 Google Image showing Project site and salient features: Nearest Residential Area of Sayla 0.3 km Proposed Project Site 0.3 km SH km NH 8A Form-1 for Environmental Clearance Page

4 Google Image showing surrounding area within 5 Km & 10 Km radius from Project Site: 5 km Radius Project Site 10 km Radius Project Site Form-1 for Environmental Clearance Page

5 ANNEXURE-2 Plant Lay-out Form-1 for Environmental Clearance Page

6 1. DIETHYL SAFRANINE: ANNEXURE-3 Detailed Manufacturing Processes Manufacturing Process 1 Charge Diethyl Aniline, conc. HCl and water in open watt. Charge ice for chilling. Charge sodium nitrite for diazotized it. Charge Zn-powder & Aniline into it then complete reaction by addition of sodium dichromate & calcium carbonate then heat & filter product. Take clear filtrate & charge salt. Pure Diethyl Safranine is isolate then dry & pulverized to get finished product. Reaction Chemistry Process Flow Diagram Diethyl aniline 200 KGS D M WATER 200KGS HCl 100kg Sodium nitrite 72 kgs Zn-dust 70kg OPEN WATT Chilled up to 0⁰C Filtration Zn-Powder 2 kg to be reused in next batch Calcium Carbonate 100 kgs Aniline 100kgs Sodium Dichromate 80kgs Stir mass under chilling for 4-5 hrs Salt 300kgs Heat Mass 90 C Centrifuge 900 kgs wastewater Drying 95kgs Drying loss Pulverizing Packing 225kgs (25 kgs *9 drum) Form-1 for Environmental Clearance Page

7 Mass Balance Sr. No. Input Qty Per Batch (Kg) Output 1. Diethyl Aniline 200 Zn powder (To be reused in next batch) 2. Water 200 Wastewater (To be treated in ETP) 3. HCl 100 Drying loss (To atmosphere through vent) Qty Per Batch (Kg) 2 4. Sodium Nitrite 72 Diethyl Safranine Zn Dust Calcium Carbonate Aniline Sodium 80 Dichromate 9. Salt 300 Total SAFRANINE-0: Manufacturing Process Charge Garnet GB, Conc. HCl and water in open watt. Charge ICE for chilling. Charge sodium Nitrite for diazotised it. Charge Fe-Powder & Aniline into it then complete reaction by addition of sodium Dichromate & Calcium Carbonate then heat & filter product. Take Clear filtrate & Charge Salt. Pure Diethyl Safranine is isolate then dry & pulverised it. Reaction Chemistry Form-1 for Environmental Clearance Page

8 Process Flow Diagram with Mass Balance Garnet GB 200 KGS D M WATER 1000KGS HCl 100kg OPEN WATT Sodium nitrite 72 kgs Fe-dust 90kg Ice 400kgs Chilled upto 0 C Filtration Fe-Powder 12kg Calcium Carbonate 40 kgs Aniline 100kgs Sodium Dichromate 60kgs Stir mass under chilling for 4-5hrs Salt 280kgs Heat Mass at 90 C Centrifuge 1990 kgs Wastewater Drying 60kgs Drying loss Pulverising Packing 280kgs (25 kgs *11 drum) Form-1 for Environmental Clearance Page

9 Mass Balance SR. NO. INPUT BATCH OUTPUT BATCH 1. Fe powder (To be Garnet GB 200 reused in next batch) Wastewater (To be Water 1000 treated in ETP) Drying loss (To HCl 100 atmosphere through 60 vent) 4. Sodium Nitrite 72 SAFRANINE Fe Dust ICE Calcium Carbonate Aniline Sodium Dichromate Salt 280 TOTAL JANUS GREEN B: Manufacturing Process Safranine, conc. HCl and water charge in open watt. Charge ice for chilling. Charge sodium nitrite for diazotised it. Charge Dimethyl Aniline into it then complete reaction by addition of Sodium Acetate & soda ash heat & filter product. Take clear filtrate & charge salt. Pure Janus Green-B is isolate then dry & pulverised it. Reaction Chemistry Form-1 for Environmental Clearance Page

