Version: Hauptstr , Aichstetten, Germany. Tel./Fax.: Tel , Fax

Transcription

1 Revised edition: Version: Identification of the Substance/Mixture and of the Company/Undertaking Product Identifier Page 1 Product Name: Chromite Article No.: Relevant identified Uses of the Substance or Mixture and Uses advised against Identified uses: Used in surface refinement for ceramic products Uses advised against: Details of the Supplier of the Safety Data Sheet (Producer/Importer) Company: Address: Kremer Pigmente GmbH & Co. KG Hauptstr , Aichstetten, Germany Tel./Fax.: Tel , Fax Internet: info@kremer-pigmente.de Importer: -- Emergency No. Emergency No.: (Mon-Fri 8:00-17:00) Hazards Identification Classification of the Substance or Mixture Classification according to EC Regulation 1272/2008 Classification according to EC Regulation No. 67/548 or No. 1999/45 This product does not require classification and labelling as hazardous according to CLP/GHS. The material is not subject to classification according to EC lists. Safety Phrases: Possible Environmental Effects: Label Elements Classification according to EC Regulation 1272/2008 Hazard designation: No classification required according to the CLP/GHS guidelines. Not applicable. Signal word: Hazard designation: Safety designation: Hazardous components for labelling: Other Hazards Composition/Information on Ingredients 2

2 Substance Mixture Page 2 Chemical Characterization: Chromite. CAS No , EINECS Cr2O3: ca %, Fe2O3: ca %, Al2O3 + MgO + SiO2: ca % Hazardous Ingredients: Additional information: First Aid Measures Description of the First Aid Measures General information: After inhalation: After skin contact: After eye contact: Remove contaminated clothes immediately. Supply fresh air. Wash with soap and rinse with plenty of water. Rinse open eyes with plenty of water for at least 15 minutes. Seek medical attention if irritation persists After ingestion: Most important Symptoms and Effects, both Acute and Delayed Rinse mouth with water and drink plenty of water. If symptoms persist consult physician. Symptoms: No further information available Effects: Indication of any Immediate Medical Attention and special Treatment needed Treatment: Fire-Fighting Measures Extinguishing Media Suitable extinguishing media: No further information available. Product itself does not burn. Use extinguishing media for surrounding fire Unsuitable extinguishing media: Special Hazards arising from the Substance or Mixture None known. Special hazards: Advice for Firefighters 3

3 Protective equipment: Wear suitable protective clothing. Page Further information: Accidential Release Measures Personal Precautions, Protective Equipment and Emergency Procedures Avoid contamination of sewage system, open water ways and ground water Personal precautions: Environmental Precautions Avoid formation of dust, wear protective clothing. Ensure adequate ventilation Environmental precautions: Methods and Material for Containment and Cleaning Up Prevent contamination of soils, drains and surface water Methods and material: Reference to other Sections Handling and Storage Precautions for Safe Handling Instructions on safe handling: Take up mechanically and collect in suitable containers for disposal. Avoid dust formation. For information for safe handling see Section 7. Protective clothing, see Section 8. Provide adequate ventilation. Avoid formation and deposition of dust. Provide adequate ventilation Hygienic measures: Conditions for Safe Storage, including any Incompatibilities Do not eat or drink during work. Do not smoke. Do not inhale dust. Wash hands before breaks and at the end of work. Storage conditions: Store in tightly sealed containers in a dry room. Requirements for storage areas and containers: Information on fire and explosion protection: Storage class (VCI): 13; Non combustible solids Further Information: Specific End Use(s) Further information: No further information available. 4