10 Process Flow Diagram Safranine 200 KGS D M WATER 200KGS HCl 100kg Open watt 500 kgs Sodium nitrite 70kgs Chilled upto 0⁰C 570KGS Sodium Acetate 70kgs Dimethyl Aniline 100kgs Soda Ash 60kgs Stir for 2hrs 800 kgs Stir R.mass under chilling for 4 5hrs 800 kgs Salt 200kgs Heat 800kgs R. Mass 90 C Centrifuge 1000 KGS 700 kgs Water Drying 300 kgs 100kgs drying loss Pulverising 200 kgs Packing 200kgs (25 kgs*8 drum) Form-1 for Environmental Clearance Page

11 Mass Balance SR. NO. INPUT BATCH OUTPUT BATCH Safranine 200 Wastewater (To be treated in ETP) 2. Water 200 Drying loss (To 100 atmosphere through vent) 3. HCl 100 Janus Green B Sodium Nitrite Sodium Acetate Dimethyl Aniline Soda Ash Salt 200 TOTAL METHYLENE BLUE ZN FREE: Manufacturing Process Methylene Blue to be charged in open watt & purify it by Soda ash & EDTA. Then filter & Salt Out done by pure salt. The purified material is isolated which is Methylene Blue Zn Free. Reaction Chemistry Form-1 for Environmental Clearance Page

12 Process Flow Diagram Methyl blue 2b 200 kgs D m water 1000kgs Open watt 1200 kgs SODA ASH 32 kgs EDTA 10kg HEAT upto 90⁰C 1242KGS Salt 20kgs Filtration 1242 kgs Zn CARBONATE 50kg 800KGS ICE Stir R. mass under chilling for 1 2hrs 1992 kgs 2012kgs R. Mass Centrifuge 350 KGS 1662 kgs Water Drying 160 kgs 190kgs drying loss Pulverising 160 kgs Packing 160kgs (25 kgs *6 drum) Form-1 for Environmental Clearance Page

13 Mass Balance SR. NO. INPUT 1. Methylene Blue 2B 2. Water 3. Soda Ash 4. EDTA BATCH OUTPUT Zn carbonate (byproduct) Wastewater (To be treated in ETP) Drying loss (To atmosphere through vent) Methylene Blue Zn Free BATCH ICE Salt 20 TOTAL TITAN YELLOW: Manufacturing Process Dehydro Thio is diazotised in the presence of sodium nitrite under Conc. HCl & chilling condition, the reaction mixture is then coupled with the Dehydro Thio. The final product is filtered & centrifuged. Before packing material is dried in tray dryer & pulverised. Reaction Chemistry Form-1 for Environmental Clearance Page

14 Process Flow Diagram Dehydrothio para toluedene sulphonic acid (DTPT) 100 KGS D M WATER 300KGS HCl 60kg Open watt 460 kgs Sodium nitrite 35 kgs Ice 200kgs Chilled upto 0⁰C 695KGS 100 kgs DTPT Sodium Carbonate 80kgs Stir R. mass under chilling 875Kgs Stir R. mass under chilling for 4 5hrs 875kgs Salt 300kgs Heat R. Mass Centrifuge 380 KGS 795 kgs Water Drying 190 kgs 190 kgs Drying loss Pulverising 190kgs Packing 190kgs (25 kgs *7 drum) Form-1 for Environmental Clearance Page

15 Mass Balance SR. INPUT NO. 1. Dehydro Thio Para Toludine Sulphonic Acid (DTPT) 2. Water BATCH OUTPUT BATCH Wastewater (To be treated in ETP) 795 Drying loss (To atmosphere through vent) 3. HCl 60 Titan Yellow Sodium Nitrite ICE Sodium Carbonate Salt 300 TOTAL SUCCINIMIDE Manufacturing Process Charge Recycle water with Succinic acid in to reactor, then slowly purge Ammonia gas & heat to 200⁰C and maintain for 2 hours. After 100⁰C collect he water and same will be use in to next batch as raw water. Cool to 70-80⁰C unload the molten mass in to trays. This material will become solidifying after Cooling. 190 Reaction Chemistry H O N O HOOCCH 2 CH 2 COOH + NH 3 Succinic acid Ammonia Mol Wt: 118 g / Mol Mol Wt: 17 g / Mol Succinimide Mol Wt: 99 g / Mol Water Mol Wt: 36 g / Mol Process Flow Diagram: Succinic acid 596 kg Ammonia 86 kg Water 182 kg Charge Into reactor & Heat Up to 200 ⁰C for 2 Hrs. 500 kg 364 Kg. 182 Kg. Wastewater Tray Dryer 500 kg Finished Product Succinimide 500 Kg. Form-1 for Environmental Clearance Page

16 Mass Balance: SR. NO. 3 INPUT BATCH OUTPUT BATCH Succinic acid 596 Wastewater (To be recycled in next batch) 2 Recycled Water 182 Wastewater (To be 182 treated in ETP) Ammonia 86 Succinimide (Product) 500 Total N BROMO SUCCINIMIDE Manufacturing Process Charge water with succinimide in the reactor. In this solution add caustic and bromine solution. In second reactor prepare sodium hypo bromide solution and transfer in to 1 st reactor to dissolve succinimide (slowly at 20⁰C) and maintain it for 1 hr at 10 ⁰C. Centrifuge the solution after reaction take place. Glue water wash & dry in to try 65⁰C temp. Finish product is ready for packing. Reaction Chemistry Process Flow Diagram Succinimide 184 kg Water 1000 kg Caustic 74 kg +Water 150 lit Bromine 296 Kg Charge into reactor 1704 kg Centrifuge 1704 kg Product 330 kg Sodium Bromide 34 kg Wastewater 1150 kg Sodium Bromide Solution 190 Kg (Send to Bromine Recovery plant) Form-1 for Environmental Clearance Page

17 Mass Balance SR. NO. INPUT BATCH 1. Succinimide 184 OUTPUT BATCH Sodium Bromide Solution (by-product) Water 1150 Waste water Caustic Sodium bromide (byproduct) Bromine 296 N Bromo Succinimide 330 TOTAL N CHLORO SUCCINIMIDE Manufacturing Process Charge water & Succcinimide in the reactor. Add acetic acid to the solution. Maintain temperature up to 20⁰C. Further sodium hypo chloride is added slowly to make ph 8.5. Precipitation observed. Stir for 1 hr and then centrifuge & dry it for packing. Reaction Chemistry N N O O O O + NaOCl + CH 3 COOH +CH 3 COONa + H 2 O Succinimide Sodium Hypo chloride Acetic acid N Chloro Succinimide Sodium acetate Water Mol Wt: 99 g/mol Wt: 74 g/mol Mol Wt: 60 g/mol Mol Wt: 134 g/mol Mol Wt: 82 g/mol 18 g/mol Process Flow Diagram Succinimide 148 kg Water 27 Lit Sodium Hypochloride 110 kg Acetic Acid 90 kg Charge into Reactor 375 kg Centrifuge 375 kg Waste Water 54 lit Sodium Acetate 121kg Product 200 kg Form-1 for Environmental Clearance Page

18 Mass Balance SR. NO. INPUT BATCH OUTPUT BATCH 1 Succinimide 148 Waste water 54 2 Sodium acetate (byproduct) 121 Water 27 3 Sodium hypo chloride 110 N Chloro Succinimide Acetic acid 90 TOTAL BROMOHEXINE HCL (BP) Manufacturing Process Charge methanol in reactor then charge nitro cyclohexyl methyl benzyl amine in reactor, then charge catalyst. Then hydrogen gas is introduced to the reactor at 60 C. After the reaction catalyst is filtered. To the filtrate bromine is added slowly at 15 C after complete addition, reaction mass is stirred for 6 hours at room temperature. This is again chilled to 20 C and centrifuged ml is collected for recycle. The centrifuge cake is charged in reactor in ethanol to this dissolved mixture carbon is added and is stirred for 2 hours. This is then filtered. To the filtrate HCl is added at 10 C and stirred for 3 hours, this is then centrifuged and ml is recycled after distillation. Then product is dried and packed. Reaction Chemistry NO2 CH2 N HCl CH3 C14H20ClN2O2HCl H2 + 4 NH2 CH2 N CH3 C14H21N HCl + 2H2O NH2 2Br2 Br CH2 316 Br C14H20Br2N N CH3 + 2HBr Br NH2 CH2 N + HCl Br NH2 CH2 N HCl Br CH Br CH3 C14H20ClN2O2HCl C14H20ClN2O2HCl Form-1 for Environmental Clearance Page