4 Page Exposure Controls/Personal Protection Parameters to be Controlled Parameters to be controlled (DE): TRGS 900 TLV: 1.25 mg/m3 air-borne fraction (general dust limit) TLV: 10 mg/m3 inhalable fraction (general dust limit) Peak limit Category: 2 (II) Parameters to be controlled (EC): Derived No-Effect Level (DNEL): Predicted No-Effect Concentration (PNEC): Additional Information: Exposure Controls Technical protective measures: Provide adequate ventilation. Personal Protection General protective measures: Respiratory protection: Hand protection: Protective glove material: Eye protection: Do not inhale dust. Do not eat, drink or smoke while working. Wash hands before breaks and at the end of work. Dust mask recommended when very dusty (with particle filter P1/P2/P3; EN 143). Protective gloves (EN 374) Nitrile rubber Safety glasses with protective shields (EN 166). Body protection: Environmental precautions: Physical and Chemical Properties Information on Basic Physical and Chemical Properties Prevent from getting into the soil, surface water and sewage system. Form: Color: Odor: Odor threshold: powder dark gray odorless ph-value:

5 Melting temperature: 1000 C (1013 hpa) Page 5 Boiling temperature: Flash point: Evaporation rate: Flammability (solid, gas): Upper explosion limit: Lower explosion limit: Vapor pressure: not available no information available no information available Vapor density: Density: Solubility in water: Coefficient of variation (n- Octanol/Water): Auto-ignition temperature: Decomposition temperature: Viscosity, dynamic: Explosive properties: Oxidizing properties: 4.5 g/cm3 (20 C) insoluble not oxidizing Bulk density: Further Information Solubility in solvents: Viscosity, kinematic Burning class: Solvent content: Solid content: Particle size: 6

6 Other information: 10. Stability and Reactivity Reactivity Stable if used according to specifications Chemical Stability The product is stable Possibility of Hazardous Reactions None if used according to specifications Conditions to Avoid Page Conditions to avoid: Thermal decomposition: Imcompatible Materials Hazardous Decomposition Products Further Information Toxicological Information Information on Toxicological Effects Acute Toxicity LD50, oral: LD50, dermal: LC50, inhalation: Primary effects Irritant effect on skin: Irritant effect on eyes: Inhalation: Ingestion: Sensitization: Mutagenicity: No information available No information available Reproductive toxicity: 7

7 Cancerogenity: Page Teratogenicity: Specific target organ toxicity (STOT): Additional toxicological information: Ecological Information Aquatic Toxicity Fish toxicity: Daphnia toxicity: Bacteria toxicity: Algae toxicity: Persistency and Degradability Bioaccumulation Mobility Results of PBT- und vpvp Assessment Other Adverse Effects Water hazard class: Behaviour in sewage systems: Further ecological effects: AOX Value: Disposal Considerations Waste Treatment Methods Product: European Waste Code (EWC): Uncleaned packaging: No toxicity expected. Not classified as PBT substance / Not classified as a vpvb substance. Not hazardous. No special effects or hazards known. Dispose of according to official national and local regulations. Dispose of according to official local regulations. Waste Code No.: 8

8 Page Transport Information UN Number ADR, IMDG, IATA UN Proper Shipping Name ADR/RID: IMDG/IATA: No hazardous goods according to ADR (land transportation). No hazardous goods according to IMDG Transport Hazard Classes ADR Class: Hazard no.: Classification code: Tunnel no.: IMDG Class (sea): Hazard no.: EmS No.: IATA Class: Hazard no.: Packaging Group ADR/RID: IMDG: IATA: Environmental Hazards Special Precautions for User None Transportation in Bulk according to Annex II of MARPOL 73/78 and IBC-Code Further Information Regulatory Information Not classified as a dangerous good under transport regulations Safety, Health and Environmental Regulations/Legislation specific for the Substance or Mixture Water hazard class: 0, not hazardous Local regulations on chemical accidents: Employment restrictions: The employment restrictions for expectant and nursing mothers in 9

9 Restriction and prohibition of application: Page 9 accordance with the Maternity Protection Guideline (94/85/EEC) are to be observed. The employment restrictions for young workers in accordance with the Youth Employment Protection Law (94/33/EC) are to be observed Technical instructions on air quality: Chemical Safety Assessment Further Information Other Information : % (classification III) A Chemical Safety Assessment has not been carried out for this product. This product should be stored, handled and used in accordance with good hygiene practices and in conformity with any legal regulations. This information contained herein is based on the present state of knowledge and is intended to describe our product from the point of view of safety requirements. It should be therefore not be construed as guaranteeing specific properties.