19 Process Flow chart 2 Nitro n Cyclohexylmethyl Benzylamine HCL 300 Kg Methanol 1000 kg Hydrogen Gas- 2 Kg Catalyst Ranickel Reactor Bromine 325 Kg Centrifuge 1000 Kg Mother Liquor Recycle Ethanol 700 lit Carbon 5 Kg Reactor HCL 45 Kg Filter Centrifuge 812 Kg Mother Liquor Recycle Drying and packing 375 Kg Mass Balance SR. NO. INPUT BATCH OUTPUT 300 Mother liquor (To be recycled) BATCH 1. 2 Nitro N Cyclohexyl 1000 Methyl Benzyl Amine 2. Hydrogen 2 Drying Loss Methanol 1000 Mother liquor (To be 812 recycled) 4. Carbon 5 Bromohexine HCl Bromine HCL Ethanol 700 TOTAL Form-1 for Environmental Clearance Page

20 10. BRONOPOL (BP) Manufacturing Process Charge methanol in Reactor then charge nitro methane, formaldehyde, caustic lye slowly to the mixture. This is maintained for 3 hours at 20 C, after that charge bromine and maintain for 4 hours at 60 C, then methanol is recovered. After total methanol recovery, charge water& Carbon this is then stir for 1 Hr. Then carbon is filtered & water is distilled. The reaction mixture is chilled to 10 C & centrifuge & dry. Ml is sodium bromide solution & is collected separately. Reaction Chemistry CH3NO2 + 2HCHO + Br2 + NaOH * * Br NO2 OH + NaBr + H2O + NaBr + H2O HO C3H6O4NBr Process Flow chart Nitro Methane Methanol Caustic Formaldehyde Bromine 100 kgs 500 kgs 70 kgs 220 kgs 265 kgs Reactor Methanol 425 kg Distillation Residue 50 kg Distillation loss 150 kg Water Carbon 500 Kgs 5 kgs Filter Water Recycle 500 Kg Centrifuge Sodium Bromide Solution 130 kg Dryer Drying loss 105 Kg Product 300 Kg Form-1 for Environmental Clearance Page

21 Mass Balance SR. NO. INPUT BATCH OUTPUT BATCH 1. Water 500 Wastewater Nitro Methane 100 Methanol (Recovered) Methanol 500 Sodium Bromide 130 Solution 4. Caustic 70 Distillation residue Formaldehyde 220 Distillation loss Carbon 5 Drying Loss Bromine 265 Bronopol (BP) 300 TOTAL NICLOSAMIDE-BP Manufacturing Process Charge xylene in reactor and then add 5 nitro salicyclic acid at room temperature. This is stir for 1 hour and chilled to 10 C. then slowly charge thionyl chloride at 15 C and maintain for 3 hours. Then slowly charge orthochloro para nitro aniline then stir for 6 hours at 85 C. This is then cooled to room temperature and centrifuged. ML is collected and recycled. Then extra water is drained to ETP and product is dried and packed. Form-1 for Environmental Clearance Page

22 Reaction Chemistry Cl OH COO + 2SOCl2 2NaO 2 * 40 Cl OH COCl + NaCl + H2O + C7H5ClO3 + 2SOCl C7H4O2Cl2 + NaCl + H2O + NaHSO Cl Cl Cl OH COC + H2N NO O2N NHO OH C7H4O2Cl2 + C6H5N2O2Cl C13H8Cl2N2O4 Cl + HCl + HCl Process Flow chart Xylene 1000 kgs O.C.P.N.A 180 kgs Thionylchloride 135 kgs 5 Chloro Salicylic Acid 175 kgs Water 600 kgs Reactor ML Recycle 1200 Kg Centrifuge Wastewater 440 kg Dryer Drying loss 100 Kg Product 350 Kg Form-1 for Environmental Clearance Page

23 Mass Balance SR. INPUT OUTPUT NO. BATCH BATCH 1. Water 600 Waste Water Xylene 1000 Water ML Re Use Ortho Chloro Para Nitro Aniline 180 Drying loss Thionylchloride 135 Niclosamide BP Chloro Salicyclic Acid 175 TOTAL OXO-O-TOLYL ACETONITRILE Manufacturing Process Charge Xylene to the reactor then charge orthotoulic acid. Add thionyl chloride at 15 C with controlled temperature. To this solution sodium cyanide and water is added at room temperature. Then stirred for 8 hours and separated. Then xylene is recovered and reused and a finished product is packed in drums. Reaction Chemistry OH OH C=O C=O CH3 + 2SOCl2 + 2NaOH CH3 + NaCl + H2O + NaHSO OH C=O CH3 + NaCN CN C=O CH3 + NaCl Form-1 for Environmental Clearance Page

24 Process Flow chart Xylene O Toluic acid Thionylchloride 700 Kg 275 Kg 225 Kg Reactor Sodium Cyanide 100 Kg Water 700 Kg Stirring and Separation Xylene (Recovered & reused in next batch) 500 Kg Wastewater 500 Kg Drying & distillation loss 550 Process waste 100 Kg Distillation residue 50 kg Final Product 300 kgs. Mass Balance SR. INPUT OUTPUT BATCH NO. BATCH 1. Water 700 Waste Water Xylene (Recovered+ 700 Xylene (Recovery) 500 Fresh) 3. Ortho toluic acid 275 Drying & distillation 550 loss 4. Thionyl chloride 225 Distillation residue Sodium cyanide 100 Process waste 100 OXO-O- Tolyl 300 Acetonitrile TOTAL NITRO 3, 5 DIMETHYL PYRIDINE : Manufacturing Process Charge Acetic acid and 3,5 lutidine.this mixture is stir for 1 hr. After this in prepared solution hydrogen peroxide is added. Then acetic acid is recovered. This is unloaded into drums. Sulphuric acid and Nitric acid mixture is prepared. In the same nitrating mixture above N-oxide mixture is added between the temperature 65 C.This is then stir for 3 hrs. Then slowly water is added at room temperature.after maintaining is to be neutralized by ammonia gas. This is then centrifuged and dry. Reaction Chemistry H3C H3C N CH3 Acetic Acid H2O2 H3C H3C N O CH3 H2SO4 HNO3 H3C H3C NO2 N O CH3 Form-1 for Environmental Clearance Page

25 Process Flow chart 3, 5 Lutidine 400 Kg Acetic acid 380 Kg Hydrogen Peroxide 280 Kg Sulphuric Acid 654 Kg Nitric acid 436 Kg Ammonia gas 387 Kg Water 1150 lit Reactor Reactor Mixing Acetic Acid Recovery Water 200 Lit Centrifuge 1350 Kg wastewater Dried & Packing 416 Kg 1821 Kg wastewater Mass Balance SR. NO. INPUT BATCH OUTPUT BATCH Aqueous layer (wastewater to ETP) ,5 lutidine Sulphuric acid 654 Acetic Acid recovery Acetic Acid 380 Emission and Drying Loss Nitro 3,5 Dimethyl Nitric acid 436 Pyridine Ammonia gas Hydrogen Peroxide Water 1350 TOTAL DICHLORO PYRIMIDINE Manufacturing Process In a glassline reactor Di hydroxy pyrimidine is dissolved in phosphorous oxychlori de and MDC as a solvent. This mixture is treated with tri ethyl amine.the above mixture is maintained at 40 C for 6 hrs. This is then chilled to 10 C, then water is added slowly. Then the mixture is stir for 1 hr. Then layer is separated, organic layer is taken for MDC recovery and final product is packed in drums. Aqueous layer contains TEA, which is recovered by treating with caustic flakes. Form-1 for Environmental Clearance Page

26 Reaction Chemistry HO N OH + 2POCl3 + 8 NaOH N Cl Cl N N + 2Na2PO4 + 8H2O + 4NaCl * * * 58.5 Process Flow chart Phosphorous Oxichloride 400 kgs Di Hydroxy Pyrimidine 225 kgs MDC 1218 kgs Reactor Water 1000 kgs TEA 72 kgs Reactor MDC Layer 1840 kgs Aqueous Layer TEA 1075 kgs MDC Distillation Pack 215 kg MDC Recovery 1000 Distilation loss 400 Distillation residue 225 Caustic 312 kg Aqueous effluent 925 kg Mother liquor + TEA 462kg Mass Balance SR. NO. INPUT BATCH OUTPUT BATCH 1. Di hydroxyl Pyridimine 225 Aqueous Effluent MDC 1218 MDC Recovery Phosphorous 400 Mother liquor + TEA 462 Oxychloride (To be recycled innext batch) 4. TEA 72 Dichloro Pyridimine Caustic 312 Distillation Loss Water 1000 Distillation residue 75 TOTAL Form-1 for Environmental Clearance Page

27 15. 2-AMINO 5-METHYL THIOZOLE Manufacturing Process In a glassline reactor sulphuric chloride is charged.it is chilled to 20 C then propenaldehyde is added in 5 hours. Then addition of 265 lit of Methanol in to solution. For adjusting ph there is addition of caustic for 10 ph. Then two layers separated aqueous layer send to ETP and organic layer treated with thiourea and HCL mixture. This is then reflux for 3 hour. Then cooled and adjust ph to 9 by dilute caustic solution. It is then centrifuge and dry. Reaction Chemistry CH3CH2CHO + 2SO2Cl2 + CH3OH + 5NaOH CH3CHClCOOCH3 + 2NaHSO3 + 3NaCl * * * * * 18 S N CH3CHClCOOCH3 + H2N-C-NH2 + 2NaOH + 2NaCl + NaOOH3 + H2N S CH * * * Form-1 for Environmental Clearance Page

28 Process Flow chart WATER 200 LITS Propenaldehyde 120 kgs Sulphuryl chloride 300 kgs Methenol 265 kgs Caustic 85 kgs lits water Reactor SEPARATION 400 lits Aqueous Layer Caustic 50 kgs lits water Toluene 300 kgs HCl 20 kgs Thiourea 100 kgs Reactor CENTRIFUGE DRYER 190 lits Aqueous Layer Drying Loss 1070 Product 100 Kg Mass Balance SR. INPUT OUTPUT BATCH NO. BATCH 1. Propenaldehyde 120 Aqueous layer Effluent Sulphuryl Chloride 300 Emission and Drying 1070 Loss 3. Methanol Caustic Toluene Thiourea HCL Water amino 5 methyl 100 thiozole TOTAL Form-1 for Environmental Clearance Page

29 16. ALLYAL ISOTHIOCYANATE ( ALLYAL MUSTARD OIL) Manufacturing Process Charge water and ammonium thiocynate in reactor with continuous stirring. Stir for 4 hours at maintained temperature between 10 C to 15 C. add slowly Allyl chloride within 1 hour. Then reflux for 4 hours at 45 C to 50 C. cool to room temperature and then stop stirring and separation for 3 hours. Separate two layers. Upper layer is product (crude) and lower layer is wastewater. Take crude product in glass distillation unit and start distillation under vaccum. Distilled out pure allyl isothiocynate. Reaction Chemistry CH 2 =CHCH 2 Cl + NH 4 SCN CH 2 =CHCH 2 NCS + NH4Cl Allyl Chloride Ammonium Allyl Iso Ammoinium Thiocyanate thiocynate Chloride (76.5) + (76.0) ( 99 ) + (54) Process Flow chart Ammonium Thiocyanate 206 kg Water 386 kg Allyl Chloride 205 kg Condensation Separation Ammonium Thiocyanate 2 kgs Ammonium Chloride 148 kgs Wastewater 387 kgs Crude Allyl Thiocyanate Distillation Distillation residue 10 kgs Final Product Mass Balance SR. INPUT BATCH OUTPUT BATCH NO. 1. Allyl Chloride 205 Allyl Iso Thiocyanate Ammonium 206 Ammonium chloride 148 Thiocyanate 3. Water 386 Ammonium 2 Thiocyanate (To be reused in next batch) Wastewater (To be 387 treated in ETP) Distillation residue 10 TOTAL Form-1 for Environmental Clearance Page

30 Sr. No. 1 Description ETP Sludge & Evaporation Residue ANNEXURE-4 Details of Hazardous Waste Management Category Quantity (MT/Annum) Used / Spent Oil Management Collection, storage and disposal at approved TSDF Site Collection, storage and used within premises as a lubricant / sold to registered recycler. Discarded bags/ drums/ Collection, storage & sell containers to authorized vendor 4 Distillation residue Collection, storage and disposal at approved 5 Process waste CHWIF Site Form-1 for Environmental Clearance Page

31 ANNEXURE-5 Details of Wastewater Treatment Systems Industrial Wastewater: Waste water having Ammonical Nitrogen content (about 300 liters/day having Ammonical Nitrogen mg/l) will be collected separately and given Ammonia stripping. Ammonia water will be recycled in process. Wastewater after Ammonical nitrogen removal and other Industrial wastewater generated from manufacturing process and washing activities will be collected in Collection tank. Then this wastewater will be given chemical treatment. Then it will be then pumped to filter press from where the sludge separated will be sent to TSDF site. The filtrate separated from the filter press will be then collected in intermediate holding tank. Boiler & Cooling Tower blow-down and R.O & DM reject will be added in this holding tank. Reverse osmosis will be provided to this water and will be reused in cooling tower, washing and gardening purpose Reject from this R.O will be evaporated in evaporator. Name of the units Volume (m 3 ) No. of Unit Collection tank and stripper system Capacity 500 liters/day 1 set Collection cum Neutralization Tank 10 1 Chemical (Fenton) Treatment Tank 10 1 Filter Press 2 m 3 /hr 1 Intermediate Water Collection Tank 20 1 Evaporator followed by Condenser 1 m 3 /hr 1 Treated Water Storage Tank 20 1 ETP Flow Diagram: High Ammonical Nitrogen effluent Ammonia Stripper (0.5 KL) Wastewate r from Process and Collection Tank (10 KL) Chemical Treatment (10KL) Filter Press (2m 3 /Hr) blowdown and reject Intermediat e Holding Tank (20 KL) Evaporato r and condenser Holding Tank for Reuse (20 KL) Pump Sludge and evaporation residue to Form-1 for Environmental Clearance Page

32 Stream-wise Quality of Effluent: Particular Unit Process Washing Composite Effluent (Before Treatment) After Chemical Treatment & Sludge Removal Quantity KL/day ph Total Suspended Solids mg/l Total Dissolved Solids mg/l Chemical Oxygen Demand mg/l Particular Unit Process & washing effluent after chemical treatment Cooling & Boiler blow down RO & DM Reject Composite Effluent After evaporation (Condensate water) Quantity KL/day ph TSS mg/l <10 TDS mg/l <500 COD mg/l <100 Form-1 for Environmental Clearance Page

33 ANNEXURE-6 Water balance diagram Source of Water Supply: Open well Total: 30 KL/day Industrial 26.5 KL/day Domestic 1.5 KL/day 2 KL/day To Septic Tank & Soak pit 1.3 KL/day 4.5 KL/day Scrubbing 0.5 KL/day Scrubbed Ammonia to be Recycled Cooling 20 KL/day 0.8 KL/day 0.5 KL/day Washing 0.5 KL/day Boiler 2.5 KL/day RO Plant 21 KL/day Permeate 9.5 KL/day Process KL/day KL/day 9 KL/day DM Plant 7 KL/day Reject 1 KL/day Reject 11.5 KL/day 6 KL/day Reject 5.5 KL/day Greenbelt Development 8 KL/day 15.5 KL/day Effluent Treatment Plant followed by Evaporator and condenser system 17 KL/day ZERO DISCHARGE Sludge to TSDF Form-1 for Environmental Clearance Page

34 ANNEXURE-7 Details of Flue Gas Stacks Sr. No. 1 Stack attached to Steam Boiler (1 TPH) 2 D.G. set (150 KVA) Stack Height (m) Fuel Requirement 30 Coal /Briquettes 2 MT/Day 6.5 HSD 30 L/Hr Expected Pollutant SPM 150 mg/nm 3 SO ppm NO X 50 ppm APC System Dust collector followed by Bag Filter and adequate stack height Adequate stack height Details of Process Gas Stacks Sr. No. Stack attached to Stack Height (m) 1 Dryer 12 2 Reactor 12 Fuel Requirement Coal /Briquettes 2 MT/Day HSD 30 L/Hr Expected Pollutant PM 150 mg/nm 3 NH mg/nm 3 APC System Cyclone Separator Water Scrubber [Scrubbed water (Ammonia water) will be reused in process] Form-1 for Environmental Clearance Page

35 ANNEXURE-8 List of Products & By-products Sr. No. Name of Product Quantity (MT/Month) 1 Diethyl Safranine 5 2 Safranine-O 5 3 Janus Green B 5 4 Methylene Blue Zn Free 5 5 Titan Yellow 5 6 Succinimide 5 7 N-Bromo Succinimide 2 8 N-Chloro Succinimide 2 9 Bromohexine HCL(BP) 2 10 Bronopol 2 11 Niclosamide 4 12 Oxo-O-Tolyl Acetonitrile Nitro 3,5 Dimethyl Pyridine 7 14 Dichloro Pyrimidine Amino 5 Methyl Thiozole 2 16 Oil Mustard 1 By-product 1 Zn Carbonate Sodium Bromide Sodium Bromide Solution Sodium Acetate Ammonium Chloride 0.6 List of raw materials Sr. No. Name of the product 1 Diethyl Safranine 2 Safranine - O Name of Raw Materials Quantity in KG/Month Diethyl Aniline 4445 HCL 2223 Sodium Nitrite 1600 Zn Dust 1556 Calcium Carbonate 2223 Aniline 2223 Sodium Dichromate 1778 Salt 6667 Garnet GB 3572 HCl 1786 Sodium Nitrite 1286 Fe Dust 1608 ICE 7143 Calcium Carbonate 715 Form-1 for Environmental Clearance Page

36 Sr. No. Name of the product 3 Janus Green B 4 METHYLENE BLUE ZN FREE 5 Titan yellow 6 Succinimide 7 N bromo succinimide 8 N CHLORO SUCCINIMIDE 9 Bromohexine HCL (BP) 10 Bronopol 11 Niclosamide Name of Raw Materials Quantity in KG/Month Aniline 1786 Sodium Dichromate 1072 Salt 5000 Safranine 5000 HCl 2500 Sodium Nitrite 1750 Sodium Acetate 1750 Dimethyl Aniline 2500 Soda Ash 1500 Salt 5000 Methylene Blue 2B 6250 Soda Ash 1000 EDTA 313 ICE Salt 625 Dehydro Thio Para Toludine Sulphonic Acid 5264 HCl 1579 Sodium Nitrite 922 ICE 5264 Sodium Carbonate 2106 Salt 7895 Succinic acid 5960 Ammonia 860 Succinimide 1116 Caustic 449 Bromine 1794 Succinimide 1480 Sodium hypochloride 1100 Acetic acid 900 2Nitro N Cyclohexyl Methyl Benzyl Amine 1600 Hydrogen 11 Methanol 5334 Carbon 27 Bromine 1734 HCl 240 Ethanol 3734 Nitro Methane 667 Methanol (Fresh) 500 Caustic 467 Formaldehyde 1467 Carbon 34 Bromine 1767 Xylene Ortho Chloro para nitro aniliine 2058 Form-1 for Environmental Clearance Page

37 Sr. No. Name of the product 12 Oxo-O-Tolyl Acetonitrile 13 4 Nitro 3,5 Dimethyl Pyridine 14 Dichloro pyrimidine 15 2 amino 5 methyl thiozole 16 Oil Mustard Name of Raw Materials Quantity in KG/Month Thiohyl chloride Chloro salicylic acid 2000 Xylene (Fresh) 3334 Ortho toluic acid 4584 Thionyl chloride 3750 Sodium cyanide ,5 lutidine 6731 Sulphuric acid Acetic acid (Fresh) 1347 Nitric acid 7337 Ammonia Gas 6512 Hydrogen Peroxide 4712 Di hydroxyl Pyridimine 5233 MDC (Fresh) 5070 Phosphorus Oxochloride 9303 TEA (Fresh) 1675 Caustic 7256 Propenaldehyde 2400 Sulphuryl Chloride 6000 Methanol 5300 Caustic 2700 Toluene 6000 Thiourea 2000 HCL 400 Allyl Chloride 820 Ammonium Thiocyanate 824 Form-1 for Environmental Clearance Page